过硫磷石膏矿渣水泥混凝土耗酸量控制方法研究

过硫磷石膏矿渣水泥混凝土中硅酸盐水泥的掺量对其性能影响极大,掺量过高后期强度将大幅度下降,掺量过低早期强度将会很低。该文通过试验发现:控制过硫磷石膏矿渣水泥混凝土中PSC浆的耗酸量,可以有效控制过硫磷石膏矿渣水泥混凝土中硅酸盐水泥的适宜配比,显著提高过硫磷石膏矿渣水泥混凝土的性能。过硫磷石膏矿渣水泥混凝土中的PSC浆滤液耗酸量应控制0.10~0.25mmol/g之间。     

基于矿渣微粉配制高性能混凝土试验研究

通过使用矿渣微粉等量替代混凝土中的普通硅酸盐水泥试验分析,研究矿渣微粉替代量对混凝土和易性和强度的影响,以及龄期对抗压强度和抗拉强度的影响。试验结果表明:矿渣微粉可以有效改善混凝土拌合物的保水性和黏聚性,提高混凝土的后期强度;低掺量(≤40%)矿渣微粉混凝土早期强度大于基准混凝土(掺量0);掺矿渣微粉混凝土的强度随着掺量的增加而降低。     

矿渣超量取代水泥高性能混凝土性能研究

研究了矿渣超量取代对水泥混凝土抗压强度、氯离子渗透性、气体渗透性和干燥收缩的影响。研究发现．矿渣等量取代30％水泥配制高性能混凝土．混凝土强度和渗透性最优;等量取代混凝土早期强度低,并且随矿渣掺量增加而下降。矿渣超量取代技术能有效提高矿渣大掺量混凝土早期强度。超量取代技术不仅能提高矿渣等量取代水泥混凝土强度,而且更能改善混凝土氯离子渗透性能和气体渗透性．最佳超代系数为1．3。矿渣超量取代水泥混凝土虽然增大了矿渣掺量．但并不会增大混凝土干燥收缩。     

矿渣粉颗粒级配、掺量的优化研究

研究掺入超细矿渣粉,改善水泥颗粒级配对水泥胶砂及混凝土的工作性、强度和耐久性的影响结果表明:矿渣粉细度大于P600,掺量不高于30%,可提高砂浆和混凝土的强度;适当提高矿渣粉的细度和掺量,可以改善混凝土抗氯离子指标;综合考虑工作性、强度、耐久性和经济性,配制高强及高性能混凝土适宜掺加10%～20%的P800型矿渣粉.     

矿渣及粉煤灰混凝土力学性能试验研究

将矿渣和粉煤灰分别等掺量替代水泥,制备了矿渣混凝土和粉煤灰混凝土立方体试件,检测了不同龄期的混凝土抗压强度,探讨了其力学性能变化规律,试验结果表明:在等量替代水泥的情况下,矿渣混凝土比粉煤灰混凝土的抗压强度大;粉煤灰混凝土的后期强度比普通混凝土大;矿渣、粉煤灰混凝土随着掺量的增大,其强度均不断降低。     

高掺量矿渣水泥配制高性能混凝土的研究

本文论述了用70%掺量的矿渣水泥配制高性能混凝土的性能试验和研究,包括混凝土强度、流动性、耐久性能的试验研究,同时与普通硅酸盐水泥配制的混凝土作了对比试验。试验结果表明,用高掺量矿渣水泥配制的高性能混凝土的力学性能和耐久性能优于普通硅酸盐水泥配制混凝土,而高掺量矿渣水泥在生产过程的能耗和污染物排放明显低于普通硅酸盐水泥.     

蒸养温度对单掺粉煤灰和矿渣蒸养混凝土性能的影响

研究了60、80℃蒸养条件下大掺量粉煤灰和矿渣蒸养混凝土力学性能、氯离子渗透性和体积稳定性,并分析了粉煤灰和矿渣的反应程度。试验结果表明,60℃蒸养条件下,混凝土早期强度在矿渣掺量大时略微增强,粉煤灰掺量大时显著降低,但两者的后期强度均仅略低于纯水泥混凝土。而80℃蒸养条件下,大掺量粉煤灰试块早期强度得到改善,大掺量矿渣却使得早期强度有所降低,3种混凝土的后期强度均有所下降,但粉煤灰和矿渣混凝土强度劣化程度低于纯水泥混凝土。主要是因为粉煤灰与矿渣可缓解钙矾石延迟生成,提升混凝土的抗氯离子渗透性和体积稳定性,改善蒸养混凝土的耐久性。     

矿渣微粉掺合料对水泥胶砂强度和流变性能的影响

根据泵送混凝土的特点以及对原材料的要求,分析了不同替代量和不同品种的矿渣微粉掺合料对水泥胶砂强度和混凝土工作性的影响。在适当的掺量范围内,水泥胶砂强度和混凝土工作性随着矿渣微粉掺合料掺量的增加而增加。     

矿渣微粉掺合料对水泥胶砂强度和流变性能的影响

根据泵送混凝土的特点以及对原材料的要求,分析了不同替代量和不同品种的矿渣微粉掺合料对水泥胶砂强度和混凝土工作性的影响。在适当的掺量范围内,水泥胶砂强度和混凝土工作性随着矿渣微粉掺合料掺量的增加而增加。     

矿渣混凝土的长期强度和抗冻融耐久性研究

通过试验研究,探讨了不同强度等级的矿渣混凝土和普通混凝土在７ ｄ,２８ ｄ,９０ ｄ,１８０ｄ,３６５ ｄ 龄期的抗压强度,研究了矿渣混凝土的抗冻融耐久性．试验表明,强度等级、养护条件、矿渣掺量等因素对矿渣混凝土的强度、抗冻融耐久性有着显著的影响;矿渣混凝土的抗冻融耐久性明显优于同等级的普通混凝土;矿渣掺量愈大,矿渣混凝土的抗冻融耐久性愈差     

粉煤灰掺量对高性能混凝土强度和耐久性的影响

本文着重研究了粉煤灰掺量对于高性能混凝土强度、氯离子渗透性的影响。水胶比为0．28,粉煤灰掺量在40％以内,可以配制出早期、后期强度均高于不掺粉煤灰、而水泥用量高达600kg/m^3的纯硅酸盐水泥混凝土的相应强度,这种配合比的混凝土28d强度在80MPa以上;并且流动性好,可以满足泵送需要;抗渗性好,属于渗透性“很低”的等级;对于高性能混凝土强度而言,有一个较优的粉煤灰掺量,约为20％－30％;早期强度对应的粉煤灰较优掺量约为10％左右。     

Splitting tensile strength of concrete using ground granulated blast furnace slag and SiO2 nanoparticles as binder

In the present study, split tensile strength together with pore structure, thermal behavior and microstructure of concrete containing ground granulated blast furnace slag and SiO₂ nanoparticles have been investigated. Portland cement was replaced by different amounts of ground granulated blast furnace slag and the properties of concrete specimens were measured. Although it negatively impacts the properties of concrete at early ages, ground granulated blast furnace slag was found to improve the physical and mechanical properties of concrete up to 45 wt% at later ages. SiO₂ nanoparticles with the average particle size of 15 nm were partially added to concrete with the optimum content of ground granulated blast furnace slag and physical and mechanical properties of the specimens were studied. SiO₂ nanoparticle as a partial replacement of cement up to 3 wt% could accelerate C-S-H gel formation as a result of increased crystalline Ca(OH)₂ amount at the early age of hydration and hence increase split tensile strength of concrete specimens. The increased the SiO₂ nanoparticles’ content more than 3 wt% causes the reduced the split tensile strength because of the decreased crystalline Ca(OH)₂ content required for C-S-H gel formation. SiO₂ nanoparticles could improve the pore structure of concrete and shift the distributed pores to harmless and few-harm pores.     

钢渣复合掺合料配制混凝土的工作性能与力学性能研究

研究了钢渣复合掺合料配制混凝土的工作性能与力学性能,并从掺合料的相组成、水化特性、形貌特征、稀释效应及体积效应的角度对试验结果进行了综合分析。研究结果表明,不同掺量下钢渣对混凝土工作性能的影响不同,钢渣-矿渣复合掺合料对混凝土的工作性能有明显不利影响；钢渣的早期活性优于矿渣及粉煤灰,后期略低于矿渣但仍明显优于粉煤灰;高掺量下钢渣与矿渣有良好的复合超叠加效应，且二者的最佳比例为3：7。     

重载高抗折强度水泥混凝土的配制及其力学性能研究

本文通过室内试验，研究了使用高效减水剂和粉煤灰、粒化高炉矿渣、沸石粉配制重载作用下高抗折强度水泥混凝土的方法，并分析了不同类型高抗折强度水泥混凝土的力学特性。     

TiO2 nanoparticles effects on physical, thermal and mechanical properties of self compacting concrete with ground granulated blast furnace slag as binder

In this work, strength assessments and percentage of water absorption of self compacting concrete containing different amounts of ground granulated blast furnace slag and TiO₂ nanoparticles as binder have been investigated. Portland cement was replaced by 45 wt% of ground granulated blast furnace slag and up to 4.0 wt% TiO₂ nanoparticles and the properties of concrete specimens were investigated. TiO₂ nanoparticle as a partial replacement of cement up to 3.0 wt% could accelerate C-S-H gel formation as a result of increased crystalline Ca(OH)₂ amount at the early age of hydration and hence increase strength and improve the resistance to water permeability of concrete specimens. Several empirical relationships have been presented to predict flexural and split tensile strength of the specimens by means of the corresponding compressive strength at a certain age of curing.     

Use of binary and ternary blends in high strength concrete

Combinations of cement additions may provide more benefits for concrete than a single one. In this study, 80 high strength concretes containing several types and amounts of additions were produced. In the first stage, silica fume contents in binary blends that give the highest strengths were determined for different binder contents. In the second stage, a third binder (Class F or Class C fly ash or ground granulated blast furnace slag) was introduced to the concretes already containing Portland cement and silica fume in the amounts found in the first stage. Results indicated that ternary blends almost always made it possible to obtain higher strengths than Portland cement + silica fume binary mixtures provided that the replacement level by the additions was chosen properly. Moreover, the performance of slag in the ternary blends was better than Class F fly ash but worse than Class C fly ash.     

The effect of slaked lime,anhydrous gypsum and limestone powder on properties of blast furnace slag cement mortar and concrete

Basic properties of blast furnace slag cement mortar and concrete are investigated by adding inorganic activators. The result of this research concludes that slag cement mixed with suitable activator agents such as lime, gypsum and limestone powder could accelerate the compressive strength and tighten pore structure at early age. The addition of activator into mortar and concrete containing slag cement produces superior properties, reduced shrinkage and less carbonation compared to mortar and concrete containing slag cement without the addition of activator. Consequently, there are possibilities for manufacturing blast furnace slag cement, which could compensate the weak properties at early curing age. When compared with ordinary Portland cement, this cement has superior characteristics for long curing age.     

The effect of curing conditions on compressive strength of ultra high strength concrete with high volume mineral admixtures

In this study, pulverized fly ash (FA), pulverized granulated blast furnace slag (PS) and silica fume (SF) were quantitatively studied with the incorporation of Portland cement (PC). PC was replaced with FA or PS at specified ratios. Basalt and quartz powder were used as an aggregate in the mixtures. Three different curing methods (standard, autoclave and steam curing) were applied to the specimens. Test results indicate that high strength concrete can be obtained with high volume mineral admixtures. Compressive strength of these mixtures is over 170 MPa. It seems that these mixtures can also be used for reactive powder concrete (RPC) production with some modifications.     

Influence of mineral admixtures on compressive strength,gas permeability and carbonation of high performance concrete

Compressive strength, gas permeability and carbonation of high performance concrete (HPC) with fly ash (FA) or ground granulated blast furnace slag (GGBFS) were experimentally investigated and the relationships among them were analyzed. Test results showed that influences of FA with replacement up to 60% on these properties investigated are significantly affected by water–binder (w/b) ratios. However, unlike FA, influences of GGBFS on HPC are little affected by w/b ratios, similar changing trends could be observed for both w/b ratios selected. Moreover, HPC with GGBFS shows much better performance than that with FA at the same w/b ratio. In general, replacing FA/GGBFS with cement could not benefit the properties investigated, especially at the higher w/b ratio selected and relationship between compressive strength and gas permeability of HPC greatly depends on w/b ratios and mineral admixture types. Carbonation is obviously related to gas permeability for both HPC with FA/GGBFS.     

Properties of sustainable concrete containing fly ash,slag and recycled concrete aggregate

The suitability of using more “sustainable” concrete for wind turbine foundations and other applications involving large quantities of concrete was investigated. The approach taken was to make material substitutions so that the environmental, energy and CO₂-impact of concrete could be reduced. This was accomplished by partial replacement of cement with large volumes of fly ash or blast furnace slag and by using recycled concrete aggregate.Five basic concrete mixes were considered. These were: (1) conventional mix with no material substitutions, (2) 50% replacement of cement with fly ash, (3) 50% replacement of cement with blast furnace slag, (4) 70% replacement of cement with blast furnace slag and (5) 25% replacement of cement with fly ash and 25% replacement with blast furnace slag. Recycled concrete aggregate was investigated in conventional and slag-modified concretes. Properties investigated included compressive and tensile strengths, elastic modulus, coefficient of permeability and durability in chloride and sulphate solutions. It was determined that the mixes containing 50% slag gave the best overall performance. Slag was particularly beneficial for concrete with recycled aggregate and could reduce strength losses. Durability tests indicated slight increases in coefficient of permeability and chloride diffusion coefficient when using recycled concrete aggregate. However, values remained acceptable for durable concrete and the chloride diffusion coefficient was improved by incorporation of slag in the mix. Concrete with 50% fly ash had relatively poor performance for the materials and mix proportions used in this study and it is recommended that such mixes be thoroughly tested before use in construction projects.