Ca对快速凝固Mg-6Zn合金薄带组织与性能的影响

采用双辊快速凝固技术制备了Mg-6Zn-xCa合金薄带,通过金相显微镜、扫描电镜、X射线衍射仪、差示扫描量热分析仪及显微硬度计研究了薄带的组织与性能特征。结果表明,不仅快速凝固显著细化晶粒和第二相,Ca也有助于合金微观组织的进一步细化;快速凝固Mg-6Zn合金的组织由过饱和固溶体a-Mg、Mg51Zn20,以及少量的Mg2Zn3和MgZn2组成。随着Ca的加入,Mg2Ca、Ca2Mg6Zn3和MgZn2相逐渐增多,而Mg2Zn3和Mg51Zn20却有所减少,因此,Ca的添加有助于提高快速凝固Mg-6Zn合金的热稳定性。     

ZL108合金的快速凝固微观组织研究

对采用单辊旋转淬冷法制备的ZL108合金进行了差示扫描量热分析(DSC)、X射线衍射分析(XRD)和透射电镜分析(TEM).试验结果表明,在快速凝固合金的衍射谱中,只有Al的衍射峰出现,且具有比常规合金小的晶格常数.在DSC分析的热流温度曲线上,合金开始熔化之前,快速凝固合金比常规合金多一个明显的放热峰.通过TEM分析得到,快速凝固ZL108合金具有无发达枝晶的亚共晶组织,由微米尺寸的晶粒和共晶区组成,共晶区中的Si颗粒达到了纳米尺寸.说明在快速凝固ZL108合金中,Si等合金元素已基本溶入Al的固溶体中,造成了溶解极限的增大和共晶点右移.     

添加Zr对快速凝固CuCr29合金液相分解微观组织的影响

使用限速熔体快淬技术研究了添加Zr对CuCr29合金液相分解微观组织的影响。研究结果表明，添加Zr可以有效地抑制快速凝固CuCr29合金的液相分解行为。当Zr元素的添加量大于1．0at％，快速凝固CuCr29合金的液相分解微观组织明显地得到细化。EDS分析和微观组织观察都表明，添加Zr元素后，在合金组织中只存在着富Cu基体和富Cr相，Zr元素以固溶形式影响着CuCr合金的凝固行为。由热力学分析可知，在CuCr29合金中添加Zr会降低过冷CuCr液体的混合自由能和液相分解的驱动力，从而增加液／固转变临界过冷度，使临界形核半径减小和形核速度增加，则快速凝固CuCr29合金的液相分解微观组织得到细化。     

凝固组织和Mg含量对A356合金快速热处理的影响

研究了凝固组织和Mg含量对A356合金快速热处理的影响。结果表明,A356合金经过Sr变质后,其凝固组织中的共晶Si形貌由纤维状变成球状,初生α相的晶粒尺寸减小。经过540℃×20 min+170℃×90 min快速热处理,合金微观组织中的Mg₂Si强化相能够充分固溶到基体中,其抗拉强度与T6态的基本相同。随着合金中Mg含量增加,固溶处理时,Mg₂Si相充分固溶进基体所需要的时间增加。当合金中Mg含量由0.3%增加到0.9%时,则需要经过540℃×40 min+170℃×90 min快速热处理,其力学性能与T6态的基本相同。     

冷却速度与Ce含量对快速凝固Al—Ce二元合金组织的影响

考察了冷却速度和成分对快速凝固Al—Ce二元合金组织的影响,结果表明,在相同冷却速度下,Ce含量少利于形成粒状弥散相;而成分一定时,提高冷却速度易于析出弥散度高的球形粒子。     

快速凝固Al—Li—Mg—Zr合金粉末粒度对组织和性能影响

研究超音雾化快速凝固Al—Li—Mg—Zr合金粉末粒度对组织和性能的影响中发现,粉末粒度越细,组织越细,合金强度越大;但粒度太细,又会导致塑性变差。试验合金粒度范围选用40—100μm为佳。     

Y对常规凝固Mg-Zn-Y合金组织和性能的影响

采用常规凝固技术制备了Mg-45Zn-xY(x=1.0,4.0,5.5,8.0,质量分数,%)合金。利用SEM、EDS、OM、TEM、XRD、DSC和硬度测试技术研究了Y对Mg-45Zn-xY系合金组织及性能的影响,同时对准晶相(I-phase)的形成机制进行了分析。结果表明:合金组织主要由α-Mg颗粒或枝晶、花瓣状的Mg3Zn6Y准晶相、层片状的(I-phase+α-Mg)共晶组织以及Mg7Zn3相组成;准晶相形貌、含量及分布与Y含量密切相关,随着Y含量的增加,花瓣状准晶相含量逐渐增加,当Y含量为5.5%时,花瓣状准晶相含量最多,合金的硬度达到最大值,HB为1557 MPa,当Y含量为8.0%时,合金中的花瓣状准晶相消失;准晶以层片状共晶组织和花瓣状形式存在,花瓣状的特殊形貌是正二十面体沿五次轴方向生长的结果。     

Ag-Cu-Sn三元合金钎料的快速凝固组织与性能

采用熔体急冷法制备出Ag<,42.47>Cu<,57.53-x>Sn<,x>(x=12.23,12.94,13.65,质量分数,%)急冷钎料箔材,分析了钎料的相组成、组织形态、电阻率和力学性能.结果表明,急冷钎料由(Ag),α-Cu及少量Cu<,13.7>Sn相组成.随着锡含量的增加,凝固组织显著细化,晶界增多,溶质截...     

快速凝固Al—8.32Fe—3.4Ce合金的热稳定性和组织结构的关系

研究了快速凝固Ａｌ－８．３２Ｆｅ－３．４Ｃｅ高温铝合金在不同温度长时间热暴露后的室温力学性能和相析出。实验结果表明Ａｌ－８．３２Ｆｅ３．４Ｃｅ一直到３１５℃有较好的热稳定性，热稳定性和相析出及相长大有密切关系。不同热暴露后得到物析出相分别为Ａｌ１３Ｆｅ４，ＡｌｍＦｅ，Ａｌ８Ｃｅ，Ａｌ１３Ｆｅ３Ｃｅ和Ａｌ１６Ｃｅ３Ｆｅ等等。其中Ａｌ８Ｃｅ和Ａｌ１３Ｆｅ３Ｃｅ在文献中未见报道。     

Mg-Y-LPC合金组织和凝固行为的研究

制备了1种稀土镁合金Mg-5.1Y-3.3LPC,并对其微观组织和凝固行为进行了研究。结果表明:稀土元素镧镨铈(LPC)主要富集在晶界处,且形成的稀土化合物沿晶界呈网状分布;而钇(Y)既存在于晶界上,又分布于镁基体内。     

Microstructures and properties of rapidly solidified Mg-Zn-Ca alloys

Ternary alloys based on the Mg-Zn-Ca system were produced by twin-roll rapid solidification.The alloys were characterized by OM,SEM,HRTEM,XRD,EDS and Micro-hardness.The results show that the rapidly solidified flakes are of fine dendritic cell structures with the cell size ranging from 1 to 5μm.The Mg-6Zn-5Ca alloy in RS and annealing(200℃for 1 h) states are mainly composed ofα-Mg,Mg_2Ca,Ca_2Mg_6Zn_3 and a small quantity of Mg_(51)Zn_(20),MgZn_2 and Mg_2Zn_3.Micro-hardness increases with the increment of...     

Morphology and microstructure of rapidly solidified tin-lead alloy powders

Sn60Pb40 al oy powders were fabricated using the planar flow casting （PFC） atomization process. By using OM, SEM and EPMA, the characteristics of the morphologies and microstructures of the powders have been investigated. It is observed that the environment of ambient gas in the atomization box has great effects on the morphology of the al oy powders. The microstructures of Sn60Pb40 al oy powders produced by the PFC atomization process are completely composed of eutectic, which is made up of both oversaturated αsolid solution and β solid solution. The microstructures of smal size powders are extraordinarily undeveloped dendritic eutectic, in which the large majority of the α phase appears nearly spherical, evidently since the cooling rate is higher and the under-cooling is larger. As for the large size powders, since the cooling rate and undercooling are relatively low, lamel ar α phase apparently increases in the eutectic microstructures of these powders, and there is even typical lamellar eutectic structure clearly observed in some micro-areas. After remelting tests by DTA, the microstructures of smal size powders are transformed, which become composed of large crumby α phase and eutectic （α＋β）, while those of large size powders change into classical tin-lead structures of primary α phase plus lamellar eutectic （α＋β）. By studying the microstructures of tin-lead alloy powders, a model has been proposed to predict the microstructure formation of Sn60Pb40 al oy powders.     

Microstructures of rapidly solidified Al-In immiscible alloy

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深冷处理时间对快凝过共晶Al-Si-Fe合金组织与性能的影响

在固溶时效的基础上研究了深冷处理时间对过共晶Al-Si-Fe合金组织与性能的影响。结果表明,随着深冷时间的延长,组织变化不大,合金的力学性能得到了很大的提高;最佳的处理工艺为固溶处理(520℃×3 h)+深冷处理(-196℃×48 h)+时效处理(120℃×10 h)。     

生物医用Mg-3Zn-0.2Ca合金显微组织与性能研究

生物医用Mg-3Zn-0.2Ca合金的显微组织,力学性能,腐蚀行为通过光学显微镜,扫描电镜,力学测试以及模拟体液浸泡手段进行了研究。X射线衍射结果表明该合金的主要第二相为Mg7Zn3, Mg2Zn3, 和Mg4Zn7的金属间化合物相。经过56:1挤压比后的挤压态Mg-3Zn-0.2Ca合金的晶粒尺寸平均为2.5um,相比铸态的119.1um下降了47.6倍。屈服强度,抗拉强度以及延伸率分别为205MPa, 336MPa 和17.85%。挤压态合金的耐蚀性也明显优于铸态合金,其原因主要为晶粒细化。本文设计的新型生物医用Mg-3Zn-0.2Ca合金呈现出良好的综合力学性能以及耐蚀性。     

Microstructure and thermal stability behavior of a rapidly solidified Al—Ti—Fe—Cr alloy

A rapidly solidified Al-2.5Ti-2.5Fe-2.5Cr(mass fraction in%) alloy was prepared by melt spinning.Asquenched and as-annealed microstructures were studied by X-ray diffractometry(XRD),transmission electron microseopy(TEM),high-resolution transmission electron microscopy(HREM) and energy dispersive spersive spectrum(EDS) analysis,The microhardness of the alloy at different annealing temperatures was measured.The results obtained indicate that the microhardness of the rapidly solidified Al-2.5Ti-2.5Fe-2.5Cr alloy does not vary with differnet annealing temperatures.The as-quenched microstructure of the alloy includes two kinds of dispersed primary phases:Al3Ti and Al13(Cr,Fe)2,After annealing at 400℃ for 10h,the stable phase Al13Fe4 appears in the microstructure.     

添加合金元素对改善快速凝固铝锂合金性能的作用

通过研制Al 2 .5Li,Al 2 5Li 0 2Zr,Al 2 5Li 1 2Mg 0 2Zr,Al 2 5Li 1 6Cu 1 2Mg 0 2Zr4种成分的快速凝固铝锂合金 ,研究了逐步添加合金元素Zr,Mg ,Cu对合金力学性能的影响。结果表明 :在快速凝固铝锂合金中逐步加入少量合金元素Zr,Mg ,Cu后 ,合金强度逐步增加 ,而延伸率无明显变化 ,这有助于强化合金基体和阻碍合金基体的剪切型断裂 ,有助于改善合金的综合力学性能 ,其中Al 2 5Li 1 6Cu 1 2Mg 0 2Zr合金综合力学性能最优 ,其密度、强度、塑性等都全面达到了国家高技术项目的技术指标。     

快速凝固镁合金开发原理及研究进展

介绍快速凝固镁合金材料研究与开发的物理冶金原理及发展历程。在开发原理中着重介绍快速凝固镁合金的镁基固溶体扩展、新型弥散合金相的形成、晶粒及显微组织细化以及合金钝化等基础理论。在这些研发理论基础上，进一步阐述镁合金雾化快凝、模冷淬火和表面重熔这3种典型的快速凝固制备技术，举例说明了这3种快速凝固技术制备的多种镁合金的各项性能及显微组织特征。综合评价快速凝固技术制备镁合金材料的优势，说明快速凝固技术是开发新型镁合金材料，扩展镁合金在工程材料中应用的重要且具有发展前途的制备技术。     

Energy-storage welding connection characteristics of rapidly solidified Cu-Co alloy foils

The connection characteristics of rapidly solidified Cu-40%Co alloy foils were studied using a self-developed micro-type energy-storage welding machine. The results show that the microstructure of the alloy foils is characterized by uniform and fine equiaxed grains, whose maximum grain size is 1.8μm. Under the optimum energy,the regular flat nugget is formed, low voltage and high capacitance are favorable for obtaining the perfect connection joints, whereas high voltage and low capacitance are likely to result in the surface burn of the alloy foils. With the increase of welding energy, the spot welding joint will be transformed from regular flat nugget to nugget-free one,and the microstructure tends to coarsen. The welding parameters recommended are, welding voltage 80 - 100 V,electric capacitance 1 800 - 2 500μF, and welding force 4 - 8 N.     

定向凝固多孔Mg-Zn合金的制备及气孔结构

采用Bridgman型定向凝固法制备出藕状多孔Mg-Zn合金.研究了不同锌含量和氢气压力对气孔形貌的影响.通过理论计算对Mg-1Zn(质量分数,％,下同)合金的孔隙率进行了预测.结果表明,锌元素的加入会对孔结构产生重大影响.随着Zn含量从0％增加到2％,平均孔径增加.随着氢气压力从0.1 MPa增加到0.6 MPa,M...