NSTX plasma operation with a Liquid Lithium Divertor

NSTX 2010 experiments were conducted using a molybdenum Liquid Lithium Divertor (LLD) surface installed on the outer part of the lower divertor. This tested the effectiveness of maintaining the deuterium retention properties of a static liquid lithium surface when refreshed by lithium evaporation as an approximation to a flowing liquid lithium surface. The LLD molybdenum front face has a 45% porosity to provide sufficient wetting to spread 37 g of lithium, and to retain it in the presence of magnetic forces. Lithium Evaporators were used to deposit lithium on the LLD surface. At the beginning of discharges, the LLD lithium surface ranged from solid to liquefied depending on the amount of applied and plasma heating. Noteworthy improvements in plasma performance were obtained similar to those obtained previously with lithiated graphite, e.g., ELM-free, quiescent edge, H-modes. During these experiments with the plasma outer strike point on the LLD, the rate of deuterium retention in the LLD, as indicated by the fueling needed to achieve and maintain stable plasma conditions, was the about the same as that for solid lithium coatings on the graphite prior to the installation of the LLD, i.e., about two times that of no-lithium conditions. The role of lithium impurities in this result is discussed. Following the 2010 experimental campaign, inspection of the LLD found mechanical damage to the plate supports, and other hardware resulting from forces following plasma current disruptions. The LLD was removed, upgraded, and reinstalled. A row of molybdenum tiles was installed inboard of the LLD for 2011 experiments with both inner and outer strike points on lithiated molybdenum to allow investigation of lithium plasma facing issues encountered in the first testing of the LLD.     

Surface chemistry analysis of lithium conditioned NSTX graphite tiles correlated to plasma performance

Lithium wall conditioning in NSTX has resulted in reduced divertor recycling, improved energy confinement, and reduced frequency of edge-localized modes (ELMs), up to the point of complete ELM suppression. NSTX tiles were removed from the vessel following the 2008 campaign and subsequently analyzed using X-ray photoelectron spectroscopy as well as nuclear reaction ion beam analysis. In this paper we relate surface chemistry to deuterium retention/recycling, develop methods for cleaning of passivated NSTX tiles, and explore a method to effectively extract bound deuterium from lithiated graphite. Li–O–D and Li–C–D complexes characteristic of deuterium retention that form during NSTX operations are revealed by sputter cleaning and heating. Heating to ～850 °C desorbed all deuterium complexes observed in the O 1s and C 1s photoelectron energy ranges. Tile locations within approximately ±2.5 cm of the lower vertical/horizontal divertor corner appear to have unused LiO bonds that are not saturated with deuterium, whereas locations immediately outboard of this region indicate high deuterium recycling. X-ray photo electron spectra of a specific NSTX tile with wide ranging lithium coverage indicate that a minimum lithium dose, 100–500 nm equivalent thickness, is required for effective deuterium retention. This threshold is suspected to be highly sensitive to surface morphology. The present analysis may explain why plasma discharges in NSTX continue to benefit from lithium coating thickness beyond the divertor deuterium ion implantation depth, which is nominally <10 nm.     

Influence of lithium coatings with large-area coverage on EAST plasma performance

Over the last two EAST campaigns, lithium coatings by oven evaporation were carried out as a routine wall conditioning method and significant progresses has been achieved. By upgrading the EAST lithium coating systems, lithium area coverage increased from ∼35% in 2010 to ∼85% in 2012. Accompanying the increased lithium coverage, carbon, oxygen and molybdenum impurities were decreased to extremely low levels. In addition, hydrogen concentration was further decreased with the H/(H + D) ratio falling as low as 2.5%. The effective recycling coefficient decreased step-by-step to ∼0.89 and remained below unity for ∼100 discharges. This allowed for effective feedback control of the plasma density. The wall retention rate increased from 55% to 75%, which also indicated stronger pumping of deuterium particles with increased Li coverage. With the help of increased lithium coverage, H-mode plasmas were generally easier to obtain and the EAST parameter space was enlarged.     

The first results of deuterium retention on EAST with a full graphite wall via particle balance

This paper introduces the first results of deuterium retention on the Experimental Advanced Superconducting Tokamak (EAST) using particle balance.In the fall 2010 EAST experiments with a full graphite wall,the average deuterium retention fraction was about 19％ (including disruptive shots) and 38％ (not including disruptive shots).Fuel retention for the short-and long-pulse discharge was different.The H-mode discharges had a slightly lower fuel retention than the L-mode discharges.However,it was observed that disruptions introduced outgassing from the wall.Wall conditioning,such as lithium coating,increases retention.     

Investigation of lithium as plasma facing materials on HT-7

First experiment of liquid lithium limiter was successfully carried out on HT-7 tokamak and a few positive results were obtained. The results showed that by using lithium limiter, specially liquid lithium limiter, Hα intensity reduced 20-30%, the emission of CIII and OV decreased about 10-20%, loop voltage had a slight decline, the core electron temperature slightly increased, the particle confinement time increased by a factor of 2, and the energy confinement time increased 20%. After lithium coating, the hydrogen recycling decreased, and core electron temperature increased significantly by a factor of 2. At the same time, after lithium coating, electron density of edge plasmas obviously decreased while electron temperature slightly increased. These encouraging results are very useful for further research of long tray lithium limiter on HT-7 and liquid divertor on EAST.     

Study of the tungsten sputtering source suppression by wall conditionings in the EAST tokamak

The steady fusion plasma operation is constrained by tungsten(W) material sputtering issue in the EAST tokamak. In this work, the suppression of W sputtering source has been studied by advanced wall conditionings. It is also concluded that the W sputtering yield becomes more with increasing carbon(C) content in the main deuterium(D) plasma. In EAST, the integrated use of discharge cleanings and lithium(Li) coating has positive effects on the suppression of W sputtering source. In the plasma recovery experiments, it is suggested that the W intensity is reduced by approximately 60% with the help of ～35 h Ion Cyclotron Radio Frequency Discharge Cleaning(ICRF-DC) and ～40 g Li coating after vacuum failure. The first wall covered by Li film could be relieved from the bombardment of energetic particles, and the impurity in the vessel would be removed through the particle induced desorption and isotope exchange during the discharge cleanings. In general, the sputtering yield of W would decrease from the source, on the bias of the improvement of wall condition and the mitigation of plasmawall interaction process. It lays important base of the achievement of high-parameter and longpulse plasma operation in EAST. The experiences also would be constructive for us to promote the understanding of relevant physics and basis towards the ITER-like condition.     

Recent progress of NSTX lithium program and opportunities for magnetic fusion research

Lithium wall coating techniques have been experimentally explored on National Spherical Torus Experiment (NSTX) for the last six years. The lithium experimentation on NSTX started with a few milligrams of lithium injected into the plasma as pellets and it has evolved to a dual lithium evaporation system which can evaporate up to ～160 g of lithium onto the lower divertor plates between re-loadings. The unique feature of the NSTX lithium research program is that it can investigate the effects of lithium coated plasma-facing components in H-mode divertor plasmas. This lithium evaporation system has produced many intriguing and potentially important results. In 2010, the NSTX lithium program has focused on the effects of liquid lithium divertor (LLD) surfaces including the divertor heat load, deuterium pumping, impurity control, electron thermal confinement, H-mode pedestal physics, and enhanced plasma performance. To fill the LLD with lithium, 1300 g of lithium was evaporated into the NSTX vacuum vessel during the 2010 operations. The routine use of lithium in 2010 has significantly improved the plasma shot availability resulting in a record number of plasma shots in any given year. In this paper, as a follow-on paper from the 1st lithium symposium [1], we review the recent progress toward developing fundamental understanding of the NSTX lithium experimental observations as well as the opportunities and associated R&D required for use of lithium in future magnetic fusion facilities including ITER.     

Study of deuterium retention on lithiated tungsten exposed to high-flux deuterium plasma using laser-induced breakdown spectroscopy

Tungsten is under consideration for use as a plasma-facing material in the divertor region of ITER. Lithiation can significantly improve plasma performance in long-pulse tokamaks like EAST. The investigation of lithiated tungsten is important for understanding the lithium conditioning effects for EAST, where tungsten will be used as a plasma-facing material. In this paper, a few important issues of lithiated tungsten interacting with high-flux deuterium plasma have been studied, such as the effect of lithiation on deuterium retention, the profile of elemental distribution, and the chemical state of lithiated tungsten. Deuterium retention inside both pure and lithiated tungsten has been investigated for the first time in the linear plasma simulator Magnum-PSI by in-situ laser induced breakdown spectroscopy (LIBS). The results indicate that, after deuterium plasma exposure, deuterium retention could be saturated in the lithiation layer, and the lithium in the lithiated layer is chemically bound with deuterium. Moreover, the lithiation can inhibit the blistering on the tungsten surface. These results can be valuable for the application of LIBS as a diagnostic technique for plasma-facing components of tokamaks.     

Deuterium ion-surface interactions of liquid-lithium thin films on micro-porous molybdenum substrates

Lithium has been utilized to enhance the plasma performance for a variety of fusion devices such as TFTR, CDX-U and NSTX. Lithium in both the solid and liquid states has been studied extensively for its role in hydrogen retention and reduction in sputtering yield. A liquid lithium diverter (LLD) was recently installed in the National Spherical Torus Experiment (NSTX) fusion reactor to investigate lithium applications for plasma-facing surfaces (PFS). Representative samples of LLD material were exposed to lithium depositing and simulated plasma conditions offline at Purdue University to study changes in surface chemical functionalities of Mo, O, Li and D. X-ray photoelectron spectroscopy (XPS) conducted on samples revealed two distinct peak functionalities of lithiated porous molybdenum exposed to deuterium irradiation. The two-peak chemical functionality noticed in porous molybdenum deviates from similar studies conducted on lithiated graphite; such deviation in data is correlated to the complex surface morphology of the porous surface and the correct “wetting” of lithium on the sample surface. The proper lithium “wetting” on the sample surface is essential for maximum deuterium retention and corresponding LLD pumping of deuterium.     

An overview of lithium experiments on HT-7 and EAST during 2012

In 2012, lithium coating with an upgraded system on EAST, the first application of lithium granules injection for ELMs pacing on EAST, and the first flowing lithium limiter experiments on HT-7 have successfully been carried out and several new results were obtained. On EAST, it was found that both the Mo first walls and the C divertors were well coated by lithium and the lithium film coverage was increased up to 85%, which greatly contributed to the new achievements of EAST, especially stationary H-mode plasma over 30 s and long pulse plasma over 400 s. And at the same time, ELMs suppression by active lithium conditioning and ELMs pacing using lithium granules injection were demonstrated and reported for the first time on EAST. On HT-7, flowing liquid lithium limiters using the TEMHD concept and using a thin flowing film concept were also initially tested and some references were obtained for the future development. Those experiments show that lithium should be an important material for fusion devices. It could be used for wall conditioning, ELMs mitigation and also provide a self-recovery plasma facing components in future fusion devices.     

Status and prospect of the development of liquid lithium limiters for stellarotor TJ-II

Stellarator concept is considered as a promising approach for power fusion reactor development because it basically free from disruptions and other extreme thermal load events. However, the potential problem of impurity accumulation in stellarator plasma should be taken into account. Very promising results in density control, plasma reproducibility and confinement characteristics have been obtained with application of “lithiation” technology. The next step in the improvement of TJ-II Heliac plasma performance is the development and creation of two poloidal liquid lithium limiters (LL). Experimental possibilities, design, structural materials and main parameters of LL based on capillary-pore structure (CPS) filled with liquid lithium are considered. Understanding in hydrogen isotope interaction with liquid lithium surface is an important aspect of lithium technology development for fusion reactor application. Therefore study of deuterium sorption/desorption process on a lithium surface of LL is stipulated. The development of lithium CPS based devices decreasing intensity of plasma–wall interaction on a central “groove” of TJ-II vacuum camera is proposed as the further step in plasma performance improvement owing to decrease in impurity flux from the wall.     

Functions of intrinsic magnetic field line structures on lithium ion transport in the LHD plasma periphery

Plasma discharge operation with lithium coating suggests that the lithium effectively control neutral particles in the plasma periphery, which can lead to improvement of plasma parameters. The effect of lithium coating on the large helical device (LHD) for a closed helical divertor configuration is discussed from viewpoints of neutral particle and impurity ion transport in the plasma periphery. It shows that the closed helical divertor configuration can enhance the neutral particle density in the divertor region, which is enough to achieve efficient particle control, and that it can effectively confine neutral lithium atoms near divertor plates. A one-dimensional impurity (lithium) ion transport analysis along magnetic field lines on divertor legs indicates that the friction force due to the plasma flow from the main plasma is dominant over the thermal force caused by the temperature gradient on the divertor legs, which prevents lithium ion contamination in the main plasma and excessive cooling of the plasma temperature in an ergodic layer. The analysis shows that the lithium coating is compatible with LHD plasma discharge operation for the closed helical divertor configuration.     

Sorption and desorption behavior of hydrogen isotopes from tungsten deposits caused by deuterium gas or deuterium plasma exposure

To understand the behavior of hydrogen isotopes in deposits formed on plasma-facing wall is an important issue for development of a fusion reactor. In this study, sorption/desorption behaviors of hydrogen isotopes when tungsten deposits were exposed to deuterium gas or deuterium plasma at 300 °C were investigated. Samples of tungsten deposits were produced by the sputtering method using hydrogen plasma. After deuterium gas exposure or deuterium plasma exposure, the desorption behavior of hydrogen isotopes from the deposit was observed by the thermal desorption spectroscopy method. It was found that not a small amount of deuterium is retained in tungsten deposit by not only the plasma exposure but also the gas exposure while the amount of hydrogen incorporated in the deposit during sputter-deposition process is reduced. The amount of deuterium retained in the deposit by the plasma exposure was larger than that by the gas exposure in the experimental conditions in this work. The amount of hydrogen left after deuterium plasma exposure was larger than that after deuterium gas exposure.     

Properties of Electrodeposited Tungsten Coatings on Graphite Substrates for Plasma Facing Components

Tungsten coating on graphite substrate is considered as one of promising candidate materials of plasma facing components. In this study, tungsten coatings on graphite substrate were successfully prepared by direct current (DC) and pulse current (PC) electrodeposition methods in Na₂WO₄–WO₃ molten salt under the air atmosphere. Pores were found on the surfaces of the tungsten coatings produced by DC electrodeposition method. For the coatings fabricated by PC method, compact and smooth tungsten coatings were successfully obtained. The crystal structure, morphology, density, microhardness, adhesive strength, oxygen content and the thermal conductivity of the coatings fabricated by PC method were investigated. The obtained tungsten coatings had a body centered cubic structure. After electro-deposition for 100 h, the thickness of the tungsten coating reached 810.02 ± 10.40 μm and the oxygen content was 0.03 wt%. The thermal conductivity of the tungsten coating was 134.29 W m^?1 K^?1. The density of the tungsten coating was 18.83 g cm^?3. The hardness of the coating was 492.0 ± 7.8 HV. After deuterium plasma irradiation, the tungsten coatings were prone to blistering.     

Lithium coatings on NSTX plasma facing components and its effects on boundary control, core plasma performance, and operation

NSTX high power divertor plasma experiments have used in succession lithium pellet injection (LPI), evaporated lithium, and injected lithium powder to apply lithium coatings to graphite plasma facing components. In 2005, following the wall conditioning and LPI, discharges exhibited edge density reduction and performance improvements. Since 2006, first one, and now two lithium evaporators have been used routinely to evaporate lithium onto the lower divertor region at total rates of 10-70 mg/min for periods 5-10 min between discharges. Prior to each discharge, the evaporators are withdrawn behind shutters. Significant improvements in the performance of NBI heated divertor discharges resulting from these lithium depositions were observed. These evaporators are now used for more than 80% of NSTX discharges. Initial work with injecting fine lithium powder into the edge of NBI heated deuterium discharges yielded comparable changes in performance. Several operational issues encountered with lithium wall conditions, and the special procedures needed for vessel entry are discussed. The next step in this work is installation of a liquid lithium divertor surface on the outer part of the lower divertor.     

Temperature and composition dependence of the high flux plasma sputtering yield of Cu-Li binary alloys

Because of its very high thermal conductivity, actively cooled copper is an attractive plasma-interactive material for long pulse fusion devices such as ETR and devices with very high wall power loadings, such as reversed-field pinched (RFPs) and the proposed compact ignition torus (CIT). Pure copper however, has an unacceptably low threshold energy for runaway self-sputtering. Low Z materials such as graphite and beryllium are not subject to runaway self-sputtering, but suffer from high light ion erosion rates and very nonuniform redeposition. It has been suggested that strongly segregating alloys such as Cu-Li might be used to provide a low-Z self-sustaining coating while maintaining the desirable redeposition, thermal and mechanical properties of the majority alloy component.High flux deuterium plasma sputtering and ion beam experiments have been performed on Cu-Li alloys to determine if the reduction in copper erosion previously predicted and observed in low flux ion beam experiments occurs at particle fluxes representative of an RFP first wall or tokamak limiter. Partial sputtering yields of the copper and lithium components have been measured as a function of alloy composition and sample temperature using optical plasma emission spectroscopy, weight loss and catcher foil techniques. It is found that the lithium sputtering yield increases with increasing sample temperature while the copper yield decreases by as much as two orders of magnitude. The temperature required to obtain the reduction in copper erosion is found to be a function of bulk lithium concentration. Consequences of these experimental results for anticipated erosion/redeposition properties are calculated, and the Cu-Li alloy is found to compare favorably with conventional low-Z materials.     

Deuterium retention in SiC coated graphite by D2+ implantation

The doped graphite tiles bolted to the active cooling heat sink, made of GBST1308 (1% B₄C, 2.5% Si, 7.5% Ti) coated with SiC, are now being used as the only plasma facing material (PFM) for the EAST device since the campaign of 2008. From the plasma density and fueling point of view, it is important to study thoroughly the hydrogen isotope retention in this kind of SiC-coated doped graphite. D₂⁺ implantations into the SiC coated doped graphite were performed at Shizuoka University. The chemical states of Si and C were studied by means of X-ray photoelectron spectroscopy (XPS), and the thermal desorption behavior of deuterium was analyzed by thermal desorption spectroscopy (TDS). It was found that deuterium was trapped by both C and Si in the SiC coatings. In the previous studies, Oya et al. reported the deuterium retention behavior in polycrystalline β-SiC. In this paper, difference of retention behavior in β-SiC and SiC coating will be also discussed.     

Mapping of hydrogen isotopes with a scanning nuclear microprobe

Elastic recoil detection analysis using heavy ions with a scanning nuclear microprobe was applied to determine the content of hydrogen isotopes in carbon material facing fusion plasma in the JET fusion reactor. The hydrogen and deuterium concentrations in re-deposited material were obtained by mapping a cross sectional cut of a wall sample. De-trapping and hydrogen release caused by the primary ion beam were investigated. For both the deuterium and hydrogen concentration a drop of ∼75% was observed from an extrapolated initial value to a final steady state region. A procedure was used to determine the initial concentration. In this way a mapping of the initial deuterium concentration could be obtained.     

Deuterium permeation of amorphous alumina coating on 316L prepared by MOCVD

The deuterium permeation behavior of the alumina coating on 316L stainless steel prepared by metal organic chemical vapor deposition (MOCVD) was investigated. The alumina coating was also characterized by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and scanning electron microscope (SEM). It was found that the as-prepared coating consisted of amorphous alumina. This alumina coating had a dense, crack-free and homogeneous morphology. Although the alumina coating was amorphous, effective suppression of deuterium permeation was demonstrated. The deuterium permeability of the alumina coating was 51–60 times less than that of the 316L stainless steel and 153–335 times less than that of the referred low activation martensitic steels at 860–960 K.     

Properties of tungsten coating deposited onto copper by high-speed atmospheric plasma spraying

Tungsten (W) coatings were fabricated on copper (Cu) by high-speed atmospheric plasma spray (HAPS) technique. The properties of the porosity, oxygen content, bonding strength and microhardness were measured. The results obtained indicated that the HAPS-W coating showed good properties particularly in terms of porosity and oxygen content. The porosity of the HAPS-W coating was 2.3% and the distribution of pore size diameter was mainly concentrated in the range of 0.01-1 μm. The oxygen content of the coating measured by means of Nitrogen/Oxygen Determinator was about 0.10 wt.%. These initial results suggest that the HAPS-W coating has achieved the reported properties of the vacuum plasma spray (VPS) W coating. Compared with VPS, HAPS-W technique could provide a convenient and low cost way to obtain adequate W coatings for fusion applications.