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多聚磷酸与丁苯橡胶复配改性沥青的性能 总被引:1,自引:0,他引:1
研究了多聚磷酸与丁苯橡胶复配改性剂对沥青的热稳定性、动态力学性能、黏度及低温抗裂性能的影响.结果表明,多聚磷酸的加入能够提高沥青的黏度,改善沥青的高温抗车辙性能;丁苯橡胶的加入提高了沥青的黏度和低温抗裂性能,但对沥青的高温抗车辙能力有一定的负面影响;使用少量交联剂可提高沥青的高温抗车辙性能,降低其黏度.综合考虑沥青的高低温性能,宜以添加2份(质量,下同)多聚磷酸、6份丁苯橡胶及0.04份硫黄为最佳改性剂配方. 相似文献
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Acar Seda Bekin Tasdelen Mehmet Atilla Karaagac Bagdagul 《Iranian Polymer Journal》2021,30(7):697-705
Iranian Polymer Journal - The addition of methacrylate-functional polyhedral oligomeric silsesquioxane (MA-POSS) nanoparticles to styrene-butadiene rubber (SBR) composites was evaluated in terms of... 相似文献
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Reaction of methyl esters of epoxidized fatty acids with paraperiodic acid led to direct cleavage of epoxide functions and
the production of aldehydes and methyl azelaaldehydate. The reaction was carried out in aqueous dioxane. The use of other
solvents and the influence of reaction variables was examined. The reaction is essentially quantitative for methyl, 9,10-epoxystearate.
Presented at the AOCS Meeting in Cineinnati, October 1965.
E. Utiliz. Res. Dev. Div., ARS, USDA. 相似文献
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Danling Wang Sheng Chen Li Chen Boyu Chen Fujun Ren Chenxi Zhu Jie Feng 《应用聚合物科学杂志》2019,136(35):47918
Effects of different silane coupling agents on scorch time of silica-filled solution styrene-butadiene rubber compounds were studied. The flocculation of silica at high temperature, which was characterized by rubber processing analyzer (RPA) and transmission electron microscope (TEM), has been proved to be an important factor affecting the scorch time of the compounds. In order to prolong the scorch time, the hybrid silane technology, that is, combining different silanes such as bis(triethoxysilypropyl)-tetrasulfide (TESPT) and n-octyltriethoxysilane (OTES) together, was developed to improve silica dispersion and suppress silica flocculation. The results showed that when the content of TESPT is fixed, the increase of OTES can effectively increase the scorch time due to the suppression of silica flocculation while not affecting the polymer crosslinking. This phenomenon is absent for the case where the OTES content is fixed, but the TESPT content is varied because the sulfur atoms in the TESPT molecules will also participate in the vulcanization process, leading to the decrease in scorch time. Through the present study, a connection between silica flocculation and scorch time has been built up, which is important for rubber composite processing. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47918. 相似文献
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Summary A polyurethane prepared from 1,9-nonanediol and toluene-2,4-diisocyanate with Mn=11,840, was capped on both ends in a reaction with 4-(benzocyclobutenyl) methanol. The polyurethane was used to crosslink styrene-butadiene rubber through Diels-Alder reactions on the benzocyclobutene functionality. The synthesis and characterization of 4-(benzocyclobutenyl) methanol, a molecule not reported previously, is presented. The crosslinking reaction was carried out on intimate mixtures of the telechelic polyurethane and SBR at elevated temperature and pressure. Various physical properties of the crosslinked material were studied.Work done at the Department of Chemistry, University of Akron, Akron, OH 44325, USA 相似文献
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以高门尼黏度丁苯橡胶(SBR)1723基础胶浆和稠环芳烃质量分数低于3.0%的环保型橡胶填充油为原料制备环保型充油SBR,考察了乳化工艺对填充油乳化效果的影响以及所制得的环保型充油SBR的性能。结果表明,在以歧化松香酸钾皂为乳化剂、先将乳化剂加入填充油中搅拌一段时间后再加入水的油乳化方式、油乳化温度为70℃、填充油/水/乳化剂(质量比)为100/200/2以及凝聚时搅拌转速为163 r/min、凝聚温度为65~70℃的条件下,所得产品的各项性能指标满足产品标准的要求。 相似文献
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通过动态剪切流变试验、四组分试验和红外光谱测试沥青中的组分胶体指数差值和官能团结构指数,考察了分别由多聚磷酸(PPA)、丁苯橡胶(SBR)及SBR/PPA复合物改性沥青的抗紫外老化性能,探讨了老化的机理。结果表明,PPA的添加有效改善了沥青的高温流变性能,改性沥青的抗车辙因子和相位角的变化幅度较小。PPA或SBR/PPA复合改性沥青在紫外老化前后的胶体指数差值较小,而后者羧基和亚砜基指数的增大幅度要小于前者,丁二烯基指数的减小幅度小于SBR改性沥青。综合来看,PPA/SBR复合改性沥青的抗紫外老化性能优于基质沥青和PPA或SBR改性沥青。 相似文献
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选取聚四氟乙烯(PTFE)分散液,采用乳液共沉法,研究其对乳聚丁苯橡胶(ESBR)性能的影响。结果表明,PTFE分散液的加入,提高了ESBR的耐油性,且其耐油性与PTFE分散液含量基本呈正比关系。此外,共混体系的力学性能也有一定改善。对于丁苯橡胶(SBR)/PTFE体系:共混比为90/10时,硬度增幅最大;在共混比为80/20时,拉伸强度达到最大值。扯断伸长率随着体系PTFE含量的增加,呈递减趋势。综合考虑,当PTFE质量份为10~20时,胶料耐焦烧性好,加工安全性较高,性能最优。 相似文献
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通过配位反应制备得到双金属硫化促进剂二乙基二硫代氨基甲酸锌镧配合物(ZnLaDC),在不添加传统活化体系氧化锌(ZnO)/硬脂酸(SA)的情况下,考察了ZnLaDC用量对丁苯橡胶(SBR)/天然橡胶(NR)胎面胶复合材料硫化特性及物理机械性能的影响,并与传统硫化体系二乙基二硫代氨基甲酸锌(ZnDC)/ZnO/SA制备的硫化胶性能进行了对比。结果表明,随着ZnLaDC用量的增加,SBR/NR胎面胶复合材料的硫化特性、压缩疲劳生热性能及耐磨性得到有效提高,当ZnLaDC用量为5份时,复合材料的综合性能最佳。与传统硫化体系ZnDC/ZnO/SA制备的硫化胶相比,采用ZnLaDC制备的硫化胶具有更优异的静态力学性能及耐切割性。 相似文献
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Extrusion of star styrene-butadiene rubber (SBR) without and with ultrasonic treatment at amplitudes 3.5, 5, 7.5, and 10 μm was carried out. The molecular structure of untreated and treated star SBR was determined. Significant reduction of die pressure was observed during ultrasonic treatment due to the thixotropic and degradation effects. Ultrasonic treatment of star SBR at 3.5 μm created molecules of higher molecular weight via long-chain branching without gel formation. Ultrasonic treatment of star SBR at 5 μm created a small amount of gel. At high ultrasonic amplitudes more gel was generated hindering mixing of star SBR with silica. Extruded star SBR was compounded with carbon black and precipitated silica, with and without silane. It was found that the long-chain branching induced by ultrasonic treatment improved the rubber–filler interaction in precipitated silica without silane, as confirmed by the increase of bound rubber content. The filler–filler interaction was reduced in silica compounds without silane, as indicated by study of Payne effect. The significantly improved rubber–filler interaction and reduced filler–filler interaction led to an increase of the modulus at 100% elongation and tensile strength of SBR/silica vulcanizates. Extensive comparisons were made with earlier study on ultrasonic treatment of linear SBR. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47451. 相似文献
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《Journal of Adhesion Science and Technology》2013,27(4):561-581
The chlorination of vulcanized styrene-butadiene rubbers (SBRs) with trichloroisocyanuric acid (TCI) has been studied. The solvent used to apply the TCI chlorinating solutions on the rubber plays an important role in the effectiveness of the treatment since the solvent determined the degree of penetration of TCI into the rubber and also different chlorinating species were produced depending on the nature of the solvent. Surface modifications produced on a synthetic sulfur-vulcanized SBR using TCI solutions in ethyl acetate (EA), methyl ethyl ketone (MEK), and EA + MEK mixtures have been compared. Furthermore, the effects of a solvent wipe with EA or MEK prior to the chlorination process were also considered. Surface modifications produced by the treatments were analyzed using ATR-IR spectroscopy, scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). Adhesion was obtained from the T-peel strength of treated rubber/polyurethane adhesive joints. TCI/MEK solutions produced a higher degree of surface modification than TCI/EA solutions, but TCI/EA solutions were more effective in removing zinc stearate from the rubber surface. When high TCI percentages (5-7 wt%) in EA solutions were used, a weak boundary layer (WBL) was created on the rubber surface as a consequence of the deposition of an excess of chlorinating agent on the rubber surface and of by-products (cyanuric and/or isocyanuric acid). The formation of the WBL led to a lack of adhesion in the rubber towards the polyurethane adhesive. When MEK was used as a solvent for TCI, this WBL was not produced on the rubber surface, and thus adhesion was considerably higher even when high concentrations of TCI/MEK were used. Similar effects were produced using EA + MEK mixtures as the solvent for TCI. The wiping of the rubber surface with MEK prior to the chlorination treatment led to good adhesion, irrespective of the percentage of TCI and the solvent used in the chlorinating solution. 相似文献
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The effects of silane coupling agents on styrene-butadiene rubber (SBR)-mica composites have been studied with special reference to the technical properties and polymer-filler interaction. Silane-treated mica improves polymer-filler interaction, which subsequently enhances the tensile and other technically important mechanical properties. Failure surfaces of tensile, tear, and wear specimens have been examined under scanning electron microscope (SEM) and the fractographs have been correlated with the strength and failure mode of the composites. 相似文献
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环保型乳聚丁苯橡胶制备技术进展 总被引:1,自引:0,他引:1
综述了乳液聚合制备不含亚硝胺化合物或生产过程中不产生亚硝胺化合物的环保型丁苯橡胶的方法,主要有使用不含亚硝基或不产生亚硝胺化合物的聚合终止剂、添加抑制剂、提高防老剂的持久性、削减部分易产生亚硝胺的次磺酰胺类促进剂用量等途径,并提出助剂行业的发展方向。 相似文献