STUDY ON PREPARATION, COMPLEX PERMITTIVITY,PERMEABILITY AND MICROWAVE PROPERTIES OF BaZnZCo2-ZFe16O27／SiO2 MICROCRYSTALLINE GLASS CERAMICS

BaZnzCo2-zFe16O27/SiO2 microcrystalline glass ceramics with Z=0.0, 0.5, 0.8 and 1.1 were prepared at temperature 1200℃ for 5h by citrate sol-gel process. The complex dielectric constant and complex permeability of BaZnzCo2-zFe16 O27/SiO2-paraffin wax composites had been measured. Both the complex dielectric constant and dielectric loss exhibit almost no variation with frequency in 0.1-6.0GHz. The real part of permeability decreases with increasing frequency for all samples, and the imaginary part of permeability exhibits a clear resonance peak at 1.44GHz for Co2 W/SiO2, 1.32GHz for Zn0.5Co1.5 W/SiO2, 1.20GHz for Zn0.8Co1.2W/SiO2, and 1.08GHz for Zn1.1 Co0.9 W/SiO2. It is also showed that the content of zinc has a close effect on the magnetic properties of BaZnzCo2-zFe16O27/SiO2 microcrystalline glass ceramics, the greater the zinc content, the higher the values of imaginary part of permeability and magnetic loss.     

MoSi_2含量对MoSi_2/Al_2O_3复合涂层介电与力学性能的影响(英文)

通过喷雾干燥法制备MoSi2包覆Al2O3的壳核结构混合粉,利用该混合粉以等离子喷涂技术制备MoSi2/Al2O3复合涂层材料。研究MoSi2/Al2O3质量比涂层材料的力学和介电性能的影响。结果表明:随着MoSi2含量从0增加到45%,复合材料的抗弯强度和断裂韧性分别从198MPa和3.05MPa·m1/2增加到324MPa和4.82MPa·m1/2,随后又降到310MPa和4.67MPa·m1/2。在8.2-12.4GHz微波频率波段内,随着MoSi2含量的增加,复合材料的介电损耗增加,而介电常数的实部却呈减小趋势。这主要是由于MoSi2颗粒熔化后的凝聚及导电网络结构的形成导致电导率的增加引起的。     

热压烧结制备Al2O3/TiCN-Ni-Ti陶瓷复合材料的组织与性能

采用真空热压烧结方法制备Al2O3/Ti(C,N)-Ni-Ti陶瓷基复合材料,采用X射线衍射与扫描电镜分析材料的物相组成和显微结构,研究烧结工艺对材料物相组成、显微结构和力学性能的影响。结果表明:Ni和Ti的添加显著提高复合材料的强度和韧性;温度小于1 600℃时,复合材料的力学性能随热压温度的升高而升高;温度高于1 600℃时,温度升高及保温时间延长不仅会导致Al2O3晶粒的异常长大和Ti(C,N)的分解,而且会使Ni发生聚集现象,复合材料的力学性能下降;当烧结温度为1 600℃、保温时间为30 min时,制备的Al2O3/Ti(C,N)-Ni-Ti陶瓷复合材料的力学性能最佳,其相对密度达到99.4%,抗弯强度为820 MPa,断裂韧性达到9.3 MPa.m1/2。     

Preparation and microwave properties of Ba4ZnzCo2_zFe36O60 hexaferrites by a sol-gel process

Ba4ZnzCo2_zFe36O60 hexaferrites with Z = 2.0, 1.5, 1.0, 0.5, and 0.0 were prepared by a citrate sol-gel process.The complex dielectric constant and complex permeability of hexaferrite-paraffin wax composites were measured in the range from 0.1 to 6.0 GHz. Measured results showed that both the complex dielectric constant and the dielectric loss exhibited no significant change as the measuring frequency increasing except for the sample with Z = 0.0. The real part of permeability decreased with increasing frequency for all samples in the whole measuring frequency range, and the natural resonance phenomena were observed in allμ" spectrum but Co2U. The results also indicate that the content of zinc closely affects the microwave properties of Ba4ZnzCo2_zFe36O60 felTites, and the greater the zinc content, the lower the natural resonance frequency is.     

Preparation and mechanical properties of Fe_3Al/Al_2O_3 nano-/micro-composite

1　INTRODUCTIONAlumina(Al2 O3)ceramicsareoftenconsideredforstructuralapplications,duetotheirpropertiesofhighhardness ,chemicalandwearresistanceandgoodmechanicalpropertiesatroomandhightemperature .Thewellknownlimitationfortheseceramics ,how ever ,istheverylowtoughness .Recentstudieshaveshownsignificantimprovementsinmechanicalprop erties ,includingtoughness ,byaddingductilesecondphaseparticles ,suchasNi,Al,MoandCu[14 ] .Anincreaseof 80 % 333%inthefracturetoughnesshasbeenreportedforAl2 O3…     

低氮气压下燃烧合成Al掺杂β-SiC粉体的微波介电性能

以硅粉(Si)和炭黑(C)为原料、聚四氟乙烯(PTFE)为助燃剂、铝粉(Al)为掺杂源,在低压氮气气氛中通过燃烧合成的方法制备出Al掺杂β-SiC粉体.用XRD、SEM和EDS对其进行了表征,同时在频率8.2～12.4 GHz范围内对其进行介电常数的测试.结果表明未掺杂Al时生成富碳β-SiC粉体;当掺杂Al时并未生成AlN-SiC固溶体,而是Al原子进入到碳化硅晶格中占据硅的位置形成了Al/SiC固溶体,引起β-SiC晶格常数的逐渐增大.当Al掺杂含量为5 mol%时晶粒最小,同时出现了Al_2O_3杂质相,但是其介电常数实部和介电损耗达到最大值,同时对Al对β-SiC介电损耗的影响进行了讨论.     

短切SiCf/LAS复合材料的显微结构与介电性能

采用热压烧结法制备出致密的短切SiC_f增强LAS玻璃陶瓷复合材料,并讨论保温时间与热压压力对复合材料介电性能的影响.结果表明,测试频率在8～12 GHz之间,复合材料复介电常数实部ε′由基体的7.6上升到10～100,虚部ε″由基体的0.34上升到40～160,介电损耗tgδ由基体的0.04上升到1～20,并具有明显的频散效应.随保温时间的延长或热压压力的提高,复合材料ε′增大,ε″与tgδ减小.此外,断口形貌的SEM观察表明,随保温时间的延长或热压压力的提高,复合材料界面层变厚.     

离心成型法制备无宏观界面的Al2O3/Ni功能梯度材料

采用一种新颖的离心成型法制备了无宏观界面的Al2O3/Ni功能梯度材料, 并研究了料浆调制工艺、离心成型制备机理和梯度材料的力学性能。结果表明, 配制料浆时,粘结剂(聚乙二醇)含量为2 mass%、固相含量为63vol.%、球磨时间为36h,可得到流动性良好的料浆,经离心成型（40min,转速3000 r/min）得到无宏观界面的坯体,在1400 C真空烧结2 h,最终得到致密、组元宏观连续过渡的Al2O3/Ni梯度材料。通过调整固相含量和粘结剂含量,可调控Al2O3/Ni复合材料的成分梯度。     

放电等离子烧结Ti/Al_2O_3复合材料机制及性能

利用放电等离子烧结技术制备了Ti/Al_2O_3复合材料,并探讨了其烧结机理,对复合材料性能进行测试.结果表明,Ti/Al_2O_3导电网络结构的形成,有利于在烧结过程中形成的"电容器"瞬间击穿,使Al_2O_3遭到轰击而产生放电离子,活化Al_2O_3晶粒,降低烧结温度;当Ti 含量为40%(体积分数,下同)时复合材料的相对密度、弯曲强度、断裂韧性和显微硬度分别为99.74%、1002 MPa、19.73 MPa·m~(1/2)和18.14 GPa;裂纹的桥联、偏转是试验材料力学性能得以提高的主要原因.     

SPRAYING-OXIDATION AND DEPOSITION PROCESS OF Al/Al2O3 COMPOSITES

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Mo(Si_(1-x)Al_x)_2/Al_2O_3复合材料的制备与强韧化

以Mo、Al、Si和Mo O_34种粉末为原料,通过燃烧合成和真空热压烧结工艺原位制备了(Si_(1-x)Al_x)_2/Al_2O_3复合材料,分析了其燃烧模式、产物相结构、微观组织和力学性能。结果表明:添加Al之后坯体的燃烧合成反应更加剧烈,燃烧模式由螺旋模式转入混沌模式。随着合金化Al含量的增加,基体相结构由C11_b型Mo Si_2转变为C40型Mo(Si,Al)_2,并且在所有复合材料中都可以鉴别出Al_2O_3衍射峰,表明通过燃烧合成技术原位制备了Mo(Si_(1-x)Al_x)_2/Al_2O_3复合材料。复合材料的断裂韧性和抗弯强度最高分别达到4.25 MPa·m~(1/2)和346 MPa,比纯Mo Si_2提高了39%和60%。复合材料的强韧化机制主要有Al合金化强韧化、Al_2O_3第二相颗粒弥散强韧化、玻璃相的消除以及断裂方式的转变。     

TiNb颗粒增韧铜锆基非晶复合材料的机制

采用放电等离子烧结(Spark Plasma Sintering,SPS)方法成功制备得到10%(体积分数)TiNb/Zr55Cu30Al10Ni5和TiNb/Cu46Zr42Al7Y5非晶基体复合材料。压缩力学实验表明,TiNb颗粒对Zr55Cu30Al10Ni5的增韧效果明显好于对Cu46Zr42Al7Y5。究其原因是Zr55Cu30Al10Ni5的塑性转变区域的长度Rp值高于Cu46Zr42Al7Y5,这就意味着TiNb颗粒分布在Zr55Cu30Al10Ni5的塑性转变区域的几率明显高于Cu46Zr42Al7Y5基体。因此,TiNb颗粒对Zr55Cu30Al10Ni5基体的增韧效果明显要好于Cu46Zr42Al7Y5。     

MICROSTRUCTURES AND MECHANICAL PROPERTIES OF IN-SITU Al2O3/TiAl COMPOSITES BY EXOTHERMIC DISPERSION METHOD

In-situ Al2O3/TiAl composites were fabricated by pressure-assisted exothermic disper-sion (PAXD) method from elemental powder mixtures of Ti, Al, TiO2, and Nb2O5.The microstructures and mechanical properties of the as-sintered composites are in-vestigated. The results show that the as-sintered products consist of γ-TiAl, α2-Ti3Al,Al2O3, and NbAl3 phases. Microstrueture analysis indicates that Al2O3 particles tend to disperse on the grain boundaries. Application of a moderate pressure of 35 Mpa at 1200℃ yields Ab2O3/TiAl composites with fine Al2O3 reinforcement and a dis-continuous network linking by Al2O3 particles. The aluminide component has a fine submicron γ+α2 larnellar rnicrostructure. With increasing Nb2O5 content, A1203 par-ticles are dispersed uniformly in the matrix. The hardness of the composites increases gradually, and the bending strength and fracture toughness of the composites reach to the maximum value, respectively.     

Microstructures And Mechanical Properties Of In-Situ Al2o3/Tial Composites By Exothermic Dispersion Method

In-situ Al2O3/TiAl composites were fabricated by pressure-assisted exothermic dispersion （PAXD） method from elemental powder mixtures of Ti, Al, TiO2, and Nb2O5. The microstructures and mechanical properties of the as-sintered composites are investigated. The results show that the as-sintered products consist of γ-TiAl, α2-Ti3Al, Al2O3, and NbAl3 phases. Microstructure analysis indicates that Al2O3 particles tend to disperse on the grain boundaries. Application of a moderate pressure of 35 MPa at 1200℃ yields Al2O3/TiAl composites with fine Al2O3 reinforcement and a discontinuous network linking by Al2O3 particles. The aluminide component has a fine submicron γ ＋α2 lamellar microstructure. With increasing Nb2O5 content, Al2O3 particles are dispersed uniformly in the matrix. The hardness of the composites increases gradually, and the bending strength and fracture toughness of the composites reach to the maximum value, respectively.     

氧化铝包覆SrTiO3纳米纤维/聚偏氟乙烯复合材料的制备与介电储能性能

目的 通过开发出工作场强更高、储能效率更高的电介质储能材料,从而提高电力设备的性能、减小电力设备体积。方法 采用静电纺丝工艺结合溶胶凝胶工艺制备具有一维核壳结构的SrTiO3@Al2O3纳米纤维填料,并结合流延成型工艺制备出聚偏氟乙烯(PVDF)电介质复合材料。系统地研究了SrTiO3纳米纤维填料表面包覆Al2O3对PVDF电介质复合材料界面极化、介电性能、储能性能的影响。结果 制备的一维纳米填料具有良好的核壳结构,其中芯层为SrTiO3,壳层为Al2O3, Al2O3包覆厚度为6 nm。低填充量下,一维核壳结构SrTiO3@Al2O3纳米纤维填料均匀地分散在PVDF基体中。在相同的体积分数填料填充下,SrTiO3@Al2O3纳米纤维/PVDF复合材料表现出更低的介电损耗和漏电流、更强的耐击穿场强、以及更高的储能密度和放电效率。SrTiO3@Al2O3纳米纤维/PVDF电介质复合材料的最大储能密度达到8.9 J/cm³。结论 Al2O3包覆层可以阻止SrTiO3纳米纤维填料在复合材料中的接触,减小Maxwell-Wagner-Sillars界面极化,降低漏电流,进而提高复合材料薄膜的击穿强度和储能性能。     

Mechanical properties and microstructure of Fe-Al/Al_2O_3 composite with Cr,Mo and Ti

1　INTRODUCTIONTheFe Alintermetalliccompoundhasaseriesofmerits[1,2 ] ,suchashighstrength ,lowdensity ,goodwearablityandlowcosts ,andithasbeenusedinsomefields .Butitshightemperaturestrengthislow er.Al2 O3ceramicsisoneofthestructuralmaterialswithwideapplication ,butboththehigherbrittlenessandlowertoughnesslimiteditsapplicationfields .Inordertogetonematerialwithbothhighstrengthandhightoughness,onenovelFe Al/Al2 O3compositewasfabricatedbytheauthors[3] .Ithasverywideap plicationprospectfori…     

Er掺杂强韧化Al_2O_3/TiAl复合材料

以Ti、Al、TiO2为起始原料,以Er2O3为掺杂剂,原位热压合成了Er掺杂Al2O3/TiAl复合材料。通过XRD、SEM分析及力学性能测试,研究了不同Er2O3引入量对合成Al2O3/TiAl复合材料微观结构和力学性能的影响。结果表明:复合材料主要由TiAl、Ti3 Al、Al2 O3相和少量Al10 Er6 O24相组成,含Er相主要分布在基体相晶界处;掺杂0.01 mol Er2 O3制得的复合材料,经1250℃保温2 h真空热压烧结后表观断裂韧性达到最大值(10.41 MPa.m1/2),经1300℃保温2 h真空热压烧结后弯曲强度达到最大值(456.06 MPa);当Er2O3掺杂量增加到0.02 mol时,复合材料的弯曲强度和表观断裂韧性均呈减小趋势。微观结构分析表明,掺杂0.01 mol Er2O3的复合材料断口毛糙,颗粒尺寸变小,增强相分布较均匀,表明适量的Er2O3掺杂可细化复合材料晶粒尺寸,提高增强颗粒分布均匀度,起到增强增韧的效果。     

稀土La对Al2O3/Cu复合材料组织与性能的影响

利用机械合金化法结合放电等离子烧结制备Al2O3/Cu铜基复合材料,采用XRD、SEM、硬度、抗拉强度和电导率等测试研究La含量对Al2O3/Cu复合粉末和烧结材料组织及性能的影响。结果表明:添加0.05%的稀土La有利于机械合金化过程中Cu晶粒的细化和Al2O3颗粒的弥散分布,从而提高烧结材料的显微硬度和抗拉强度。烧结材料的导电率随着La含量的增加先升后降,当La的质量分数为0.10%时,Al2O3/Cu复合材料的导电率提高11.3%IACS。     

B_4C粒度配比对B_4C-Al复合材料显微组织与力学性能的影响

在B_4C预烧体中真空熔渗铝制备B_4C-Al复合材料,研究不同粒度配比对复合材料显微组织和力学性能的影响.结果表明:B_4C-Al复合材料主要由B_4C、Al、AlB_2和Al_3BC等相组成;随着细颗粒B_4C(d_(50)=1 μm)含量的增加,复合材料的HRA硬度逐渐降低,抗弯强度逐渐增大,断裂韧性先增大后稍微降低,当细颗粒B_4C含量为40%(质量分数)时,复合材料的气孔率、硬度HRA、抗弯强度和断裂韧性分别为1.08%、71.7、505.8 MPa和6.41 MPa·m~(1/2);延性铝的加入和细颗粒B_4C的增加是造成材料断裂韧性提高的主要原因;随着Al渗入量的增加,复合材料断口中金属撕裂棱及韧窝的比例增加.     

利用Al氧化反应修复陶瓷宏观裂纹

基于金属Al在高温下氧化形成氧化铝并伴随体积膨胀的效应，利用该体积膨胀抵消烧结致密化导致的体积收缩，设计了Al、Al2O3为主要组成、少量的Y2O3和SiO2为烧结助剂的填充相组分，以95氧化铝方形小坩埚模拟陶瓷宏观裂纹，进行了陶瓷宏观裂纹的修复研究。通过比较Al含量、烧成温度和升温制度对填充组分膨胀量和修复界面微观结构的影响，证实氧化物陶瓷宏观裂纹可通过选择适宜的Al／Al2O，填充组分实现修复。