Thermal conductivity of tomato paste

Experimental measurements of the thermal conductivity and thermal diffusivity of tomato paste at concentrations of 27–44° Brix are reported. The thermal conductivity was measured in a guarded hot-plate apparatus while the diffusivity was estimated by a simplified transient method. The thermal conductivity (λ) values fell in the region of 0·460–0·660 W m^?1 K^?1, decreasing with increasing solids concentration and increasing as the temperature was raised from 30 to 50°C. The temperature effect was less pronounced at higher solids concentration. The thermal diffusivity of tomato paste at 35° Brix and 20°C was estimated as 1·42 × 10^?7 m² s^?1, which is in good agreement with data from the steady-state method.     

Influence of Moisture Content and Temperature on Thermal Conductivity and Thermal Diffusivity of Rice Flours

The thermal conductivity and thermal diffusivity for four types of rice flours and one type of rice protein were determined at temperatures ranging from 4.8 to 36.8?°C, bulk densities 535 to 875.8 kg m^?3, and moisture contents 2.6 to 16.7% (w.b.), using a KD2 Thermal Properties Analyzer. The thermal conductivity of rice flours and rice protein increased with the increase in temperature, moisture content as well as with increase in bulk density. Thermal diffusivity decreased with increase in moisture content, increase in temperature and bulk density. The thermal conductivities values obtained were within the range of 0.045 to 0.124 W m^?1 K^?1 whereas the thermal diffusivity values were in the range of 0.094 to 0.138 mm² s^?1.     

Thermophysical Properties of Sugarcane,Palmyra Palm,and Date-palm Granular Jaggery

Effect of moisture content on thermo-physical properties of sugarcane, palmyra palm, and date-palm granular jaggery were investigated. Thermal conductivity and diffusivity were determined by line-heat-source transient heat-transfer methodology, while specific heat was calculated from additional data on bulk density of the samples. Thermal conductivity, diffusivity, specific heat, and bulk density was found to vary from 0.08 to 0.39 W m^?1 K^?1, 0.10 to 0.13 × 10^?6 m² s^?1, 1.19 to 2.97 kJ kg^?1 K^?1, and 510 to 1310 kg m^?3, respectively, for a moisture range of 2.0–14.3 (%d.b.); all at an average temperature of 30°C. All these properties except—thermal diffusivity—followed an increasing trend; with the increase in moisture content, each showed a high correlation coefficients. The variation of thermal diffusivity was found to be insignificant.     

Intrinsic Thermal Conductivity of Starch: A Model-independent Determination

Effective thermal conductivities of two-phase mixtures of potato or soluble starch granules with pure liquids or aqueous solutions (thermal conductivities in the range 0.169–0.602 W.m^?1.K^?1) were measured at 18.5±2.2°C using the steady state method. Measured values were compared with the thermal conductivities of the liquids and the results indicated a range of 0.38–0.40 W.m^?1K^?l for intrinsic thermal conductivity. Similar measurements, at temperatures up to 50°C for soluble starch (to assess the temperature dependence of the intrinsic thermal conductivity) indicated no significant change over the range of temperature studied for mixtures with pure liquids.     

Thermophysical Properties of Papaya Puree

The effects of soluble solids content and temperature on thermal properties of papaya puree were studied. Density and specific heat were measured using a pycnometer and differential scanning calorimeter, respectively, while thermal conductivity was measured using a line heat source probe. Thermal diffusivity was then calculated from the experimental results of the specific heat, thermal conductivity, and density. Thermal properties of papaya puree were experimentally determined within a soluble solids content range of 10 to 25 °Brix and temperature between 40 and 80°C. The density, specific heat, thermal conductivity, and thermal diffusivity of papaya puree were found to be in the ranges of 1014.6 to 1098.9 kg/m³, 3.652 to 4.092 kJ/kg °C, 0.452 to 0.685 W/m °C, and 1.127?×?10^?7 to 1.650?×?10^?7 m²/s, respectively. Moreover, the empirical models for each property as a function of soluble solids content and temperature were obtained.     

Effect of Moisture Content on Density, Heat Capacity and Conductivity of Restructured Pork/Soy Hull Mixtures

Sixteen restructured pork/soy hull mixtures were studied. Incorporation of unprocessed and processed and two particle sizes of hydrated soy hulls in the mixture resulted in moisture contents ranging from 74% to 85%. Standard laboratory procedures were used to measure density, heat capacity and thermal conductivity. Thermal diffusivity was calculated as a mathematical function of these three properties. Thermal diffusivity values were affected the most (1.14–2.01 × 10^-7 m²/sec) by moisture, followed by heat capacity (2.75–4.18 J/g°C), and thermal conductivity (4.80–5.72 x 10^-3W/cm°C). No significant changes in density occurred (1.02–1.06 g/cm³).     

Thermo‐physical properties of composite bread dough with maize and cassava flours

Composite wheat–cassava and wheat–maize flours were produced in ratio 100:0. 60:40, 50:50, 40:60 and 0:100 respectively. Thermo‐physical properties of bread dough were determined. For wheat –cassava composite bread dough, moisture content ranged between 44.02 ± 2.04 to 51.31 ± 2.99% dry basis (db), density (1035.2 ± 20.4 to 975.6 ± 12.6 kg m^?3), specific heat capacity (2.51 ± 0.61 to 3.01 ± 0.42 kJ kg^?1 K) and thermal conductivity (0.362 ± 0.13 to 0.473 ± 0.12 W mK^?1). While wheat–maize mixture gave 44.14 ± 1.94 to 45.09 ± 1.26%(db) of moisture content, 981.4 ± 16.3–960.4 ± 22.5 kg m^?3 density, 1.77 ± 0.17–2.61 ± 0.63 kJ kg^?1 K specific heat capacity and 0.36 ± 0.07–0.39 ± 0.02 W mK^?1 thermal conductivity. Effects of substitutions was significant on moisture content and thermal conductivity of dough while non significant influence was recorded on density and specific heat capacity at P < 0.05.     

The enzymic release of fatty acids from phosphatidylcholine in green peas (Pisum sativum)

‘Phospholipid acyl-hydrolase’ (PLAH), an enzymic activity releasing fatty acid from phosphatidylcholine (PC), has been identified and characterised in green peas. The K_m value for PC dipalmitoyl ester was 0·167 mm. The enzymic activity possessed a pH optimum of 5·6 and was stable for 20 min only at that pH value. The optimum temperature was 45°C and thermal sensitivity was indicated by a 94% decrease in activity upon exposure of the enzyme to 55°C for 3 min, and by an exponential decrease in activity upon storage at 4°C for 1 week. The enzyme was optimally activated by 2·0 mm calcium chloride at pH 5·6, and the optimal concentration of sodium dodecyl sulphate was 0·75 mg ml^?1. Pea PLAH was non-competitively inhibited by sodium cyanide, EDTA and p-chloromercuribenzoate, with no activity in the presence of mercuric chloride. The results from this study are related to those of other workers on lipid-degrading enzymes in peas, and a pathway is proposed for the enzymic degradation of endogenous lipids in fresh or unblanched frozen peas during post-harvest storage.     

THERMAL PROPERTIES OF CHEDDAR CHEESE: EXPERIMENTAL AND MODELING

Thermal properties (thermal conductivity, thermal diffusivity and heat capacity) of Cheddar cheese were measured as a function of cheese age and composition. The composition ranged from 30–60% moisture, 8–37% fat, and 22–36% protein (wet basis). The thermal conductivity and heat capacity ranged from 0.354–0.481 W/m °C and from 2.444–3.096 kJ/kg °C. Both thermal conductivity and heat capacity increased with moisture and protein content and decreased with fat content. The thermal diffusivity ranged from 1.07×10^?7 ? 1.53 × 10^?7 m²/s. There was no significant relationship between thermal diffusivity and moisture, fat and protein content of cheese. No statistically significant effect (at the 10% level) of age (0 to 28 wk) on thermal properties was observed. Models predicting thermal properties as a function of cheese composition were developed and their predictive ability was compared with that of empirical models available in the literature. In addition, several theoretical thermal conductivity models were evaluated for their usefulness with Cheddar cheese. Published thermal conductivity models cannot accurately predict (mean error was from 3.4 to 42%) the thermal conductivity of Cheddar cheese.     

Estimation of Heat and Mass Transfer Coefficients During Air-Freezing of Cucumber

Freezing of foods involves coupled heat and mass transfer. It is essential to optimally design the freezing equipment and maximise the efficiency of the freezing process. Therefore, it is necessary to estimate the heat and mass transfer coefficients. In this study, the surface heat and mass transfer coefficients were estimated employing the Hilbert equation as well as the corresponding thermal and diffusive boundary layers during freezing of unpeeled cucumber at low air temperatures (?10 to??18 and??25°C). The estimated mean heat transfer coefficients ranged from 10.99 W m^?2 K^?1 for 0.5 m s^?1 up to 40.07 W m^?2 K^?1 for 5.0 m s^?1. The respective mass transfer coefficients ranged from 8.98 up to 32.40 m s^?1. The estimated heat transfer coefficients were compared with the respective ones calculated from Dincer and Dincer and Cengeli during air-cooling (22 to 2°C) of unpeeled cucumbers of similar size as well as other agricultural cylindrical products.     

Thermal Properties of Sweet Potato with its Moisture Content and Temperature

Thermal properties of sweet potato were experimentally determined and modeled as a function of temperature and moisture content. The purpose is to develop empirical correlations that could predict thermal properties during sweet potato processing. Thermal conductivity from the study was 0.49 ± 0.038 Wm^?1K^?1 (mean ± s.d.), thermal diffusivity was 1.2?×?10^?7 ± 9.05?×?10^?9 m²s^?1, specific heat was 3660 ± 477.4 Jkg^?1K^?1, and density was 1212 ± 73.5 kgm^?3. All properties were determined within temperature range of 20 to 60°C and moisture content range of 0.45 to 0.75 w.b. Prediction models for the thermal properties of sweet potato were developed as a function of product temperature and moisture content with experimental data from this study. Mechanistic models were also developed for thermophysical properties of sweet potato using major food components of the product. Developed models were all presented and compared.     

THERMOPHYSICAL PROPERTIES OF FRESH AND ROASTED COFFEE POWDERS1

The present work deals with experimental determination of bulk specific heat, bulk thermal conductivity, bulk and true density and moisture content of Columbian and Mexican coffee bean powders. Specific heat was determined by DSC, thermal conductivity by modified Fitch apparatus, density by stereopycnometer and moisture contents by standard vacuum oven method. Specific heat values showed marginal rise over the temperature range (45 to 150C) studied. Thermal conductivity values, determined in the temperature range of 20–60C were not found to have any definite trend with rise in moisture in the experimental range of 4.8 to 9.8% moisture (dry basis). Bulk density of powders varied appreciably (1.298 to 0.882 g.cm^?3), while the change was negligible for true density (1.361 to 1.092 g.cm^?3) with the degree of roasting. Statistical analysis of the data shows the reliability of the experimental determinations. Suitable correlations were developed to determine bulk specific heat and bulk density.     

Effective Thermal Conductivity of Granular Starch Materials

The effective thermal conductivity (k_eff of two granular starches was investigated at various bulk densities, temperatures and moistures, using the method of heated probe. Granular powders of high-amylose and high-amylopectin starches were used at bulk densities 500-800 kg/m³, temperatures 25–70°C. and moistures of 0–40%. The k_eff increased linearly with bulk density, from 0.065 to 0.220 W/mK. Temperature had a positive effect up to 6.5% moisture. At higher moistures k_eff increased sharply above 50°C, indicating starch-water interaction. The k_eff increased linearly with moisture at low (0–15%) and high (> 25%) moistures, remaining nearly constant at intermediate moistures. These changes were related to the porosity of the starches.     

Thermal properties of wood-gypsum boards

Transient simultaneous measurements of thermal conductivity, volume heat capacity and thermal diffusivity of laboratory wood-gypsum boards have been performed with ISOMET 2104 at room temperature. The influences of wood particle content, density and moisture content on thermal properties were investigated. The measurements were performed in a direction perpendicular to the board plane. The effect of density and wood particle content on the thermal properties may be related to the presence of voids both between and inside particles. It seems, that the dominant mechanism of heat transfer across the board is the heat conduction through the voids. Wood-gypsum boards with a density of 850–1300 kg/m³, a moisture content of 2–11% and a wood particle content of 0–35% have the following thermal conductivity of 0.189–0.753 W m^-1 K^-1, volume heat capacity of 0.683–1.43×10⁶ J m^-3 K^-1 and thermal diffusivity of 0.171–0.367×10^-6 m² s^-1; their magnitudes are higher than those ones of OSB, MDF, particleboard and plywood.     

Properties of polyphenol oxidase in mango (Mangifera indica) kernel

Polyphenol oxidase (PPO) activity of filtered extract of ground mango kernel suspension (400 g litre⁻¹) was studied spectrophotometrically at 420 nm using catechol as substrate. The enzyme was most active at pH 6·0 and 25°C. Activity was reduced by 50% at pH values of 5·0 and 7·1, and also at temperatures of 14°C and 30°C. The calculated activation energy and the Michaelis constant (K_m) were 21·4 kcal mol⁻¹ °C⁻¹ and 24·6 mM , respectively. The V_max value was 2·14 units g⁻¹ mango kernel. The time to heat inactivate PPO decreased rapidly to < 10 min with increasing temperature of ⩾ 70°C at 50% activity. © 1998 SCI.     

Kinetic studies on strawberry anthocyanin hydrolysis by a thermostable anthocyanin-β-glycosidase from Aspergillus niger

Several kinetic characteristics of a thermostable anthocyanin-β-glycosidase from Aspergillus niger have been evaluated. With strawberry anthocyanins as substrate, at pH optimum (4·0) and t = 30°C, K_m was found to be $\text{123 ± 4 μ}\text{m}$ and V_max, 1·16 ± 0·06 μmol min^?1mg^?1 protein. Temperature optimum was observed at about 68°C. The apparent energy of activation was calculated to be 11 ± 1 kcal/mol. The inhibitory effect of different sugars and sugar derivatives was examined. Glucono-deltalactone ($\text{K}{}_{\mathrm{<mtext>i</mtext>}}\text{= 2·3 ± 0·1 μ}\text{m}$), gluconic acid ($\text{K}{}_{\mathrm{<mtext>i</mtext>}}\text{= 82 ± 2 μ}\text{m}$) and glucose ($\text{K}{}_{\mathrm{<mtext>i</mtext>}}\text{= 1·3 ± 0·1}\text{m}\text{m}$) appeared to be competitive inhibitors of this enzyme.     

Acid phosphatase in the tubers of Dioscorea species and its purification from the white yam (D. rotundata poir)

Acid phosphatase activity was determined in 15 cultivars from four species of yam. A 12-fold purification of the enzyme from Dioscorea rotundata (cv. chikakwondo) gave a homogeneous preparation as demonstrated by polyacrylamide gel electrophoresis. This enzyme preparation has an apparent molecular weight of 115 000 ±2000 and an optimum activity at a pH of 5·20 and a temperature of 50°C. The K_m of the enzyme is 3·81 mM with disodium p-nitrophenylphosphate (p-NNP) as a substrate. The energy of activation, heat of activation, energy of inactivation and heat of inactivation are 7·0, 6·4, 4·41 and 4·34 kcal M^?1, respectively. Although it has very little activity with most organic phosphoric acid esters, it is significantly inhibited by Ca²⁺, Hg²⁺ and EDTA and activated by Mg²⁺. The enzyme has a half-life of 50,17 or 13 days, respectively, when stored at 6-8°C, 0°C or room temperature (29±2°C).     

Thermal properties of wood-gypsum boards

Transient simultaneous measurements of thermal conductivity, volume heat capacity and thermal diffusivity of laboratory wood-gypsum boards have been performed with ISOMET 2104 at room temperature. The influences of wood particle content, density and moisture content on thermal properties were investigated. The measurements were performed in a direction perpendicular to the board plane. The effect of density and wood particle content on the thermal properties may be related to the presence of voids both between and inside particles. It seems, that the dominant mechanism of heat transfer across the board is the heat conduction through the voids. Wood-gypsum boards with a density of 850–1300 kg/m³, a moisture content of 2–11% and a wood particle content of 0–35% have the following thermal conductivity of 0.189–0.753 W m^-1 K^-1, volume heat capacity of 0.683–1.43×10⁶ J m^-3 K^-1 and thermal diffusivity of 0.171–0.367×10^-6 m² s^-1; their magnitudes are higher than those ones of OSB, MDF, particleboard and plywood.     

A new process for preparing transparent alkalised duck egg and its quality

When fresh duck (Anas plotyrhyncus) eggs (pH 8·0–8·5) are heated, their albumen develops a turbid gel. Through appropriate alkalisation (pH 11·5–12·8), the gel's transparency can be increased. The transparency of the heated duck egg-white is affected by pH value, heating temperature, heating rate and salt concentration. This research deals with the process for preparing the transparent alkalised duck egg and the change in its quality when stored. If fresh duck eggs are pickled in a solution of 42 g NaOH+50 g NaCl litre^?1 (25·3°C) for 8 days, removed, put in a water bath and heated at 70°C for 10 min they become transparent, their hardness and penetration increasing with storage. Total bacterial count and volatile basic nitrogen also increase with storage. The total bacterial count and the volatile basic nitrogen were 4·6 × 10⁶ cfu g^?1, 0·32 mg g^?1 when stored at a temperature of under 25°C for 4 weeks, respectively.     

Effect of cooking and drying on the thermal conductivity of rice

The transient line source technique was used to determine the thermal conductivity of rice during cooking and drying of cooked rice. A temperature range of 50‐70°C, moisture content of 10‐70% (wet basis), bulk (packing) density range of 500‐850 kg/m³ and porosity range of 0.265‐0.7 were studied. Thermal conductivity increased with increasing temperature, moisture content and bulk density, and the values were in the range 0.082‐0.543 W/m °C. This value is comparable with the literature values for granular and gelatinized starch. The data on the effect of phase change due to gelatinization have also been included. The experimental values were statistically analyzed and empirical polynomial equations were developed in terms of temperature, bulk density, porosity and moisture content of rice during cooking and drying the cooked material.