Air emissions scenarios from ethanol as a gasoline oxygenate in Mexico City Metropolitan Area

The Mexican Biofuel Introduction Program states that during year 2010 the three biggest Mexican cities will have a gasoline blending with 6% ethanol available for all gasoline on-road vehicle fleet. Also in 2010 Mexican government has programmed to start the substitution of Tier 1 – the adopted US emission standards – by Tier 2, which are more stringent emission standards for motor vehicles and gasoline sulfur control requirements. How will the air emissions in the Mexico City Metropolitan Area (MCMA) be modified by using this blending? Four scenarios up to year 2030 were constructed and simulated using the Long-Range Energy Alternatives Planning model. Beginning with a BAU or reference scenario, in this scenario the current available fuel is a blending composed by 5% methyl tertiary butyl ether and 95% gasoline (MTBE5). Then, three alternative scenarios that use ethanol as an oxygenate are considered, one with the already programmed E6 blending (6% anhydride ethanol, 94% gasoline), for the sake of comparison the E10 blending (10% anhydride ethanol, 90% gasoline), and the other alternative to compare, ETBE13.7 (13.7% ethyl tertiary butyl ether, 86.3% gasoline; where ETBE is an ether composed by 48% anhydride ethanol and 52% isobutene). Emissions of carbon dioxide (CO₂), carbon monoxide (CO), nitrogen oxides (NOx), particulate matter (PM10), sulfur dioxide (SO₂), total hydrocarbons (THC), benzene, formaldehyde, acetaldehyde and 1,3-butadiene were calculated using emission factors previously calculated using the adapted US-EPA computer model called MOBILE6-Mexico. Results show that Tier 1 and Tier 2 standards effectively lowers all emissions in all studied scenarios with the exception of PM10 and CO₂ emissions. The alternative scenario E10 has the most total avoided emissions by weight but it is not the best when considering some individual pollutants. The greatest environmental benefit of ethanol in its final use as a gasoline oxygenate is for avoiding CO₂ emissions.     

Economics, environment, and energy life cycle assessment of automobiles fueled by bio-ethanol blends in China

This study examines the life cycle economics, environment impacts, and energy consumptions of Chinese automobiles fueled by bio-ethanol blends, utilizing life cycle assessment (LCA) techniques, and puts forward C, Env, En, EEE indicators to assess the economics, combined environmental impacts, energy consumption, and the balance of the three, as a means to evaluate whether the energy utilization efficiency and the domestic environment improvement are achieved at the lowest cost possible. A generic gasoline fueled car is used as a baseline case, and the cassava-based E85 fueled FFV in Guangxi is used as a case study. On the life cycle basis, the cost of cassava-based E85 fueled FFV is about 15% higher than that of gasoline fueled car, of which the two key factors are the price of cassava and gasoline, through a cost breakdown analysis. It also has lower life-cycle emissions of CO₂, CO, HC, and PM pollutants, higher NO_X emissions, while about 20% combined environment indicator is lower than that of the gasoline fueled car. And, it is higher in total energy consumption, lower in fossil fuels and petroleum consumptions, and has a better combined energy indicator. Lastly, the EEE indicator of the cassava-based E85 fueled FFV is about 29% less than that of the gasoline fueled car. Hence, E85 fueled FFV is a better vehicle than the gasoline fueled car, taking the balance of all the 3 “E”s, the energy, environmental and economical aspects, into considerations.     

Energy efficiency and environmental pollution of brickmaking in China

This paper examines the technologies, energy use and environmental pollution of brickmaking in China. China's brick industry is characterized by its enormous size and large number of small producers with outdated technologies. More than 90% of the bricks are fired in annular kilns with coal as the predominant fuel, resulting in substantial SO₂, CO₂ and other air emissions. Based on available energy coefficients and emission factors, coal use for brickmaking and associated SO₂ and CO₂ emissions are estimated. Government policies and options for energy-efficiency improvements in brickmaking are also discussed.     

Inserting renewable fuels and technologies for transport in Mexico City Metropolitan Area

This article describes three future scenarios for the potential reduction of CO₂ emissions and associated costs when biogenic ethanol blends and oxygenates are substituted for gasoline, and hybrid, flex fuel and fuel cell technologies are introduced in passenger automobiles (including pickups and sport-utility vehicles (SUVs)) in the densely populated Mexico City Metropolitan Area (MCMA), analyzed up to the year 2030. A reference (REF) scenario is constructed in which most automobiles are driven by internal combustion engines (ICE) fuelled by gasoline. In the first alternative scenario (ALT1), hybrid electric-ICE gasoline-fuelled cars are introduced in 2006. In the same year, ethyl tertiary butyl ether (ETBE) is introduced as a replacement for methyl tertiary butyl ether (MTBE) oxygenate for gasoline. In the second alternative scenario (ALT2), in addition to the changes introduced in ALT1, flex fuel ICE technology fuelled by E85 is introduced in 2008 and electric motor vehicles driven by direct ethanol fuel cells (DEFC) fuelled by E100 in 2013. A comparison between the reference and alternate scenarios shows that while the total number of vehicles is the same in each scenario, energy consumption decreases by 9% (ALT1) and 17% (ALT2), the total non-biogenic CO₂ emissions drop by 15% (ALT1) and 34% (ALT2), CO₂ mitigation cost is 140.14 $US1997/ton CO₂ (ALT2), and ALT1 has savings and is considered a “no regrets” scenario.     

Energy and greenhouse gas balances of cassava-based ethanol

Biofuel production has been promoted to save fossil fuels and reduce greenhouse gas (GHG) emissions. However, there have been concerns about the potential of biofuel to improve energy efficiency and mitigate climate change. This paper investigates energy efficiency and GHG emission saving of cassava-based ethanol as energy for transportation. Energy and GHG balances are calculated for a functional unit of 1 km of road transportation using life-cycle assessment and considering effects of land use change (LUC). Based on a case study in Vietnam, the results show that the energy input for and GHG emissions from ethanol production are 0.93 MJ and 34.95 g carbon dioxide equivalent per megajoule of ethanol respectively. The use of E5 and E10 as a substitute for gasoline results in energy savings, provided that their fuel consumption in terms of liter per kilometer of transportation is not exceeding the consumption of gasoline per kilometer by more than 2.4% and 4.5% respectively. It will reduce GHG emissions, provided that the fuel consumption of E5 and E10 is not exceeding the consumption of gasoline per kilometer by more than 3.8% and 7.8% respectively. The quantitative effects depend on the efficiency in production and on the fuel efficiency of E5 and E10. The variations in results of energy input and GHG emissions in the ethanol production among studies are due to differences in coverage of effects of LUC, CO₂ photosynthesis of cassava, yields of cassava, energy efficiency in farming, and by-product analyses.     

Environmental aspects of ethanol-based fuels from Brassica carinata: A case study of second generation ethanol

One of the main challenges faced by mankind in the 21st century is to meet the increasing demand for energy requirements by means of a more sustainable energy supply. In countries that are net fossil fuel importers, expectation about the benefit of using alternative fuels on reducing oil imports is the primary driving force behind efforts to promote its production and use. Spain is scarce in domestic energy sources and more than 50% of the energy used is fossil fuel based. The promotion of renewable energies use is one of the principal vectors in the Spanish energy policy. Selected herbaceous crops such as Brassica carinata are currently under study as potential energy sources. Its biomass can be considered as potential feedstock to ethanol conversion by an enzymatic process due to the characteristics of its composition, rich in cellulose and hemicellulose. This paper aims to analyse the environmental performance of two ethanol-based fuel applications (E10 and E85) in a passenger car (E10 fuel: a mixture of 10% ethanol and 90% gasoline by volume; E85 fuel: a mixture of 85% ethanol and 15% gasoline by volume) as well as their comparison with conventional gasoline as transport fuel. Two types of functional units are applied in this study: ethanol production oriented and travelling distance oriented functional units in order to reflect the availability or not of ethanol supply. E85 seems to be the best alternative when ethanol production based functional unit is considered in terms of greenhouse gas (GHG) emissions and E10 in terms of non-renewable energy resources use. Nevertheless, E85 offers the best environmental performance when travelling distance oriented functional unit is assumed in both impacts. In both functional unit perspectives, the use of ethanol-based fuels reduces the global warming and fossil fuels consumption. However, the contributions to other impact indicators (e.g. acidification, eutrophication and photochemical oxidants formation) were lower for conventional gasoline.Life Cycle Assessment (LCA) procedure helps to identify the key areas in the B. carinata ethanol production life cycle where the researchers and technicians need to work to improve the environmental performance. Technological development could help in lowering both the environmental impact and the prices of the ethanol fuels.     

Cost and CO2 aspects of future vehicle options in Europe under new energy policy scenarios

New electrified vehicle concepts are about to enter the market in Europe. The expected gains in environmental performance for these new vehicle types are associated with higher technology costs. In parallel, the fuel efficiency of internal combustion engine vehicles and hybrids is continuously improved, which in turn advances their environmental performance but also leads to additional technology costs versus today’s vehicles. The present study compares the well-to-wheel CO₂ emissions, costs and CO₂ abatement costs of generic European cars, including a gasoline vehicle, diesel vehicle, gasoline hybrid, diesel hybrid, plug in hybrid and battery electric vehicle. The predictive comparison is done for the snapshots 2010, 2020 and 2030 under a new energy policy scenario for Europe. The results of the study show clearly that the electrification of vehicles offer significant possibilities to reduce specific CO₂ emissions in road transport, when supported by adequate policies to decarbonise the electricity generation. Additional technology costs for electrified vehicle types are an issue in the beginning, but can go down to enable payback periods of less than 5 years and very competitive CO₂ abatement costs, provided that market barriers can be overcome through targeted policy support that mainly addresses their initial cost penalty.     

Ethanol in gasoline: environmental impacts and sustainability review article

This study concerns the use of ethanol as a gasoline (petrol) additive, at levels around 10% by volume (‘E10’) as well as an 85% blend (‘E85’). By detailed reviews of the peer-reviewed and technical literature, five environmental aspects of ethanol enrichment are examined: (1) its purported reduction in air pollutant emissions; (2) its potential impact on subsurface soils and groundwater; (3) its purported reduction in greenhouse gas emissions; (4) the energy efficiency of ethanol; and (5) the overall sustainability of ethanol production. The study indicates that E10 is of debatable air pollution merit (and may in fact increase the production of photochemical smog); offers little advantage in terms of greenhouse gas emissions, energy efficiency or environmental sustainability; and will significantly increase both the risk and severity of soil and groundwater contamination. In contrast, E85 offers significant greenhouse gas benefits, however it will produce significant air pollution impacts, involves substantial risks to biodiversity, and its groundwater contamination impacts and overall sustainability are largely unknown.     

Monetary value of the environmental and health externalities associated with production of ethanol from biomass feedstocks

This research is aimed at monetizing the life cycle environmental and health externalities associated with production of ethanol from corn, corn stover, switchgrass, and forest residue. The results of this study reveal current average external costs for the production of 1 l of ethanol ranged from $0.07 for forest residue to $0.57 for ethanol production from corn. Among the various feedstocks, the external costs of PM₁₀, NO_X, and PM_2.5 are among the greatest contributors to these costs. The combustion of fossil fuels in upstream fertilizer and energy production processes is the primary source of these emissions and their costs, especially for corn ethanol. The combined costs of emissions associated with the production and use of nitrogen fertilizer also contribute substantially to the net external costs. For cellulosic ethanol production, the combustion of waste lignin to generate heat and power helps to keep the external costs lower than corn ethanol. Credits both for the biogenic carbon combustion and displacement of grid electricity by exporting excess electricity substantially negate many of the emissions and external costs. External costs associated with greenhouse gas emissions were not significant. However, adding estimates of indirect GHG emissions from land use changes would nearly double corn ethanol cost estimates.     

Dual-injection: The flexible,bi-fuel concept for spark-ignition engines fuelled with various gasoline and biofuel blends

Dual-injection strategies in spark-ignition engines allow the in-cylinder blending of two different fuels at any blend ratio, when simultaneously combining port fuel injection (PFI) and direct-injection (DI). Either fuel can be used as the main fuel, depending on the engine demand and the fuel availability. This paper presents the preliminary investigation of such a flexible, bi-fuel concept using a single cylinder spark-ignition research engine. Gasoline has been used as the PFI fuel, while various mass fractions of gasoline, ethanol and 2,5-dimethylfuran (DMF) have been used in DI. The control of the excess air ratio during the in-cylinder mixing of two different fuels was realized using the cross-over theory of the carbon monoxide and oxygen emissions concentrations. The dual-injection results showed how the volumetric air flow rate, total input energy and indicated mean effective pressure (IMEP) increases with deceasing PFI mass fraction, regardless of the DI fuel. The indicated efficiency increases when using any ethanol fraction in DI and results in higher combustion and fuel conversion efficiencies compared to gasoline. Increasing the DMF mass fraction in DI reduces the combustion duration more significantly than with increased fractions of ethanol or gasoline in DI. The hydrocarbon (HC), oxides of nitrogen (NO_x) and carbon dioxide (CO₂) emissions mostly reduce when using any gasoline or ethanol fraction in DI. When using DMF, the HC emissions reduce, but the NO_x and CO₂ emissions increase.     

Environmental and economic feasibility of sugarcane ethanol for the Mexican transport sector

This study analyzes the environmental and economic feasibility of ethanol produced from sugarcane for use as a potential gasoline substitute in the Mexican transport sector from 2010 to 2030. One scenario was created by projecting the historical trend of energy demand assuming that a fraction of this demand is satisfied with ethanol produced from the cultivation of 2.9 million hectares of sugarcane. A life cycle study was performed according to the recommendations from the European Union Directive on Renewable Energies (that include direct land use change emissions) and was used to estimate life cycle Greenhouse gas (GHG) emissions. The method used by Fingerman et al. (2010) was adopted to estimate the water consumption. In the economic analysis, the production cost of ethanol was calculated, and a mitigation cost for carbon dioxide equivalent emissions was estimated. The potential for employment generation was also estimated. The results demonstrate that water use increases by 29.4 times and that the costs increase by 10,706 million USD with the alternative scenario. This scenario, however, has the potential to create 560,619 direct jobs. Furthermore, GHG mitigation is confirmed since the reference scenario resulted in GHG gasoline life cycle emissions of 78.7 kgCO_2e/GJ while the alternative scenario resulted in Ethanol GHG emissions in the life cycle of 57.52 kgCO_2e/GJ.     

Marginal reductions in vehicle emissions under a dual-blend ethanol mandate: Evidence from a natural experiment

Among the many reasons policy makers across the world have sought to supplement fuel supplies with ethanol-blended fuels are the cited environmental benefits that come with replacing a fossil-fuel with a cleaner burning alternative. Dual-blend ethanol mandates, in which multiple ethanol blends are simultaneously available, are one way policy markers can move forward with more aggressive mandates more quickly. The recent ethanol mandate in the state of New South Wales, Australia offers a unique natural experiment to quantify the potential environmental benefits and costs of a dual blend ethanol policy. This paper estimates the impact on carbon dioxide (CO₂) emissions from road-activity that are attributable to the implementation of the New South Wales ethanol requirements. We find that there was a decrease in emissions due to the policy, but that the decrease is relatively minor given the size of the market and that it comes at a high cost. The cost was over $1200 per ton of carbon to reduce gasoline emissions by just 1.2%.     

Energy balance and GHG-abatement cost of cassava utilization for fuel ethanol in Thailand

Since 2001, in order to enhance ethanol's cost competitiveness with gasoline, the Thai government has approved the exemption of excise tax imposed on ethanol, controlling the retail price of gasohol (a mixture of ethanol and gasoline at a ratio of 1:9) to be less than that of octane 95 gasoline, within a range not exceeding 1.5 baht a litre. The policy to promote ethanol for transport is being supported by its positive effects on energy security and climate change mitigation. An analysis of energy, greenhouse gas (GHG) balances and GHG abatement cost was done to evaluate fuel ethanol produced from cassava in Thailand. Positive energy balance of 22.4 MJ/L and net avoided GHG emission of 1.6 kg CO₂ eq./L found for cassava-based ethanol (CE) proved that it would be a good substitute for gasoline, effective in fossil energy saving and GHG reduction. With a GHG abatement cost of US$99 per tonne of CO₂, CE is rather less cost effective than the many other climate strategies relevant to Thailand in the short term. Opportunities for improvements are discussed to make CE a reasonable option for national climate policy.     

Modeling of current and future energyintensity and greenhouse gas emissions ofthe Lebanese industrial sector: assessmentof mitigation options

Greenhouse gas emissions in Lebanon mainly come from energy activities, which are responsible for 85% of all CO₂ emissions. The CO₂ emissions from energy use in manufacturing industries and construction represent 24% of the total emissions of the energy sector. Lebanese manufacturers' accounted for 39.15 million gigajoules of fuel consumption for heat and power generation in 1994, including both fuel used directly and fuel burned remotely to generate electricity used in the sector. In addition to being processed by combustion, CO₂ is generated in calcining of carbonates in the manufacture of cement, iron and glass. Electricity, the most expensive form of energy, represented 25.87% of all fuel used for heat and power. Residual fuel oil and diesel, which are used mainly in direct combustion processes, represent 26.85 and 26.55% of all energy use by industry, respectively. Scenarios for future energy use and CO₂ emissions are developed for the industrial sector in Lebanon. The development of the baseline scenario relied on available data on major plants' outputs, and on reported amounts of fuels used by the industrial sector as a whole. Energy use in industry and the corresponding greenhouse gas (GHG) emissions for Lebanon are projected in baseline scenarios that reflect technologies, activities and practices that are likely to evolve from the base year 1994 to year 2040. Mitigation work targets a 15% of CO₂ emissions from the baseline scenario by year 2005 and a 20–30% reduction of CO₂ emissions by year 2040. The mitigation options selected for analysis are screened on the basis of GHG emissions and expert judgement on the viability of their wide-scale implementation and economic benefits. Using macroeconomic assessment and energy price assumptions, the final estimates of potential GHG emissions and reduction costs of various mitigation scenarios are calculated. The results show that the use of efficient electric motors, efficient boilers and furnaces with fuel switching from fuel oil to natural gas has the largest impact on GHG emissions at a levelized annual cost that ranges from −20 to −5 US$/tonne of CO₂ reduced. The negative costs are indicative of direct savings obtained in energy cost for those mitigation options.     

Coal cleaning: a viable strategy for reduced carbon emissions and improved environment in China?

China is a dominant energy consumer in global context and current energy forecasts emphasise that China's future energy consumption also will rely heavily on coal. The coal use is the major source of the greenhouse gas CO₂ and particles causing serious health damage. This paper looks into the question if coal washing might work as low cost strategy for both CO₂ and particle emission reductions. Coal washing removes dirt and rock from raw coal, resulting in a coal product with higher thermal energy and less air pollutants. Coal cleaning capacity has so far not been developed in line with the market potential. In this paper an emerging market for cleaned coal is studied within a CGE model for China. The macro approach catches the repercussions of coal cleaning through increased energy efficiency, lower coal transportation costs and crowding out effect of investments in coal washing plants. Coal cleaning stimulates economic growth and reduces particle emissions, but total energy use, coal use and CO₂ emissions increase through a rebound effect supported by the vast reserve of underemployed labourers. A carbon tax on fossil fuel combustion has a limited effect on total emissions. The reason is a coal leakage to tax exempted processing industries.     

Fuel specification,energy consumption and CO2 emission in oil refineries

The more stringent environmental quality specifications for oil products worldwide are tending to step up energy use and, consequently, CO₂ emissions at refineries. In Brazil, for example, the stipulated reduction in the sulfur content of diesel and gasoline between 2002 and 2009 should increase the energy use of Brazil's refining industry by around 30%, with effects on its CO₂ emissions. Thus, the world refining industry must deal with trade-offs between emissions of pollutants with local impacts (due to fuel specifications) and emissions of pollutants with global impacts (due to the increased energy use at refineries to remove contaminants from oil products). Two promising technology options for refineries could ease this clash in the near-to-mid term: the reduction per se of the energy use at the refinery; and the development of treatment processes using non-hydrogen consuming techniques. For instance, in Brazilian refineries, the expanded energy use resulting from severe hydrotreatment to comply with the more stringent specifications of oil products may be almost completely offset by energy saving options and alternative desulfurization techniques, if barriers to invest in technological innovations are overcome.     

Multi-objective design optimization of a natural gas-combined cycle with carbon dioxide capture in a life cycle perspective

The use of multi-objective optimization techniques is attractive to incorporate environmental objectives into the design of energy conversion systems. A method to locally optimize a given process while considering its global environmental impact by using life cycle assessment (LCA) to account for avoidable and unavoidable off-site emissions for each independent material input is presented. It is applied to study the integration of a CO₂-capture process using monoethanolamine in a natural gas-combined cycle power plant, simultaneously optimizing column dimensions, heat exchange, and absorbent flow configuration with respect to two objectives: the levelized cost of electricity and its life cycle global-warming potential. The model combines a process flow-sheeting model and a separate process-integration model. After optimization using an evolutionary algorithm, the results showed that widening the absorber and generating near-atmospheric pressure steam are cost-effective options but that increasing stripper complexity is less so. With $7.80/GJ natural gas and $20/ton CO₂ handling, the minimum on-site CO₂ abatement cost reaches $62.43/ton on a life cycle basis, achieved with a capture rate of over 90%. Of this, $2.13/ton is related to off-site emissions – a specific advantage of LCA that could help industries and governments anticipate the actual future costs of CO₂ capture.     

Effect of different types of fuels tested in a gasoline engine on engine performance and emissions

In this study, three different fuels named G100 (pure gasoline), E20 (volume 20% ethanol and 80% gasoline blend) and ES20 (20% sodium borohydride added ethanol solution and 80% gasoline) were used to test in a gasoline engine. First of all, G100 fuel, E20 and ES20 blended fuels, respectively, were tested in a gasoline engine and the effects of fuels on engine performance and exhaust emissions were investigated experimentally. Experiments were carried out at full load and at five different engine speeds ranging from 1400 to 3000 rpm, and engine performance and exhaust emission values were determined for each test fuel. When the test results of the engine operated with E20 and ES20 blended fuels are compared with the test results of the engine operated with gasoline; engine torque of E20 blended fuel increased by 1.87% compared to pure gasoline, while engine torque of ES20 blended fuel decreased by 1.64%. However, the engine power of E20 and ES20 blended fuels decreased by 2.02% and 5.10%, respectively, compared to the power of pure gasoline engine, while their specific fuel consumption increased by 5.02% and 6.57%, respectively, compared to pure gasoline fueled engine. On the other hand, CO and HC emissions of the engine operated with E20 and ES20 blended fuels decreased compared to the pure gasoline engine, while CO₂ and NO_x emissions increased.     

Assessing total and renewable energy in Brazilian automotive fuels. A life cycle inventory (LCI) approach

This article uses a first approach LCI procedure to evaluate total and renewable energy and CO₂ emissions in Brazilian automotive fuels life cycle (LC). The LC model is structured and modular, capable of being successively refined if necessary. The procedure is applied to passenger car use in urban traffic, comparing three fuels used in Brazil (gasoline with 25% ethanol, pure ethanol and compressed natural gas), considering their use in urban traffic in the city of Rio de Janeiro. An in deep research was made to collect representative and unpublished data of Brazilian automotive fuels LC reality, what is considered a main contribution. The results show where specific advantages occur, particularly in the use of renewable fuels made from biomass, an option already practiced and appropriate for Brazilian reality. The use of gasoline with 25% ethanol shows the lowest total energy consumption for the LC, with similar performance to that of compressed natural gas and 36% better than ethanol from sugarcane. However, the last alternative has the advantage of depending almost exclusively on renewable energy (93%) and producing less net CO₂ emissions.     

Consumer lifestyle approach to US energy use and the related CO2 emissions

Historically, a sectoral approach (based on the industrial, transportation, commercial, and residential sectors) has shaped the way we frame and analyze issues of energy conservation and CO₂ mitigation. This sectoral categorization, however, is limited in its capacity to reveal the total impacts of consumer activities on energy use and its related environmental impacts. In this paper, we propose an alternative paradigm, called the Consumer Lifestyle Approach (CLA), to explore the relationship between consumer activities and environmental impacts in the US. Estimates based on our methodology reveal that more than 80% of the energy used and the CO₂ emitted in the US are a consequence of consumer demands and the economic activities to support these demands. Direct influences due to consumer activities (home energy use and personal travel) are 4% of the US GDP, but account for 28% and 41% of US energy use and CO₂ emissions, respectively. Indirect influences (such as housing operations, transportation operations, food, and apparel) involve more than twice the direct energy use and CO₂ emissions. Characterization of both direct and indirect energy use and emissions is critical to the design of more effective energy and CO₂ emission policies. It may also help erode the false dichotomy of “them versus us” (industrial polluters versus consumers) references to the locus of responsibility for control of energy use and CO₂ emissions.