三套管式相变蓄热器分形肋片设计及(火积)耗散分析

通过数值模拟的方法,根据分形原理设计了三套管式相变蓄热器的肋片并分析其蓄、放热特性,运用(火积)耗散原理对其蓄、放热过程进行分析。结果表明:相比其他结构的相变蓄热器,安装分形肋片的相变蓄热器可使蓄、放热时间缩短,效率提高;模型2(T形分形模型)和模型3(Y形分形模型)比模型1(直肋模型)的蓄热时间分别缩短了35.64%和33%,放热时间分别缩短了47.65%和43.4%;模型2和模型3相比模型5(2倍填充直肋模型)所需蓄、放热时间基本接近,说明分形设计只需较低的金属填充量便可达到很好的蓄、放热效果;安装分形肋片的相变蓄热器在蓄、放热过程中(火积)耗散率(或其绝对值)下降更快,可逆性更好,换热效率更高。     

基于■理论的多级套管式相变蓄热系统优化

基于最小■耗散热阻原理,在考虑相变材料导热热阻以及非稳态传热过程的基础上,对多级套管式相变蓄热系统的融化温度进行了数值优化,获得了最优融化温度分布。在此基础上,研究了相变材料导热系数和传热管长度对最优融化温度、■耗散热阻和平均蓄热速率的影响。研究结果表明:与现有理论优化方法相比,提出的数值优化方法具有更好的适用性;优化后多级套管式相变蓄热系统可有效提高相变蓄热系统的平均蓄热速率,降低■耗散热阻;随着相变材料导热系数增大和传热管长度增加,多级套管式相变蓄热系统最优融化温度的温差愈加明显,其强化传热性能呈上升趋势。     

组合式相变材料蓄热系统中相变温度分布研究

建立了组合式相变材料蓄热系统物理模型，在忽略显热的假设条件下研究了相变温度呈线性分布的组合式相变材料蓄热系统传热特性，得出了最优线性相变温度分布，并采用考虑显热的数值计算（有限差分法）证实了理论分析得出的最优相变温度与实际相变温度分布几乎相同。     

火电厂换热器火积耗散分析

基于描述热量传递能力的物理量——火积,定义了评价换热器传热性能的火积耗散原理.同时,推出了换热器火积耗散的公式,并且通过代人数据计算,得出了火电厂各级加热器的火积耗散,并进行分析,对优化换热器的性能有一定的指导作用.     

水平及竖直放置套管式相变蓄热单元传热特性的数值模拟

以赤藻糖醇为相变材料,采用Fluent软件对同心套管式相变蓄热单元的熔化和凝固过程进行了三维非稳态数值研究。在考虑自然对流的前提下,对比了水平入射式、顶部入射式及底部入射式相变蓄热单元的传热特性,得到了固液界面分布图和温度云图随时间的变化特性,对比了各自的蓄放热速率。研究表明:自然对流在熔化过程中起主要作用,而在凝固过程中起的作用很小;蓄热速率从大到小排列,依次是水平入射式、顶部入射式和底部入射式,相比于底部入射式,水平入射式的总熔化时间可减少27.2%,而顶部入射式的总熔化时间仅减少3.7%;放热速率从大到小排列,依次是顶部入射式、水平入射式和底部入射式,相比于底部入射式,顶部入射式的总凝固时间可减少9.2%,而水平入射式的总凝固时间仅减少0.6%;水平入射式蓄热单元是满足蓄放热速率快这一要求的首选型式。     

基于火积理论的螺旋折流板换热器的优化结构分析

为了比较平面螺旋折流板换热器和折面螺旋折流板换热器的传热和阻力性能,应用了换热器常用评价标准PEC准则和火积理论对两种换热器实验结果进行了分析,同时采用火积耗散极值原理对两种换热器的传热火积耗散率、阻力火积耗散率以及总火积耗散率进行了对比。结果表明:火积耗散理论分析换热器性能的结果与传统换热器评价标准PEC准则相符,说明了火积耗散理论的可靠性;折面螺旋折流板换热器的综合性能得到了有效的改进,火积耗散率也均优于原始结构,表明折面螺旋折流板换热器的性能得到较大改善;两种换热器传热火积耗散率值要远远大于阻力火积耗散率,约为阻力火积耗散率的一千余倍,说明传热损失为换热器的主要不可逆损失。     

太阳能蓄热墙相变蓄热材料的研究进展

综述了国内外关于太阳能蓄热墙相变材料的研究进展.其中包括太阳能相变材料的分类,物理、化学性质等.目前对于一些相变材料缺陷的改进方法,及相变材料在墙体中的应用.     

圆柱形等距螺旋盘管式相变蓄热装置蓄热性能研究

文章设计了一种以石蜡为相变材料的圆柱形等距螺旋盘管式相变蓄热装置,并通过实验分析了该装置的传热特性,以及传热流体入口温度、入口流量对石蜡的融化特性、相变蓄热装置的蓄热量及相变蓄热系统总传热系数的影响。分析结果表明:融化后期,石蜡的融化速率会明显加快;当传热流体入口温度一定时,随着入口流量逐渐增大,蓄热装置的最终显热蓄热量略微升高;与传热流体入口流量相比,传热流体入口温度对石蜡融化速率影响较大;相变阶段,石蜡的传热性能较强,传热流体入口温度越高,石蜡的传热性能越不稳定。     

含相变材料的壁板的潜热蓄热试验

含相变材料的壁板具有潜热蓄热能力。本文研究安装含相变材料的壁板的房间做了蓄热试验，并将试验结果与安装普通壁板的主心间进行了比较。     

高温相变蓄热的研究进展

从如下两个方面总结了高温相变蓄热的研究现状：①在高温相变材料(PCM)方面，重点介绍了高温相变材料的一些重要性能及其测量，高温相变材料的封装，高温复合相变材料及高温相变材料的应用；②在传热分析方面，主要介绍了相变过程的数值模拟和相变蓄热系统(LTES)的热力学优化。     

Application of entransy dissipation theory in heat convection

In the present work, formulas for calculating the rates of the local thermodynamic entransy dissipation in convective heat transfer in general, and the internal and external flows in particular, are established. Practically, these results may facilitate the application of entransy dissipation theory in thermal engineering. Theoretically they shed light on solving the contradiction of the minimum entropy production principle with balance equations in continuum mechanics.     

Development of graphite foam infiltrated with MgCl2 for a latent heat based thermal energy storage (LHTES) system

Thermal energy storage (TES) systems that are compatible with high temperature power cycles for concentrating solar power (CSP) require high temperature media for transporting and storing thermal energy. To that end, TES systems have been proposed based on the latent heat of fusion of the phase change materials (PCMs). However, PCMs have relatively low thermal conductivities. In this paper, use of high-thermal-conductivity graphite foam infiltrated with a PCM (MgCl₂) has been investigated as a potential TES system. Graphite foams with two porosities were infiltrated with MgCl₂. The infiltrated composites were evaluated for density, heat of fusion, melting/freezing temperatures, and thermal diffusivities. Estimated thermal conductivities of MgCl₂/graphite foam composites were significantly higher than those of MgCl₂ alone over the measured temperature range. Furthermore, heat of fusion, melting/freezing temperatures, and densities showed comparable values to those of pure MgCl₂. Results of this study indicate that MgCl₂/graphite foam composites show promise as storage media for a latent heat thermal energy storage system for CSP applications.     

Analytical solution of heat transfer in a shell-and-tube latent thermal energy storage system

An analytical solution of a latent heat storage unit (LHSU) consisting of a shell-and tube was obtained by using the Exponential Integral Function and the variables separation technique. The working fluid (water) circulating by forced convection inside the inner tube charges and discharges the storage unit. The comparison between analytical predictions and experimental data shows good agreement. Extensive parametric studies were conducted in order to examine the effect of the pertinent parameters (such as natural convection, mass flow rate of HTF, outer tube radius, pipe length etc.) on the melting and solidification processes of paraffin as a PCM. In order to provide guidelines for system performance and design optimisation, unsteady temperature distributions within PCM during melting/solidification, energy stored, position of moving interface and thermal efficiency have been obtained by a series of numerical calculations and represented graphically.     

基于恒截面流道矩形单元体的积耗散率最小传质构形优化

以质量积耗散率最小为优化目标,对恒截面高渗透率通道的矩形单元体传质构形问题进行了分析和优化,得到结构体内平均传质效果最好的结构外形。结果表明:对于单元体和各级构造体,其平均传质压差均为最大传质压差的2/3。因为高渗透率材料中质流率密度符合线性分布,所以基于积耗散率最小与最大压差最小的最优构形完全一致。所得最优构形同时使得传质能力和传质安全性最好。     

Optimization simulation of tube-type phase change heat storage unit

列管式换热器具有结构牢固、传热面积大、材料使用适应性强等优点,是相变储热领域应用较为广泛的一种换热器。但由于大部分相变材料热导率偏低,导致换热器的换热性能较差,因此提高相变储热器的储热效率,是目前国内外研究的热点。本工作对列管式相变储热单元进行了二维非稳态模拟优化,研究了换热器结构、翅片数目及中心距3种参数对储热性能的影响,并探讨了熔化过程中相变材料的温度和液相率变化趋势。研究结果表明,与圆形换热器结构相比,正方形换热器储热性能更优;相比于无翅片的储热换热器,添加翅片后储热性能得到显著提升,相变材料熔化时间缩短66%;对中心距而言,在一定范围内,随中心距减小进出口降压增大,但储热性能相应提高。     

Experimental study on the thermal storage performance and preparation of paraffin mixtures used in the phase change wall

In this paper, several admixtures including n-heptadecane, n-octadecane, n-eicosane, 46^# paraffin, 48^# paraffin and liquid paraffin are prepared with different mixed proportion, aiming for appropriate phase change materials used in the building envelope. The phase change temperatures and phase change latent heats of several kinds of paraffin mixtures were studied experimentally by differential scanning calorimeter (DSC). The experimental results showed that the phase change temperatures and latent heats of paraffin mixtures change with their composition. Paraffin mixtures in different mass proportions have a wider phase change temperature range and higher phase change latent heat. So the paraffin mixtures can be used in the different thermal storage fields by adjusting the mixed proportion. Several paraffin mixtures with appropriate phase change temperatures and higher phase change latent heats were given, and they can be used in the building wall to storage thermal. The results in this paper can provide references and basis for the application of phase change material in the wall.     

Second law analysis of a diesel engine waste heat recovery with a combined sensible and latent heat storage system

The exhaust gas from an internal combustion engine carries away about 30% of the heat of combustion. The energy available in the exit stream of many energy conversion devices goes as waste. The major technical constraint that prevents successful implementation of waste heat recovery is due to intermittent and time mismatched demand for and availability of energy. The present work deals with the use of exergy as an efficient tool to measure the quantity and quality of energy extracted from a diesel engine and stored in a combined sensible and latent heat storage system. This analysis is utilized to identify the sources of losses in useful energy within the components of the system considered, and provides a more realistic and meaningful assessment than the conventional energy analysis. The energy and exergy balance for the overall system is quantified and illustrated using energy and exergy flow diagrams. In order to study the discharge process in a thermal storage system, an illustrative example with two different cases is considered and analyzed, to quantify the destruction of exergy associated with the discharging process. The need for promoting exergy analysis through policy decision in the context of energy and environment crisis is also emphasized.     

An experimental and numerical investigation of heat transfer during technical grade paraffin melting and solidification in a shell-and-tube latent thermal energy storage unit

The latent thermal energy storage system of the shell-and-tube type during charging and discharging has been analysed in this paper. An experimental and numerical investigation of transient forced convective heat transfer between the heat transfer fluid (HTF) with moderate Prandtl numbers and the tube wall, heat conduction through the wall and solid–liquid phase change of the phase change material (PCM), based on the enthalpy formulation, has been presented. A fully implicit two-dimensional control volume Fortran computer code, with algorithm for non-isothermal phase transition, has been developed for the solution of the corresponding mathematical model. The comparison between numerical predictions and experimental data shows good agreement for both paraffin non-isothermal melting and isothermal solidification. In order to provide guidelines for system performance and design optimisation, unsteady temperature distributions of the HTF, tube wall and the PCM have been obtained by a series of numerical calculations for various HTF working conditions and various geometric parameters, and the thermal behaviour of the latent thermal energy storage unit during charging and discharging has been simulated.     

Phase change behaviour of some latent heat storage media based on calcium chloride hexahydrate

Phase change behaviour of pure and some chemically modified calcium chloride hexahydrate materials suggested in the literature as suitable heat storage media was studied in storage systems with a low degree of mixing in order to evaluate their long-term reversibility. The influence of gravitation on the phase change properties of the pure system was elaborated by determining local salt concentrations in the liquid phase and changes in the volume of the system during repeated melting and crystallization, whereby the amounts of the different phases being present could be assessed. It was found that thermo gravitational effects are of minor importance in generating salt concentration gradients in the liquid phase when compared to the concentration gradients resulting from the sedimentation of the formed tetrahydrate and the hexahydrate during the phase change reactions. Due to these effects it was not possible to prevent irreversible tetrahydrate formation and deterioration in heat storage capability by adding a surplus of water to the hexahydrate materials, if seeds for the tetrahydrate were present during repeated melting and crystallization. Upon addition of SrCl₂ · 6H₂O a solid solution of the two hexahydrates is formed and as a result the formation of the tetrahydrate is suppressed. Due to irreversible formation of SrCl₂ · 2H₂O a state of true congruent melting seems, however, not possible to reach. Phase segregation effects also in this case lead to irreversible calcium chloride tetrahydrate formation if seeds for the latter are added during repeated melting and crystallization. If Ca(OH)₂ is also added, the tetrahydrate formation can be further suppressed. But, even in this case, irreversible tetrahydrate formation can not be prevented if the composition of the liquid phase corresponds to the hexahydrate. On addition of 5 wt% KCl or 5 wt% KCl + 2 wt% SrCl₂ · 6H₂O or 5 wt% KCl + 0.4 wt% NaCl, repeated melting and crystallization in the presence of seeds of the tetrahydrate can, however, be carried out without irreversible formation of the latter occurs. In the heat storage system CaCl₂ · 6H₂O + 5 wt% KCl, formation of tetrahydrate is observed but its rate of dissolution is found considerably faster than in the pure hexahydrate system. It was concluded that with those modified calcium chloride hexahydrate systems reversible phase change cycling can be performed and therefore there is for example no the need for thickener agents to be added to avoid irreversible tetrahydrate formation successively reducing heat storage capability of systems in those cases.     

基于火积耗散热阻的新型板式省煤器传热分析

建立了新型板式省煤器的传热模型,计算了新型板式省煤器的火积耗散热阻以及空气侧压降,分析了新型板式省煤器结构参数及空气流速变化时,火积耗散热阻及空气侧压降的变化情况。研究结果表明:增大长轴可以减小火积耗散热阻,有利于提高板式省煤器的传热性能,并且空气侧压降变化幅度不大;增大短轴可以减小火积耗散热阻,有利于提高板式省煤器的传热性能,但空气侧压降增大;减小板束间距可以减小火积耗散热阻,有利于提高板式省煤器的传热性能,但空气侧压降增大,尤其是在板束间距小于20 mm时,继续减小板束间距会造成空气侧压降急剧增大;增大空气进口流速可以减小火积耗散热阻,有利于提高板式省煤器的传热性能,但空气侧压降增大,对换热器的磨损也会增加。