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高活性、高选择性催化剂是解决蒽醌法生产过氧化氢过程中瓶颈问题的根本途径。评述近年来新型蒽醌加氢用钯催化剂研究中载体改性、新型载体(包括高分子载体和纳米纤维状氧化铝载体)、助催化剂及新制备技术等方面的最新进展,指出通过载体改性可提高现有催化剂的活性和选择性,而助催化组分和新催化剂制备工艺应是今后蒽醌加氢催化剂研究的重点方向。 相似文献
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丁苯热塑橡胶SBS是由苯乙烯和丁二烯在锂系催化剂的作用下聚合而成的一种新型弹性体高分子材料,具有塑料和橡胶双重属性,被誉为“第三代橡胶”。因其在制鞋、塑料改性、沥青改性、防水卷材、粘合剂等方面具有独特的优异性能,在世界各国发展十分迅猛。 相似文献
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介绍了聚合金属酞菁的特性,因其具有大的共轭结构和较高的化学稳定性,和芳香环既有电子给体的特性、电子受体的特性,因此表现出良好的电催化氧还原活性;聚合金属酞菁作为催化剂,能使氧化反应在低温下高效进行,作为敏化剂,能有效提高光电转换效率.阐述了国内外聚合金属酞菁的研究方法和应用前景,提出了自由设计聚合金属酞菁分子结构,拓展... 相似文献
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新型茂金属催化剂使古老的聚烯烃领域重焕青春。本文主要介绍了茂金属在功能聚烯烃合成中的应用,包括共聚、使用阳离子型茂金属催化剂和活性聚合等方法。 相似文献
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《精细化工原料及中间体》2017,(10)
<正>本发明公开了一种大分子聚合酚改性聚双环戊二烯材料及其制备方法,该改性聚双环戊二烯材料是以双环戊二烯单体、主催化剂、助催化剂及大分子聚合酚为原料,通过反应注射成型工艺制成的;其中,所述双环戊二烯单体、主催化剂、助催化剂的摩 相似文献
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Polypropylene (PP) is one of the most promising thermoplastic polymer materials. However, the application of PP is restricted to coating and adhesion fields due to its high crystallinity, low surface energy and weak interfacial layer. This review introduces the modification approaches that can improve the coating or adhesion performance of PP, including the development of chemical oxidation and several novel methods of chemical modification, such as the grafting polymerization with high-energy inducement, organoborane initiator, reversible – addition – fragmentation – chain transfer and atom transfer radical polymerization. 相似文献
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The process of surface modification of hydrophobic organic (copper phthalocyanine (CuPc)) as well as hydrophilic inorganic pigments (titanium dioxide) in aqueous dispersions by employing tailor-made thermo-responsive copolymers and the colloidal stability have been studied as a function of temperature. The pigment surface modification is achieved by conventional adsorption and by thermoprecipitation of amphiphilic methyl vinyl ether (MVE) containing block and graft copolymers, exhibiting a lower critical solution temperature (LCST), with poly(isobutyl vinyl ether) blocks and poly(ethylene oxide) side chains, respectively. The effect of mechanical treatment of the pigment dispersion by ultrasonic power alone or in combination with the LCST property was investigated. The course of the pigment surface coating process was followed by the electrokinetic sonic amplitude (ESA) method. The temperature-controlled sorption of PMVE-g-PEO graft copolymers on both inorganic and organic pigment surfaces was investigated. It was found that ultrasonic treatment together with LCST thermoprecipitation is a promising method for the surface modification of pigments with regard to dispersion stability. 相似文献
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Shaohai Fu Changsen Du Mingjun Zhang Anli Tian Xia Zhang 《Progress in Organic Coatings》2012,73(2-3):149-154
Polymer-encapsulated phthalocyanine blue pigment dispersion was prepared with a polymerizable dispersant by emulsion polymerization method, and the effect of preparation conditions on the particle size of dispersion was investigated. Dynamic light scattering measurement demonstrated that allyloxy nonyl-phenoxypropanolpolyoxyethyleneetherammonium sulfonate (ANPS) was suitable for phthalocyanine blue pigment modification. The polymer-encapsulated phthalocyanine blue pigment dispersion with the small particles was obtained when the mass ratio of ANPS to phthalocyanine blue pigment, styrene (St) to phthalocyanine blue pigment, and ammonium persulfate (APS) to St was about 0.2, 0.2, and 0.01, respectively. Transmission electron microscopy (TEM), Fourier transforms infrared spectra (FTIR) and thermogravimetric analyses (TGA) provided supporting evidences for the encapsulation of phthalocyanine blue pigment with the formed copolymer. The polymer-encapsulated phthalocyanine blue pigment dispersion showed excellent stabilities to freeze–thaw treatment and centrifugal force. 相似文献
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The effects of surface modification of silicas by plasma‐polymerization coating, together with modification using a silane coupling agent for a comparison on the dispersion and physical properties of styrene–butadiene rubber (SBR) are reported. The chemical compositions of the plasma‐polymerization coating were characterized using FTIR and Auger spectrometer and it was found that the plasma coating was composed of C?C and C? H bonds. The surface modification of silica by either plasma polymerization or silane greatly improved the dispersion of silica particles in SBR vulcanizates. The plasma‐polymerization modification of silica improved the tensile modulus of SBR vulcanizates without deterioration of important basic properties such as tensile strength and elongation at break. © 2002 Society of Chemical Industry 相似文献
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合成了7种无毒的新型有机铋催化剂,采用核磁共振仪、质谱仪(MS)和红外光谱仪(FTIR)等对其进行表征,确认了其化学组成,并将其应用于聚氨酯涂膜材料制备,研究催化剂结构和添加量等对涂膜的固化时间、抗腐蚀性能和拉伸性能等的影响。结果表明,五价有机铋催化剂性能明显好于三价铋,0.3 %(质量分数,下同)的铋金属催化剂即可将聚氨酯涂膜的固化时间缩短至其四分之一,耐溶剂性能提高30 %,拉伸强度增加33 %,断裂伸长率降低35 %;铋分子中芳基的平面性对其活性影响很大,含有氧桥二苯结构配体的催化剂由于平面性好,显示出了较好的催化性能。 相似文献
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A novel manufacturing process for high performance metallic can coating was carried out based on an epoxy‐grafted acrylic resin. Firstly, the epoxy resin was reacted with acrylic amide forming a ring opened product epoxy‐amide resin, and then the product obtained copolymerized with all other monomers, such as acrylic acid (AA), butyl acrylate (BA), hydroxypropyl acrylate (HPA), 2‐ethylhexyl acrylate (2‐EHA), methyl methacrylate (MMA), styrene (St), using free radical solvent polymerization in the presence of BPO. The resins prepared present the transparent appearance, and the target resin coating based on these resins exhibits excellent boiling resistance and chemicals resistance and can be applied as the protective coating for metallic can. The effects on the coating properties, such as amount of acrylic acid, 2‐EHA wt % between 2‐EHA and BA, amount of amino resin, amount of catalyst, and so forth, were investigated. In addition, the influences of polymerization time on the conversion ratio of monomers were also studied. Results show that under the optimal conditions, the target resin coating provides excellent physical and mechanical properties. The various properties tests for this coating have been performed in accordance with the standards of ASTM. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
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彩色聚氨酯防水涂料的研制 总被引:5,自引:0,他引:5
介绍了一种双组分聚氨酯防水涂料,它是由聚醚多元醇、甲苯二异氰酸酯、芳香族二胺、填料、增塑剂、催化剂等为原料制成,不合煤焦油,气味小,符合环保要求。对合成聚氨酯防水涂料的原料选择进行了讨论,并论述了这种防水涂料的合成工艺及涂膜物性。 相似文献