共查询到19条相似文献,搜索用时 109 毫秒
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采用环氧树脂E-51与甲基二乙醇胺(MDEA)在加热条件下进行反应,再利用乙酸中和叔胺,制备出反应型季铵盐乳化剂树脂;将该乳化剂树脂与环氧树脂E-20按照一定比例在一定温度下进行接枝反应,得到水性环氧乳液。对环氧乳液进行了FT-IR表征,考察了反应型季铵盐乳化剂树脂与环氧树脂E-20的比例、反应温度、反应时间对水性环氧乳液稳定性、粒径、配漆后涂膜性能等方面的影响。研究结果表明:在60~70℃下,反应型季铵盐乳化剂树脂加量为8%时,制备的水性环氧乳液具有较好的贮存稳定性,与水性环氧固化剂配漆后的涂膜具有较好的耐盐雾、耐酸碱性能和良好的力学性能。 相似文献
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《粘接》2016,(3)
以二乙醇胺(DEOA)、环氧树脂E-51为主要原料,合成了DEOA化学改性的自乳化水性环氧树脂乳液,并与水性环氧树脂固化剂按一定比例配制成涂膜。采用红外光谱对改性环氧树脂结构进行表征,通过纳米粒度分析仪和透射电镜(TEM)研究了环氧树脂乳液的粒径和形貌,同时研究了反应温度对环氧基转化率的影响,DEOA加入量对乳液稳定性、粒径的影响。结果表明,随着DEOA用量的增加,环氧树脂乳液的稳定性提高,粒径减小且分布变窄。当n(DEOA):n(环氧基)=0.35:1时,乳液粒径约30~60 nm,制备的涂膜铅笔硬度为3H,柔韧性为1 mm,附着力为1级,耐冲击性为50 kg/cm。 相似文献
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New polymeric polyol for thermoset coatings: Superacid-catalyzed copolymerization of water and epoxy resins 总被引:2,自引:0,他引:2
Frederick H. Walker John B. Dickenson Charles R. Hegedus Frank R. Pepe Renee Keller 《Journal of Coatings Technology》2002,74(928):33-47
Though free-radical emulsion polymerization has been studied extensively, published reports of cationic (i.e., acid-catalyzed)
polymerizations of emulsified monomers are rare. It was recently discovered that treatment of an emulsion of liquid epoxy
resin with select superacid catalysts yields a polymeric polyol. Catalysis with one percent perchloric acid at room temperature
yields a product with a number average molecular weight of 1650, and a polydispersity of 5.0 as measured by GPC. The polyol’s
structure differs from that of conventional high molecular weight epoxy resins prepared by the advancement process in several
ways, including the incorporation of two glycidyl units in the repeat unit. In essence, the product is a copolymer of the
epoxy resin and water, in which water is incorporated in the repeat unit structure by reaction with two epoxide groups. A
similar product can be prepared by solution polymerization, where the molecular weight is controlled by the ratio of water
to epoxy resin. The product was shown to have lower levels of residual bisphenol-A diglycidyl ether (BADGE) and bisphenol-A
than conventional advanced epoxy resins. Polyols prepared by these new processes were crosslinked with melamine-formaldehyde
resins in waterborne coating formulations which were free of added cosolvent, as well as solventborne coating formulations.
The coatings developed excellent solvent resistance at lower bake temperatures than traditional epoxy resins.
Presented at the 79th FSCT Annual Meeting in Atlanta, GA, Nov. 5–7, 2001.
7201 Hamilton Blvd., Allentown, PA 18195-1501. 相似文献
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A novel reactive diol, bis-biphenyloxy (4-hydroxy) phenyl phosphine oxide (BBPHPPO) which contains both biphenylyl and phenyl phosphonic groups was synthesized. Flame retardant advanced epoxy resin was obtained by chain extension of diglycidyl ether of bisphenol-A (DGEBA) with the phosphorus-containing diol (BBPHPPO). The thermal properties and flame retardancy of cured epoxy resin were studied. The resulting BBPHPPO containing epoxy system exhibited higher glass transition temperature than that of advanced epoxy resins prepared from bisphenol-A (BA) and tetrabromobisphenol-A (TBBA). The high char yield and the high LOI value were observed to prove the excellent flame retardancy of this phosphorus-containing epoxy resin. 相似文献
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为提高水性环氧涂料的固化性能和适用期,以自制聚酰胺和生物基戊二胺为起始原料,聚乙二醇二缩水甘油醚( PEGGE)为亲水链段,双酚 A型环氧树脂( E-51)为疏水链段,邻甲苯缩水甘油醚( CGE)为封端剂制备了非离子型低温水性环氧固化剂,并与自制水性环氧乳液复配制得双组分水性环氧涂料。考察了环氧固化剂合成工艺参数及涂膜各项性能。结果表明:该固化剂含有较长的柔性脂肪烃碳链和聚醚链段能够提高涂膜的柔韧性;双酚 A型环氧树脂参与扩链反应能够解决与乳液不兼容等问题;苯环结构增加了涂膜的硬度;涂膜室温固化后性能优异,具有良好的物理机械性能、耐水性、耐酸碱性和耐盐雾性。 相似文献
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A novel hyperbranched polyphosphate ester (HPE) was synthesized via the polycondensation of bisphenol-A and phosphoryl trichloride.
The formed HPE was characterized by FTIR, 1H NMR and 31P NMR to confirm its structure. Then, a series flame retardant epoxy resins from bisphenol-A epoxy cured with HPE and bisphenol-A
were prepared. The combustion behavior of the flame retardant epoxy resins was studied using limiting oxygen index (LOI) and
cone calorimeter test. The LOI value increased from 23 to 32 when HPE, instead of bisphenol-A, was used as a curing agent.
The cone calorimeter test data revealed that the cured bisphenol-A epoxy resin with HPE as a curing agent possessed improved
flame retardancy. The photo graphs and scanning electron microscopy (SEM) of char residues confirmed the cone calorimeter
results. 相似文献
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《国际聚合物材料杂志》2012,61(3):211-218
Colored epoxy resin containing azo moiety was synthesized by reaction between epichlorohydrin and bis-azodiol, which was synthesized by coupling bisphenol-A with aromatic amine. Colored epoxy resin was characterized by epoxy equivalent weight, IR spectra, Viscosity and UV visible spectroscopy. The curing of colored epoxy resin and DGEBA were characterized by differential scanning calorimetry (DSC). The thermal stability of cured products was characterized by thermogr avimetric analysis (TGA). The cured products have good thermal stability. Several glass fiber epoxy composites were fabricated and their mechanical properties, electrical properties and chemical resistance were studied. 相似文献
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高沸醇木质素环氧树脂的合成与性能研究 总被引:2,自引:2,他引:2
利用高沸醇木质素的化学活性,直接与环氧氯丙烷反应,生成木质素环氧树脂和木质素改性双酚A型环氧树脂,用环氧值、红外光谱、TGA和DSC等对树脂进行表征,并与未改性的双酚A型环氧树脂进行对比。结果表明,高沸醇木质素很容易合成木质素环氧树脂,其最佳合成条件是:n(ECH)∶n(-OH)=8,温度55~60℃,碱浓度为5%;高沸醇木质素环氧树脂能显著提高环氧树脂的耐溶剂性和耐热性。 相似文献
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Tsung-Han Ho Hann-Jang Hwang Jeng-Yueh Shieh Ming-Chin Chung 《Reactive and Functional Polymers》2009,69(3):176-182
Two phosphorus-containing advanced epoxy resins were obtained by chain-extension of diglycidyl ether of bisphenol-A epoxy (DGEBA) resin with 2-(6-oxido-6H-dibenz(c,e)(1,2)-oxaphosphorin-6-yl)-1,4-benzenediol (DOPOBQ), at different stoichiometric ratios. The phosphorus-containing advanced epoxy was separately cured with various dicyanate esters to form flame-retardant epoxy/cyanate ester systems. The effects of phosphorus content and dicyanate ester structure were studied, and compared with those of the control (advanced bisphenol-A epoxy) system. The DOPOBQ-containing epoxy/cyanate ester systems exhibited higher glass transition temperatures, better dimensional stability and better thermal stability. 相似文献
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A method for studying the curing of 100 μm-thick epoxy-based layers coated on steel substrates is described. A simple waterborne epoxy reactive system based on a diglycidylether of bisphenol-A prepolymer and with a polyether triamine was set up by emulsifying the epoxy resin with the use of an ethoxylated-nonylphenol emulsifier. The parliculur phenomena involved during the isothermal curing of such an epoxy emulsion were decomposed by considering the same formulation without water and without water + emulsifier. The chemical kinetics were determined by DSC and by size exclusion chromatography. As previously proposed for numerous epoxy-amine reactive systems, for the three types of coatings, a second-order autocatalytic law was able to interpret the data. The presence of water delays the gelation characterized by rheological measurements. As a consequence, the epoxy conversion at the gel point increases. This phenomenon can be related to the inhomogeneous polymerization process during which the epoxy groups can be trapped into the initial epoxy particles. In addition, the microdielectrometry technique was used to follow the curing degree of the epoxy reactive system of thin layers during the drying and curing processes under radiant heatings such as infrared curing. 相似文献