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1.
To expand the application of electrospun fibers or electrosprayed beads, micro-nano hierarchical structures of polystyrene (PS) have been constructed through the adjustment of solvent, polymer concentration, environment humidity, electrospinning temperature, etc. Primary structures, such as fibers, beads and bead-on-string structure, as well as secondary structures, such as nanopores, nanopapilla and net-work structure, have been constructed. Solvent plays an important role in the construction of both primary structures and secondary structures. By using N,N-dimethylformamide (DMF), tetrahydrofuran (THF) and mixed solvent of DMF/THF, the micro-nano hierarchical structures can be controlled. Humidity is a key factor to the construction of secondary structures. The obtained fibers or beads have smooth surface at low humidity. While at high humidity, secondary structures tend to appear. For the PS/DMF system, vapor-induced phase separation may be the most pertinent mechanism to explain the formation of secondary structures. While for the PS/THF system, breath figure theory can explain the formation of uniform nanopores properly. 相似文献
2.
The electrospinning behavior of a block copolymer of trimethylene carbonate (TMC) and ε‐caprolactone dissolved in N,N‐dimethylformamide (DMF) and methylene chloride (MC) was studied. The effects of the blended solvent volume ratio, concentration, voltage, and tip–collector distance (TCD) on the morphology of the electrospun fibers were investigated by scanning electron microscopy. The results indicated that the diameter of the electrospun fibers decreased with a decreasing molar ratio of MC to DMF, but beads formed gradually. With a decreasing concentration of the solution, the fiber diameter decreased; at the same time, beads also appeared and changed from spindlelike to spherical. A higher voltage and larger TCD favored the formation of smaller diameter electrospun fibers. The results of differential scanning calorimetry and X‐ray diffraction showed that the crystallinity and melting point of the electrospun fibers decreased when increasing the TMC content in the copolymer. Compared with the corresponding films, the crystallinity and melting point of the electrospun fibers were obviously increased. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 1462–1470, 2006 相似文献
3.
Yakai FENG Fanru MENG Ruofang XIAO Haiyang ZHAO Jintang GUO 《Frontiers of Chemical Science and Engineering》2011,5(1):11
Polycarbonate urethane (PCU) nano-fibers were fabricated via electrospinning using N,N - dimethylformamide (DMF) and tetrahydrofuran (THF) as the mixed solvent. The effect of volume ratios of DMF and THF in the mixed solvent on the fiber structures was investigated. The results show that nano-fibers with a narrow diameter distribution and a few defects were obtained when mixed solvent with the appropriate volume ratio of DMF and THF as 1∶1. When the proportion of DMF was more than 75% in the mixed solvent, it was easy to form many beaded fibers. The applied voltage in the electrospinning process has a significant influence on the morphology of fibers. When the electric voltage was set between 22 and 32 kV, the average diameters of the fibers were found between 420 and 570 nm. Scanning electron microscopy (SEM) images showed that fiber diameter and structural morphology of the electrospun PCU membranes are a function of the polymer solution concentration. When the concentration of PCU solution was 6.0 wt-%, a beaded-fiber microstructure was obtained. With increasing the concentration of PCU solutions above 6.0 wt-%, beaded fiber decreased and finally disappeared. However, when the PCU concentration was over 14.0 wt-%, the average diameter of fibers became large, closed to 2 μm, because of the high solution viscosity. The average diameter of nanofibers increased linearly with increasing the volume flow rate of the PCU solution (10.0 wt-%) when the applied voltage was 24 kV. The results show that the morphology of PCU fibers could be controlled by electrospinning parameters, such as solution concentration, electric voltage and flow rate. 相似文献
4.
By means of the electrospinning technique, micron- and nanofibers can be obtained from polymer solutions under a very high electrical field. A special challenge is to produce bead-free uniform fibers since any minor changes in the electrospinning parameters such as slight variations in the polymer solutions and/or electrospinning experimental parameters may result in significant variations in the final nanofiber morphology. Furthermore, it is often not trivial at all to obtain reproducible uniform electrospun nanofibers for the optimized electrospinning conditions. Here we report that the conductivity of the solvent is the key factor for the reproducible electrospinning of uniform polystyrene (PS) fibers from dimethylformamide (DMF) solutions. It is shown that even slight changes in the conductivity of the DMF solutions can greatly affect the morphology of the resulting electrospun PS fibers. Here, we have carried out a thorough and systematic study on the effect of solution conductivity on the electrospinning of bead-free polystyrene (PS) fibers when dimethylformamide (DMF) was used as the solvent. Interestingly, we found out that different grades of solvent as-received (DMF) from various suppliers have slightly different solution conductivities. Consequently, the polymer solutions prepared with the same PS concentration have different conductivities, which are shown to have significant changes on the morphology of the PS fibers resulting in beaded or bead-free uniform fibers when electrospun under the identical electrospinning conditions. Such as, bead-free PS fibers were obtained from PS solutions in the range of 20% (w/v) through 30% (w/v) depending on the DMF grade used. In brief, it was observed that solutions with a higher conductivity yielded bead-free fibers from lower polymer concentrations, which confirms that the solution conductivity plays a very significant role in producing bead-free uniform PS fibers. 相似文献
5.
Summary A new recycling technique has been developed. In this method, EPS (expanded polystyrene), generally called Styrofoam, is dissolved with natural solvent, d-limonene and electrospun. This method can economically produce the nanofibers. The electrospinning process produces a nonwoven mat of long polymer fibers with diameters in the range of 10–500 nm and high surface areas per unit mass. PS (Polystyrene) polymer dissolved in different solvents such as THF (Tetrahydrofuran), DMF (Dimethylformaide), and DMAc (Dimethylacetamide) etc. may all be electrospun into nanofibers. These solvents cause environmental problem and difficulty of process handling. Natural solvent, d-limonene is used for dissolving PS. PS nanofibers are produced with PS solution using d-Limonene. This paper describes the use of polystyrene (PS) nanofibers electrospun from recycled EPS solution dissolved in d-limonene. The electrospun polystyrene nanofiber diameters vary from 300 to 900 nm, with an average diameter of about 700 nm. 相似文献
6.
Todsapon Nitanan Praneet Opanasopit Prasert Akkaramongkolporn Theerasak Rojanarata Tanasait Ngawhirunpat Pitt Supaphol 《Korean Journal of Chemical Engineering》2012,29(2):173-181
This study focused on the preparation of electrospun polystyrene (PS) nanofibers. PS solutions were prepared in single (dimethylformamide;
DMF, dimethylacetamide; DMAc or tetrahydrofuran; THF) and mixed solvent (DMF/THF and DMAc/THF) systems with and without tetrabutylammonium
bromide (TBAB) salt. The effects of PS concentration, solvent system, the addition of salt, appearance and diameter of PS
fibers were examined. The average diameter of the as-spun fibers increased upon increasing PS concentration. The morphology
of the fibers significantly depended on the properties of the solvents. The obtained fibers were smooth without any beads
and their diameters were affected by the amount of THF in the solvent and PS concentration. The beads in the fibers disappeared
and the fiber diameter significantly decreased after the addition of TBAB. The smallest diameter and the narrowest diameter
distribution of PS nanofibers (376±36 nm) were obtained from 15% PS solution in DMAc with 0.025% w/v TBAB. 相似文献
7.
Gil-Tae Kim Yu-Jin Hwang Young-Chull Ahn Hee-Soo Shin Jae-Keun Lee Chang-Mo Sung 《Korean Journal of Chemical Engineering》2005,22(1):147-153
Electrospinning is a process of electrostatic fiber formation which uses electrical forces to produce polymer nanofibers from
polymer solution. The electrospinning system consists of a syringe feeder system, a collector system, and a high power supplier.
The important parameters in the morphology of electrospun polystyrene fibers are concentration, applied voltage, and solvent
properties. Higher concentrations of the polymer solution form thicker fibers and fewer beads. When the concentration is 7
wt%, electrospun fibers have an average diameter of 340 nm, but as the concentration of PS increases to 17 wt%, the fiber
diameter gradually thickens to 3,610 nm. The fiber morphology under different solvent mixture ratios and solvent mixtures
has also been studied. 相似文献
8.
Fiber formation from atactic polystyrene (aPS) and alternating poly(styrene‐maleic anhydride) (PSMA) synthesized by free radical polymerization (AIBN, 90°C, 4 h) were investigated by electrospinning from various solutions. aPS was soluble in dimethylformamide (DMF), tetrahydrofuran (THF), toluene, styrene, and benzene, whereas PSMA was soluble in acetone, DMF, THF, dimethylsulfoxide (DMSO), ethyl acetate, and methanol. aPS fibers could be electrospun from 15 to 20% DMF and 20% THF solutions, but not from styrene nor toluene. PSMA, on the other hand, could be efficiently electrospun into fibers from DMF and DMSO at 20 and 25%, respectively. Few PSMA fibers were, however, produced from acetone, THF, or ethyl acetate solutions. Results showed that solvent properties and polymer–solvent miscibility strongly influenced the fiber formation from electrospinning. The addition of solvents, such as THF, generally improved the fiber uniformity and reduced fiber sizes for both polymers. The nonsolvents, however, had opposing effects on the two polymers, i.e., significantly reducing PSMA fiber diameters to 200 to 300 nm, creating larger and irregularly shaped aPS fibers. The ability to incorporate the styrene monomer and divinylbenzene crosslinker in aPS fibers as well as to hydrolyze PSMA fibers with diluted NaOH solutions demonstrated potential for post‐electrospinning reactions and modification of these ultrafine fibers for reactive support materials. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
9.
Yi Lin Yongyi Yao Xiaozhan Yang Na Wei Xuqing Li Ping Gong Ruixia Li Dacheng Wu 《应用聚合物科学杂志》2008,107(2):909-917
Poly(ether sulfone) (PES) nanofibers were prepared by the gas‐jet/electrospinning of its solutions in N,N‐dimethylformamide (DMF). The gas used in this gas‐jet/electrospinning process was nitrogen. The morphology of the PES nanofibers was investigated with scanning electron microscopy. The process parameters studied in this work included the concentration of the polymer solution, the applied voltage, the tip–collector distance (TCD), the inner diameter of the needle, and the gas flow rate. It was found from experimental results that the average diameter of the electrospun PES fibers depended strongly on these process parameters. A decrease in the polymer concentration in the spinning solutions resulted in the formation of nanofibers with a smaller diameter. The use of an 18 wt % polymer solution yielded PES nanofibers with an average diameter of about 80 nm. However, a morphology of mixed bead fibers was formed when the concentration of PES in DMF was below 20 wt % during gas‐jet/electrospinning. Uniform PES nanofibers with an average diameter of about 200 nm were prepared by this electrospinning with the following optimal process parameters: the concentration of PES in DMF was 25 wt %, the applied voltage was 28.8 kV, the gas flow was 10.0 L/min, the inner diameter of the needle was 0.24 mm, the TCD was 20 cm, and the flow rate was 6.0 mL/h. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008 相似文献
10.
Mei-Ling Cheng 《Polymer》2008,49(2):546-553
Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBHHx) nanofibrous membranes were first fabricated via electrospinning from chloroform (CHCl3) or CHCl3/dimethylformamide (DMF) polymer solutions. The electrospinning conditions such as the polymer concentration, the solvent composition, and the applied voltage were optimized in order to get smooth and nano-sized fibers. The crystalline structure, the melting behaviors and the mechanical properties of the obtained nanofibrous membranes were characterized. With pure CHCl3 as the solvent in the electrospinning process, the finest smooth PHBHHx fibers were about 1 μm in diameter. When DMF is added to CHCl3 as a co-solvent, the conductivity and volatility of the solution increased and reduced, respectively, and the electrospinnability of the polymer solution increased as a result. The averaged diameters of PHBHHx fibers could be reduced down to 300-500 nm when the polymer concentration was kept at 3 wt%, the ratio of DMF/CHCl3 was maintained at 20/80 (wt%), and the applied voltage was fixed at 15 kV during electrospinning. WAXD and DSC results indicated that the crystallization of the PHBHHx nanofibers was restricted to specific crystalline planes due to the molecular orientation along the axial direction of the fibers. The crystallization behaviors of the electrospun nanofibers were significantly different from that of the cast membranes because of the rapid solidification and the one-dimensional fiber size effect in the electrospinning process. Mechanically, the electrospun PHBHHx nanofibrous membranes were soft but tough, and their elongation at break averaged 240-300% and could be up to 450% in some cases. This study demonstrated how the size of electrospun PHBHHx fibers could be reduced by adding DMF in the solvent and gave a clue of the presence of oriented molecular chain packing in the crystalline phase of the electrospun PHBHHx fibers. 相似文献
11.
The electrospinning of the polycarbonate (PC) solutions was performed for the variable electrospinning parameters such as polymer concentration, solvent composition, applied voltage, flow rate, and take‐up velocity in order to evaluate changes of morphology, mechanical properties, and flammability of the aligned PC nanofibers as a function of the electrospinning parameters. It was found that the ratio of THF/DMF solvent in the electrospinning parameters had a major effect on the spinnability and fiber morphology. Furthermore, it was confirmed that the mechanical properties were dependent upon the fiber morphology. The spinnability of the PC solutions with a lower THF ratio in THF/DMF solvent was poor. The aligned electrospun PC fiber with the best morphology was made in the range of polymer concentration of 22%, solvent ratio of 50:50 THF : DMF, applied voltage of 14 kV, flow rate of 0.050 ml/m, and a take‐up velocity of 7.3 m/s. The ultimate strength and initial modulus of the 80% drawn 22% PC fiber were 64 ± 2 MPa (commercial 55–75 MPa) and 1.9 ± 0.1 GPa. The heat release capacity (HRC) of the 22 and 25% PC fiber were 275 ± 27 J/g K and 198 ± 1 J/g K. It was found that the flame resistance of the electrospun PC nanofiber was superior to that of the PC raw material (HRC ~360 J/g K). POLYM. ENG. SCI., 2008. © 2008 Society of Plastics Engineers 相似文献
12.
In this study, we have successfully fabricated electrospun polystyrene (PS) nanofibers having a diameter of 326 ± 50 nm with a parallel grooved texture using a mixed solvent of tetrahydrofuran (THF) and N,N-dimethylformamide (DMF). We discovered that solvent system, solution concentration, and relative humidity were the three key factors to the formation of grooved texture and the diameter of nanofibers. We demonstrated that grooved nanofibers with desired properties (e.g., different numbers of grooves, widths between two adjacent grooves, and depths of grooves) could be electrospun under certain conditions. When THF/DMF ratio was higher than 2:1, the formation mechanism of single grooved texture should be attributed to the formation of voids on the jet surface at the early stage of electrospinning and subsequent elongation and solidification of the voids into a line surface structure. When THF/DMF ratio was 1:1, the formation mechanism of grooved texture should be ascribed to the formation of wrinkled surface on the jet surface at the early stage of electrospinning and subsequent elongation into a grooved texture. Such findings can serve as guidelines for the preparation of grooved nanofibers with desired secondary morphology. 相似文献
13.
采用75%四氢呋喃(THF)和25%N,N-二甲基甲酰胺(DMF)的混合溶液作溶剂,通过气流-静电纺丝法制备了苯乙烯-丁二烯-苯乙烯嵌段共聚物(SBS)超细纤维。利用扫描电镜(SEM),研究了溶液浓度、电压、接收距离(喷丝孔到接收板的距离)、喷丝孔内径对静电纺纤维的直径和形貌的影响。研究发现:溶液浓度对电纺纤维的直径和形貌有非常重要的影响,当溶液浓度由10%增加到18%时,电纺纤维平均直径随之成线性增加;当电压由23.8kV增加到33.8kV时,纤维平均直径先减小后增加。最佳工艺条件为:溶液质量分数为14%,电压为28.8kV,接收距离为20cm,喷丝孔内径为0.27mm,所得SBS电纺超细纤维平均直径为429nm。 相似文献
14.
Nano-structured poly(ε-caprolactone) (PCL) nonwoven mats were prepared by electrospinning process. In this study, three types of solution were used. One dissolved in only methylene chloride (MC), the second dissolved in mixture of MC and N,N-dimethylformamide (DMF), the third dissolved in mixture of MC and toluene. MC, toluene and DMF are a good, poor, and nonsolvent for PCL, respectively. For the MC only, electrospun fibers had very regular diameter of about 5500 nm, but electrospinng is not facilitated. For the mixture of MC and DMF, electrospinning is certainly enhanced as well as fiber diameter decreased dramatically as increasing DMF volume fraction. It was due to high electric properties of solution such as dielectric constant and conductivity. Whereas, as increasing toluene volume fraction, electrospinning is strictly restricted due to very high viscosity and low conductivity. As the results, it has regarded that solution properties is one of the important parameter in electrospinning. Properties such as conductivity, surface tension, viscosity and dielectric constant of the PCL solutions prepared from three types of solvent system were studied. The morphology, crystallinity and mechanical properties of electrospun PCL nonwoven mats were characterized by scanning electron microscopy (SEM), wide angle X-ray diffraction (WAXD) and universal testing method (UTM), respectively. 相似文献
15.
The submicron fibers were prepared via electrospinning the styrene–isoprene–styrene (SIS) triblock copolymer from a pure solvent of tetrahydrofuran (THF) and a mixed solvent of THF and N, N‐dimethylformamide (DMF). The addition of DMF to THF resulted in a beneficial effect on the fiber formation and the electrospinnability. The obtained results revealed that the fibers were only formed in a narrow solution concentration range of 8–15 wt %; the morphology, diameter, structure, and mechanical performance of as‐spun fibers from PS and SIS solutions were affected by the composition weight ratio and the solution properties; and those from the solution at the intermediate concentration of 10 wt % exhibited a maximum tensile strength and strain at break. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
16.
Rajneesh Verma Stephen Creager John Ballato Dennis W Smith Jr 《Polymer International》2013,62(8):1152-1158
A statically non‐wetting highly hydrophobic fibrous surface was generated from biphenyl perfluorocyclobutyl aryl ether polymer (BP‐PFCB) by electrospinning. The optimization of solution parameters, which include concentration of the solution and number‐average molecular weight of the polymer, was followed by optimization of the instrumental parameters, which include flow rate, inter‐electrode voltage and inter‐electrode distance. Varying these parameters resulted in different degrees of hydrophobicity on the generated surfaces. The degree of hydrophobicity was determined by measuring static water contact angles. The effects of these variations in electrospinning parameters on the thickness of the fibers constituting the surface were also observed. It was found that the hydrophobic nature of the electrospun fibrous surface of BP‐PFCB depended on two factors: fluorine concentration and thickness of the fibers. During the optimization of the parameters, three different morphological regimes, namely beads, beaded fibers and fibers, were observed. The fine tuning of electrospinning parameters eventually produced a statically non‐wetting, highly hydrophobic surface which predominantly consisted of an intricate network of nanoscale fibers. © 2013 Society of Chemical Industry 相似文献
17.
Morphology, structure and properties of conductive PS/CNT nanocomposite electrospun mat 总被引:3,自引:0,他引:3
The morphologies and properties of Polystyrene (PS)/Carbon Nanotube (CNT) conductive electrospun mat were studied in this paper. Nanocomposite fibers were obtained through electrospinning of PS/Di-Methyl Formamide (DMF) solution containing different concentrations and types of CNTs. The dispersion condition of CNTs was correlated to morphologies and properties of nanocomposite fibers. A copolymer as an interfacial agent (SBS, Styrene-butadiene-styrene type) was used to modify the dispersion of CNTs in PS solution before electrospinning. The results showed that the presence of the copolymer significantly enhances CNT dispersion. The fiber diameters varied between 200 nm and 800 nm depending on CNT type, polymer concentration and copolymer. The final morphological study of the fibers showed that CNT addition caused a decrease in beads formation along fiber axis before percolation threshold. However, addition of CNTs above percolation increased the beads formation, depending on the dispersion condition. The presence of SBS modified the dispersion, reduced the fiber diameter and the number of bead structures. Electrical conductivity measurements on nanocomposite mats of 15-300 μm in thickness showed an electrical percolation threshold around 4 wt% MWCNT; while the samples containing SBS showed higher values of conductivities below percolation compared to the samples with no compatibilizer. Enhancement in mechanical properties was observed by the addition of CNTs at concentrations below percolation. 相似文献
18.
采用聚醚砜(PES)的良溶剂二甲基甲酰胺(DMF)和非良溶剂丙酮(AC)为共溶剂体系,研究了溶剂组成、纺丝成形条件对静电纺丝PES纤维的形貌及纤维直径的影响。结果表明:DMF/AC的配比对于静电纺丝PES纤维形貌具有直接的调控作用,随着DMF/AC混合溶剂中AC用量的增加,纤维平均直径变大,纤维毡中串珠数目明显减少,纤维均一性变好;随着纺丝液浓度的升高,纺丝电压的增大,纤维的平均直径变大;接收距离的变化对纤维平均直径影响不大;PES最佳纺丝工艺条件为纺丝溶液质量分数13%,纺丝电压15 kV,接收距离10 cm,mDMF/mAC为8.5/1.5,在此条件下,可以获得纤维平均直径为96 nm的PES纤维毡。 相似文献
19.
Polystyrene (PS) with a concentration of 20% by weight in THF/DMF was electrospun on a flat sheet collector. At a concentration of THF above 75%, blocking at the needle tip caused bead formation. However, a nice fiber mat was obtained with the 75/25 THF/DMF. Moreover, at a traveling distance of 10 and 15 cm and voltages from 10 to 16 kV, the PS fibers exhibited alignment. This alignment was reproducible when voltage stabilizer was connected to the voltage supply. This suggested that the uniformly positive charges arising from external voltage interacted with the aromatic rings on the PS chain, yielding a uniform dipole moment. As a result, during jet traveling, the solvent evaporated and the molecules were oriented and frozen at the ground collector. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 相似文献
20.
Ultrafine polyacrylonitrile (PAN) fibers, as a precursor of carbon nanofibers, with diameters in the range of 220–760 nm were
obtained by electrospinning of PAN solution using N,N-dimethyl formamide (DMF) as solvent. Morphology of the nanofibers for varying concentration and applied voltage was investigated
by field emission scanning electron microscopy (FESEM). The thermal properties and structural changes during the oxidative
stabilization process were primarily investigated by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA),
and Fourier transform infrared (FT-IR) and Raman spectroscopy. The nanofiber diameters increase as the applied voltage is
increased and they also increase with an increase in the concentration of the polymer solution. It was also concluded that
the electrospun fibers displayed a very sharp exothermic peak at 297.34 °C. A transition temperature observed by FT-IR and
Raman was approximately 300 °C, which was closely consistent with the results of DSC and TGA studies. It was also found that
oxidative stabilization in air was accompanied by a change in color of nanofibers webs. 相似文献