Monitoring current–voltage characteristics and energy output of silicon photovoltaic modules

Photovoltaic (PV) system designers use performance data of PV modules to improve system design and make systems more cost effective. The collection of this valuable data is often not done due to the high costs associated with data acquisition systems. In this paper, we report on the design of a low-cost current–voltage (I–V) measuring system used to monitor the I–V characteristics of PV modules. Results obtained from monitoring seven crystalline silicon modules between October 2001 and November 2002 are presented and discussed. Results obtained also show the value of being able to continuously monitor the current–voltage characteristics of PV modules.     

退役晶体硅光伏组件的回收技术综述

自2020年起的未来10年,大规模的光伏组件将要退役,如何经济高效地处理废旧光伏组件将成为一大难题.晶体硅光伏组件中的材料种类较多,也难以分离,而且所得到的回收材料价值不高,低于组件回收的成本.但是,若退役晶体硅光伏组件处理不当,将会对生态环境造成极端恶劣的影响.晶体硅光伏组件在土壤中很难降解,如果只是简单的掩埋处理,...     

Energy matrices analysis of hybrid PVT greenhouse dryer by considering various silicon and non-silicon PV modules

In this paper, a study was carried out to evaluate the annual thermal and exergy performance of hybrid photovoltaic-thermal greenhouse dryer, located at IIT Delhi, India by considering various silicon and non-silicon-based photovoltaic (PV) modules namely mono crystalline silicon (c-Si), multi crystalline silicon (mc-Si), nano crystalline silicon, amorphous silicon, Cadmium Telluride and Copper Indium Gallium Selenide. The annual net electrical energy savings for these modules for a, b, c and d type weather conditions for New Delhi has been calculated. Embodied energy and annual energy outputs have been used for evaluation of energy matrices such as energy payback time, electricity production factor (EPF) and life cycle conversion efficiency (LCCE) of the system. The results also showed that EPF, LCCE, CO ₂ mitigations and carbon credits earned, were maximum for c-Si-type PV module, and hence it was recommended for the proposed system.     

非晶硅与晶硅太阳电池在太阳能光伏发电应用中热性能的研究

对在北京地区屋面上固定角度安装(目前光伏发电应用中最常见的安装形式)的非晶硅和多晶硅太阳电池组件进行了近二年的数据采集,纪录了北京地区温度数据和太阳电池阵列的实际发电量,分析了它们各自的特点,为用户更为关心的户外使用情况提供了参考依据;认为如果仅从温度特性考虑,是否采用非晶硅替代晶体硅电池在不同地区应有不同考虑,如果再考虑到人们普遍认为的非晶硅电池没有解决的稳定性问题,表面玻璃的非钢化、效率低等其它问题,非晶硅的使用应慎重,不应盲从.同时在使用中不论何种电池都不应忽视组件的通风问题.     

A power-rating model for crystalline silicon PV modules

A model for the performance of generic crystalline silicon photovoltaic (PV) modules is proposed. The model represents the output power of the module as a function of module temperature and in-plane irradiance, with a number of coefficients to be determined by fitting to measured performance data from indoor or outdoor measurements. The model has been validated using data from 3 different modules characterized through extensive measurements in outdoor conditions over several seasons. The model was then applied to indoor measurement data for 18 different PV modules to investigate the variability in modeled output from different module types. It was found that for a Central European climate the modeled output of the 18 modules varies with a standard deviation (SD) of 1.22%, but that the between-module variation is higher at low irradiance (SD of 3.8%). The variability between modules of different types is thus smaller than the uncertainty normally found in the total solar irradiation per year for a given site. We conclude that the model can therefore be used for generalized estimates of PV performance with only a relatively small impact on the overall uncertainty of such estimates resulting from different module types.     

Calculation of the PV modules angular losses under field conditions by means of an analytical model

Photovoltaic (PV) modules in real operation present angular losses in reference to their behaviour in standard test conditions, due to the angle of incidence of the incident radiation and the surface soil. Although these losses are not always negligible, they are commonly not taken into account when correcting the electrical characteristics of the PV module or estimating the energy production of PV systems. The main reason of this approximation is the lack of easy-to-use mathematical expressions for the angular losses calculation. This paper analyses these losses on PV modules and presents an analytical model based on theoretical and experimental results. The proposed model fits monocrystalline as well as polycrystalline and amorphous silicon PV modules, and contemplates the existence of superficial dust. With it angular losses integrated over time periods of interest can be easily calculated. Monthly and annual losses have been calculated for 10 different European sites, having diverse climates and latitudes (ranging from 32° to 52°), and considering different module tilt angles.     

Present status and future of crystalline silicon solar cells in Japan

Crystalline silicon solar cells show promise for further improvement of cell efficiency and cost reduction by developing process technologies for large-area, thin and high-efficiency cells and manufacturing technologies for cells and modules with high yield and high productivity.In this paper, Japanese activities on crystalline Si wafers and solar cells are presented. Based on our research results from crystalline Si materials and solar cells, key issues for further development of crystalline Si materials and solar cells will be discussed together with recent progress in the field. According to the Japanese PV2030 road map, by the year 2030 we will have to realize efficiencies of 22% for module and 25% for cell technologies into industrial mass production, to reduce the wafer thickness to 50–100 μm, and to reduce electricity cost from 50 Japanese Yen/kWh to 7 Yen/kWh in order to increase the market size by another 100–1000 times.     

非晶硅太阳能光伏/光热空气集热器性能对比实验研究

文章设计了新型非晶硅太阳能PV/T空气集热器,该空气集热器能够解决传统太阳能PV/T热水器在高温波动情况下,晶硅电池热应力大的问题,同时避免了冬季管道发生霜冻的现象。文章通过实验对比,分析了非晶硅太阳能PV/T空气集热器、单独非晶硅光伏电池和传统太阳能空气集热器的能量效率和[火用]效率的差异。分析结果表明:非晶硅太阳能PV/T空气集热器的平均热效率为45.70%,比传统太阳能空气集热器的平均热效率降低了约25.88%;当空气质量流量增大至0.048 kg/s时,非晶硅太阳能PV/T空气集热器中的非晶硅光伏电池的平均电效率高于单独非晶硅光伏电池,它们的平均电效率分别为4.70%,4.54%;非晶硅太阳能PV/T空气集热器的总[火用]效率高于传统太阳能空气集热器的热[火用]效率和单独非晶硅光伏电池的电[火用]效率,非晶硅太阳能PV/T空气集热器总[火用]效率最大值为7.14%。文章的分析结果为非晶硅太阳能PV/T空气集热器的推广提供了参考。     

Conformal thin film silicon photovoltaic modules

A polymer composite material system and a process for encapsulation of thin film solar cells were developed for profiled roofing elements, in view of building-integrated photovoltaic (PV) applications. Amorphous silicon cells were deposited on a polyethylene naphthalate film and encapsulated with additional polymer layers in the form of a flat laminate using industrial processes. The process technology developed in this work included a pre-forming step of the PV laminate and a moulding step of a glass fibre-reinforced polyester composite. These two steps were optimised using thermo-elastic analyses, with attention paid to laminate designs and process windows compatible with the thermo-mechanical limits of the fragile active PV layers. A demonstrator with standard 1.0 m×1.8 m corrugated roofing profile, a weight of 6.3 kg and 60 W of output power was produced. The long-term endurance of the conformal modules was also validated using humidity-freeze, damp-heat and water immersion tests.     

Impact of environment factors on solar cell parameters of a-Si∥μc-Si photovoltaic modules

The behavior of amorphous silicon∥micro crystalline silicon (a-Si∥μc-Si) tandem-type photovoltaic (PV) module is complex because the output current is limited by the lower current component cell. Also, the outdoor behaviors are not fully understood. The impact of environment factors on solar cell parameters of a-Si∥μc-Si PV module was quantitatively analyzed and the module was compared with other silicon-based PV modules (single crystalline silicon (sc-Si) and amorphous silicon (a-Si)). The contour maps of solar cell parameters were constructed as a function of irradiance and module temperature. The contour map of a-Si∥μc-Si PV modules is similar to that of a-Si modules. The results imply that output characteristics of a-Si∥μc-Si PV modules are mainly influenced by the a-Si top cell. Furthermore, the efficiency of a-Si∥μc-Si PV modules was compared other solar cell parameters and the contour map of efficiency is similar to that of fill factor.     

Germanium-doped Czochralski silicon for photovoltaic applications

Germanium (Ge)-doped Czochralski (GCZ) silicon has been grown for photovoltaic (PV) applications. It is found that Ge doping improves the mechanical strength of CZ silicon, resulting in the reduction of breakage during wafer cutting, cell fabrication and module assembly. Boron-oxygen (B-O) defects that lead to the light-induced degradation (LID) of carrier lifetime are effectively suppressed by Ge doping. The decrease in the maximum concentration of B-O defects increases with an increase of Ge concentration. The efficiency of GCZ silicon solar cells and the power output of corresponding PV modules both exhibit smaller loss under sunlight illumination. The current work suggests that GCZ silicon should be potentially a novel substrate for thin solar cells with low LID effect.     

Porous silicon Bragg mirrors on single- and multi-crystalline silicon for solar cells

Porous silicon Bragg mirrors at back-side of single crystalline and multicrystalline silicon solar cell were numerically simulated by transfer matrix method. It allows to choose the optimal parameters of porous stack of bi-layers (indexes of refraction, number of bi-layers) when the increase of photon absorption in 900–1050 nm spectral region is achieved. Application of Bragg mirrors at back-side of single crystalline solar cell can improve the efficiency on more than 0.8% in absolute for 200 μm both-side textured thickness wafer. The simulated results were compared with characteristics of Bragg mirrors fabricated by electrochemical etching of single- and multi-crystalline silicon. It is shown that despite the natural crystallites disorientation the efficient Bragg mirrors can be fabricated on multicrystalline silicon wafers in such way. Maximum measured reflectivity for Bragg mirrors on multicrystalline substrate achieves approximately 62%, whereas for single crystalline silicon the reflectivity in maximum is more than 90%.     

Spatial and orientational distribution of cracks in crystalline photovoltaic modules generated by mechanical load tests

Cracks in crystalline silicon solar cells influence the photovoltaic (PV) module power output in accelerated aging tests. A detailed insight into the formation of cracks offers the potential to optimize the PV module design in order to reduce the risk of power degradation in its lifetime. In this paper we present a statistical analysis on the crack formation in 27 crystalline silicon PV modules caused by a standard mechanical load test according to IEC 61215 10.16. The criticality of cracks depends strongly on the crack orientation, therefore we analyze both the spatial distribution of cracks and its dependence on the orientation of the cracks in the tested PV modules. We find that 50% of the damaged cells are cracked parallel to the busbars, which is a crack orientation with high potential impact on the power output of the PV module. A simplified numerical analysis is used to give an explanation for the statistical data and we propose a strategy for the reduction of the crack criticality.     

An evaluation on the life cycle of photovoltaic energy system considering production energy of off-grade silicon

In this study, single-crystalline silicon (c-Si) photovoltaic (PV) cells and residential PV systems using off-grade silicon supplied from semiconductor industries were evaluated from a life cycle point of view. Energy payback time (EPT) of the residential PV system with the c-Si PV cells made of the off-grade silicon was estimated at 15.5 years and indirect CO₂ emission per unit electrical output was calculated at 91 g-C/kWh even in the worst case. These figures were more than those of the polycrystalline-Si and the amorphous-Si PV cells to be used in the near future, but the EPT was shorter than its lifetime and the indirect CO₂ emissions were less than the recent average CO₂ emissions per kWh from the utilities in Japan. The recycling of the c-Si PV cells should be discussed for the reason of the effective use of energy and silicon material.     

Application and validation of algebraic methods to predict the behaviour of crystalline silicon PV modules in Mediterranean climates

Predicting both PV module and generator performances under natural sunlight is a key issue for designers and installers. Five simple algebraic methods addressed to predict this behaviour in Mediterranean climates have been empirically validated. Firstly, the calibration in STC of all significant electrical parameters of both a monocrystalline and a polycrystalline silicon PV modules was entrusted to an accredited independent laboratory. Then, a 12-month test and measurement campaign carried out on these modules in the city of Jaén (Spain, latitude 38°N, longitude 3°W) has provided the necessary experimental data. Results show that (a) crystalline silicon PV module outdoors performance may be described with sufficient accuracy – for PV engineering purposes – only taking into account incident global irradiance, cell temperature, and using any one of two simple algebraic methods tried in this paper and (b) regardless the used method, poor results may be achieved if the PV specimens under study are not electrically characterised in STC prior to analysing their outdoors performance. Even so, the methods recommended in (a) perform best.     

Ten years outdoor operation of silicon based photovoltaic modules at central latitude of Japan

For the estimation of energy output from photovoltaic (PV) modules, considering the impact of degradation is essential. In this study, the longtime outdoor performance of various types of silicon-based PV modules [single crystalline Si (sc-Si), multi crystalline Si (mc-Si), amorphous Si (a-Si), a-Si/micro crystalline Si tandem, and a-Si/a-SiGe/a-SiGe three-stack (3-stack)] which were installed at the same outdoor exposure condition in Shiga Prefecture, Japan were investigated using Performance Ratio (PR) as an index of performance of PV modules for ten years from 2000 to 2009. Yearly PR and monthly PR were analyzed and degradation rates (DR) were calculated. The DR was different on the kinds of PV modules from 0.404 to 3.51%/year. The a-Si PV module showed the largest DR and the 3-stack PV module had the least trend to degrade. The analysis of the monthly DR indicated that the high DR of the a-Si PV module was due to the quite large DR in summer, whereas the monthly DR of sc-Si and mc-Si PV modules did not differ much from each other throughout the years.     

Electrical and optical characterization of crystalline silicon/porous silicon heterojunctions

We have investigated the photovoltage and photocurrent spectra of crystalline silicon/porous silicon heterojunctions. The porous silicon layers were prepared using anodic etching of p-type crystalline silicon at a current density of 25 mA/cm². From the spectral dependence of the photovoltage and photocurrent, we suggest that the photovoltaic properties of the junction are dominated by absorption in crystalline silicon only. We have also studied the effect of increase in the thickness of porous silicon layers on these spectra. We find that the open-circuit voltage of the devices increases, but the short-circuit current decreases with an increase in the thickness of the porous silicon layers. We propose a qualitative explanation for this trend, based on the increase in the series and the shunt resistance of these devices. The effect of hydrogen passivation on the junction properties by exposing the devices to hydrogen plasma is also reported.     

Thermal treatment of waste photovoltaic module for recovery and recycling: Experimental assessment of the presence of metals in the gas emissions and in the ashes

The rapid expansion of the photovoltaic (PV) module market in the last years will determine in the near future a remarkable growth of corresponding waste. Then, the hazardous materials contained in the modules, such as Cd, Pb and Cr, could be released in the environment if the waste panels will not be handled adequately. Recycling processes of silicon crystalline panels, finalized to separate PV cells from the glass, involve the removal of the EVA (Ethylene Vinyl Acetate) layer through different methods, as the thermal treatment. During this treatment, some hazardous components can be released due to thermal degradation process. In this paper the metals released in the gas emissions and in the ashes due to the thermal treatment of modules were evaluated. For this purpose, three samples of crystalline panels were heated in furnace up to 600 °C and the complete degradation of the EVA was obtained. A mass balance between the sample and its components, before and after treatment, was performed in order to assess the weight loss percentage. Finally, after thermal treatment a qualitative analysis on the separated PV cell surface was performed by SEM-EDS (Scanning Electron Microscope equipped with Energy Dispersive Spectrometer).     

Fabrication of nanoporous antireflection surfaces on silicon

After the surface of a silicon wafer has been texturized, the reflectance of the wafer surface can be reduced to increase the power generation efficiency of a silicon-based solar cell. This study presents the integration of self-assembled nanosphere lithography (SANSL) and photo-assisted electrochemical etching (PAECE) to fabricate a nanostructure array with a high aspect ratio on the surface of silicon wafer, to reduce its reflectance. The experimental results show that the etching depth of the fabricated nanopore array structure is about and its diameter is about 90 nm, such that the aspect ratio of the pore can reach about 68:1. The weighted mean reflectance of a blank silicon wafer is 40.2% in the wavelength range of 280-890 nm. Five-minute PAECE without SANSL reduces the weighted mean reflectance to 5.16%. Five-minute PAECE with SANSL reduces the weighted mean reflectance to 1.73%. Further coating of a 200 Å thick silicon nitride layer on the surface of a nanostructure array reduces the weighted mean reflectance even to 0.878%. The novel fabrication technology proposed in this study has the advantage of being low cost, and the fabricated nanostructure array can be employed as an antireflection structure in single crystalline silicon solar cells.     

Large area multicrystalline silicon solar cells in high volume production environment—history, status, new processes, technology transfer issues

Cast multicrystalline silicon (mc-Si) solar cell technology, accounted for nearly 41% of all the PV modules manufactured worldwide in 2000. Since 1995 the use of cast mc-Si as a substrate has increased every year and that increase is expected to accelerate in the coming years as the PV market grows further. This impressive growth has been enabled by several factors—wafer suppliers, improvements in casting technology, sawing technology and cell process technology. In this paper the enabling factors will be discussed. The new processes used to enhance the efficiency of the cast multicrystalline silicon solar cells and the criteria for technology transfer will also be discussed.