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BaTiO_3半导体陶瓷广泛用做PTC热敏电阻和晶界层电容器。BaTiO_3半导体陶瓷是多晶材料,其性能不仅决定于化学组成,而且与其显微结构有着密切关系。BaTiO_3半导体陶瓷的电阻正温度系数效应(PTC效应)最先由W.Heywang提出的晶界势垒模型进行了解释。随后,又有一些作者对Heywang提出的晶界势垒模型进行了修正。为了能从直接的实验数据验证势垒模型,很多人研究了BaTiO_3PTC陶瓷的显微结构。这些有关BaTiO_3陶瓷显微结构 相似文献
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PTC热敏电阻的开发应用现状 总被引:9,自引:0,他引:9
介绍了正温度系数(PTC)效应,PTC材料的分类、发展历史及现状,分析其电阻温度、电压电流和电流时间三大特性,通过对PTC材料三大特性的研究概述了陶瓷基PTC热敏电阻作为恒温加热元件和自动开关元件,高分子基PTC热敏电阻作为自控温加热元件和过电流保护元件等领域的应用状况及产业化发展情况,展望了今后PTC材料及生产工艺的技术发展动向。 相似文献
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叙述了电阻温度系数为9%(±0.2%)的缓变型BaCO_3-TiO_2高精度PTC陶瓷的原理和研制过程,并就其选料、配方、预处理、成型、烧结、测试等工艺过程进行了详细的论述,有助于对高精度BaCO_3-TiO_2PTC陶瓷进一步研究。 相似文献
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本文利用相变扩张理论分析了粒界缓冲型展宽效应对BaTiO_3系PTC陶瓷的介电系数及温度系数a_r的影响,指出了晶粒尺寸和温度系数的关系。 相似文献
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PTC陶瓷材料制备与应用 总被引:1,自引:0,他引:1
描述了PTC效应及其原理,并从粉体制备、掺杂物的选择与加入和烧成制度各方面介绍了高性能PTC陶瓷研究方面的一些工艺新进展,进而从理论上探讨了获得高性能PTC陶瓷材料的途径。 相似文献
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ONACCURACYOFANALYSISOFOFHYDROGEN1前言我公司目前应用的氢气纯度分析方法有两种,一种是爆炸反应法,另一种是焦性没食子酸吸收法。几年来,人们对两种分析方法的准确性曾有过褒贬不一的评论。这里我们也谈谈自己粗浅的观点。2爆炸法测定氢气纯度一定量的氢气样品与适量的空气之均匀混合物因反应后生成液体水而引起气体体积减少,减少的体积等于参加反应气体体积之和。其中l/3为氧气,2/3为氢气。根据氢气取样量和反应前后混气体体积之差,以及氢气在反应中的体积比例关系,可计算出样品的氢气纯度。计算公式式中:A一混… 相似文献
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P. P. Budnikoff 《Journal of the American Ceramic Society》1924,7(11):817-820
The different analytical methods proposed for the evaluation of gypsum have been subjected to an experimental test. A combination method, consisting of a fusion with KHCO3 and determination of CaO by KMnO4 titration, the SO3 by Andrews method of titration of BaCrO4 has been found to give very reliable results with the least consumption of time. 相似文献
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A model is developed for the sedimentation from a suspension of two particle species of unequal densities and of different sizes. The composition and the thickness of various layers in the sediments are predicted using graphical and analytical methods. The model predictions were in excellent agreement with experimental results, when the particle size ratio was ≥ 108. When size ratio of the particles was 2.60 and 4.31 the agreement occurred in about 50 percent of the cases. 相似文献
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A novel technique serves to monitor instantaneous rates of loss of a volatile solute from a suspended drop during drying. A highly sensitive electron capture detector is used to monitor concentrations of SF6 released into a flowing gas stream from a suspended, drying drop. Simultaneously, the appearance and morphological development of the drop are monitored with a video camera. This provides the wherewithal of relating instantaneous rates of loss of the volatile solute to particular events during the development of particle morphology.
Initial experiments have been carried out with drops of aqueous solutions of glucose, sucrose, maltodextrin and coffee extract. The results clearly display the onset of the volatiles-retentive selective diffusion phenomenon. There is also substantial loss of the volatile component later in the drying process, when the drops undergo repeated ex ansion, bursting and cratering due to the formation of internaf bubbles. These experiments appear to be the first quantitative demonstration of major losses accompanying changes in drop morphology. 相似文献
Initial experiments have been carried out with drops of aqueous solutions of glucose, sucrose, maltodextrin and coffee extract. The results clearly display the onset of the volatiles-retentive selective diffusion phenomenon. There is also substantial loss of the volatile component later in the drying process, when the drops undergo repeated ex ansion, bursting and cratering due to the formation of internaf bubbles. These experiments appear to be the first quantitative demonstration of major losses accompanying changes in drop morphology. 相似文献
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ANALYSIS OF RECENT MEASUREMENTS OF THE VISCOSITY OF GLASSES 总被引:5,自引:0,他引:5
Viscosity of Simple Soda-Silicate 500° to 1400°C Comparison of the results given by English with those of Washburn, Shelton and Libman, indicates a discrepancy in the absolute values of log10 viscosity amounting to 0.6, those of Washburn et al., being relatively too high. If correction for this is made, the isothermal curves of log10 viscosity as a function of soda content are smooth up to 50% Na2O, showing no inflection. The observations as a function of temperature T are all represented within accidental error by an equation of the type where all three constants vary regularly with the composition. Change of Viscosity of Glass (6SiO2, 2Na2O) due to Molecular Substitution of CaO, MgO and Al2O3 for Na2O The effect is clearly brought out by plotting (from the results of English) the change of log10η due to the substitution as a function of temperature. The curves each show a sharp bend at a temperature between 840° and 1050°C, which is designated the aggregation temperature Ta. If we divide these curves by the corresponding percentage substituted, we get curves for each oxide which are straight and parallel below the aggregation temperatures, the slopes (increase of change of log10η per 100°C) being −0.056 (CaO), −0.055 (MgO), −0.018 (A12O3) per per cent oxide substituted. For substitution of 1/2 molecule the slopes are −0.325 (CaO), −0.23 (MgO) and −0.18 (Al2O3) per 100°. At the aggregation temperature the change of log10η per per cent is a minimum, 0.03 to 0.06 for CaO, 0.12 for MgO, 0.07 for Al2O3. Evidence of Aggregation in Glasses, from viscosity Measurements The sharp bends in the plots of change of log10η due to substitution of an oxide for Na2O, suggest the beginning of molecular aggregation at these temperatures. These aggregation temperatures are close to the devitrification temperatures, but the effect on the viscosity curves cannot be due to actual devitrification since it does not change with time. Taking the aggregation temperatures as equal to devitrification temperatures, additional isotherms are roughly sketched into the equilibrium triangle of the system Na2O-CaO-SiO2. Change of Viscosity of Glass (4SiO2, 2Na2O) due to of Substitution of B2O3 for SiO2 The change of log10η (from the results of English) is plotted as a function of temperature, and also the change of log10η per per cent B2O3. The curves are more complex than for the substitution for Na2O. 相似文献
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面对日益激烈的市场竞争,摩托车油箱外观质量越来越成为影响销售的因素之一。文章介绍了改进工艺后的油箱涂装,该涂装体系提高了油箱外观的丰满度,降低了油箱涂装的生产成本。 相似文献