Numerical model to analyze Nox reduction by ammonia injection in diesel-hydrogen engines

Nowadays, the even increasing stringent environmental legislations have promoted interest in alternative fuels for internal combustion engines. Particularly, hydrogen is becoming a promising fuel due to its high specific energy and low emissions production. Environmentally, the main disadvantage of hydrogen is the high level of nitrogen oxides (NO_x) which produces. In this regard, this work proposes a NO_x reduction method which consists on direct injection of ammonia (NH₃) into the combustion chamber. A numerical model validated with experimental measurements was carried out to analyze emissions and brake specific consumption in a commercial engine operating with diesel-hydrogen blends. Comparing to diesel operation, a 10% hydrogen content increases a 5.3% the peak pressure and 5.7% the maximum temperature. The CO₂, CO and HC emissions are reduced but NO_x emissions increase up to 18.3%. Several injection instants and ammonia flow rates were analyzed, obtaining more than 70% NO_x reductions with a negligible effect on other emissions and brake specific consumption. It was found that the start of ammonia injection is too critical since the maximum NO_x reduction takes place when the temperature is around 1200 K. The NO_x reduction increases with the ammonia flow rate but an excessive quantity of ammonia can lead to un-reacted ammonia slip to the exhaust.     

An experimental and modelling study of dual fuel aqueous ammonia and diesel combustion in a single cylinder compression ignition engine

The ability of ammonia to act as a hydrogen carrier, without the drawbacks of hydrogen gas-storage costs and low stability-renders it a potential solution to the decarbonisation of transport. This study combines both modelling and experimental techniques to determine the effect of varying the degree of aspiration of ammonium hydroxide (NH₄OH) solution, at different engine loads, in the combustion of a compression ignition engine. Ignition delay was extended as ammonia injection increased, causing an increase in peak in-cylinder temperature, but generally lower combustion quality-increasing incomplete combustion products, while decreasing particle size. The higher peak in-cylinder temperatures generally correlated with higher nitrous oxide (NO_x) emissions in the exhaust, though a fuel-bound nitrogen effect was apparent. Chemical kinetic modelling at equivalent conditions found increasing levels of unburnt ammonia with greater aspiration. Moreover, the ignitability of NH₄OH was found to improve in simulations substituting diesel with hydrogen peroxide direct injection.     

Ammonia as hydrogen carrier for transportation; investigation of the ammonia exhaust gas fuel reforming

In this paper we show, for the first time, the feasibility of ammonia exhaust gas reforming as a strategy for hydrogen production used in transportation. The application of the reforming process and the impact of the product on diesel combustion and emissions were evaluated. The research was started with an initial study of ammonia autothermal reforming (NH₃ – ATR) that combined selective oxidation of ammonia (into nitrogen and water) and ammonia thermal decomposition over a ruthenium catalyst using air as the oxygen source. The air was later replaced by real diesel engine exhaust gas to provide the oxygen needed for the exothermic reactions to raise the temperature and promote the NH₃ decomposition. The main parameters varied in the reforming experiments are O₂/NH₃ ratios, NH₃ concentration in feed gas and gas – hourly – space – velocity (GHSV). The O₂/NH₃ ratio and NH₃ concentration were the key factors that dominated both the hydrogen production and the reforming process efficiencies: by applying an O₂/NH₃ ratio ranged from 0.04 to 0.175, 2.5–3.2 l/min of gaseous H₂ production was achieved using a fixed NH₃ feed flow of 3 l/min. The reforming reactor products at different concentrations (H₂ and unconverted NH₃) were then added into a diesel engine intake. The addition of considerably small amount of carbon – free reformate, i.e. represented by 5% of primary diesel replacement, reduced quite effectively the engine carbon emissions including CO₂, CO and total hydrocarbons.     

Assessing the effects of partially decarbonising a diesel engine by co-fuelling with dissociated ammonia

The proven feasibility of ammonia combustion in compression-ignition engines has led to it being considered as a carbon-free replacement for diesel fuel. Due to its high auto-ignition temperature, however, a more realistic strategy would be to aim for a step-change reduction in carbon emissions by co-fuelling a diesel engine with ammonia. In assessing this strategy, ammonia gas was introduced into the air-intake manifold of a compression-ignition engine, while diesel fuel was injected directly into the cylinder to ignite the mixture. By substituting only 3% of the air intake by ammonia, the diesel consumption and the CO₂ emissions decreased by 15%. The combustion and emission characteristics were then compared when the same percentage of air intake (by mass) was substituted by either dissociated ammonia (a mixture of H₂, N₂ with small percentages of NH₃) or pure hydrogen, to mimic the other possible forms in which the co-fuel can be delivered to the engine. The addition of pure hydrogen resulted in the best engine performance, both in terms of combustion efficiency and regulated emission quality. The thermal combustion efficiency declined by only ∼0.5% when the H₂ was replaced by undissociated ammonia at low load, but N₂O now appeared in the emissions. Co-fuelling the engine with dissociated ammonia may provide the ideal compromise in terms of thermal combustion efficiency and emission quality, while also providing a waste-heat recovery mechanism.     

Effect of hydroxy (HHO) gas addition on performance and exhaust emissions in compression ignition engines

In this study, hydroxy gas (HHO) was produced by the electrolysis process of different electrolytes (KOH_(aq), NaOH_(aq), NaCl_(aq)) with various electrode designs in a leak proof plexiglass reactor (hydrogen generator). Hydroxy gas was used as a supplementary fuel in a four cylinder, four stroke, compression ignition (CI) engine without any modification and without need for storage tanks. Its effects on exhaust emissions and engine performance characteristics were investigated. Experiments showed that constant HHO flow rate at low engine speeds (under the critical speed of 1750 rpm for this experimental study), turned advantages of HHO system into disadvantages for engine torque, carbon monoxide (CO), hydrocarbon (HC) emissions and specific fuel consumption (SFC). Investigations demonstrated that HHO flow rate had to be diminished in relation to engine speed below 1750 rpm due to the long opening time of intake manifolds at low speeds. This caused excessive volume occupation of hydroxy in cylinders which prevented correct air to be taken into the combustion chambers and consequently, decreased volumetric efficiency was inevitable. Decreased volumetric efficiency influenced combustion efficiency which had negative effects on engine torque and exhaust emissions. Therefore, a hydroxy electronic control unit (HECU) was designed and manufactured to decrease HHO flow rate by decreasing voltage and current automatically by programming the data logger to compensate disadvantages of HHO gas on SFC, engine torque and exhaust emissions under engine speed of 1750 rpm. The flow rate of HHO gas was measured by using various amounts of KOH, NaOH, NaCl (catalysts). These catalysts were added into the water to diminish hydrogen and oxygen bonds and NaOH was specified as the most appropriate catalyst. It was observed that if the molality of NaOH in solution exceeded 1% by mass, electrical current supplied from the battery increased dramatically due to the too much reduction of electrical resistance. HHO system addition to the engine without any modification resulted in increasing engine torque output by an average of 19.1%, reducing CO emissions by an average of 13.5%, HC emissions by an average of 5% and SFC by an average of 14%.     

On-board LPG reforming system for an LPG · hydrogen mixed combustion engine

In this study, we evaluated the properties of a reforming catalyst system for generating hydrogen from liquified petroleum gas (LPG) fuel and supplying hydrogen to an LPG engine. The fuel supply system of the LPG engine was modified in order to supply LPG to a reforming catalyst prior to combustion. A test apparatus was also built to evaluate the performance of a reforming catalyst system. Gas chromatography was used to measure H₂, N₂, O₂, CH₄, and CO emissions, while CO₂ emissions were measured using an exhaust gas analyzer. The products concentration of the reforming reactions according to reforming fuel quantity and air flow was analyzed. In actual engine operating conditions, H₂ yield and air flow were proportional, whereas H₂ yield and fuel reforming fuel quantity were inversely proportional. The experimental results of the reforming reaction under various conditions will be used as the basic data for integrating the reforming catalyst system into an actual operating engine.     

In-line adsorption system for reducing cold-start ammonia emissions from engines fueled with ammonia and hydrogen

Ammonia-free emissions from an engine system fueled with ammonia and hydrogen during cold-start and warm-up periods are demonstrated. The fuels are supplied into a single-cylinder test engine under constant-speed conditions. The exhaust system consists of a redox catalyst followed by an in-line adsorber, the latter of which stores the ammonia that flows through the former. The results show that all adsorbers, H-ZSM-5, Cu-ZSM-5, and Pt-ZSM-5, can adsorb ammonia during cold-start conditions although the engine should be operated with retarded spark timing and a high hydrogen ratio because of low combustion efficiency at low coolant temperatures. Cu-ZSM-5 and Pt-ZSM-5 are regenerated after adsorption through their catalytic reactions without ammonia slip. Cu-ZSM-5, which has the largest adsorption capacity among the tested adsorbers, favors lean burn operation for regeneration. Pt-ZSM-5 has the advantage of simple regeneration control.     

Effect of ammonia addition on combustion and emissions performance of a hydrogen engine at part load and stoichiometric conditions

The development of alternative fuels is important in the fight against climate change. Both hydrogen and ammonia are renewable energy sources and are carbon-free combustible fuels. In a recent experimental study, the performance and emission characteristics of a spark-ignition engine burning a premixed hydrogen/ammonia/air mixture were evaluated. The manifold absolute pressure was adjusted to 61 kPa and the engine speed was stabilized at 1300 rpm. The difference between a mixture with a 2.2% volume fraction of ammonia and a pure hydrogen fuel was analyzed in comparison. Specifically, the addition of ammonia increased the ignition delay and flame development periods and reduced the rate of in-cylinder pressure rise. In conjunction with the ignition timing strategy, the addition of ammonia did not affect the engine performance. Nitrogen oxides emissions are increased due to the addition of ammonia. The experimental results suggest that ammonia can be used as a combustion inhibitor, which provides a new reference for the development of hydrogen-fuelled engines.     

Assessment of the co-combustion process of ammonia with hydrogen in a research VCR piston engine

The presented work concerns experimental research of a spark-ignition engine with variable compression ratio (VCR), adapted to dual-fuel operation, in which co-combustion of ammonia with hydrogen was conducted, and the energy share of hydrogen varied from 0% to 70%. The research was aimed at assessing the impact of the energy share of hydrogen co-combusted with ammonia on the performance, stability and emissions of an engine operating at a compression ratio of 8 (CR 8) and 10 (CR 10). The operation of the engine powered by ammonia alone, for both CR 8 and CR 10, is associated with either a complete lack of ignition in a significant number of cycles or with significantly delayed ignition and the related low value of the maximum pressure p_max. Increasing the energy share of hydrogen in the fuel to 12% allows to completely eliminate the instability of the ignition process in the combustible mixture, which is confirmed by a decrease in the IMEP uniqueness and a much lower p_max dispersion. For 12% of the energy share of hydrogen co-combusted with ammonia, the most favorable course of the combustion process was obtained, the highest engine efficiency and the highest IMEP value were recorded. The conducted research shows that increasing the H₂ share causes an increase in NO emissions, for both analyzed compression ratios.     

Comparative assessments of two integrated systems with/without fuel cells utilizing liquefied ammonia as a fuel for vehicular applications

In the current study, two different integrated systems for vehicular applications are presented and thermodynamically analyzed. The first system consists of liquefied ammonia tank, dissociation and separation unit (DSC) for decomposition of ammonia and an internal combustion engine (ICE) to power the vehicle. The second system is a hybrid system consisting of liquefied ammonia tank, DSC unit, a small ICE and a fuel cell system. In the second system, the main power unit is fuel cell and a supplementary internal combustion engines is also utilized. The exhaust gasses emitted from the ICE are used to provide the required heat for the thermal decomposition process of ammonia. The ICE is fueled with a mix of ammonia and hydrogen generated from the DSC unit that is installed in the two systems. Hydrogen generated from DSC unit will be utilized to operate fuel cell installed in system 2. The proposed systems are analyzed and assessed both energetically and exergetically. A comprehensive parametric study is carried out for comparative assessments to determine the influence of altering design and operating parameters such as the amount of ammonia fuel supplied to the two systems on the performance of the two systems. The overall energy and exergy efficiencies for system 1 and system 2 are found to be 61.89%, 63.34%, 34.73% and 38.44% respectively. The maximum exergy destruction rate in the two systems occurred in the ICE.     

Exergoeconomic analysis and optimization of a new hybrid fuel cell vehicle

This paper introduces thermodynamic and economic analyses on a newly developed energy system for powering hybrid vehicles based on both energy and exergy concepts. The proposed hybrid propulsion system incorporates a liquefied ammonia tank, ammonia dissociation and separation unit (DSU), an internal combustion engine (ICE), and a fuel cell (FC) system. The exhaust gases released from the ICE are exploited to supply the necessary thermal energy to decompose ammonia thermally into hydrogen and nitrogen on board. The ICE is fuelled with a blend of ammonia and hydrogen generated from the DSU. The additional hydrogen released from the DSU will also be provided to the fuel cell system to run the FC and generate electric power, which will be supplied to the electric motor to provide the required traction to the vehicle. An optimization study is also performed to identify optimum design variables. The parametric studies are included in this investigation to evaluate the influence of varying the different operational parameters on the system energy and exergy efficiencies and both total cost rate and exergoeconomic factor values of the system.     

Performance assesment of hydrogen and ammonia combustion with various fuels for power generators

This paper proposes the use of hydrogen and ammonia as possible fuels for power generators and to do so the combustion is modelled by using different types of fuels which are; hydrogen, gasoline, diesel, ethanol, methanol, propane, butane and natural gas to see the effects of these fuel sources on combustion. The main aim of using a clean fuel is to decrease the greenhouse emissions, and by looking at the results, the reduction in CO₂ emissions shows that blending hydrogen and ammonia will result in a reduction for the deleterious emissions occurring after combustion. The reason behind using a dual fueled system is to make use of the secondary fuel source as a combustion promoter to help increase the low flame temperatures of ammonia that causes it not to ignite when used solely. In the modelling of combustion the maximum power output is set to 3.65 kW as this is the maximum power output for the power generator used in the experimental studies. In the studies the increase of clean fuel percentage in the fuel blend cause a reduction in the performance measures as expected with the lower energy density and lower heating values that ammonia offers but the reduction in CO₂ and NO_x emissions makes it a fuel source worth using with a combustion promoter.     

Role of mixture richness,spark and valve timing in hydrogen-fuelled engine performance and emission

The use of hydrogen as an engine fuel has a great potential for reducing exhaust emissions. With the exception of a little amount of hydrocarbon emissions originating from the lubricating oil, NO_x is the only pollutant emitted. The special properties of hydrogen compel much more study on hydrogen internal combustion engines (ICEs). Studying and analyzing the behavior of hydrogen ICE and its sensitivity to controllable parameters can help designers to have better understanding over hydrogen characteristics and its combustion in an ICE. In this paper, firstly a quasi-dimensional two-zone thermodynamic model of an SI hydrogen ICE is developed and validated by experimental data. The model is used as an engine simulator. Spark advance (SA), air to fuel ratio and valve timing are selected as the main effective and controllable parameters on engine emissions and performance characteristics. Valve timing parameter is defined as the intake and exhaust valves' lift, opening time and duration. Secondly, the effects of variation of the mentioned three parameters on emission and performance characteristics of the modeled engine are illustrated. Finally, the reasons of the engine behavior and characteristics under variations of these parameters are fully discussed.     

Influence of operating parameters on performance and emissions for a compression-ignition engine fueled by hydrogen/diesel mixtures

Hydrocarbon exhaust emissions are mainly recognized as a consequent of carbon-based fuel combustion in compression ignition (CI) engines. Alternative fuels can be coupled with hydrocarbon fuels to control the pollutant emissions and improve the engine performance. In this study, different parameters that influence the engine performance and emissions are illustrated with more details. This numerical work was carried out on a dual-fuel CI engine to study its performance and emission characteristics at different hydrogen energy ratios. The simulation model was run with diesel as injected fuel and hydrogen, along with air, as inducted fuel. Three-dimensional CFD software for numerical simulations was implemented to simulate the direct-injection CI engine. A reduced-reaction mechanism for n-heptane was considered in this work instead of diesel. The Hiroyasu-Nagel model was presented to examine the rate of soot formation inside the cylinder. This work investigates the effect of hydrogen variation on output efficiency, ignition delay, and emissions. More hydrogen present inside the engine cylinder led to lower soot emissions, higher thermal efficiency, and higher NO_x emissions. Ignition timing delayed as the hydrogen rate increased, due to a delay in OH radical formation. Strategies such as an exhaust gas recirculation (EGR) method and diesel injection timing were considered as well, due to their potential effects on the engine outputs. The relationship among the engine outputs and the operation conditions were also considered.     

Theoretical investigation of the combustion performance of ammonia/hydrogen mixtures on a marine diesel engine

Ammonia is a good hydrogen carrier and can be well combined with hydrogen for combustion. The combustion performance of the mixtures of ammonia and hydrogen in a medium-speed marine diesel engine was investigated theoretically. The HCCI combustion mode was selected for reducing thermal-NO_x production. The start fire characteristic of the NH₃–H₂ mixtures was studied under different equivalence ratio, hydrogen-doped ratio, and intake air temperature and pressure. Then, the combustion performance of the NH₃–H₂ mixtures (doping 30% hydrogen) was analyzed at a typical operation condition of engine. The addition hydrogen improved the laminar flame velocity of ammonia, and affected the NO_x emission. For the medium-speed marine engine fueled with NH₃–H₂, reducing combustion temperature, introducing EGR and combining with post-treatment technology would be a feasible scheme to reduce NO_x emission.     

Numerical investigation and Pareto optimization on performance,emission and in-cylinder reforming characteristics for two cylinder reciprocating engine with COx free fuel

The main objective of this study is to introduce the applicability of ammonia to the downsized compression ignition diesel engine for power generation or range extender. For this research objective, the two cylinder engine, which was the result of the previous study, fueled with diesel-ammonia blends was considered and the performance and NOx emission tendency were identified using the numerical method. Ammonia was mixed with diesel via injection at a specific fuel energy fraction (0%, 5%, 10%, or 15%) to evaluate the engine performance and emission characteristics. In addition, concept of “in-cylinder reforming” was introduced adopting negative valve overlap (NVO) by advancing the exhaust valve closing time to investigate the effect of adding ammonia as a hydrogen carrier. Subsequently, the primary variables affecting the brake-specific fuel consumption and NO_X are determined via multi-objective Pareto analysis. The optimal Pareto front confirms that exhaust valve timing exerts a greater effect on the performance and emissions than injection timing. Moreover, in-cylinder reformed hydrogen was increased under negative valve overlap strategy.     

The effects of hydrogen on the combustion,performance and emissions of a turbo gasoline direct-injection engine with exhaust gas recirculation

The effects of hydrogen on the combustion characteristics, thermal efficiency, and emissions of a turbo gasoline direct-injection engine with exhaust gas recirculation (EGR) were investigated experimentally at brake mean effective pressures of 4, 6, and 8 bar at 2000 rpm. Four cases of hydrogen energy fraction (0%, 1%, 3% and 5%) of total fuel energy were studied. Hydrogen energy fraction of total fuel energy was hydrogen energy in the sum of energy of consumed gasoline and added hydrogen. The test results demonstrated that hydrogen addition improved the combustion speed and reduced cycle-to-cycle variation. In particular, cylinder-to-cylinder variation dramatically decreased with hydrogen addition at high EGR rates. This suggests that the operable EGR rate can be widened for a turbo gasoline direct-injection engine. The improved combustion and wider operable EGR rate resulted in enhanced thermal efficiency. However, the turbocharging effect acted in opposition to the thermal efficiency with respect to the EGR rate. Therefore, a different strategy to improve the thermal efficiency with EGR was required for the turbo gasoline direct-injection engine. HC and CO₂ emissions were reduced but NO_X emissions increased with hydrogen addition. The CO emissions as a function of engine load followed different trends that depended on the level of hydrogen addition.     

Performance and emission studies on port injection of hydrogen with varied flow rates with Diesel as an ignition source

Automobiles are one of the major sources of air pollution in the environment. In addition CO₂ emission, a product of complete combustion also has become a serious issue due to global warming effect. Hence the search for cleaner alternative fuels has become mandatory. Hydrogen is expected to be one of the most important fuels in the near future for solving the problems of air pollution and greenhouse gas problems (carbon dioxide), thereby protecting the environment. Hence in the present work, an experimental investigation has been carried out using hydrogen in the dual fuel mode in a Diesel engine system. In the study, a Diesel engine was converted into a dual fuel engine and hydrogen fuel was injected into the intake port while Diesel was injected directly inside the combustion chamber during the compression stroke. Diesel injected inside the combustion chamber will undergo combustion first which in-turn would ignite the hydrogen that will also assist the Diesel combustion. Using electronic control unit (ECU), the injection timings and injection durations were varied for hydrogen injection while for Diesel the injection timing was 23° crank angle (CA) before injection top dead centre (BITDC). Based on the performance, combustion and emission characteristics, the optimized injection timing was found to be 5° CA before gas exchange top dead centre (BGTDC) with injection duration of 30° CA for hydrogen Diesel dual fuel operation. The optimum hydrogen flow rate was found to be 7.5 lpm. Results indicate that the brake thermal efficiency in hydrogen Diesel dual fuel operation increases by 15% compared to Diesel fuel at 75% load. The NO_X emissions were higher by 1–2% in dual fuel operation at full load compared to Diesel. Smoke emissions are lower in the entire load spectra due to the absence of carbon in hydrogen fuel. The carbon monoxide (CO), carbon dioxide (CO₂) emissions were lesser in hydrogen Diesel dual fuel operation compared to Diesel. The use of hydrogen in the dual fuel mode in a Diesel engine improves the performance and reduces the exhaust emissions from the engine except for HC and NO_X emissions.     

An experimental investigation on performance and emissions study with port injection using diesel as an ignition source for different EGR flow rates

Exhaust gas recirculation, EGR, is one of the most effective means of reducing NO_x emissions from IC engines and is widely used in order to meet the emission standards. In the present work, experimental investigation has been carried out to study the NO_x reduction characteristics by exhaust gas recirculation in a dual fueled engine using hydrogen and diesel. A single cylinder diesel engine was converted to operate on hydrogen-diesel dual fuel mode. Hydrogen was injected in intake port and diesel was injected directly inside the cylinder. The injection timing and injection duration of hydrogen were optimized initially based on the performance and emissions. It was observed that start of injection at 5° before gas exchange top dead center (BGTDC) and injection duration of 30° crank angle gives the best results. The flow rate of hydrogen was optimized as 7.5 lpm for the best start of injection and injection duration of hydrogen. Cold exhaust gas recirculation technique was adopted for the optimized injection parameter of hydrogen and flow rate. Maximum quantity of exhaust gases recycled during the test was 25% beyond this the combustion was not stable resulting in increase in smoke.     

Performance and combustion characteristic of CI engine fueled with hydrogen enriched diesel

The combustion of hydrogen–diesel blend fuel was investigated under simulated direct injection (DI) diesel engine conditions. The investigation presented in this paper concerns numerical analysis of neat diesel combustion mode and hydrogen enriched diesel combustion in a compression ignition (CI) engine. The parameters varied in this simulation included: H₂/diesel blend fuel ratio, engine speed, and air/fuel ratio. The study on the simultaneous combustion of hydrogen and diesel fuel was conducted with various hydrogen doses in the range from 0.05% to 50% (by volume) for different engine speed from 1000 – 4000 rpm and air/fuel ratios (A/F) varies from 10 – 80. The results show that, applying hydrogen as an extra fuel, which can be added to diesel fuel in the (CI) engine results in improved engine performance and reduce emissions compared to the case of neat diesel operation because this measure approaches the combustion process to constant volume. Moreover, small amounts of hydrogen when added to a diesel engine shorten the diesel ignition lag and, in this way, decrease the rate of pressure rise which provides better conditions for soft run of the engine. Comparative results are given for various hydrogen/diesel ratio, engine speeds and loads for conventional Diesel and dual fuel operation, revealing the effect of dual fuel combustion on engine performance and exhaust emissions.