Hydrogen impacts on performance and CO2 emissions from a diesel power generator

This work investigates the performance and carbon dioxide (CO₂) emissions from a stationary diesel engine fueled with diesel oil (B5) and hydrogen (H₂). The performance parameters investigated were specific fuel consumption, effective engine efficiency and volumetric efficiency. The engine was operated varying the nominal load from 0 kW to 40 kW, with diesel oil being directly injected in the combustion chamber. Hydrogen was injected in the intake manifold, substituting diesel oil in concentrations of 5%, 10%, 15% and 20% on energy basis, keeping the original settings of diesel oil injection. The results show that partial substitution of diesel oil by hydrogen at the test conditions does not affect significantly specific fuel consumption and effective engine efficiency, and decreases the volumetric efficiency by up to 6%. On the other hand the use of hydrogen reduced CO₂ emissions by up to 12%, indicating that it can be applied to engines to reduce global warming effects.     

H2 effects on diesel combustion and emissions with an LPL-EGR system

In this study, we examined H₂ effects on the combustion and emissions of a diesel engine with low-pressure loop (LPL) exhaust gas recirculation (EGR). We converted a 2.2-L four-cylinder direct-injection diesel engine satisfying Euro5 for H₂ supply. An LPL-EGR system replaced the high-pressure loop (HPL) EGR system. For all tests, the brake mean effective pressure (BMEP) was kept at 4 bar and the EGR ratio was varied from 9 to 42%. The H₂ energy percentage was varied from 0 to 7.4% independently to evaluate the H₂ effects and EGR effects separately. The heat release rate was calculated from the measured cylinder pressure. We found that substitution of H₂ for diesel fuel made the premixed burn fraction larger, and reduced the nitrous oxide (NOx) and particulate matter (PM) emissions simultaneously. For example, the NOx emissions were reduced by 36% for an EGR of 42% and an H₂ percentage of 7.4%. PM emissions were reduced by 18% for an EGR of 35% and an H₂ percentage of 7.4% compared with diesel fuel only cases.     

Investigation of the effects of hydrogen on cylinder pressure in a split-injection diesel engine at heavy EGR

The distinctive properties of hydrogen have initiated considerable applied research related to the internal combustion engine. Recently, it has been reported that NO_x emissions were reduced by using hydrogen in a diesel engine at low temperature and heavy EGR conditions. As the continuing study, cylinder pressure was also investigated to determine the combustion characteristics and their relationship to NO_x emissions. The test engine was operated at constant speed and fixed diesel fuel injection rate (1500 rpm, 2.5 kg/h). Diesel fuel was injected in a split pattern into a 2-L diesel engine. The cylinder pressure was measured for different hydrogen flow rates and EGR ratios. The intake manifold temperature was controlled to be the same to avoid the gas intake temperature variations under the widely differing levels (2%-31%) of EGR. The measured cylinder pressure was analyzed for characteristic combustion values, such as mass burn fraction and combustion duration.The rising crank angle of the heat release rate was unaffected by the presence of hydrogen. However, supplying hydrogen extended the main combustion duration. This longer main combustion duration was particularly noticeable at the heavy EGR condition. It correlated well with the reduced NO_x emissions.     

Optimization of exhaust emissions,vibration, and noise of a hydrogen enriched fuelled diesel engine

In this study, the effects of various input parameters are examined on exhaust emissions, vibration, and noise of an unmodified diesel engine. The primary aim of this study is to optimize the vibration, noise, and exhaust emissions of the engine to get optimal configuration parameters. Experiments were carried out on a four-stroke, four-cylinder, diesel engine fuelled with diesel-biodiesel-hydrogen blends. To minimize the number of experiments Box-Behnken design (BBD) has been adopted. Optimum desirability is found as 0.862 with hydrogen addition of 4.63 L/min, fuel blend of 26.8% and 1500 rpm engine speed for the diesel engine. When the diesel engine is operated at 1500 rpm engine speed and fuelled with 4.63 L/min hydrogen addition and 26.8% biodiesel blend ratio; the optimum responses of CO, CO₂, NO_x, vibration, and noise are established as 214 ppm, 1.35%, 90.4 ppm, 38.6 m/s², and 91.3 dB[A], respectively. The predicted values were confirmed experimentally and the errors in predicted values are found in a limit range.     

Effect of changing injection pressure on Mahua oil and biodiesel combustion with CeO2 nanoparticle blend on CI engine performance and emission characteristics

Alternative fuels have sparked a lot of interest as oil deposits have decreased and environmental concerns have grown. Biodiesel is an alternative fuel that is being researched as a possible replacement for fossil fuels. In the current investigation, the combustion performance, and emission characteristics of CI(Compression Ignition) engine were examined by changing the fuel injection pressure (180, 200, 220 and 240 bar). The biodiesel (B20) used in this analysis was obtained from Mahua oil at 20% v/v blended with neat diesel (20% Mahua Biodiesel + 80% Diesel). CeO₂(Cerium Oxide) nanoparticles were introduced to the B20 fuel at four distinct concentrations are 25, 50, 75, and 100 ppm. Performance characteristics such as BTE(Brake Thermal Efficiency) and BSFC(Brake Specific Fuel Consumption) were inferior to diesel, at 240 bar B20 with 25 ppm CeO₂ indicated 1.9% increased BTE and 3.8% reduced BSFC compared B20 and 6% lower EGT (Exhaust Gas Temperature) compared diesel. At 200 bar, fuel samples indicated slightly higher In-Cylinder pressure and lower HRR (Heat release rate) compared to diesel. At 200 bar FIP(Fuel Injection Pressure), HC(Hydro Carbon) and CO(Carbon Monoxide) emissions were reduced significantly compared to diesel. The largest reduction in smoke opacity and NOx(Nitrous Oxide) emissions were observed at 240 bar with 75 ppm dosage, but CO₂(Carbon Dioxide) emissions were higher at 220 bar.     

Numerical and experimental investigation of hydrogen enrichment in a dual-fueled CI engine: A detailed combustion,performance, and emission discussion

An effort has been made to simulation a compression ignition engine using hydrogen-diesel, hydrogen-diethyl ether, hydrogen-n-butanol and base diesel fuel as alternatives. The engine measured for the simulation is a single cylinder, four stroke, direct injection, diesel engine. During the simulation the injection timing and engine speed are kept constant at 23°bTDC and 1500 rpm. Diesel-RK, a piece of commercial software employed for this project, can forecast an engine emission, performance and combustion characteristics. The examination of the anticipated outcomes reveals that adding hydrogen to diesel leads in a small increase in efficiency and fuel consumption. With the usage of hydrogen-blend fuels, the majority of dangerous pollutants in exhaust are greatly decreased. The shortest ignition delay was consistently given by 5H295DEE. The lowest CO₂ (578.61 g/kWh) was given by 5H295nB at CR 19.5. Hydrogen blends increase NOx emissions more than base diesel fuel. In the case of smoke and particulate matter emission, the reduce tendency was seen.     

Saving energy and reducing pollution by use of emulsified palm-biodiesel blends with bio-solution additive

Advances in biodiesel, emulsified diesel and artificial chemical additives are driven by consumer demand to save energy and reduce emissions from diesel engines. However, the effect of emulsified bio-solution/palm-biodiesel/diesel blends in diesel engines has not been assessed. Experimental results in this work demonstrate that the emulsified bio-solution/palm-biodiesel/diesel blends have the advantage in saving energy and reducing emissions of both polycyclic aromatic hydrocarbons (PAHs) and particulate matter (PM) from diesel engines. When comparing with P0 (premium diesel fuel as base fuel), E16P20 fuel (16 vol% bio-solution + 20 vol% palm-biodiesel + 64 vol% P0, an additional 1 vol% surfactant) saved 12.4% fuel consumption and reduced emissions of PM by 90.1%, total PAHs by 69.3%, and total BaP_eq (benzo[a]pyrene equivalent concentration) by 69.6%. Emulsified palm-biodiesel with bio-solution can be considered as a clean and alternative fuel.     

Study of antioxidant effect on oxidation stability and emissions in a methyl ester of neem oil fuelled DI diesel engine

Biodiesel as an alternative diesel fuel prepared from vegetable oils or animal fats has attracted more and more attention because of its renewable and environmental-friendly nature. But biodiesel undergoes oxidation and degenerate more quickly than mineral diesel. Further several studies report NO_x emissions increases for biodiesel fuel compared with conventional diesel fuel. In this paper, the experimental investigation of the effect of antioxidant additive (Butylated hydroxytoluene) on oxidation stability and NO_x emissions in a methyl ester of neem oil fuelled direct injection diesel engine has been reported. The antioxidant additive is mixed in various proportions (100–400 ppm) with methyl ester of neem oil. The oxidation stability was tested in Rancimat apparatus and emissions, performance in a computerized 4-stroke water-cooled single cylinder diesel engine of 3.5 kW rated power. Results show that the antioxidant additive is effective in increasing the oxidation stability and in controlling the NO_x emissions of methyl ester of neem oil fuelled diesel engines.     

Experimental investigation of the combustion characteristics,emissions and performance of hydrogen port fuel injection in a diesel engine

Diesel engines are indispensable in daily life. However, the limited supply of petroleum fuels and the stringent regulations on such fuels are forcing researchers to study the use of hydrogen as a fuel. In this study, a diesel engine is operated using hydrogen–diesel dual fuel, where hydrogen is introduced into the intake manifold using an LPG-CNG injector and pilot diesel is injected using diesel injectors. The energy contents of the total fuel, 0%, 16%, 36% and 46% hydrogen (the 0% hydrogen energy fraction represents neat diesel fuel), were tested at 1300 rpm of constant engine speed and 5.1 kW of constant indicated power. According to test results, the indicated thermal efficiency of the engine decreases and the isfc increases with an increasing hydrogen energy fraction. Additionally, indicated specific CO, CO₂ and smoke emissions decrease with an increasing percentage of hydrogen fuel. However, indicated specific NO_x emissions do not change at the 16% hydrogen energy fraction, in other words, with an increase in the hydrogen amount (36% and 46% hydrogen energy fraction of total fuel), a dramatic increase (58.8% and 159.7%, respectively) is observed. Additionally, the peak in-cylinder pressure and the peak heat release rate values increase with the increasing hydrogen rate.     

The effects of hydrogen enriched natural gas under different engine loads in a diesel engine

Natural gas, which is among the alternative fuels, has become widespread in the transportation as it is both economical and environmentally friendly. While the use of natural gas is at a significant level in spark ignition engines, it has not yet been implemented in compression ignition engines (CI) as it worsens combustion due to ignition delay. In CI engines, however, the combustion properties of natural gas (NG) can be improved by adding hydrogen (H₂) to NG. This is one of the methods applied to use natural gas in CI engines. In this experimental study, two different volumetric rates of NG and NG/H₂ mixtures were added to the combustion air in a CI engine, and engine performance and emissions were examined under different engine loads. The experiments were performed at two different engine speeds, four different engine loads and no-load condition. An engine cylinder pressure of 59.16 bar, which is the closest value to the 59.39 bar obtained in the use of diesel fuel, was obtained at 1500 rpm for “Diesel + NG(500 g/h)” and 59.9 bar (highest values) was obtained for “Diesel + (500 g/h) [80%NG+20%H₂]" at 1750 rpm. For “Diesel + NG(250 g/h)” (Mix1) and “Diesel + NG(500 g/h)” (Mix2), as the engine speed increases, at the point where the maximum in-cylinder pressure is obtained occurs further to the right from top dead center (TDC). With the addition of 500 g/h NG, an increase of 4.5% was achieved in the cylinder pressure at full load, while an increase of 6.5% was achieved in the case of using “Diesel + (500 g/h) [80%NG+20%H₂]". Although the effect of the NG and NG/H₂ mixtures on in-cylinder pressure was small, the fuel consumption and thermal efficiency improved. Substantial improvements in hydrocarbon (HC) emissions were observed with the use of “Diesel + (250 g/h)[80%NG+20%H₂]”. Carbon dioxide (CO₂) emissions decreased with speed increase, but no significant differences in terms of CO₂ emissions were observed between the mixtures. There was a maximum difference of 15% between the diesel and the mixtures in CO₂ emissions. Although there was a decrease in nitrogen oxide (NO_x) levels with the increase in engine speed, the lowest NO_x emissions of 447.6 ppmvol was observed in “Diesel + NG(250 g/h)” (Mix1) at 1750 rpm at maximum load.     

Combustion,performance and emissions of ULSD,PME and B50 fueled multi-cylinder diesel engine with naturally aspirated hydrogen

An experimental study was conducted on a diesel engine fueled with ultra-low sulfur diesel (ULSD), palm methyl ester (PME), a blended fuel containing 50% by volume each of the ULSD and PME, and naturally aspirated hydrogen, at an engine speed of 1800 rev min⁻¹ under five loads. Hydrogen was added to provide 10% and 20% of the total fuel energy. The following results are obtained with hydrogen addition. There is little change in peak in-cylinder pressure and peak heat release rate. The influence on fuel consumption and brake thermal efficiency is engine load and fuel dependent; being negative for the three liquid fuels at low engine loads but positive for ULSD and B50 and negligible for PME at medium-to-high loads. CO and CO₂ emissions decrease. HC decreases at medium-to-high loads, but increases at low loads. NO_x emission increases for PME only but NO₂ increases for the three liquid fuels. Smoke opacity, particle mass and number concentrations are all reduced for the three liquid fuels.     

Conversion of a commercial spark ignition engine to run on hydrogen: Performance comparison using hydrogen and gasoline

The modifications performed to convert the spark ignition gasoline-fueled internal combustion engine of a Volkswagen Polo 1.4 to run with hydrogen are described. The car is representative of small vehicles widely used for both city and interurban traffic. Main changes included the inlet manifold, gas injectors, oil radiator and the electronic management unit. Injection and ignition advance timing maps were developed for lean mixtures with values of the air to hydrogen equivalence ratio (λ) between 1.6 and 3. The established engine control parameters allowed the safe operation of the hydrogen-fueled engine (H₂ICE) free of knock, backfire and pre-ignition as well with reasonably low NO_x emissions. The H₂ICE reached best brake torque of 63 Nm at 3800 rpm and maximum brake power of 32 kW at 5000 rpm. In general, the brake thermal efficiency of the H₂ICE is greater than that of gasoline-fueled engine except for the H₂ICE working at very lean conditions (λ = 2.5) and high speeds (above 4000 rpm). A significant effect of the spark advance on the NO_x emissions has been found, specially for relatively rich mixtures (λ < 2). Small changes of spark advance with respect to the optimum value for maximum brake torque give rise to an increase of pollutant emissions. It has been estimated that the hydrogen-fueled Volkswagen Polo could reach a maximum speed of 140 km/h with the adapted engine. Moreover, there is enough reserve of power for the vehicle moving on typical urban routes and routes with slopes up to 10%.     

Bio-fuels production and the environmental indicators

The paper evaluates the role of the bio-fuels production in the transportation sector in the world, for programs of greenhouse gases emissions reductions and sustainable environmental performance. Depending on the methodology used to account for the local pollutant emissions and the global greenhouse gases emissions during the production and consumption of both the fossil and bio-fuels, the results can show huge differences. If it is taken into account a life cycle inventory approach to compare the different fuel sources, these results can present controversies. A comparison study involving the American oil diesel and soybean diesel developed by the National Renewable Energy Laboratory presents CO₂ emissions for the bio-diesel which are almost 20% of the emissions for the oil diesel: 136 g CO₂/bhp-h for the bio-diesel from soybean and 633 g CO₂/bhp-h for the oil diesel [National Renewable Energy Laboratory—NREL/SR-580-24089]. Besides that, important local environmental impacts can also make a big difference. The water consumption in the soybean production is much larger in comparison with the water consumption for the diesel production [National Renewable Energy Laboratory—NREL/SR-580-24089]. Brazil has an important role to play in this scenario because of its large experience in bio-fuels production since the seventies, and the country has conditions to produce bio-fuels for attending great part of the world demand in a sustainable pathway.     

Performance and combustion characteristic of CI engine fueled with hydrogen enriched diesel

The combustion of hydrogen–diesel blend fuel was investigated under simulated direct injection (DI) diesel engine conditions. The investigation presented in this paper concerns numerical analysis of neat diesel combustion mode and hydrogen enriched diesel combustion in a compression ignition (CI) engine. The parameters varied in this simulation included: H₂/diesel blend fuel ratio, engine speed, and air/fuel ratio. The study on the simultaneous combustion of hydrogen and diesel fuel was conducted with various hydrogen doses in the range from 0.05% to 50% (by volume) for different engine speed from 1000 – 4000 rpm and air/fuel ratios (A/F) varies from 10 – 80. The results show that, applying hydrogen as an extra fuel, which can be added to diesel fuel in the (CI) engine results in improved engine performance and reduce emissions compared to the case of neat diesel operation because this measure approaches the combustion process to constant volume. Moreover, small amounts of hydrogen when added to a diesel engine shorten the diesel ignition lag and, in this way, decrease the rate of pressure rise which provides better conditions for soft run of the engine. Comparative results are given for various hydrogen/diesel ratio, engine speeds and loads for conventional Diesel and dual fuel operation, revealing the effect of dual fuel combustion on engine performance and exhaust emissions.     

Crude palm oil fuel for diesel-engines: Experimental and ANN simulation approaches

In the current work, the effect of using CPO (crude palm oil)-OD (ordinary diesel) blends as fuel on the performance of CI (compression ignition) engine is studied. Three different blends of CPO-OD (25%, 50% and 75%) were investigated using direct-injection, stationary diesel engine. The CPO-OD blends were preheated to about 60 °C before the injection to reduce the viscosity of the blends. The experiments were conducted at variable engine speeds (1000 rpm through 3000 rpm) under fixed throttle opening. The results revealed that the CPO-OD exhibited higher torque and power output at engine speeds lower than 2000 rpm, while the BSFC (brake specific fuel consumption) was found to be higher than the OD at the same engine speeds. CPO enhanced the BSFC at higher engine speeds (above 2000 rpm). The CPO-OD blends exhibited lower emissions of NO_x and higher emission of CO compared to the OD.     

Comparative study of a hybrid research vessel utilizing batteries or hydrogen fuel cells

The Scripps Institution of Oceanography (SIO) current coastal/local research vessel, the R/V Robert Gordon Sproul, is nearing the end of its service life and will soon require replacement. This study compares three potential variants for an R/V Sproul replacement vessel (SRV): a Baseline SRV consisting of a traditional diesel-electric powertrain, a Battery Hybrid SRV (battery/diesel-electric) and a Hydrogen Hybrid SRV (hydrogen fuel cell/diesel-electric). All three variants meet the science mission requirements of the SRV but with varying levels of zero-emission runtime, energy efficiency and emissions. The Battery Hybrid SRV can provide 2.5 h of zero emissions (battery only) operation, but could not complete any of the identified SRV science missions without also engaging the diesel generators. In contrast, the Hydrogen Hybrid SRV can provide 23.4 h of zero emission (hydrogen only) runtime, and can complete 74% of the SRV science missions solely with zero-emission operation. The superior performance of the Hydrogen Hybrid SRV is attributable to the higher volumetric energy storage density of the LH₂/fuel cell combination. The capital costs of these vessels are estimated to be: ∼ $21.4 M for the diesel-electric Baseline SRV, ∼ $26.0 M for the Battery Hybrid SRV vessel and ∼ $34.4 M for the Hydrogen Hybrid SRV. The “well-to-waves” (WTW) greenhouse gas (GHG) and criteria pollutant emissions were estimated using various sourcings for the diesel fuel, electricity and hydrogen fuel. The lowest emission levels are achieved with the Hydrogen Hybrid variant using 100% renewable hydrogen. The annual WTW GHG emissions from the Hydrogen Hybrid using renewable LH₂ in combination with fossil diesel in the hybrid arrangement yields a 26.7% GHG emissions reduction from the Baseline vessel using fossil-derived diesel fuel. The Battery Hybrid vessel with 100% renewable electricity combined with diesel fuel provides a 6.9% reduction in GHG emissions. Similar results are seen for the criteria pollutant emissions. The hybrid vessels are also compared with regard to operational safety. The study reveals that hydrogen fuel-cell technology provides an effective hybrid supplement to diesel power for a coastal/local research vessel.     

The characteristics of waste-cooking palm biodiesel-fueled CRDI diesel engines: Effect hydrogen enrichment and nanoparticle addition

The influence of iron nanoparticle (INP) addition (75 ppm) and hydrogen enrichment (10 lpm) with waste cooking palm biodiesel blend (WCB) on a CRDI diesel engine is evaluated. A blend of 20% WCB and 80% diesel is used, and the dosing level of INP has been kept at 75 ppm, which has been decided based on the oxygen content of biodiesel. Results indicate that the combination of H₂ enrichment and INP addition improves the BTE and BSFC of biodiesel blends as that of diesel. A maximum improvement of BTE of 7.1% than that of diesel is obtained at 90% loading. The combined impact of better hydrogen combustion characteristics and improved air-fuel mixing with nanoparticles reduces CO and HC emissions by 37.5% and 41.8%, respectively, for the WCB fuel sample. However, NO_X emission shows an elevation of 27.4% compared to diesel. Combustion parameters, namely ICP (80.1 bar) and HRR (89.5 J/˚CA) indicate an improvement of 5.3% and 6.7% compared to diesel for WCB + INP + H₂. This is owing to the combination of hydrogen's rapid flame speed and INP-added biodiesel's increased thermal conductivity.     

The effects of turbocharger on the performance and exhaust emissions of a diesel engine fuelled with biodiesel

This paper investigates the effects of turbocharger on the performance of a diesel engine using diesel fuel and biodiesel in terms of brake power, torque, brake specific consumption and thermal efficiency, as well as CO and NO_x emissions. For this aim, a naturally aspirated four-stroke direct injection diesel engine was tested with diesel fuel and neat biodiesel, which is rapeseed oil methyl ester, at full load conditions at the speeds between 1200 and 2400 rpm with intervals of 200 rpm. Then, a turbocharger system was installed on the engine and the tests were repeated for both fuel cases. The evaluation of experimental data showed that the brake thermal efficiency of biodiesel was slightly higher than that of diesel fuel in both naturally aspirated and turbocharged conditions, while biodiesel yielded slightly lower brake power and torque along with higher fuel consumption values. It was also observed that emissions of CO in the operations with biodiesel were lower than those in the operations with diesel fuel, whereas NO_x emission in biodiesel operation was higher. This study reveals that the use of biodiesel improves the performance parameters and decreases CO emissions of the turbocharged engine compared to diesel fuel.     

Experimental study of various effects of exhaust gas recirculation (EGR) on combustion and emissions of an automotive direct injection diesel engine

Cooled exhaust gas recirculation (EGR) is a common way to control in-cylinder NO_x production and is used on most modern high-speed direct injection (HSDI) diesel engines. However EGR has different effects on combustion and emissions production that are difficult to distinguish (increase of intake temperature, delay of rate of heat release (ROHR), decrease of peak heat release, decrease in O₂ concentration (and thus of global air/fuel ratio (AFR)) and flame temperature, increase of lift-off length, etc.), and thus the influence of EGR on NO_x and particulate matter (PM) emissions is not perfectly understood, especially under high EGR rates. An experimental study has been conducted on a 2.0 l HSDI automotive diesel engine under low-load and part load conditions in order to distinguish and quantify some effects of EGR on combustion and NO_x/PM emissions. The increase of inlet temperature with EGR has contrary effects on combustion and emissions, thus sometimes giving opposite tendencies as traditionally observed, as, for example, the reduction of NO_x emissions with increased inlet temperature. For a purely diffusion combustion the ROHR is unchanged when the AFR is maintained when changing in-cylinder ambient gas properties (temperature or EGR rate). At low-load conditions, use of high EGR rates at constant boost pressure is a way to drastically reduce NO_x and PM emissions but with an increase of brake-specific fuel consumption (BSFC) and other emissions (CO and hydrocarbon), whereas EGR at constant AFR may drastically reduce NO_x emissions without important penalty on BSFC and soot emissions but is limited by the turbocharging system.     

Effects of H2 on the number concentration of particulate matter in diesel engines using a low-pressure loop exhaust-gas recirculation system

We investigated the effects of H₂ on the number concentration of particulate matter (PM) emissions from a diesel engine fitted with a low-pressure loop exhaust gas recirculation system. We used a 2.2-L four-cylinder direct-injection diesel engine satisfying EURO V regulations, and converted this engine to include an H₂ feed. The air/fuel (A/F) ratio was varied in the range of 21.9–45.5 and the brake mean effective pressure was varied in the range of 2–6 bars to control the O₂ concentration and in-cylinder temperature, both of which are significant for PM emissions. The number concentration of the emitted PM was measured using a scanning mobility particle sizer. We found that the emitted PM decreased by the addition of H₂ which caused the unburned gas temperature increased. Furthermore, the degree of reduction was larger as the A/F ratio, load, and H₂ energy fraction increased. However, with A/F ratios of less than 21.9, the addition of H₂ increased the number concentration of emitted PM which was attributed to the small O₂ concentration at these A/F ratios.