共查询到20条相似文献,搜索用时 125 毫秒
1.
阴离子分散松香胶中性施胶的研究 总被引:6,自引:0,他引:6
介绍了采用实验室制备的一种特殊的阴离子分散松香胶NL01进行中碱性条件下施胶实验的有关情况,结果表明;pH值6.0-8.5的范围内,采用NL01能获得良好的施胶效果,并且相对传统强化松香胶而言,其消耗硫酸铝的量降低了约80%。NL01中性胶对碱性填料碳酸钙的相容性良好,在用量达到15%时,仍有相当不错的施胶度,而且突破了传统的“阴离子分散松香胶-硫酸铝体系不可用于中性施胶”的观念。 相似文献
2.
研究对比了松香胶-硫酸铝施胶体系下,半水、无水两种石膏晶须用于瓦楞纸加填时对纸张施胶和强度性能的影响,发现以阴离子分散松香胶对加填石膏晶须瓦楞纸进行施胶时,采用先加硫酸铝后加松香胶的逆向施胶工艺,比采用先加松香胶后加硫酸铝的正向施胶工艺施胶效果更好;瓦楞纸生产中加填石膏晶须基本不会影响阴离子分散松香胶的应用效果,对于无水石膏晶须加填纸张,阴离子分散松香胶的最佳用量在3%左右,而对于加填半水石膏晶须纸张施胶剂最佳用量为2%,且相比半水石膏晶须加填纸张在最佳施胶剂用量下有更好的抗水性能;在较低阴离子分散松香胶用量时,施胶剂添加对加填石膏晶须纸张强度影响较小,甚至对半水石膏晶须加填纸张而言,其抗张及耐破强度还有一定改善,但之后随着松香胶用量的进一步增加,加填两种石膏晶须纸张的强度性能呈明显下降趋势。 相似文献
3.
4.
ER-892高分散松香胶的制备和应用研究 总被引:2,自引:0,他引:2
介绍了高浓度、高分散松香胶的制备和应用方法.研究结果表明:该胶游离松香含量高,乳液粒径细,施胶能力强,可减少松香和硫酸铝用量50%~60%,克服夏季施胶障碍,提高纸张理化性能. 相似文献
5.
武工 《精细与专用化学品》1995,(6)
一、概述分散松香胶是一种新型造纸施胶剂,用来代替传统松香皂胶进行施胶,一般可降低松香用量40~60%,硫酸铝20~70%,增白剂50%,使抄造可以在较高pH值下进行提高成纸强度、白度、施胶度等理化指标。 相似文献
6.
武工 《精细与专用化学品》1995,(7)
一、概述分散松香胶是一种新型造纸施胶剂,用来代替传统松香皂胶进行施胶,一般可降低松香用量40%~60%,硫酸铝20%~70%,增白剂50%,使抄造可以在较高pH值下进行提高成纸强度、白度、施胶度等理化指标。 相似文献
7.
8.
《精细与专用化学品》1999,(8)
道纯化工最新推出低泡型分散松香胶 郑州市道纯化工技术公司继首推分散松香胶后再次推出低泡分散松香胶。该分散松香胶采用高分子聚合物代替传统的乳化剂,因此泡沫极小,施胶性能更佳,有利于提高纸机车速、纸张匀度和强度。其产品各项指标和性能均已达到或超过国外同类产品水平。同时其制造成本较阳离子分散松香胶更低,更适合我国国情,是我国造纸企业向中性抄造过渡的质优价廉的原料。 相似文献
9.
10.
11.
ASA emulsions costabilized by Laponite and polyaluminum sulfate (PAS) were prepared by homogenizing the mixture of ASA and aqueous dispersion of Laponite and PAS. The properties, sizing performance and hydrolysis resistance of the prepared ASA emulsions, were investigated in this article. The results show that the introduction of PAS significantly improves the stability, hydrolysis resistance, and sizing performance of ASA emulsions. The ASA emulsion stabilized by 0.5% of Laponite (based on total mass of emulsion) and 2% of PAS (based on the mass of Laponite) shows high hydrolysis stability and high sizing efficiency on bleached chemi‐thermomechanical pulp. At the addition level of 0.3% based on bleached chemi‐thermomechanical pulp, the sizing degree of ASA‐sized paper can be as high as 120 s. Even when the storage time of the ASA emulsion exceeds 3 h, its sizing performance is hardly changed. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
12.
介绍了国内外烷基烯酮二聚体(AKD)中性施胶剂的发展情况,并对AKD的合成原理(脂肪酸的酰氯化和脂肪酸的脱氯化)、施胶机理、影响AKD施胶效率的因素(乳液存放时间和条件、纸张类型、pH值和总碱度、Zeta电位、填料以及其他添加剂等)和AKD的改性等进行了综述。 相似文献
13.
无皂马来酸酐-苯乙烯-丙烯酸酯乳液施胶剂的研究 总被引:1,自引:1,他引:0
以马来酸酐(MAH)、苯乙烯(St)和丙烯酸丁酯(BA)为共聚单体,以过硫酸钾(KPS)/亚硫酸氢钠为氧化还原型引发剂,采用无皂种子乳液共聚法合成了一种阴离子型乳液施胶剂;然后将该施胶剂与氧化淀粉复配制成施胶液。讨论了反应条件对乳液稳定性及施胶液应用性能等影响。结果表明:制备施胶剂的较佳反应条件为m(MAH)∶m(St)∶m(BA)=1.7∶5.7∶4.3、n(KPS)∶n(亚硫酸氢钠)=3∶2且w(KPS+亚硫酸氢钠)=2.5%、反应温度68~75℃和反应时间6 h;该施胶剂的玻璃化转变温度(Tg)为39.02℃和105℃;将该施胶液用于纸张表面施胶时,其纸张施胶度比原纸提高了4倍,其纸张平滑度、耐破度及张力等比纯淀粉施胶液分别提高了89%、17%和58%。 相似文献
14.
比较了聚乙烯醇、十二烷基苯磺酸钠、聚丙烯酰胺、乳化剂TY-01作为纳米碳酸钙的乳化剂时的乳化效果;选用乳化剂TY-01时,确定了其最佳用量以及搅拌、超声波振荡的工作参数;研究了乳化液固含量对黏度和pH值的影响;通过投射电镜观察了纳米碳酸钙的分散情况。结果表明:①4种乳化剂中,乳化剂TY—01的乳化效果最好,其与纳米碳酸钙的最佳质量比为1:20;②配制乳化液时,搅拌转速应大于800r/min,提高搅拌转速、进行超声波振荡可以缩短搅拌时间;③随着乳化液固含量的增加,乳化液的pH值基本不变,乳化液黏度急剧增大;④添加乳化剂的纳米碳酸钙在水中分散均匀,且粒度均匀,平均为50nm。 相似文献
15.
以甲基丙烯酸甲酯(MMA)、丙烯酸(AA)、丙烯酸丁酯(BA)、丙烯腈(AN)和苯乙烯(St)为共聚单体,过硫酸铵(APS)为引发剂,十二烷基硫酸钠(SDS)和非离子型乳化剂(OP-10)为阴/非离子型复合乳化剂,采用种子乳液聚合法和碱溶胀后处理法制备了P(MMA/AA/BA)为核、P(St/AA/AN)为壳的纸张施胶用中空聚合物乳液。研究结果表明:当w(引发剂)=0.80%、m(SDS)∶m(OP-10)=2∶1和w(乳化剂)=1.5%时,中空乳液的综合性能较好,其单体转化率较高、乳液黏度适中、粒径较小且分布较窄。 相似文献
16.
17.
Juan Chen Xin‐Rui Zhou He‐Yi Ge Dong‐Zhi Wang Hua‐Shi Liu Shun Li 《Polymer Composites》2016,37(2):334-341
The nano‐SiO2 particles modified by silane coupling agent A‐1100 were used for preparing the vinyl ester resin (VE) Pickering emulsion. The stable emulsion could be served as the film former of sizing agent for glass fiber (GF). The influence of the wettability and the addition amount of nano‐SiO2 on the stability of film former emulsion was explored. The effect of nano‐SiO2 Pickering emulsion type sizing agent on the properties of GF was investigated. SEM images show that there existed a layer of sizing agent film with nano‐SiO2 particles evenly on the GF surface. The abrasion resistance of the sized GF reached 3,579 times and the stiffness was 69 mm. The strand integrity also performed well. The fracture strength of GF bundles treated by Pickering emulsion type sizing agent increased by 28.6% to 0.504 N/Tex compared with that of the unsized GF bundles. The interlaminar shear strength (ILSS) of GF/VE composites sized by self‐made sizing agent which contained nano‐SiO2 has improved, compared to the unsized GF reinforced VE composite. POLYM. COMPOS., 37:334–341, 2016. © 2014 Society of Plastics Engineers 相似文献
18.
Partially aminated poly‐N‐vinylformamides (APNVF) were prepared by the hydrolysis of PNVF and used as the retention aid of rosin size. The dual retention aids system, consisting of this modern polymer and aluminum sulfate (alum) for neutral‐alkaline paper sizing using acid rosin sizes, was evaluated by experiment. The results indicated that APNVF was very effective and a small amount of the polymer used together with alum considerably increased the size retention and sizing degree of paper under neutral‐alkaline conditions. The cationic charge density of APNVF significantly influenced the sizing efficiency of the rosin sizes. Furthermore, the retention of alkaline filler CaCO3 and paper strength were improved by the polymer addition. It is clear that the polymer can be used as a multifunctional additive for papermaking. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 78: 1805–1810, 2000 相似文献
19.
20.
以廉价无机铝盐硫酸铝为原料,氨水为沉淀剂,十二烷基硫酸钠为添加剂,采用简单沉淀法制备得到较大比表面积γ-Al2O3。通过N2低温物理吸附-脱附、X射线衍射、红外光谱、热重、元素分析、扫描及透射电镜等,研究制备过程中沉淀温度、溶液pH值和添加剂用量对产物γ-Al2O3及其前驱体的晶相结构、形貌织构等性质的影响。结果表明,在沉淀温度75 ℃、硫酸铝浓度0.25 mol·L-1、溶液pH=9.0、老化时间12 h和n(十二烷基硫酸钠)∶n[Al2(SO4)3]=0.375∶1条件下,所得前驱体(拟薄水铝石)经600 ℃焙烧后,可获得大比表面积(416.65 m2·g-1)γ-Al2O3,并且样品中因十二烷基硫酸钠添加,引入的S及Na等杂质含量极少。 相似文献