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1.
Z.A. Foroulis 《Wear》1984,96(2):203-218
The work presented in this report summarizes an evaluation of the relative sliding wear characteristics of several commonly used commercial hardfacing alloys. The alloys studied include cobalt-base, nickel-base and Fe-Cr-Ni alloys which also contain small amounts of cobalt. Selecting the most effective alloy combination to withstand sliding wear is a challenge for materials engineers, equipment designers and fabricators. Accurate guidelines for selecting compatible alloys from a wear resistance point of view are not available. On the basis of the results of this work several hardfacing alloy combinations were identified which provide good sliding wear resistance. In addition, several hardfacing alloy combinations were found to exhibit poor wear resistance compatibility. The guidelines presented in this report will aid in the selection of suitable hardfacing alloy combinations with adequate sliding wear resistance. The wear guidelines are also supplemented with corrosion data in several environments of importance in the chemical process industries. These data should assist in the selection and optimization of hardfacing alloys in the presence of aggressive environments.  相似文献   

2.
The β-Zn4Sb3, emerged as a compelling p-type thermoelectric material, is widely used in heat-electricity conversion in the 400-650 K range. In order to probe the effects of slight doping on the crystal structure and physical properties, we prepared the samples of Al-added Zn-Sb based alloys by spark plasma sintering and evaluated their microstructures and thermoelectric properties. After a limited Al addition into the Zn-Sb based alloys we observed many phases in the alloys, which include a major phase β-Zn4Sb3,intermetallic phases ZnSb and AISb. The major β-Zn4Sb3 phase plays a fundamental role in controlling the thermoelectric performance, the precipitated phases ZnSb and AISb are of great importance to tailor the transport properties, such as the gradual enhancement of lattice thermal conductivity, in spite of an increased phonon scattering in additional grain boundaries. The highest thermoelectric figure of merit of 0.55 is obtained for the alloy with a limited AI addition at 653 K, which is 0.08 higher than that of un-doped β-Zn4Sb3 at the corresponding temperature. Physical property experiments indicate that there is a potentiality for the improvement of thermoelectric properties if a proper elemental doping is carried out into the Zn-Sb based alloys, which was confirmed by AI addition in the present work.  相似文献   

3.
Ion beam thinning of aluminium–lithium alloys under conventional conditions required to produce electron microscope thin foils is shown to induce significant microstructural changes, equivalent to heating the specimen in excess of ~400 K.  相似文献   

4.
To determine long-range order parameters from electron diffraction intensities, the authors have developed a CCD camera system to detect precisely electron diffraction intensities, a method for quickly and precisely measuring specimen thickness, and a computer programming to calculate long-range order parameters from the ratio of superlattice and fundamental diffraction intensities. Thickness variation over a diffraction area is taken into consideration in the calculation of electron diffraction intensities on the basis of the multi-slice method, and long-range order parameters are calculated by the successive approximation method. The absorptive form factors are also calculated from experimental data of diffraction intensities by parameter fitting, and the effect of absorption on the calculation of long-range order parameters is examined. The values of Cu(3)Au alloys aged at 523 and 653 K that were obtained by averaging long-range order parameters determined for several diffraction areas with the developed method are close to the reported data obtained by the X-ray diffraction method. The main causes for the deviation of long-range order parameters determined for several diffraction areas are also discussed.  相似文献   

5.
The aim of this work was to assess the changes in the microstructure of hot‐deformed specimens made of alloys containing 46–50 at.% Al, 2 at.% Cr and 2 at.% Nb (and alloying additions such as carbon and boron) with the aid of scanning electron microscopy and transmission electron microscopy techniques. After homogenization and heat treatment performed in order to make diverse lamellae thickness, the specimens were compressed at 1000 °C. Transmission electron microscopy examinations of specimens after the compression test revealed the presence of heavily deformed areas with a high density of dislocation. Deformation twins were also observed. Dynamically recrystallized grains were revealed. For alloys no. 2 and no. 3, the recovery and recrystallization processes were more extensive than for alloy no. 1.  相似文献   

6.
The methods of speckle-interferometry, electron, optic, and atom-force microscopy were used to study the structure and regularities of deformation of surface layers on metals and alloys in friction. The causes of deformation localization are analyzed. An explanation of the strong wear resistance of Hadfield steel is proposed using data on the evolution of the surface layer structure.  相似文献   

7.
Two phase titanium alloys are important for high‐performance engineering components, such as aeroengine discs. The microstructures of these alloys are tailored during thermomechanical processing to precisely control phase fractions, morphology and crystallographic orientations. In bimodal two phase (α + β) Ti‐6Al‐2Sn‐4Zr‐2Mo (Ti‐6242) alloys there are often three microstructural lengthscales to consider: large (~10 μm) equiaxed primary α; >200 nm thick plate α with a basketweave morphology; and very fine scaled (<50 nm plate thickness) secondary α that grows between the larger α plates surrounded by retained β. In this work, we utilise high spatial resolution transmission Kikuchi diffraction (TKD, also known as transmission‐based electron backscatter diffraction, t‐EBSD) and scanning electron microscopy (SEM)‐based forward scattering electron imaging to resolve the structures and orientations of basketweave and secondary α in Ti‐6242. We analyse the α variants formed within one prior β grain, and test whether existing theories of habit planes of the phase transformation are upheld. Our analysis is important in understanding both the thermomechanical processing strategy of new bimodal two‐phase titanium alloys, as well as the ultimate performance of these alloys in complex loading regimes such as dwell fatigue. Our paper champions the significant increase in spatial resolution afforded using transmission techniques, combined with the ease of SEM‐based analysis using conventional electron backscatter diffraction (EBSD) systems and forescatter detector (FSD) imaging, to study the nanostructure of real‐world engineering alloys.  相似文献   

8.
Measurements are presented of the friction and wear during sliding of specimens of Nimonic 75, C263, Nimonic 108 and Incoloy 901 on like specimens in air nominally at room temperature. The worn specimens have been examined using microhardness measurements, optical and scanning electron microscopy, X-ray diffraction and electron diffraction. These techniques suggest mechanisms for the room-temperature wear of these alloys associated with their strength properties. In particular, changes in the coefficient of friction and the wear rate during sliding can be correlated with work hardening, and possibly some degree of age hardening, of the load-bearing areas, due to the severe mechanical and thermal stresses developed. There is no evidence that oxide films formed on the contact areas during sliding have a significant effect on the tribological behaviour of these alloys. Such films are merely removed from the surface as wear debris.  相似文献   

9.
It is generally assumed that amorphous magnetic alloys respond to field annealing by a process of local directional ordering which leaves the amorphous structure intact. We have made a comparative microstructural study of field-annealed Co95-xFe5(BSi)x amorphous alloys using transmission electron microscopy (TEM) and scanning transmission electron microscopy (STEM) with thin sections parallel to the ribbon surface. Field annealing response was measured from anisotropy in low-field hysteresis loops. These alloys show appreciable surface crystallization for annealing as much as 80 K below the bulk crystallization temperature. The surface crystallization proceeds by a known mechanism (selective oxidation) to which we have added a more detailed understanding. Three steps are involved: (1) formation of an amorphous borosilicate surface oxide layer during annealing; (2) depletion of glass stabilizing elements (boron and silicon) from the underlying amorphous metal substrate; (3) primary crystallization of the destabilized, metal-enriched subsurface layer to an fee or hep cobalt-rich phase. Striking differences in the microstructural morphology were revealed for different glass former ratios B/Si. For high B/Si ratios, the surface crystallites are predominantly fee Co and show a high density of oxygen faults. For low B/Si ratios, the surface crystallites are predominantly hep Co and almost free of faults. Response to field annealing is proportional to the B/Si ratio and correlates with the presence of oxygen faults in surface crystallites. Electron diffraction and microprobe analysis indicate that the surface oxide in silicon-rich alloys is a dense silica glass which appears to be an effective diffusion barrier to oxygen. The surface oxide in boron-rich alloys is a more porous oxide richer in B2O3. These observations appear to be related to those from perminvar alloys where oxygen was found to be necessary for field annealing to be effective.  相似文献   

10.
V.M. Desai  C.M. Rao  T.H. Kosel  N.F. Fiore 《Wear》1984,94(1):89-101
A study of the effect of carbide size on the abrasion resistance of two cobalt-base powder metallurgy alloys, alloys 6 and 19, was conducted using low stress abrasion with a relatively hard abrasive, A12O3. Specimens of each alloy were produced with different carbide sizes but with a constant carbide volume fraction. The wear test results show a monotonie decrease in wear rate with increasing carbide size.Scanning electron microscopy of the worn surfaces and of wear debris particles shows that the primary material removal mechanism is micromachining. Small carbides provide little resistance to micromachining because of the fact that many of them are contained entirely in the volume of micromachining chips. The large carbides must be directly cut by the abrasive particles. Other less frequently observed material removal mechanisms included direct carbide pull-out and the formation of large pits in fine carbide specimens. These processes are considered secondary in the present work, but they may have greater importance in wear by relatively soft abrasives which do not cut chips from the carbide phase of these alloys. Some indication of this is provided by limited studies using a relatively soft abrasive, rounded quartz.  相似文献   

11.
Nowadays, the implementation of sophisticated in situ electron microscopy tests is providing new insights in several areas. In this work, an in situ high‐temperature strain test into a scanning electron microscope was developed. This setup was used to study the grain boundary sliding mechanism and its effect on the ductility dip cracking. This methodology was applied to study the mechanical behaviour of Ni‐base filler metal alloys ERNiCrFe‐7 and ERNiCr‐3, which were evaluated between 700°C and 1000°C. The ductility dip cracking susceptibility (threshold strain; εmin) for both alloys was quantified. The εmin of ERNiCrFe‐7 and ERNiCr‐3 alloys were 7.5% and 16.5%, respectively, confirming a better resistance of ERNiCr‐3 to ductility dip cracking. Furthermore, two separate components of grain boundary sliding, pure sliding (Sp) and deformation sliding (Sd), were identified and quantified. A direct and quantitative link between grain boundary tortuosity, grain boundary sliding and ductility dip cracking resistance has been established for the ERNiCrFe‐7 and ERNiCr‐3 alloys.  相似文献   

12.
《Wear》2006,260(9-10):1028-1034
In many machining applications, adhesion of the workpiece to the tool is a major problem. Adhesion may be reduced by changing the microstructure of the tool steel, e.g. by increasing the carbide content. The present work deals with the influence of some microstructural parameters in the adhesive wear of tool steels. The investigations were conducted using six model alloys based on the powder metallurgy high speed steel AISI M4, all of which had the same martensitic matrix composition after heat treatment. The alloys had MC carbide contents which varied between 0 and 25 mol% in 5 mol% increments. Ball-on-disc experiments were carried out in ambient air at room temperature using austenitic stainless steel and aluminum balls as counterfaces. Wear tracks on the disks were characterized using both a scanning electron microscope and an optical profiler. The results show that two main parameters determine the adhesive wear behavior: the carbide content and the distance between carbides.  相似文献   

13.
Splat-quenched, as-cast and aged (2 h at 600 °C after casting) AlCoCrCuFeNi high entropy alloys were investigated by means of transmission electron microscopy and three-dimensional atom probe (3D-AP). 3D-AP revealed anti-correlated fluctuations of the Cr and Fe-Co compositions in Cr-Fe-Co-rich regions of the as-cast alloy. The ferromagnetic behavior of AlCoCrCuFeNi high entropy alloy was correlated with the decomposition of the Cr-Fe-Co-rich regions into ferromagnetic Fe-Co-rich and antiferromagnetic Cr-rich domains, the size of which was determined by statistical analysis of 3D-AP data. The splat-quenched alloy showed a softer magnetic behavior as compared to the as-cast and aged alloys. The aged alloy possessed a higher saturation magnetization and coercivity as compared to the as-cast alloy.  相似文献   

14.
In a Ti-20mass%Mo alloys aged by two steps aging at 623 and 823K, a new phase has been observed. In the first step aging, [Formula: see text] -phase crystals appear and at the second step aging, these crystals disappear and are replaced with the newly discovered phase crystals. Observations in the dark field image and analysis of composition of the new phase crystals have shown that the formation is closely related to the [Formula: see text] -phase structure. The new phase crystals have been also observed in four kinds of [Formula: see text] -type Ti alloys and a ( [Formula: see text] ) type Ti alloy aged at high elevated temperatures. Based on high-resolution electron microscope observations, the atomic structure of the new phase is assumed.  相似文献   

15.
K.-H.Zum Gahr 《Wear》1981,74(2):353-373
Decohesion of wear debris by abrasive particles was studied using polycrystalline pure metals and alloys. Wear debris were formed by steel riders with attack angles of 30°, 60° and 90° and also in the pin-on-disk test on commercial abrasive paper. Microstructural changes due to abrasion were investigated by transmission electron microscopy and X-ray diffraction examination of wear debris and worn surfaces. Simple models for the interaction between abrasive particles and material surfaces used to estimate friction and wear provided a better quantitative understanding of the influence of microstructural factors such as hardness, work hardening, crystal structure, anisotropy and phase transformation.  相似文献   

16.
The mechanical, magnetic, and thermal properties of water-quenched (from 1150°C) alloys, such as H36K10T3, H36K10X5T2, and H36K5T2, which were strengthened by aging (at 650°C) and high-temperature deformation (1100–800°C) followed by aging, are studied. The decomposition of a supersaturated solid solution in the Invar alloys under study was shown to increase the strength properties and coercive force but to decrease the plasticity and saturation magnetization. In this case, the aging ambiguously affects thermal expansion coefficient α of the different alloys; the temperature range of invariance decreases. The plastic deformation of Invars was found to increase the ultimate strength, yield strength, and coercive force. The additional aging of deformed materials increases the strength and decreases the plastic properties; among the magnetic parameters, the saturation magnetization exhibits the most adequate correlation with the mechanical properties. The thermal properties (the α coefficient and invariance range) resulting from the complex heat treatment differ slightly from those resulting from the single aging.  相似文献   

17.
Daniel P. Anderson 《Wear》1983,90(2):187-197
Recent work at the Foxboro Analytical ferrography laboratory on the recognition of non-ferrous metal particles, particles from lead-, tin- and Pb- Sn-based alloys, ferrous oxide particles and corrosive wear debris is described. An explanation of polarized light microscopy as it applies to ferrography is given. Ferrograms made from conductive substrates which can be used in a scanning electron microscope without requiring coating are discussed.  相似文献   

18.
The Al-Si-Mg alloy which can be strengthened by heat treatment is widely applied to the key components of aerospace and aeronautics. Iron-rich intermetallic compounds are well known to be strongly influential on mechanical properties in Al-Si-Mg alloys. But intermetallic compounds in cast Al-Si-Mg alloy intermetallics are often misidentified in previous metallurgical studies. It was described as many different compounds, such as AlFeSi, Al8Fe2Si, Al5(Fe, Mn)3Si2 and so on. For the purpose of solving this problem, the intermetallic compounds in cast Al-Si alloys containing 0.5% Mg were investigated in this study. The iron-rich compounds in Al-Si-Mg casting alloys were characterized by optical microscope(OM), scanning electron microscope(SEM), energy dispersive X-ray spectrometer(EDS), electron backscatter diffraction(EBSD) and X-ray powder diffraction(XRD). The electron backscatter diffraction patterns were used to assess the crystallographic characteristics of intermetallic compounds. The compound which contains Fe/Mg-rich particles with coarse morphologies was Al8FeMg3Si6 in the alloy by using EBSD. The compound belongs to hexagonal system, space group P2m, with the lattice parameter a=0.662 nm, c=0.792 nm. The β-phase is indexed as tetragonal Al3FeSi2, space group I4/mcm, a=0.607 nm and c=0.950 nm. The XRD data indicate that Al8FeMg3Si6 and Al3FeSi2 are present in the microstructure of Al-7Si-Mg alloy, which confirms the identification result of EBSD. The present study identified the iron-rich compound in Al-Si-Mg alloy, which provides a reliable method to identify the intermetallic compounds in short time in Al-Si-Mg alloy. Study results are helpful for identification of complex compounds in alloys.  相似文献   

19.
Measurements are presented of friction and wear during sliding of specimens of Ni-Cr alloys containing 0% to 40% Cr on like specimens in air at 20°, 400° and 800 °C. The worn specimens have been examined by optical and scanning electron microscopy, electron probe microanalysis and electron diffraction and microhardness measurements have been made.Under the sliding conditions used, all the alloys show a transition temperature above which a low coefficient of friction and usually relatively low wear are observed after a time and below which these parameters remain relatively high throughout. Above the transition temperatures, the frictiontime loci show sharp reproducible changes from relatively high to low coefficients of friction. Such changes can be associated with the formation of a thermally softened oxide layer (termed a glaze) on the bearing areas during sliding. Once the glaze is formed, very little further wear occurs for the high chromium-content alloys, although further damage does take place with the weaker low chromium-content alloys, especially at temperatures just above the transition temperature. These tribological properties of the glaze are associated with its low shear strength and the strength of the underlying alloy substrate.During sliding at temperatures below the transition temperatures, metal-to-metal contact takes place, although oxide is formed on the bearing area of the low chromium-content alloys even at 20 °C. The friction and wear behaviour is largely determined by the strength and work-hardenability of the alloy.Correlations between the tribological behaviour of these binary Ni-Cr alloys and commercial Nimonic alloys indicate that the trace elements in the latter play only a relatively minor role in determining this behaviour. It is concluded that high strengths and relatively rapid transient oxidation rates of the alloys, and appropriate physical properties of the resulting oxide films, are important qualities of the alloys under the conditions used.  相似文献   

20.
Huang JC 《Scanning》2012,34(5):325-331
High‐entropy alloys have been studied extensively for their excellent properties and performance, including outstanding strength and resistance to oxidation at high temperatures. This study employed molecular dynamics simulation to produce a high‐entropy alloy containing an equal molar ratio of Al, Co, Cr, Fe, and Ni and investigated the tribological behavior of the material using a diamond tool in a vacuum environment. We also simulated a AlCoCrFeNi high‐entropy alloy cooled from a high temperature molten state to 300 K in a high‐speed quenching process to produce an amorphous microstructure. In a simulation of nanoscratching, the cutting force–distance curve of high‐entropy alloys was used to evaluate work hardening and stick–slip. An increase in temperature was shown to reduce the scratching force and scratching resistance. Nanoscratching the high‐entropy alloy at elevated temperatures provided evidence of work hardening; however, the degree of work hardening decreased with an increase in temperature. And it can also be found that when the temperature is higher, the fluctuation of the cutting force curve is greater. SCANNING 34: 325–331, 2012. © 2012 Wiley Periodicals, Inc.  相似文献   

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