A novel hybrid oxy-fuel power cycle utilizing solar thermal energy

An advanced oxy-fuel hybrid power system (AHPS) is proposed in this paper. Solar thermal energy is used in the AHPS to produce saturated steam as the working fluid, and natural gas is internally combusted with pure oxygen. It is in configuration close to the zero emission Graz cycle. The thermodynamic characteristics at design conditions of the AHPS are analyzed using the advanced process simulator Aspen Plus. The corresponding exergy loss analyses are also carried out to gain understanding of the loss distribution. The results are given in detail. The solar thermal hybrid H₂O turbine power generation system (STHS) is evaluated in this study as the reference. The comparison results demonstrate that the proposed cycle has notable advantages in thermodynamic performances. For example, the net fuel-to-electricity efficiency of the AHPS is 95.90%, which is 21.61 percentage points higher than that of the STHS. The exergy efficiency (based on the exergy input of fuel and solar thermal energy without radiation) of the AHPS is 55.88%, which is 2.13 percentage points higher than that of the STHS.     

Theoretical thermodynamic analysis of Rankine power cycle with thermal driven pump

A new approach to improve the performance of supercritical carbon dioxide Rankine cycle which uses low temperature heat source is presented. The mechanical pump in conventional supercritical carbon dioxide Rankine cycle is replaced by thermal driven pump. The concept of thermal driven pump is to increase the pressure of a fluid in a closed container by supplying heat. A low grade heat source is used to increase the pressure of the fluid instead of a mechanical pump, this increase the net power output and avoid the need for mechanical pump which requires regular maintenance and operational cost. The thermal driven pump considered is a shell and tube heat exchanger where the working fluid is contained in the tube, a tube diameter of 5 mm is chosen to reduce the heating time. The net power output of the Rankine cycle with thermal driven pump is compared to that of Rankine cycle with mechanical pump and it is observed that the net power output is higher when low grade thermal energy is used to pressurize the working fluid. The thermal driven pump consumes additional heat at low temperature (60 °C) to pressurize the working fluid.     

An integrated system for thermal power generation,electrical energy storage and CO2 capture

This work reports a newly proposed system for electrical energy storage. The new system combines a direct open nitrogen (cryogen) expansion cycle with a natural gas‐fuelled closed Brayton cycle and the CO₂ produced in the system is captured in the form of dry ice. Thermodynamic analyses are carried out on the system under the baseline conditions of 1 kg s^?1 natural gas, a combustor operating pressure of 8 bars and a cryogen topping pressure of 100 bars. The results show that the exergy efficiency of the proposed system is as high as 64% under the baseline conditions, whereas the corresponding electricity storage efficiency is about 54%. A sensitivity analysis has also been carried out on the main operating conditions. The results indicate that the baseline performance can be enhanced by increasing the gas turbine (GT) inlet temperature, decreasing the approach temperature of the heat exchange processes, operating the combustor at an optimal pressure of ～7 bars and operating the cryogen topping pressure at ～90 bars. Further enhancement can be achieved by increasing the isentropic efficiency of the GT and the liquefaction process. The results of this work also suggest that the power capacity installation of peak‐load units and fuel consumption could be reduced by as much as 50% by using the newly proposed system. Further work is suggested for an economic analysis of the system. Copyright © 2010 John Wiley & Sons, Ltd.     

A comparative study of the carbon dioxide transcritical power cycle compared with an organic rankine cycle with R123 as working fluid in waste heat recovery

The organic rankine cycle (ORC) as a bottoming cycle¹ to convert low-grade waste heat into useful work has been widely investigated for many years. The CO₂ transcritical power cycle, on the other hand, is scarcely treated in the open literature. A CO₂ transcritical power cycle (CO₂ TPC) shows a higher potential than an ORC when taking the behavior of the heat source and the heat transfer between heat source and working fluid in the main heat exchanger into account. This is mainly due to better temperature glide matching between heat source and working fluid. The CO₂ cycle also shows no pinch limitation in the heat exchanger. This study treats the performance of the CO₂ transcritical power cycle utilizing energy from low-grade waste heat to produce useful work in comparison to an ORC using R123 as working fluid.Due to the temperature gradients for the heat source and heat sink the thermodynamic mean temperature has been used as a reference temperature when comparing both cycles. The thermodynamic models have been developed in EES² The relative efficiencies have been calculated for both cycles. The results obtained show that when utilizing the low-grade waste heat with the same thermodynamic mean heat rejection temperature, a transcritical carbon dioxide power system gives a slightly higher power output than the organic rankine cycle.     

Analysis of oxy-fuel combustion power cycle utilizing a pressurized coal combustor

Growing concerns over greenhouse gas emissions have driven extensive research into new power generation cycles that enable carbon dioxide capture and sequestration. In this regard, oxy-fuel combustion is a promising new technology in which fuels are burned in an environment of oxygen and recycled combustion gases. In this paper, an oxy-fuel combustion power cycle that utilizes a pressurized coal combustor is analyzed. We show that this approach recovers more thermal energy from the flue gases because the elevated flue gas pressure raises the dew point and the available latent enthalpy in the flue gases. The high-pressure water-condensing flue gas thermal energy recovery system reduces steam bleeding which is typically used in conventional steam cycles and enables the cycle to achieve higher efficiency. The pressurized combustion process provides the purification and compression unit with a concentrated carbon dioxide stream. For the purpose of our analysis, a flue gas purification and compression process including de-SO_x, de-NO_x, and low temperature flash unit is examined. We compare a case in which the combustor operates at 1.1 bars with a base case in which the combustor operates at 10 bars. Results show nearly 3% point increase in the net efficiency for the latter case.     

An evaluation on the life cycle of photovoltaic energy system considering production energy of off-grade silicon

In this study, single-crystalline silicon (c-Si) photovoltaic (PV) cells and residential PV systems using off-grade silicon supplied from semiconductor industries were evaluated from a life cycle point of view. Energy payback time (EPT) of the residential PV system with the c-Si PV cells made of the off-grade silicon was estimated at 15.5 years and indirect CO₂ emission per unit electrical output was calculated at 91 g-C/kWh even in the worst case. These figures were more than those of the polycrystalline-Si and the amorphous-Si PV cells to be used in the near future, but the EPT was shorter than its lifetime and the indirect CO₂ emissions were less than the recent average CO₂ emissions per kWh from the utilities in Japan. The recycling of the c-Si PV cells should be discussed for the reason of the effective use of energy and silicon material.     

A combined power and ejector refrigeration cycle for low temperature heat sources

A combined power and ejector refrigeration cycle for low temperature heat sources is under investigation in this paper. The proposed cycle combines the organic Rankine cycle and the ejector refrigeration cycle. The ejector is driven by the exhausts from the turbine to produce power and refrigeration simultaneously. A simulation was carried out to analyze the cycle performance using R245fa as the working fluid. A thermal efficiency of 34.1%, an effective efficiency of 18.7% and an exergy efficiency of 56.8% can be obtained at a generating temperature of 395 K, a condensing temperature of 298 K and an evaporating temperature of 280 K. Simulation results show that the proposed cycle has a big potential to produce refrigeration and most exergy losses take place in the ejector.     

COOLCEP (cool clean efficient power): A novel CO2-capturing oxy-fuel power system with LNG (liquefied natural gas) coldness energy utilization

A novel liquefied natural gas (LNG) fueled power plant is proposed, which has virtually zero CO₂ and other emissions and a high efficiency. The plant operates as a subcritical CO₂ Rankine-like cycle. Beside the power generation, the system provides refrigeration in the CO₂ subcritical evaporation process, thus it is a cogeneration system with two valued products. By coupling with the LNG evaporation system as the cycle cold sink, the cycle condensation process can be achieved at a temperature much lower than ambient, and high-pressure liquid CO₂ can be withdrawn from the cycle without consuming additional power. Two system variants are analyzed and compared, COOLCEP-S and COOLCEP-C. In the COOLCEP-S cycle configuration, the working fluid in the main turbine expands only to the CO₂ condensation pressure; in the COOLCEP-C cycle configuration, the turbine working fluid expands to a much lower pressure (near-ambient) to produce more power. The effects of some key parameters, the turbine inlet temperature and the backpressure, on the systems' performance are investigated. It was found that at the turbine inlet temperature of 900 °C, the energy efficiency of the COOLCEP-S system reaches 59%, which is higher than the 52% of the COOLCEP-C one. The capital investment cost of the economically optimized plant is estimated to be about 750 EUR/kWe and the payback period is about 8–9 years including the construction period, and the cost of electricity is estimated to be 0.031–0.034 EUR/kWh.     

Solar thermal power cycle with integration of methanol decomposition and middle-temperature solar thermal energy

In this paper, we have proposed a new solar thermal power cycle which integrates methanol decomposition and middle-temperature solar thermal energy, and investigated its features based on the principle of the cascade utilization of chemical exergy. Also, the methanol decomposition with a catalyst was experimentally studied at temperatures of 150–300 °C and under atmospheric pressure. The chemical energy released by methanol fuel in this cycle consisted of two successive processes: solar energy drives the thermal decomposition of methanol in a solar receiver-reactor, and the syngas of resulting products is combusted with air, namely, indirect combustion after methanol decomposition. As a result, the net solar-to-electric efficiency of the proposed cycle could be 35% at the collector temperature of 220 °C and the turbine inlet temperature of 1300 °C, and the exergy loss in the indirect combustion of methanol was about 7% points lower than that in the direct combustion of methanol. The promising results obtained in this study indicated that this new solar thermal power cycle could make significant improvements both in the efficient use of the chemical energy of clean synthetic fuel and in the middle-temperature solar thermal energy in a power system.     

Two novel oxy-fuel power cycles integrated with natural gas reforming and CO2 capture

Two novel system configurations were proposed for oxy-fuel natural gas turbine systems with integrated steam reforming and CO₂ capture and separation. The steam reforming heat is obtained from the available turbine exhaust heat, and the produced syngas is used as fuel with oxygen as the oxidizer. Internal combustion is used, which allows a very high heat input temperature. Moreover, the turbine working fluid can expand down to a vacuum, producing an overall high-pressure ratio. Particular attention was focused on the integration of the turbine exhaust heat recovery with both reforming and steam generation processes, in ways that reduce the heat transfer-related exergy destruction. The systems were thermodynamically simulated, predicting a net energy efficiency of 50–52% (with consideration of the energy needed for oxygen separation), which is higher than the Graz cycle energy efficiency by more than 2 percentage points. The improvement is attributed primarily to a decrease of the exergy change in the combustion and steam generation processes that these novel systems offer. The systems can attain a nearly 100% CO₂ capture.     

Thermoeconomic analysis of a novel zero-CO2-emission high-efficiency power cycle using LNG coldness

This paper presents a thermoeconomic analysis aimed at the optimization of a novel zero-CO₂ and other emissions and high-efficiency power and refrigeration cogeneration system, COOLCEP-S (Patent pending), which uses the liquefied natural gas (LNG) coldness during its revaporization. It was predicted that at the turbine inlet temperature (TIT) of 900 °C, the energy efficiency of the COOLCEP-S system reaches 59%. The thermoeconomic analysis determines the specific cost, the cost of electricity, the system payback period and the total net revenue. The optimization started by performing a thermodynamic sensitivity analysis, which has shown that for a fixed TIT and pressure ratio, the pinch point temperature difference in the recuperator, ΔT_p1, and that in the condenser, ΔT_p2 are the most significant unconstrained variables to have a significant effect on the thermal performance of novel cycle. The payback period of this novel cycle (with fixed net power output of 20 MW and plant life of 40 years) was 5.9 years at most, and would be reduced to 3.1 years at most when there is a market for the refrigeration byproduct. The capital investment cost of the economically optimized plant is estimated to be about 1000 $/kWe, and the cost of electricity is estimated to be 0.34–0.37 CNY/kWh (0.04 $/kWh). These values are much lower than those of conventional coal power plants being installed at this time in China, which, in contrast to COOLCEP-S, do produce CO₂ emissions at that.     

Conversion of fossil and biomass fuels to electric power and transportation fuels by high efficiency integrated plasma fuel cell (IPFC) energy cycle

The IPFC is a high efficiency energy cycle, which converts fossil and biomass fuel to electricity and co-product hydrogen and liquid transportation fuels (gasoline and diesel). The cycle consists of two basic units, a hydrogen plasma black reactor (HPBR) which converts the carbonaceous fuel feedstock to elemental carbon and hydrogen and CO gas. The carbon is used as fuel in a direct carbon fuel cell (DCFC), which generates electricity, a small part of which is used to power the plasma reactor. The gases are cleaned and water gas shifted for either hydrogen or syngas formation. The hydrogen is separated for production or the syngas is catalytically converted in a Fischer–Tropsch (F–T) reactor to gasoline and/or diesel fuel. Based on the demonstrated efficiencies of each of the component reactors, the overall IPFC thermal efficiency for electricity and hydrogen or transportation fuel is estimated to vary from 70 to 90% depending on the feedstock and the co-product gas or liquid fuel produced. The CO₂ emissions are proportionately reduced and are in concentrated streams directly ready for sequestration. Preliminary cost estimates indicate that IPFC is highly competitive with respect to conventional integrated combined cycle plants (NGCC and IGCC) for production of electricity and hydrogen and transportation fuels.     

Design of highly efficient coal-based integrated gasification fuel cell power plants

Integrated gasification fuel cell (IGFC) technology combining coal gasification and solid oxide fuel cell (SOFC) is believed to be the only viable solution to achieving U.S. Department of Energy (DOE)’s performance goal for next generation coal-based power plants, producing electricity at 60% efficiency (coal HHV-AC) while capturing more than 90% of the evolved CO₂. Achieving this goal is challenging even with high performance SOFCs; design concepts published to date have not demonstrated this performance goal. In this work an IGFC system concept consisting of catalytic hydro-gasification, proven low-temperature gas cleaning and hybrid fuel cell-gas turbine power block (with SOFC operating at about 10 bar) is introduced. The system is demonstrating an electricity efficiency greater than 60% (coal HHV basis), with more than 90% of the carbon present in the syngas separated as CO₂ amenable to sequestration. A unique characteristic of the system is recycling de-carbonized, humidified anode exhaust back to the catalytic hydro-gasifier for improved energy integration. Alternative designs where: (1) anode exhaust is recycled directly back to SOFC stacks, (2) SOFC stack operating pressure is reduced to near atmospheric and (3) methanation reactor in the reactor/expander topping cycle is removed, have also been investigated and the system design and performance differences are discussed.     

CO2 capture efficiency and energy requirement analysis of power plant using modified calcium-based sorbent looping cycle

This paper examines the average carbonation conversion, CO₂ capture efficiency and energy requirement for post-combustion CO₂ capture system during the modified calcium-based sorbent looping cycle. The limestone modified with acetic acid solution, i.e. calcium acetate is taken as an example of the modified calcium-based sorbents. The modified limestone exhibits much higher average carbonation conversion than the natural sorbent under the same condition. The CO₂ capture efficiency increases with the sorbent flow ratios. Compared with the natural limestone, much less makeup mass flow of the recycled and the fresh sorbent is needed for the system when using the modified limestone at the same CO₂ capture efficiency. Achieving 0.95 of CO₂ capture efficiency without sulfation, 272 kJ/mol CO₂ is required in the calciner for the natural limestone, whereas only 223 kJ/mol CO₂ for the modified sorbent. The modified limestone possesses greater advantages in CO₂ capture efficiency and energy consumption than the natural sorbent. When the sulfation and carbonation of the sorbents take place simultaneously, more energy is required. It is significantly necessary to remove SO₂ from the flue gas before it enters the carbonator in order to reduce energy consumption in the calciner.     

Solar energy powered Rankine cycle using supercritical CO2

A solar energy powered Rankine cycle using supercritical CO₂ for combined production of electricity and thermal energy is proposed. The proposed system consists of evacuated solar collectors, power generating turbine, high-temperature heat recovery system, low-temperature heat recovery system, and feed pump. The system utilizes evacuated solar collectors to convert CO₂ into high-temperature supercritical state, used to drive a turbine and thereby produce mechanical energy and hence electricity. The system also recovers heat (high-temperature heat and low-temperature heat), which could be used for refrigeration, air conditioning, hot water supply, etc. in domestic or commercial buildings. An experimental prototype has been designed and constructed. The prototype system has been tested under typical summer conditions in Kyoto, Japan; It was found that CO₂ is efficiently converted into high-temperature supercritical state, of while electricity and hot water can be generated. The experimental results show that the solar energy powered Rankine cycle using CO₂ works stably in a trans-critical region. The estimated power generation efficiency is 0.25 and heat recovery efficiency is 0.65. This study shows the potential of the application of the solar-powered Rankine cycle using supercritical CO₂.     

An experimental study on the organic Rankine cycle to determine as to how efficiently utilize fluctuating thermal energy

Thermal properties of the available energy such as maximum temperature and thermal energy capacity are greatly influenced to the design of energy conversion system like the organic Rankine cycle (ORC). Useful thermal energy can be obtained from: waste heat energy, geothermal energy, solar heat energy, biomass energy, and so on. However, these cannot usually be supplied at constant levels. Hence, the temperature and flowrate of the thermal energy can vary while the ORC is working. In order to efficiently utilize such fluctuating thermal energy, an experimental study was conducted while adjusting the mass flowrate and the temperature of the working fluid. Three supersonic nozzles and an impulse type turbine were applied. The supersonic nozzle was adopted to increase the spouting velocity for efficient operation of the impulse turbine. The nozzle was designed to reach a velocity of Mach 1.6 at the nozzle exit, and three nozzles were used to control the mass flowrate in this experiment. The experimental results were compared with the predicted results obtained by the cycle analysis.     

Pre-combustion, post-combustion and oxy-combustion in thermal power plant for CO2 capture

This paper presents a summary of technical-economic studies. It allows evaluating, in the French context, the production cost of electricity derived from coal and gas power plants with the capture of CO₂, and the cost per tonne of CO₂ avoided. Three systems were studied: an Integrated Gasification Combined Cycle (IGCC), a conventional combustion of Pulverized Coal (PC) and a Natural Gas Combined Cycle (NGCC). Three main methods were envisaged for the capture of CO₂: pre-combustion, post-combustion and oxy-combustion.For the IGCC, two gasification types have been studied: a current technology based on gasification of dry coal at 27 bars (Shell or GE/Texaco radiant type) integrated into a classical combined cycle providing 320 MWe, and a future technology (planned for about 2015–2020) based on gasification of a coal–water mixture (slurry) that can be compressed to 64 bars (GE/Texaco slurry type) integrated into an advanced combined cycle (type H with steam cooling of the combustion turbine blades) producing a gross power output of 1200 MWe.     

太阳能热力发电的生命周期分析

应用生命周期分析法(LCA)，对塔式太阳能热力电站所用设备材料的生产、运输、电站基本建设等3个过程进行了分析，分别计算出3个过程中的能耗及其对环境的影响，并与燃煤发电进行了比较。结果表明．太阳能热力电站每发电10MWh，即可节省能源3．78t标准煤，少向大气排放粉尘、CO2、NOx、SO2分别为498．7，9 933，49．94，78．75kg。太阳能热力发电具有显著的节能和环保效益。     

Optimal operation of an integrated energy system including fossil fuel power generation, CO2 capture and wind

This study considers the optimization of operations for an integrated fossil-renewable energy system with CO₂ capture. The system treated consists of a coal-fired power station, a temperature-swing absorption CO₂ capture facility powered by a natural gas combustion turbine, and wind generation. System components are represented in a modular fashion using energy and mass balances. Optimization is applied to determine hourly system dispatch to maximize operating profit given energy prices and wind generation data. A CO₂ emission constraint, modeled after a California law, is enforced. Idealized and realistic scenarios are considered, along with several different system specifications. For a year of operation, simulated using available wind and energy price data, operating profit for optimized operation is shown to be approximately 20% greater than profit using a heuristic procedure. The benefit from optimization is positively correlated with electricity price variability and mean wind generation. The impact of different component specifications and different CO₂ absorption solvents on the optimal operation of the energy system is also assessed. In total, this study demonstrates that the effective operating cost of an integrated energy system operating under a CO₂ emission constraint can be substantially reduced via optimal flexible operation.     

Solar thermal aided power generation

Fossil fuel based power generation is and will still be the back bone of our world economy, albeit such form of power generation significantly contributes to global CO₂ emissions. Solar energy is a clean, environmental friendly energy source for power generation, however solar photovoltaic electricity generation is not practical for large commercial scales due to its cost and high-tech nature. Solar thermal is another way to use solar energy to generate power. Many attempts to establish solar (solo) thermal power stations have been practiced all over the world. Although there are some advantages in solo solar thermal power systems, the efficiencies and costs of these systems are not so attractive. Alternately by modifying, if possible, the existing coal-fired power stations to generate green sustainable power, a much more efficient means of power generation can be reached. This paper presents the concept of solar aided power generation in conventional coal-fired power stations, i.e., integrating solar (thermal) energy into conventional fossil fuelled power generation cycles (termed as solar aided thermal power). The solar aided power generation (SAPG) concept has technically been derived to use the strong points of the two technologies (traditional regenerative Rankine cycle with relatively higher efficiency and solar heating at relatively low temperature range). The SAPG does not only contribute to increase the efficiencies of the conventional power station and reduce its emission of the greenhouse gases, but also provides a better way to use solar heat to generate the power. This paper presents the advantages of the SAPG at conceptual level.