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This paper deals with the introduction of necessary conditions for anionic homopolymerization of different polar monomers [alkyl(methyl)methacrylates], such as initiators,solvents,ligands as well as reaction temperatures;besides,some block copolymers synthesized from mentioned polar monomers with styrene and butadiene are also introduced, respectively. 相似文献
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This paper deals with the introduction of necessary conditions for anionic homopolymerization of different polar monomers [alkyl(methyl)methacrylates], such as initiators,solvents,ligands as well as reaction temperatures;besides,some block copolymers synthesized from mentioned polar monomers with styrene and butadiene are also introduced, respectively. 相似文献
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The anionic graft polymerization of lauryl methacrylate on the potassium alkoxide derivative of starch was studied. The yield of graft polymer increased with increasing alkoxide concentration. With increasing monomer concentration and with increasing temperature, the extent of homopolymer formation increased. The composition of the graft polymers depends on the reaction conditions; graft polymers having about 30–65% polylauryl methacrylate were obtained. 相似文献
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光引发合成阴离子聚丙烯酰胺及其应用 总被引:1,自引:0,他引:1
以丙烯酸钠(NaAA)、丙烯酰胺(AM)为单体,在光引发剂作用下,通过水溶液共聚法合成阴离子型聚丙烯酰胺(APAM)。采取单因素优化实验,研究了单体配比、单体质量分数、引发剂用量、光照时间、p H值等因素的影响,探究最优合成条件,以合成特性粘数高、絮凝性能好的产品为控制指标。得到最优制备条件:摩尔比为n(AM)∶n(NaAA)=1∶0.35,单体质量分数为32%,引发剂用量为0.04%,光照时间2h,p H为6.5时,APAM特性粘数最高,为1213m L/g。通过IR表征,产品与APAM特征基团相符合。絮凝实验表明,其具有良好的絮凝效果。 相似文献
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Summary: The dicationic [(dppp)Pd(NCCH3)2](BF4)2 catalyst (dppp = 1,3‐bis(diphenylphosphino)propane) was applied in a liquid monomer, two phase process for the CO/propene copolymerization reaction. For the first time it was possible to synthesize propene/CO copolymers with an activity up to 7 500 g/(mol · h) and molecular weights of 500 000 g/mol. Activities up to 40 000 g/(mol · h) could be obtained with the use of the unsymmetric catalyst [(CF3‐dppp)Pd(NCCH3)](BF4)2 (CF3‐dppp = 1‐diphenylphosphino‐3‐bis[3,5‐di(trifluormethyl)phenyl]phosphinopropane) in homogeneous liquid propene solution.
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David H. Richards 《Polymer International》1980,12(3):89-94
The paper considers three areas of current interest in anionic polymerisation. Firstly, the factors governing the efficiencies of initiation of anionic electron transfer catalysts are discussed, and the differences between the initiation mechanism of this class of catalysts and that of alkali metals are highlighted. Secondly, the problems relating to the synthesis of telechelic polydienes of high 1,4 content by an anionic technique are examined in relation to the contradictory claims of recent authors. Finally an account is given of the present position in developing transformation reactions to prepare novel block copolymers. 相似文献
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The kinetic study of the anionic polymerization of isoprens is carried out in tetrahy-drofuran(THF), using n-BuLi as initiator. Kinetic parameters are obtained, which comprise chain propagation rate constant, kp, and partial rate constants, k3 and k4 k5, propagstion orders with respect to monomer and active species concentration, α and β, real activation energy, E, as well as partial activation energies, E3 and E4 5 and so on. The relationship between the microstruc-ture of polyisoprene and the ratio of [THF]/[n-BuLi] has been investigated. On the basis of the studies mentioned above, a resonable mechanism of the anionic polynerization of isoprene is THF is proposed. 相似文献
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Yuichi Nakahara Mai Furusawa Yuta Endo Toshiya Shimazaki Keita Ohtsuka Yusuke Takahashi Yiyuan Jiang Aiichiro Nagaki 《化学工程与技术》2019,42(10):2154-2163
A continuous‐flow reaction system was developed, allowing flow conditions of the entire system to be maintained at a predetermined constant level, which is one of the most significant factors for successful industrial application. Controlled/living anionic polymerization was selected as a model reaction since the characteristics of its polymer products, molecular weights, and molecular weight distributions are highly susceptible to changes in the relative flow rates of a monomer and initiator solutions. In flow microreactors, controlled/living anionic polymerization of styrene in tetrahydrofuran (THF)/hexane initiated by THF‐diluted n‐butyllithium (n‐BuLi) was examined. Poly(styrenes) of larger molecule sizes such as Mn > 15 000 were successfully synthesized. After continuous operation for four hours, ca. 0.5 kg of the polymer was readily produced with narrow molecular weight distribution, demonstrating the applicability of this continuous‐flow system for controlled/living anionic polymerization on considerably large scale with a view to its industrial usage in the future. 相似文献
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采用HDI脲二酮接枝端羟基聚丁二烯液体橡胶(HTPB),再用己内酰胺封端异氰酸酯基团,制得橡胶改性剂,通过阴离子聚合制得液体橡胶改性尼龙(PA)6树脂。分析表明,HDI脲二酮接枝到HTPB的羟基上后被己内酰胺成功封端,进而阴离子聚合生成橡胶改性PA6共聚物。冲击断面分析,当橡胶质量分数高于15%以后,改性PA6树脂表现出明显的韧性断裂,脆断后甲苯刻蚀表明,随着橡胶活化剂含量增加,未参与聚合橡胶含量增加,导致橡胶微相尺寸变大且均匀性下降。在180℃条件下,聚合生成橡胶改性PA6树脂表现为α晶型,橡胶的加入并没有改变PA6的晶型;树脂熔融再速冷结晶后,PA6以亚稳定γ晶型为主,随着橡胶含量的增加,α晶型明显增强,说明橡胶相的存在有助于形成较稳定的α晶型。 相似文献
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