Study of interface state density and effective oxide charge inpost-metallization annealed SiO2-SiC structures

A systematic study of post-metallization annealing (PMA) effect on the quality of thermal SiO₂ on p-type 6H- and 4H-SiC has been carried out. A simultaneous quasi-static hi-lo frequency capacitance-voltage method has been employed to measure the total effective oxide charge (N_eff) and interface state density (D _it). To ensure accurate results, D_it was measured at 350°C which, depending on the hole capture cross sections, should enable the measurement of interface states located in the band gap as deep as 1.3-1.5 eV from the valence band edge. The dependence of N_eff and D_it on annealing temperature and ambient as well as the effect of thermal and sputtered gate metal on the oxide quality are reported. It is shown that N_eff values close to the detection limit due to the uncertainty in SiC electron affinities and D_it values below 1×10¹¹ cm^-2/eV deep in the band gap can be reproducibly obtained for both p-type 6H- and 4H-SiC     

Avalanche phenomena in 4H-SiC p-n diodes fabricated by aluminum orboron implantation

Characteristics of p-n junction fabricated by aluminum-ion (Al⁺) or boron-ion (B⁺) implantation and high-dose Al⁺-implantation into 4H-SiC (0001) have been investigated. By the combination of high-dose (4×10¹⁵ cm^-2) Al⁺ implantation at 500°C and subsequent annealing at 1700°C, a minimum sheet resistance of 3.6 kΩ/□ (p-type) has been obtained. Three types of diodes with planar structure were fabricated by employing Al+ or B+ implantation. B ⁺-implanted diodes have shown higher breakdown voltages than Al⁺-implanted diodes. A SiC p-n diode fabricated by deep B+ implantation has exhibited a high breakdown voltage of 2900 V with a low on-resistance of 8.0 mΩcm² at room temperature. The diodes fabricated in this study showed positive temperature coefficients of breakdown voltage, meaning avalanche breakdown. The avalanche breakdown is discussed with observation of luminescence     

Characterization of highly doped n- and p-type 6H-SiCpiezoresistors

Highly doped (~2×10¹⁹ cm^-3) n- and p-type 6H-SiC strain sensing mesa resistors configured in Wheatstone bridge integrated beam transducers were investigated to characterize the piezoresistive and electrical properties. Longitudinal and transverse gauge factors, temperature dependence of resistance, gauge factor (GF), and bridge output voltage were evaluated. For the n-type net doping level of 2×10¹⁹ cm^-3 the bridge gauge factor was found to be 15 at room temperature and 8 at 250°C. For this doping level, a TCR of -0.24%/°C and -0.74%/°C at 100°C was obtained for the n- and p-type, respectively. At 250°C, the TCR was -0.14%/°C and -0.34%/°C, respectively. In both types, for the given doping level, impurity scattering is implied to be the dominant scattering mechanism. The results from this investigation further strengthen the viability of 6H-SiC as a piezoresistive pressure sensor for high-temperature applications     

1.1 kV 4H-SiC power UMOSFETs

Silicon Carbide (4H-SiC), power UMOSFETs were fabricated and characterized from room temperature to 200°C. The devices had a 12-μm thick lightly doped n-type drift layer, and a nominal channel length of 4 μm. When tested under Fluorinert^TM at room temperature, blocking voltages ranged from 1.0 kV to 1.2 kV. Effective channel mobility ranged from 1.5 cm²/V.s at room temperature with a gate bias of 32 V (3.5 MV/cm) up to 7 cm²/V.s at 100°C with an applied gate bias of 26 V (2.9 MV/cm). Specific on-resistance (R_on,sp) was calculated to be as low as 74 mΩ.cm² at 100°C under the same gate bias     

High voltage 4H-SiC Schottky barrier diodes

Characteristics of 4H-SiC Schottky barrier diodes with breakdown voltages up to 1000 V are reported for the first time. The diodes showed excellent forward I-V characteristics, with a forward voltage drop of 1.06 V at an on-state current density of 100 A/cm². The specific on-resistance for these diodes was found to be low (2×10 ^-3 Ω-cm² at room temperature) and showed a T ^1.6 variation with temperature. Titanium Schottky barrier height was determined to be 0.99 eV independent of the temperature. The breakdown voltage of the diodes was found to decrease with temperature     

4H-SiC MOSFETs utilizing the H2 surface cleaningtechnique

The H₂ cleaning technique was examined as the precleaning of the gate oxidation for 4H-SiC MOSFETs. The device had a channel width and length of 150 and 100 μm, fabricated on the p-type epitaxial layer of 3×10¹⁶ cm^-3. The gate oxidation was performed after the conventional RCA cleaning, and H₂ annealing at 1000°C. The obtained channel mobility depends on the pre-cleaning process strongly, and was achieved 20 cm²/N s in the H₂ annealed sample. The effective interface-state density was also measured by the MOS capacitors fabricated on the same chips, resulting 1.8×10¹² cm^-2 from the photo-induced C-V method     

High performance of high-voltage 4H-SiC Schottky barrier diodes

High performance of high-voltage rectifiers could be realized utilizing 4H-SiC Schottky barrier diodes. A typical specific on-resistance (R_on) of these devices was 1.4×10³ Ω cm³ at 24°C (room temperature) with breakdown voltages as high as 800 V. These devices based on 4H-SiC had R _on's lower than 6H-SiC based high-power rectifiers with the same breakdown voltage. As for Schottky contact metals, Au, Ni, and Ti were employed in this study. The barrier heights of these metals for 4H-SiC were determined by the analysis of current-voltage characteristics, and the reduction of power loss could be achieved by controlling the barrier heights     

Electrical characterization of annealed Ti/TiN/Pt contacts onN-type 6H-SiC epilayer

We report results of the electrical characteristics of in vacuo deposited Ti/TiN/Pt contact metallization on n-type 6H-SiC epilayer as function of impurity concentration in the range of 3.3×10¹⁷ cm^-3 to 1.9×10¹⁹ cm^-3. The as-deposited contacts are rectifying, except for the highly doped sample. Only the lesser doped remains rectifying after samples are annealed at 1000°C between 0.5 and 1 min in argon. Bulk contact resistance ranging from factors of 10^-5 to 10^-4 Ω-cm² and Schottky barrier height in the range of 0.54-0.84 eV are obtained. Adhesion problems associated with metal deposition on pre-processed titanium is not observed, leading to excellent mechanical stability. Auger electron spectroscopy (AES) reveals the out diffusion of Ti-Si and agglomeration of Ti-C species at the epilayer surface. The contact resistance remains appreciably stable after treatment in air at 650°C for 65 h. The drop in SBH and the resulting stable contact resistance is proposed to be associated with the thermal activation of TiC diffusion barrier layer on the 6H-SiC epilayer during annealing     

Improved inversion channel mobility for 4H-SiC MOSFETs followinghigh temperature anneals in nitric oxide

Results presented in this letter demonstrate that the effective channel mobility of lateral, inversion-mode 4H-SiC MOSFETs is increased significantly after passivation of SiC/SiO₂ interface states near the conduction band edge by high temperature anneals in nitric oxide. Hi-lo capacitance-voltage (C-V) and ac conductance measurements indicate that, at 0.1 eV below the conduction band edge, the interface trap density decreases from approximately 2×10¹³ to 2×10¹² eV^-1 cm^-2 following anneals in nitric oxide at 1175°C for 2 h. The effective channel mobility for MOSFETs fabricated with either wet or dry oxides increases by an order of magnitude to approximately 30-35 cm²/V-s following the passivation anneals     

The planar 6H-SiC ACCUFET: a new high-voltage power MOSFETstructure

A novel planar accumulation channel SiC MOSFET structure is reported in this paper. The problems of gate oxide rupture and poor channel conductance previously reported in SiC UMOSFETs are solved by using a buried P⁺ layer to shield the channel region. The fabricated 6H-SiC unterminated devices had a blocking voltage of 350 V with a specific on-resistance of 18 mΩ.cm² at room temperature for a gate bias of only 5 V. This measured specific on-resistance is within 2.5× of the value calculated for the epitaxial drift region (10¹⁶ cm^-3, 10 μm), which is capable of supporting 1500 V     

Metal-insulator-semiconductor structures of InSb/SiO2with very low interface trap density

MIS structures fabricated using InSb and silicon dioxide with an interface trap density as low as 4×10¹⁰ cm^-2 eV^-1 have been achieved. This is about one order of magnitude less than any other reported figure for the InSb MIS system. Both capacitance/voltage and conductance techniques have been employed to study the interface properties of InSb/SiO₂. A low state density of <10¹⁰ cm^-2 was observed and the dielectric breakdown field of the oxide was greater than 4 mV cm^-1      

Carrier transport related analysis of high-power AlGaN/GaN HEMTstructures

Shubnikov-de Haas (SdH) oscillation and Hall measurement results were compared with HEMT DC and RF characteristics for two different MOCVD grown AlGaN-GaN HEMT structures on semiinsulating 4H-SiC substrates. A HEMT with a 40-nm, highly doped AlGaN cap layer exhibited an electron mobility of 1500 cm²/V/s and a sheet concentration of 9×10¹² cm at 300 K (7900 cm²/V/s and 8×10¹² cm^-2 at 80 K), but showed a high threshold voltage and high DC output conductance. A 27-nm AlGaN cap with a thinner, lightly doped donor layer yielded similar Hall values, but lower threshold voltage and output conductance and demonstrated a high CW power density of 6.9 W/mm at 10 GHz. The 2DEG of this improved structure had a sheet concentration of n_SdH=7.8×10¹² cm^-2 and a high quantum scattering lifetime of τ_q=1.5×10^-13 s at 4.2 K compared to n_SdH=8.24×10¹² cm^-2 and τ_q=1.72×10^-13 s for the thick AlGaN cap layer structure, Despite the excellent characteristics of the films, the SdH oscillations still indicate a slight parallel conduction and a weak localization of electrons. These results indicate that good channel quality and high sheet carrier density are not the only HEMT attributes required for good transistor performance     

Si/Si1-xGex heterojunction bipolartransistors produced by limited reaction processing

Si/Si_1-xGe_x heterojunction transistors (HBTs) fabricated by a chemical vapor deposition (CVD) technique are reported. A rapid thermal CVD limited-reaction processing (LRP) technique was used for the in situ growth of all three device layers, including a 20-mm Si_1-xGe_x layer in the base. The highest current gains observed (β=400) were for a Si/Si_1-x Ge_x HBT with a base doping of 7×10¹⁸ cm^-3 near the junction and a shallow arsenic implant to form ohmic contacts and increase current gain. Ideal base currents were observed for over six decades of current and the collector current remained ideal for nearly nine current decades starting at 1 pA. The bandgap difference between a p-type Si layer doped to 5×10¹⁷ cm^-3 and the Si_1-xGe_x(x=0.31) base measured 0.27 eV. This value was deduced from the measurements of the temperature dependence of the base current and is in good agreement with published calculations for strained Si_1-xGe_x layers on Si     

Experimental determination of electron drift velocity in 4H-SiC p+-n-n+ avalanche diodes

4H-SiC p⁺-n-n⁺ diodes of low series resistivity (<1×10^-4 Ω·cm²) were fabricated and packaged. The diodes exhibited homogeneous avalanche breakdown at voltages U_b=250-270 V according to the doping level of the n layer. The temperature coefficient of the breakdown voltage was measured to be 2.6×10^-4 k^-1 in the temperature range 300 to 573 K. These diodes were capable of dissipating a pulsed power density of 3.7 MW/cm² under avalanche current conditions. The transient thermal resistance of the diode was measured to be 0.6 K/W for a 100-ns pulse width, An experimental determination of the electron saturated drift velocity along the c-axis in 4H-SIC was performed for the first time, It was estimated to be 0.8×10⁷ cm/s at room temperature and 0.75×10⁷ cm/s at approximately 360 K     

Formation of 0.05-μm p+-n and n+-pjunctions by very low (<500 eV) ion implantation

The current-voltage (I-V) characteristics of ultrashallow p⁺ -n and n⁺-p diodes, obtained using very-low-energy (<500-eV) implantation of B and As, are presented. the p⁺-n junctions were formed by implanting B⁺ ions into n-type Si (100) at 200 eV and at a dose of 6×10¹⁴ cm^-2, and n⁺-p junctions were obtained by implanting As⁺ ions into p-type (100) Si at 500 eV and at a dose 4×10¹² cm^-2. A rapid thermal annealing (RTA) of 800°C/10 s was performed before I-V measurements. Using secondary ion mass spectrometry (SIMS) on samples in-situ capped with a 20-nm ²⁸Si isotopic layer grown by a low-energy (40 eV) ion-beam deposition (IBD) technique, the depth profiles of these junctions were estimated to be 40 and 20 nm for p⁺-n and n⁺-p junctions, respectively. These are the shallowest junctions reported in the literature. The results show that these diodes exhibit excellent I-V characteristics, with ideality factor of 1.1 and a reverse bias leakage current at -6 V of 8×10^-12 and 2×10^-11 A for p⁺-n and n⁺-p diodes, respectively, using a junction area of 1.96×10^-3 cm²     

Minority-carrier transport parameters in heavily doped p-typesilicon at 296 and 77 K

Minority-carrier electron lifetime, mobility and diffusion length in heavily doped p-type Si were measured at 296 and 77 K. It was found that a 296 K μ_n (pSi)≈μ_n (nSi) for N _AA≲5×10¹⁸ cm^-3, while μ_n (pSi)/μ_n (nSi)≈1 to 2.7 for higher dopings. The results also show that for N_AA≲3×10¹⁹ cm^-3, D (pSi) at 77 K is smaller than that at 296 K, while for higher dopings D_n (pSi) is larger at 77 K than at 296 K. μ_n (pSi) at 77 K increases with the increasing doping above N_AA>3×10¹⁸ cm^-3, in contrast to the opposite dependence for μ_n (nSi) in n⁺ Si     

3100 V, asymmetrical, gate turn-off (GTO) thyristors in 4H-SiC

A 2-mm×2-mm, 4H-SiC, asymmetrical npnp gate turn-off (GTO) thyristor with a blocking voltage of 3100 V and a forward current of 12 A is reported. This is the highest reported power handling capability of 37 kW for a single device in SiC. The 5-epilayer structure utilized a blocking layer that was 50 μm thick, p-type, doped at about 7-9×10¹⁴ cm^-3. The devices were terminated with a single zone junction termination extension (JTE) region formed by ion-implantation of nitrogen at 650°C. The device was able to reliably turn-on and turn-off 20 A (500 A/cm²) of anode current with a turn-on gain (I_K/I_{G, on}) of 20 and a turn-off gain (I_K/I_{G, off}) of 3.3     

10 A, 2.4 kV Power DiMOSFETs in 4H-SiC

We report the characteristics of large area (3.3 × 3.3 mm ²) high-voltage 4H-SiC DiMOSFETs. The MOSFETs show a peak MOS channel mobility of 22 cm²/V·s and a threshold voltage of 8.5 V at room temperature. The DiMOSFETs exhibit an on-resistance of 4.2 mΩ·cm² at room temperature and 85 mΩ·cm² at 200°C. Stable avalanche characteristics at approximately 2.4 kV are observed. An on-current of 10 A is measured on a 0.103 cm² device. High switching speed is also demonstrated. This suggests that the devices are capable of high-voltage, high-frequency, low-loss switching applications     

Current gain dependence on subcollector and etch-stop doping inInGaP/GaAs HBTs

The DC current gain dependence of InGaP/GaAs heterojunction bipolar transistors (HBTs) on subcollector and etch-stop doping is examined. Samples of InGaP/GaAs HBTs having various combinations of subcollector doping and etch-stop doping are grown, and large area 60 μm×60 (μ) HBTs are then fabricated for DC characterization. It is found that the DC current gain has a strong dependence on the doping concentration in the subcollector and the subcollector etch-stop. Maximum gain is achieved when the subcollector is doped at 6~7×10 ¹⁸ cm^-3 while the subcollector etch-stop is doped either above 6×10¹⁸ cm^-3 (current gain/sheet resistance ratio, β/R_b=0.435 at I_c=1 mA) or below 3.5×10¹⁷ cm^-3 (β/R_b=0.426~0.438 at I_c=1 mA). The data show that it is not necessary to heavily dope the subcollector etch-stop to reduce the conduction barrier and to obtain high current gain. The high current gain obtained with the low InGaP etch-stop doping concentration is attributed to the reduction of the effective energy barrier thickness due to band bending at the heterojunction between the InGaP etch-stop and the GaAs subcollector. These results show that the β/R_b of InGaP/GaAs HBTs can improve as much as 69% with the optimized doping concentration in subcollector and subcollector etch-stop     

Counter-doped MOSFETs of 4H-SiC

In this paper, we investigate the effect of counter-doping of nitrogen at the channel region of epitaxial n-channel 4H-SiC MOSFETs on the channel mobility and the threshold voltage. From this study, we have found that the channel mobility steeply improves as the nitrogen dose increases. At a dose of 2× or 2.5×10¹² cm^-2 the enhancement MOSFET has achieved an effective channel mobility of 20 cm²/Vs or a field effect mobility of 38 cm²/Vs at a peak