共查询到20条相似文献,搜索用时 109 毫秒
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复合镀层由于具有优异的耐磨性、耐蚀性、自润滑等性能而受到广泛关注.采用电沉积或化学镀可以获得复合镀层,复合电镀也是制备复合材料的一种重要方法.本文主要对近几年国内外在镍基自润滑复合镀层方面取得的研究成果进行了概述. 相似文献
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采用电沉积方法,在船用柴油机活塞杆表面分别制备纳米微粒增强镍基复合镀层、亚微米微粒增强镍基复合镀层和微米微粒增强镍基复合镀层。分析了三者的显微形貌、晶相结构及磨痕形貌,并测定了硬度。结果表明:与亚微米微粒增强镍基复合镀层和微米微粒增强镍基复合镀层相比,纳米微粒增强镍基复合镀层的外观显得更加光亮,硬度接近5 800 MPa。 相似文献
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铝基体复合电沉积镍–碳纳米管复合镀层 总被引:1,自引:0,他引:1
采用电沉积法在铝基体上制备了镍–碳纳米管复合镀层,探讨了镀液中碳纳米管含量、电流密度、搅拌速率、温度、电镀时间等因素对镀层碳纳米管含量和厚度的影响,得出制备镍–碳纳米管复合镀层的适宜工艺条件为:碳纳米管质量浓度4 g/L,电流密度8 A/dm2,搅拌速率440 r/min,温度40°C,沉积时间40 min。采用扫描电镜和X射线衍射仪对镀层表面形貌和成分进行分析,通过电化学测试比较了不同镀层在不同腐蚀介质中的耐腐蚀性。与纯镍镀层相比,镍–碳纳米管复合镀层的晶粒尺寸更小,表面更粗糙,耐腐蚀性更好。 相似文献
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镍基纳米复合镀层的研究进展 总被引:2,自引:0,他引:2
综述了镍基纳米复合镀层的研究现状。阐述了复合镀层的沉积机理、纳米微粒在复合镀层中的作用机理、纳米微粒在镍基镀液中的分散以及镍基纳米复合镀层的种类和性能。指出了纳米复合镀技术研究中存在的问题和发展方向。 相似文献
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研究了加入稀土对电沉积Ni-W-B-SiC复合镀层的成份、结构、表面形貌、硬度等性能的影响规律.结果表明加入稀土有利于SiC与Ni-W-B的共沉积,使镀层结晶细化,RE-Ni-W-B-SiC复合镀层的硬度高于Ni-W-B-SiC复合镀层. 相似文献
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《Ceramics International》2023,49(6):9239-9250
Zinc oxide coatings were electrodeposited on Ti6Al4V substrates from a nitrate bath with and without 1 wt% BG nanoparticles at ?1.2 and ?1.4 VAg/AgCl, where the former voltage created a spherical morphology, the latter developed a flower-like one. The spherical morphology was modified through the incorporation of BG nanoparticles, where surface roughness, wettability, and adhesion strength of the coating were enhanced. The coatings with spherical morphology also revealed complete barrier property after immersion in PBS solution. However, fully adverse effects were found for the coatings deposited at ?1.4 VAg/AgCl. This indicates that morphology is the most important factor determining the properties of ZnO and ZnO-BG coatings. The highest corrosion barrier performance was achieved for the ZnO-BG composite coating with spherical morphology. Although the composite coating with flower-like morphology did not provide complete barrier property at short immersion times, it earned that at longer times due to the plugging supported by the BG nanoparticles. The bioactivity tests in SBF at long times showed that the formation of Ca-P deposits on the surface of the composite coatings was noticeably improved. 相似文献
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Polyaniline (PANI) and poly(N-methylaniline) (PNMA) have been electrodeposited on mild steel from oxalic acid bath using cyclic voltammetric technique. Pretreatments like passivation and primer polymer coatings were required for effective coating. Differently stacked composite polymer layers on the metal surface by layer-by-layer approach have also been obtained and their properties have been compared with their corresponding copolymer coatings. FTIR study confirms the formation of electroactive polymer compounds on mild steel. Evaluation of these coatings in 3.5% NaCl solution by potentiodynamic polarization and electrochemical impedance spectroscopy reveals significant corrosion resistant behavior. Relatively higher corrosion protection is exhibited by copolymer coatings and composite-bilayer coatings than the corresponding homopolymer coatings. The composite metal–PANI–PNMA layer shows higher stability and better protection than the metal–PNMA–PANI layer. 相似文献
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Camelia Ungureanu Cristian PirvuMihaela Mindroiu Ioana Demetrescu 《Progress in Organic Coatings》2012
In order to enhance properties of the polymer composite films, composite coatings based on polypyrrole (PPy) and polyethylene glycol (PEG), using various percentages of PEG (0.5%, 2%, 4%), were electrodeposited on a new titanium alloy electrode as insulating material. The structure of the coatings was investigated via infrared (FTIR) analysis, and the surface features were studied using contact angle determination, atomic force microscopy (AFM) and scanning electronic microscopy (SEM). When testing the antibacterial properties of the coatings, the best effect was found for the coating with 2% PEG concentration, which has hydrophilic character and small roughness. Such results are in concordance with mechanism of biomaterial–bacteria interaction which involves as factors affecting bacterial adhesion and growth an initial physicochemical interaction stage, where roughness and wettabilitty are factors promoting bacterial adhesion and biofilm deposition. 相似文献
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Nano-composite coatings were formed by incorporating 3 wt% nano-ZnO in a polyurethane-based waterborne coating. The nano-ZnO based composite coatings were applied on standard phosphated steel panels by cathodic electrodeposition. The electrodeposited nano-composite coatings were then baked for 20 min at 165 °C. To investigate the corrosion resistance of the coatings, the coated panels were immersed in 3.5 wt% NaCl solutions for 2880 h (120 days). The improvement in corrosion performance of the composite coatings was evaluated using electrochemical impedance spectroscopy technique. It was found that the films containing nano-sized ZnO particles show a corrosion resistance of 2 orders of magnitude higher than that of the neat films. 相似文献
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Sanja Eraković Djordje Veljović Papa N. Diouf Tatjana Stevanović Miodrag Mitrić Djordje Janaćković Ivana Z. Matić Zorica D. Juranić Vesna Mišković-Stanković 《Progress in Organic Coatings》2012
Composite coatings based on lignin, obtained by electrophoretic deposition (EPD) on titanium, were investigated. The aim of this work was to produce hydroxyapatite/lignin (HAP/Lig) coatings on titanium and to investigate the effect of the lignin concentration on microstructure, morphology, phase composition, thermal behavior and cytotoxicity of the HAP/Lig coatings. An organosolv lignin was used for the production of the composite coatings studied in this research. The properties of HAP/Lig coatings were characterized using X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), thermogravimetric analysis (TGA), attenuated total reflection Fourier transform infrared spectroscopy (ATR-FT-IR) and X-ray photoelectron spectroscopy (XPS), as well as the MTT test of cytotoxicity. The results showed that higher lignin concentrations protected the HAP lattice during sintering, thereby improving the stability of the HAP/Lig coatings. The cell survival of peripheral blood mononuclear cells (PBMC) after proliferation indicates that the HAP/Lig coating with 1 wt% Lig electrodeposited on titanium was non-toxic with significant promise as a potential bone-repair material. 相似文献