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  总被引:1,自引:0,他引:1  
Seeds are considered to be agro-industrial residues, which can be used as source of macronutrients and/or raw material for extraction of vegetable oils, since they present great quantities of bioactive compounds. This study aimed to characterize the lipid fractions and the seeds of pumpkin (Cucurbita sp) varieties Nova Caravela, Mini Paulista, Menina Brasileira, and Moranga de Mesa aiming at using them in food. The chemical composition of the seeds was performed according to the official methods of American Oil Chemists' Society and Association of Official Analytical Chemists. Total carotenoids and phenolic compounds were determined by spectrophotometry, while the levels of tocopherols were analyzed by high efficiency liquid chromatography. It was noted that the seeds contain high amounts of macronutrients that are essential for the functioning of the human organism. As to total carotenoids, Mini Paulista and Menina Brasileira pumpkin varieties presented significant amounts, 26.80 and 26.03 μg/g, respectively. Mini Paulista and Nova Caravela pumpkin varieties showed high amounts of total phenolic compounds in the lipid fractions and in the seeds. It was also found that γ-tocopherol is the isomer that stood out in the lipid fractions and in the seeds, mainly in Menina Brasileira. Finally, the consumption of these seeds and use of lipid fractions provide the supply of large quantities of compounds that are beneficial for health and that may be potentially used in food, besides representing an alternative to better use of agro-industrial residues. PRACTICAL APPLICATION: Bioactive compounds, besides presenting basic nutritional functions, provide metabolic and physiological health benefits when consumed as part of the usual diet. Therefore, there is a growing interest in vegetable oils of special composition, such as the ones extracted from fruit seeds. The seeds of Cucurbita sp are shown to be promising sources of oils, and especially the Cucurbita moschata and maxima species have not yet been fully elucidated. For this reason, it becomes important to investigate the chemical composition and lipid fractions of these seeds, aiming to use them in food.  相似文献   

3.
This work was conducted to investigate changes in the bioactive nutrient content of hot (pungent) paprika as a function of ripening in four of the most important varieties cultivated in Hungary. For the quantitative determination, recent liquid chromatographic (HPLC) methods were applied. Forty carotenoids were separated, with β‐carotene and lutein of interest from the biological point of view. The major component of vitamin E was α‐tocopherol. Capsaicin, dihydrocapsaicin and nordihydrocapsaicin were the dominant pungency principles. As for vitamin C components, only ascorbic acid could be detected and determined. The results indicated that all the examined compounds were at low level in the mature green fruits, and the onset of climacteric ripening caused their content to grow. In accord with the advance in ripening, carotenoids were being formed even at the overripening stage, while tocopherols, capsaicinoids and ascorbic acid reached their maximum level at the colour break or red stage and then declined. The highest values with regard to carotenoids were estimated in SZ‐178 and F0‐3 cultivars. The best retention of ascorbic acid was found in SZ‐178, which contained 4.86 mg g?1 dry matter in the dry pods. On the other hand, retention of α‐tocopherol during ripening and natural drying was found to depend on variety. The highest value for vitamin E was recorded in SZ‐178 followed by K‐V2, which contained the highest level of α‐tocopherol at the red stage of ripening. © 2001 Society of Chemical Industry  相似文献   

4.
Rosehip extracts of 18 samples representing six taxa in the genus Rosa were evaluated for antioxidant activities by use of different test systems. The ferric‐reducing antioxidant power (FRAP) and Trolox‐equivalent antioxidant capacity (TEAC) of the crude extracts ranged from 983.4 to 2187.1 µmol FRAP g−1 dry matter and from 457.2 to 626.2 µmol TEAC g−1 dry matter. The high antioxidant capacity was related to high contents of phytonutrients. The overall mean of antioxidants was 23.23 mg g−1 total carotenoids and 76.26 mg g−1 total phenolics. The phenolic component made a major contribution to the total antioxidant activities in both assays (overall mean was 90.5% and 75.7%), whereas the ascorbate made a minor contribution (8.6% and 16.9%) and the lipophilic component made an even smaller one (0.9% and 7.3%). However, the lipophilic component was the most effective when the comparison was based on the ratio of antioxidant activity to content of antioxidants. The crude extracts exhibited 50.9% (46.6–60.3%) inhibitory effect against the lipid peroxidation induced by 2,2′‐azobis(2,4‐dimethylvaleronitrile) (AMVN) and 85.0% (80.1–90.2%) inhibition in 2,2′‐azobis(2‐amidinopropane)hydrochloride (AAPH) assay at a concentration of 250 µg ml −1. Ascorbate acted as an antioxidant in both peroxy radical‐induced lipid peroxidations, but as a pro‐oxidant in the metal ion‐induced lipid peroxidation. The crude extracts showed a large inhibitory effect in the ferric ion‐induced lipid peroxidation and caused 83.7% inhibition at a concentration of 25 µg ml −1 dried rosehip powder. © 2000 Society of Chemical Industry  相似文献   

5.
用体外化学试验和TLC比较法对拐枣用乙醇、石油醚、乙酸乙酯、正丁醇和水提取物的抗氧化作用和抗氧化成分极性强弱进行了比较分析。结果表明拐枣提取物抗氧化作用从强到弱依次为乙酸乙酯提取物>正丁醇提取物>石油醚提取物>乙醇提取物>水提取物。拐枣具有较强的抗氧化活性,抗氧化活性成分主要存在乙酸乙酯提取物中。  相似文献   

6.
特殊颜色谷物作为一种重要的特殊类型品种,因兼具功能性、营养性和观赏性,愈来愈受到人们的青睐,成为高端农产品创制的热点方向。这些天然色素不仅可以增添食品色泽,还具有抗氧化、抗癌、提高视力等特殊功能。围绕特殊颜色谷物中花青素、麦黄酮和类胡萝卜素等三种重要色素,介绍其生物合成、主要功能和相关作物品种,进而聚焦重要粮食作物小麦,介绍最新培育审定的两种色素类功能性小麦“山农蓝麦1号”和“山农101”(山农黄酮麦1号)。为特殊颜色农作物研究和品种创制提供参考借鉴。  相似文献   

7.
BACKGROUND: Fatty acid, tocopherol, tocotrienol and carotene contents were assessed in four oil palm species from the National Centre of Agronomical Research of Côte d'Ivoire, two of which were the basal Lamé (HP1) and Deli (HP2) collections and two of which resulted from crossings between HP1 and HP2 varieties of Eleais guineensis, HP3 and HP4 being identified as the first and second cycle selection, respectively. RESULTS: Palm oil species were characterized by the richness in polyunsaturated fatty acids composition (48–60%) compared to saturated fatty acids (40–52%), especially the first variety, which was from the base collection, and the two hybrids ensuing from crossing. Total carotene content of those varieties was higher and accounted for 832–3575 µg g?1, and the β‐carotene level (580–2390 µg g?1) was predominant. Total vitamin E content was 864–1124 µg g?1, with a notable higher content of tocotrienols, especially γ‐and α‐tocotrienol, ranging from 400 to 515 µg g?1 and from 238 to 350 µg g?1, respectively. CONCLUSION: Crossing seemed to be useful in improving the performance and analytical characteristics of the base collection materials. Copyright © 2009 Society of Chemical Industry  相似文献   

8.
Natural antioxidants such as vitamin C, tocopherols and tocotrienols, carotenoids, and phenolic compounds are largely distributed in plant products. Most of them are not synthesized by human and need to be introduced with diet according to the Recommended Daily Intake (RDI). This work was aimed to give a comprehensive overview on the occurrence of these antioxidants in plants, in particular in plant foods, on the mechanisms of biosynthesis, and on conventional (liquid–liquid or solid–liquid extraction, Soxhlet) and innovative (enzymatic-assisted, pressurized fluid, supercritical fluid, ultrasound-assisted, microwave-assisted, pulsed electric field) extraction systems.  相似文献   

9.
干白葡萄酒清除DPPH自由基的能力及其与总酚含量的关系   总被引:1,自引:1,他引:0  
利用电子自旋共振(ESR)技术对不同品种的干白葡萄酒抗氧化特性进行研究,并分析干白葡萄酒总酚含量与清除DPPH自由基能力的相关性。结果表明,选择ESR测定条件为:干白葡萄酒稀释倍数为30倍,反应时间10min;运用Origin 8.0绘图和数据分析软件对电子自旋共振波谱图进行积分,得到不同品种干白葡萄酒对DPPH自由基的清除率,用Folin-ciocalteus比色法测定总酚含量,长相思葡萄酒清除自由基的能力最强可达到68%,其总酚含量为311mg/L;清除DPPH自由基的能力与总酚含量呈正相关。  相似文献   

10.
    
Annona crassiflora, known commonly as araticum, is an exotic tropical fruit consumed mainly by native people of the Brazilian Cerrado (2nd biggest biome of Brazil). In this study, pulp, seed, and peel of slight ripe and overripe fruits were extracted using ethanol and water. The extracts showed high content of total phenols and were screening for their potential as antioxidants using the in vitro model 1,1‐ dipheniyl‐2‐picryl hydrazyl (DPPH). The ethanol extracts of peel and seeds showed IC50 of 48.82 μg/mL and 31.14 μg/mL, respectively, for the slightly ripe fruits. As the ethanolic fractions of araticum showed the highest antioxidant activity, they were selected for testing of its effect on lipid peroxidation. The ethanolic extracts of slightly ripe fruits showed IC50 of 4.44 μg/mL, 1.72 μg/mL, and 8.62 μg/mL for the peel, seed, and pulp, respectively. This is the 1st report on the antioxidant properties of the extracts of araticum. Owing to these properties, the studies can be further extending to exploit them for their possible application as natural antioxidant for cosmetic, supplements, and functional ingredients for food products.  相似文献   

11.
    
The antioxidant activities of fruits (n = 21), vegetables (n = 67) and legumes (n = 7) commonly consumed in Korea were determined by both the lipophilic antioxidant performance assay (LAP) and the hydrophilic oxygen radical absorbance capacity assay (ORAC). The LAP assay used the lipophilic radical initiator MeO‐AMVN [2,2′‐azobis(4‐methoxy‐2,4‐dimethylvaleronitrile)] and the lipophilic probe BODIPY 581/591 [4,4‐difluoro‐5‐(4‐phenyl‐1,3‐butadienyl)‐4‐bora‐3a, 4a‐diaza‐s‐indacene‐3‐undecanoic acid]. The ORAC assay used the hydrophilic radical initiator AAPH [2,2′‐azobis(2‐amidinopropane) dihydrochloride] and the hydrophilic probe fluorescein. In addition, the lipid‐soluble phytonutrients, carotenoids and tocopherols were determined by a reverse‐phase HPLC system using a C30 column with a UV detector. The water‐soluble phytonutrient, ascorbic acid, was analyzed using an HPLC system with an electrochemical detector. Total phenols were determined by UV spectrophotometry. Tocopherols (r = 0.774, p < 0.0001) and carotenoids (r = 0.569, p < 0.0001) were significantly correlated with LAP in total samples (n = 95). ORAC was significantly correlated with total phenols (r = 0.893, p < 0.0001), but not with ascorbic acid (r = 0.009, p = 0.929) in total samples (n = 95). These data indicate that carotenoids and tocopherols and total phenols are the major contributors to the lipophilic and hydrophilic antioxidant capacities, respectively. Therefore, the contribution of both the hydrophilic and lipophilic components of fruits and vegetables should be considered when determining the actual ‘total’ antioxidant activity of fruits and vegetables. Copyright © 2007 Society of Chemical Industry  相似文献   

12.
    
A range of blackberry genotypes harvested in different seasons and regions in Mexico (Michoacan) and in the United States (Pacific Northwest) were collected to determine their antioxidant capacity using oxygen radical absorbance capacity (ORAC) and ferric reducing antioxidant power (FRAP) assays. Total acidity, ascorbic acid, soluble solids, total phenols, and total anthocyanins, as well as the correlation between all these parameters, were determined for all treatments. Total acidity ranged from 4.22% in wild blackberry from Patzcuaro, Mexico, to 1.02% in ‘Evergreen’ from Woodburn, Oreg. These treatments were also the outliers in terms of ascorbic acid content. Cultivar ‘Brazos’ did not exhibit any significant differences in acidity or ascorbic acid as a consequence of the geographic origin or harvest season. The highest concentration of soluble solids was recorded for ‘Evergreen’ from Woodburn and relatively low soluble solids levels were recorded for all the Mexican treatments. Wild blackberry from Patzcuaro exhibited the highest values for ORAC, FRAP, total phenolic and anthocyanin content. Other relatively high antioxidant capacity values were detected for ‘Marion’ and ‘Evergreen’, both produced in Oregon. Different cultivars grown in the same region/season consistently showed differences in antioxidant capacity. There was little effect of harvest season on phenolic levels. We conclude that levels of total acidity, ascorbic acid, soluble solids, antioxidant capacity, and polyphenols mainly depended on the genotype and not on the climate or the season. ORAC and FRAP values were both highly correlated with each other, and with total phenols and anthocyanin content.  相似文献   

13.
  总被引:1,自引:0,他引:1  
The causes of color modification in blood orange juice due to the heating concentration process were investigated. A Not From Concentrate (NFC) juice and a Reconstituted From Concentrated (RFC) juice, arising from the same stock of pigmented oranges, appeared very different in color although they had the same content of anthocyanins. CIE (Commision Internationale des Enclarages)-Lab measurements showed a slight decrease of L* and a* values and a very large increase of b* and hue values in RFC juice. Different distribution of carotenoids between serum and pulps and modification of pulp size appeared to be responsible for color modification.  相似文献   

14.
    
BACKGROUND: Bioactive compounds are capable of providing health benefits, reducing disease incidence or favoring body functioning. There is a growing search for vegetable oils containing such compounds. This study aimed to characterize the pulp and kernel oils of the Brazilian palm species guariroba (Syagrus oleracea), jerivá (Syagrus romanzoffiana) and macaúba (Acrocomia aculeata), aiming at possible uses in several industries. RESULTS: Fatty acid composition, phenolic and carotenoid contents, tocopherol composition were evaluated. The majority of the fatty acids in pulps were oleic and linoleic; macaúba pulp contained 526 g kg?1 of oleic acid. Lauric acid was detected in the kernels of all three species as the major saturated fatty acid, in amounts ranging from 325.8 to 424.3 g kg?1. The jerivá pulp contained carotenoids and tocopherols on average of 1219 µg g?1 and 323.50 mg kg?1, respectively. CONCLUSION: The pulps contained more unsaturated fatty acids than the kernels, mainly oleic and linoleic. Moreover, the pulps showed higher carotenoid and tocopherol contents. The kernels showed a predominance of saturated fatty acids, especially lauric acid. The fatty acid profiles of the kernels suggest that these oils may be better suited for the cosmetic and pharmaceutical industries than for use in foods. Copyright © 2011 Society of Chemical Industry  相似文献   

15.
The effects of adding 140, 180, 220, 260 and 300 g water to 1 kg grass pea seeds and using three levels of extrusion temperature, 90/100/120/100 °C, 120/140/170/160 °C and 140/180/220/200 °C, on concentrations of total lipids, tocopherols, carotenoids and fatty acids in extruded seeds were determined. Extrusion-cooking and a higher moisture content resulted in a lower content of polyenoic fatty acids. The smallest decrease in the content of polyenoic fatty acids in grass pea seeds was observed during extrusion-cooking at 120/140/170/160 °C. Moisturising as well as extrusion lowered significantly the content of the natural antioxidants: α-tocopherol, γ-tocopherol, β-carotene and lutein. © 1999 Society of Chemical Industry  相似文献   

16.
  总被引:1,自引:0,他引:1  
BACKGROUND: Carotenoid and anthocyanin contents of 26 maize landraces cultivated in southern Brazil were determined to evaluate their potential as natural colorants or functional food ingredients. RESULTS: The major carotenoids detected in the whole grain flour were zeaxanthin and lutein. Anthocyanins of landraces with purple starchy endosperm (Lingua de Papagaio and Mato Grosso Palha Roxa) were more extractable in methanol–HCl (1%, v/v), exhibiting 2.45 and 0.94 g kg?1 of whole grains flour, respectively. In contrast, butanol–HCl (30%, v/v) was more effective for the extraction of anthocyanins from the purple‐colored landraces Roxo 29 and Roxo 41; genotypes with pigments localized in the outer parts (pericarp) of grains (2.60 and 2.19 g kg?1). The Roxo 41 landrace showed the highest concentration of pigments, e.g. 11.72 10?3 g kg?1 of total carotenoids and 2.16 g kg?1 of total anthocyanins. Similarly, the yellow‐colored MPA 1 and the purple‐colored Roxo 29 landraces showed prominent amounts of carotenoids (10.86 10?3 g kg?1) and anthocyanins (2.60 g kg?1), respectively. CONCLUSION: Our findings suggest that the colored grains of maize landraces studied may hold promise for the development of grain‐based functional foods or natural colorants regarding their carotenoid and anthocyanin contents and as genetic resource in breeding programs. Copyright © 2011 Society of Chemical Industry  相似文献   

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This study was conducted to characterize the lipid fraction of 15 chia seed samples originating from five countries (Argentina, Paraguay, Uganda, Bolivia, and Peru). On average, chia seeds contained 34.5 g oil per 100 g dry-solids, in which the average contents of sterols, tocopherols, squalene, carotenoids, and phenolic compounds were 7,061, 600, 17.7, 2.2, and 9.7 mg/kg of oil, respectively. Alpha-linolenic acid share varied from 54.35% to 60.48%, and was accompanied by declining shares of linoleic, palmitic, oleic, and stearic acid, respectively. Principal component analysis showed that chia oil induction time was positively correlated with tocopherols and phenols, while negatively with quality indices and squalene content.  相似文献   

19.
    
Extracts containing anthocyanins (ACN), and skin tannins (SKIN) and seed tannins (SEED) were prepared from Vitis vinifera cv. Cabernet Franc grapes grown in the Loire Valley, and characterised. Phenolic fractions from Cabernet Franc wines made from three Loire Valley locations were also isolated and characterised. Bitterness and astringency of ACN, SEED and SKIN as well as the wine extracts were evaluated by time intensity procedures in citric acid solution and in a base white wine. SEED and SKIN were equally astringent when tasted at the same concentration in spite of differences in tannin composition. The lower molecular weight (MW) of SEED was equal in astringency to larger MW SKIN which had a lower percentage of galloylation. The SEED fraction was slightly more bitter than the SKIN fraction in the citric acid solution, although no difference could be detected between samples in base white wine. Astringency of ACN alone was much lower than either SKIN or SEED. Addition of ACN to either tannin fraction produced very small sensory effects in citric acid. In wine, addition of ACN to either SEED or SKIN increased astringency significantly over either fraction alone, but had no effect on bitterness. The wine fractions differed only in astringency, which was correlated with tannin units as determined by thiolysis.  相似文献   

20.
    
BACKGROUND: The effect of maturation and senescence on the chemical composition of two myrtle cultivars was studied in mature, overripe and cold‐stored fruits in order to find the most appropriate harvesting period and best storage technology for industrial purposes. RESULTS: After cold storage at 10 °C for 15 days, berry weight loss ranged from 12.5 to 18.4%, with the highest losses in less mature fruits. Titratable acidity decreased during maturation and cold storage in both cultivars. Reducing and total sugars increased during maturation. Anthocyanin concentration increased during maturation but decreased in overripe berries. The major organic acids in myrtle fruits were quinic, malic and gluconic acids. In fresh and cold‐stored fruits, malic acid rose to 3 g kg?1 and decreased thereafter. Quinic acid peaked at 90 or 120 days after bloom and decreased thereafter to reach low concentrations in mature fruits. CONCLUSION: Cold storage for 15 days at 10 °C does not affect myrtle fruit quality for liqueur production. Anthocyanin concentration is the best indicator of harvest time for industrial purposes. Gluconic acid concentration is high in mature, overripe and cold‐stored berries. This parameter can be used as a marker of the onset of fruit senescence. Copyright © 2012 Society of Chemical Industry  相似文献   

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