激光熔覆Ni3Si基复合涂层相、组织及高温抗氧化性能研究

采用激光熔覆技术在镍基高温合金GH864表面制备了原位合成碳化物TiC、NbC陶瓷颗粒增强Ni3Si金属间化合物基复合涂层，采用XRD、SEM和EDAX等方法，对熔覆层相、组织进行了表征。采用循环氧化法研究了熔覆层在1100℃下的高温抗氧化性能。     

激光熔覆Ni基非晶复合涂层组织结构及性能研究

在45钢基体表面预涂覆Ni42Zr30Ta28合金粉末,采用DL-HL-T5000B型无氦横流CO2激光器进行激光熔覆制备非晶复合涂层。利用X射线衍射仪、金相显微镜对熔覆层进行微观组织分析,同时进行了硬度及摩擦性能测试。结果表明:熔覆层组织主要由金属间化合物(Fe7Ta3,Ni7Zr2,FeNi3,Ni3Ta等)、非晶相及纳米晶组成。当功率为3.3 kW时,熔覆层硬度达到最高,为2 954.3HK;磨损率最小,为0.571 mg/mm2。     

激光熔覆Zr65Al7.5Ni10Cu17.5复合涂层组织结构

在钛基体上激光熔覆Zr65Al7.5Ni10Cu17.5合金粉末，得到含非晶、纳米晶复合涂层。涂层由金属间化合物和非晶、纳米晶构成。涂层按组织形貌分为3层：表面枝晶区、中部细晶区和结合区枝晶区。金属间化合物为Al2Zr3,Zr2Cu和Zr2Ni，纳米晶为简单四方Al2Zr3相，晶格常数为：a=b=76．18nm，c=69．85nm。     

激光熔覆TiFe/β-Ti复合涂层组织及耐磨性

以Ti85-Fe15合金粉末为原料,利用激光熔覆技术在TA15钛合金表面制得了由β-Ti初生树枝晶和枝晶间TiFe金属间化合物组成的复合涂层,研究了涂层的显微组织及室温耐磨性能.结果表明,该涂层在室温干滑动磨损条件下具有优异的耐磨性能.     

激光熔覆镍基自润滑涂层的性能

在TC4钛合金表面激光熔覆Ni60/30%WS₂自润滑涂层,研究了不同扫描速度下熔覆层的组织及性能。结果表明,Ni60/30%WS₂激光熔覆层均以W为硬质相,Ti、Ni的固溶体为基体。但不同扫描速度下,熔覆层生成的润滑相不同。扫描速度4 mm/s时,TiS为润滑相;扫描速度12 mm/s时,CrS为润滑相。激光熔覆层硬度在1000~1200 HV0.5之间,较基体提高2倍左右,摩擦因数及磨损率较基体都明显降低。     

激光熔覆陶瓷涂层的组织和性能的研究现状

激光熔覆陶瓷涂层技术是一项新兴的高新技术。该技术利用高能密度的激光束实现金属基体与表面陶瓷层的冶金结合，从而使金属表面获得高的耐磨性、耐热性、耐高温和抗氧化性等综合性能。1激光熔覆陶瓷涂层的组织1．1陶瓷涂层材料和基体材料按组成不同，陶瓷分为氧化物和非氧化物两大类。常用氧化物陶瓷有Al2O3、ZrO2等。非氧化物陶瓷主要是由金属、类金属与C、N、B、Si等元素组成的化合物。陶瓷还可按功能分类。在热功能方面，耐热性较好的有AI刃3、MgO、ZtOZ、TIN等；绝热性较好的有SIO。、AI刀3、SIOZ、AI刀3等。在力学性能方…     

激光熔覆生物陶瓷涂层的组织结构

借助ＸＲＤ及ＳＥＭ对ＴＣ４钛合金表面激光熔覆陶瓷涂层的组织结构进行了研究。结果表明,该涂层为含ＨＡ等钙磷基复合相结构,其组织具有择优取向,有序分布的胞状微晶特征,晶内局部区域有细小粒状物析出,晶界存在第二相,涂层与基体界面为化学冶金结合。该涂层提高了与自然生物硬组织组织结构特性的相似程度。     

激光熔覆Fe-Al复合涂层组织及性能研究

采用粉末预置法,在Q235钢表面激光熔覆Fe-Al复合涂层。采用SEM、XRD等方法分析了涂层的显微组织和物相结构,研究了不同激光工艺参数对涂层显微硬度和耐磨性的影响。结果表明,在优化工艺参数下,涂层与基体形成了良好的冶金结合,组织均匀细密,涂层中含有Al2O3硬质颗粒相及金属间化合物Fe3Al,其硬度和耐磨性得到提高。     

激光熔覆含SiC金属陶瓷涂层显微组织特征

采用连续ＣＯ２激光器在钢表面进行熔覆含ＳｉＣ金属陶瓷涂层。对不同工艺条件下激光熔属层组织结构、成分与硬度进行了研究，对试验结果和凝固过程进行了传热分析。     

激光熔覆MoSi2粉末涂层的组织结构和性能

用XRD、SEM、EDAX和显微硬度仪研究了 4 5钢基体激光熔覆MoSi2 粉末涂层的组织结构和硬度。结果表明 ,由于基体的稀释作用 ,涂层的相组成为FeMoSi、Fe2 Si和少量的Mo5Si3 。涂层组织呈现典型的细小枝晶组织特征 ,枝晶为FeMoSi领先相 ,枝晶间为FeMoSi和Fe2 Si两相共晶 ,组织中无孔隙和裂纹等缺陷。Mo、Si、Fe线扫描成分分析表明 ,这些元素都分布在涂层 基体界面处 ,且缓慢过渡 ,基体与涂层发生互扩散 ,为冶金结合。涂层硬度可达 84 5HV0 5 ,基体硬度为 180HV0 5 ,涂层硬度比基体高 3 7倍。从涂层到基体硬度逐渐降低 ,过渡区比较缓和。     

激光熔覆立铣刀的熔覆层微观结构和性能

采用YAG激光在45号钢表面熔覆钴基自熔合金,利用光学显微镜和电子显微镜技术观察和分析了激光熔覆层的微观组织特征,用X射线衍射仪测试熔覆层的相组成,分析了激光熔覆钴基合金的强化原理,测量了熔覆层金属的显微硬度,证明了激光熔覆层的性能达到了高速钢立铣刀要求的材料性能。     

激光加工参数与熔覆层特征和性能的关系

在HT150基体上进行宽带送粉激光熔覆,研究不同扫描速度和送粉速率条件下熔覆层的显微组织与性能,并对产生熔覆层组织不均匀性的原因进行了探讨.实验结果表明:随着扫描速度和送粉速率的增大,熔覆层组织趋于细化,耐磨性有所提高,在送粉速率较小时,扫描速度作用较显著;其他参数不变的前提下,随扫描速度增大,熔覆层显微硬度增大,界面硬度梯度变陡.     

激光熔覆在金属间化合物涂层材料制备中的应用

在分析金属间化合物涂层材料特点的基础上,综述各种激光熔覆合成金属间化合物涂层的研究现状,分析了各种金属间化合物涂层的组织和性能.研究表明,激光熔覆合成的金属间化合物涂层均具有优异的耐磨、耐腐蚀、抗氧化等性能.     

铁基合金+WC激光熔覆层的显微组织与性能

在Q235钢和QT-600球铁表面激光熔覆铁基合金+WC粉末.利用扫描电镜(SEM)、光学显微镜(OM)、能谱仪(EDS)和X射线衍射仪(XRD)分析了熔覆层的微观组织,测试了熔覆层硬度和磨损性能.结果表明,Q235钢表面熔覆层组织较细,熔覆层与基体结合界面波形不明显,且出现白亮层.QT-600球铁表面熔覆层组织粗大,界面波形较大,基体混入多,无白亮层,硬度、耐磨性相对较低.分析认为,组织与性能的不同是由于Q235钢熔点较高,熔化量少,且熔池冷速快,组织细化.QT-600球铁表面熔覆层组织不均匀,其中等轴品的耐磨性高于柱状晶,原因在于较细的等轴晶晶界较多,增大了滑动阻力.     

Fabrication and microstructure of Fe-based amorphous composite coatings by laser cladding

Fe-based amorphous composite coatings were fabricated on AISI 1045 steel by laser cladding. The results of the X-ray diffraction and transmission electron microscopy analyses show the coating is composed of an amorphous phase in majority and a nanocrystalline phase in minority. Phase composition of the coating changes along the depth of the coating. The reasonable scanning speed for fabricating an amorphous composite coating is 3 500mm/min when the laser power is 4 800W and the laser beam diameter is 2mm. If the scanning speed is lower than 3 500mm/min, the intensity of the two main diffraction peaks in X-ray diffraction patterns of the coatings decreases with the scanning speeds increasing. At the same time, a broad halo peak emerges and enlarges. High laser power and fast scanning speed are the essential conditions of amorphization. The coating exhibits high microhardness.     

Microstructures and properties of Fe-Co-B-Si-Nb coating prepared by laser cladding and remelting

High power laser cladding of [(Fe0.5Co0.5)0.75B0.2Si0.05] 95.7 Nb4.3 powder mixture afier-remelting was performed to fabricate Fe-based metallic glass coating on the surface of steel of China Classification Society:Grade B (CCS-B).Scanning electron microscopy (SEM),X-ray diffraction (XRD),transmission electron microscopy (TEM)with energy dispersive spectrometer (EDS),Vickers hardness tester and corrosion resistance tester were employed to characterize microstructures and evaluate properties of this coating.According to the results of SEM ,XRD and TEM ,the cladding coating consisted of nanocrystalline embedded in amorphous phase.EDS data indicated that Nb segregated in the amorphous matrix.The results of hardness test revealed that the hardness of the top layer was higher than that of the inner layer of the coating.The coating exhibited excellent corrosion resistance in a 3.5% NaCl solution.     

Microstructure and properties of WC-12Co composite coatings prepared by laser cladding

A comprehensive study of the phase composition, microstructure evolution, microhardness and wear performance of WC-12Co composite coatings fabricated by laser cladding using coaxial powder-feed mode was presented. It was shown that a combination of high scan speed and high laser energy density made WC on the edge of WC-12Co composite powders partially melt in liquid Co and 304 stainless steel matrix, and then new carbides consisting of lamellar WC and herringbone M₃W₃C (M=Fe, Co) were formed. Meanwhile, WC-12Co composite coatings with no porosity, cracks and drawbacks like decarburization were obtained, showing high densification and good metallurgical bonding with the substrate. Furthermore, a considerably high microhardness of HV_0.3 1500-1600, low coefficient of friction of 0.55 and wear rate of (2.15±0.31)×10^-7 mm³/(N·m) were achieved owing to the synergistic effect of excellent metallurgical bonding and fine microstructures of composite coating under laser power of 1500 W.     

304LN不锈钢表面激光熔覆钴基合金组织和性能

为了提高304LN不锈钢的耐磨性,延长控制棒导向筒组件使用寿命,采用激光熔覆技术在304LN不锈钢表面制备了Stellite 6钴基熔覆层.利用光学显微镜(OM)、能谱仪(EDS)、显微硬度计、摩擦磨损试验机、腐蚀试验装置等多种试验测试设备,分析了熔覆层组织形貌、成分、显微硬度、摩擦磨损性能及腐蚀行为,确定了多道多层钴基熔覆层的工艺参数.结果表明,熔覆层与基体之间形成了冶金结合,显微组织主要由平面晶区、胞状和柱状晶区、树枝晶区和等轴晶区组成.熔覆层硬度为500 ~ 550 HV,摩擦磨损系数为0.30 ~ 0.35,熔覆层均匀腐蚀速率和缝隙腐蚀速率分别为0.153 和0.143 mg/(dm2·d). 激光熔覆钴基合金可以有效提高304LN不锈钢表面的硬度、耐磨性能和耐腐蚀性能.     

钛合金表面激光熔覆钴基合金层的组织及力学性能

在TC4钛合金表面利用激光熔覆Co基合金粉末涂层,利用扫描电镜(SEM)、能谱分析仪(EDS)和洛氏硬度计研究涂层的微观组织及力学性能。结果表明:当扫描速度固定为400 mm/s,激光功率为1.3、1.5、1.7 k W熔覆时,涂层与基体之间都实现了冶金结合。其中,激光功率为1.5 k W时熔覆效果最好,熔覆层内组织均匀致密无气孔和裂纹等缺陷。激光功率为1.3 k W时,熔覆层内出现了裂纹。当激光功率固定为1.5 k W,扫描速度为300、350、400 mm/s时,熔覆层和基体的结合情况良好,熔覆层内组织均匀致密无缺陷。随着激光功率和扫描速度的增大,涂层表面硬度呈减小的趋势,但都高于TC4基体硬度的两倍左右,表明在TC4表面激光熔覆Co基合金粉末涂层可以显著提高其硬度。     

Investigation of microstructure of laser cladding Ni-WC layer on Al-Si alloy

A plasma-sprayed Ni-WC layer was deposited on an Al-Si cast alloy surface, and then it was further melted by a 5 kW CO₂ laser. The microstructure and chemical composition of the laser-melted zone were investigated, and the microhardness in different parts was measured. Experimental results showed that the chemical composition of the sample was not uniform. Compositional segregation in the laser-melted zone was found. Some amorphous structure appeared in the nickel-rich locations after laser melting. Owing to the thermal effect of the laser scanning, an intermediate-phase Ni₃Al segregated from this region and formed Ni₃Al grains and amorphous grains. Some WC particles melted in the matrix, and chromium carbide Cr2;|C6 and (Cr,W)C separated during the cooling process. The highest microhardness (1027HV) was found in the high-nickel region.