Patterns in groundwater nitrogen concentration in the riparian zone of a large semi‐arid river (River Murray,Australia)

Lateral exchanges of surface water between river channels and their floodplains are important for vegetation health and aquatic food‐web productivity in semi‐arid ecosystems. However, the significance of the lateral connectivity via sub‐surface pathways in these systems is not as well understood. Patterns in nitrogen concentration in groundwater and in the unsaturated zone were used to infer the sub‐surface biogeochemistry of N in the riparian zone of a large semi‐arid floodplain (Hattah‐Kulkyne National Park) of the River Murray, Australia. The riparian zone plays a special role in this system as it is an area of transition between fresh surface waters and saline floodplain groundwater. The river was losing water to the floodplain during baseflow conditions but gradients were temporarily reversed following floods. In general, the redox conditions were sub‐oxic to anoxic in riparian groundwater and the main forms of N present were NH and dissolved organic N. There was a gradient in NH concentration from the river to the floodplain, suggesting that the main source of NH was from the decomposition of organic matter in fluvial sediments. Elevated concentrations of NO were occasionally found in shallow groundwater away from the river following floods but tended not to persist. The source of the NO appeared to be unsaturated‐zone NO displaced to the water table during floods. Assuming that denitrification was the main attenuation process, this displacement of unsaturated zone NO to anoxic groundwater could be a significant N removal process from the ecosystem (estimated at 18 kg N ha^?1 for the largest flood during the study). Understanding the impact of river regulation on floodplain nutrient cycles in River Murray floodplains will be challenging because the changes in floodplain hydrology are complex and coincide with salinization of soils and groundwater. Copyright © 2005 John Wiley & Sons, Ltd.     

Disinfection of sludge with high pathogenic content using silver and other compounds.

A physicochemical sludge with high microbial content (10(2)-10(4) FPU/g TS bacteriophages, 10(6)-10(7) MPN/g TS faecal coliforms, 10(4) MPN/g TS Salmonella spp., 10(4) MPN/g TS Shigella spp., 10(3) MPN/g TS Pseudomonas aeruginosa, 10(2) MPN/g TS Vibrio cholerae, 10(2)-10(3) cysts/g TS Giardia sp., 10(2)-10(4) oocyts/g TS Cryptosporidium sp., 168-215 viable helminth ova/g TS) was disinfected using silver, silver-copper, and silver-copper plus a synergistic agent (SA). Twenty milligrams Ag/g TS inactivated 4.8 log of faecal coliforms in 1 h; however, 40 mg Ag/g TS are needed to reduce helminth ova viability from 84 to 38.4% in the same period of time. Combinations of Ag-Cu (60:600 mg Ag-Cu/g TS) and Ag-SA (60:24 mg Ag-SA/g TS) inactivated 7.8 log of faecal coliforms and around 90% of helminth ova in 60 min. To produce USEPA class A biosolids, 10:100:8 and 5:50:13.3 mg Ag-Cu-SA/gTS are needed. Bacterial regrowth was not observed for all conditions producing <1000 MPN/gTS faecal coliforms, suggesting a residual disinfection effect. Recommended doses to produce class A biosolids inactivated 2-4 log of bacteriophages, 4 log of Salmonella spp., 4 log of Shigella spp., 3 log of Pseudomonas aeruginosa, 2 log of Vibrio cholerae, 87-99.9% of Giardia sp., and 75-99.9% of Cryptosporidium sp.     

Seasonal variation in nutrient retention during inundation of a short‐hydroperiod floodplain

Floodplains are generally considered to be important locations for nutrient retention or inorganic‐to‐organic nutrient conversions in riverine ecosystems. However, little is known about nutrient processing in short‐hydroperiod floodplains or seasonal variation in floodplain nutrient retention. Therefore, we quantified the net uptake, release or transformation of nitrogen (N), phosphorus (P) and suspended sediment species during brief periods (1–2 days) of overbank flooding through a 250‐m floodplain flowpath on the fourth‐order Mattawoman Creek, Maryland U.S.A. Sampling occurred during a winter, two spring and a summer flood in this largely forested watershed with low nutrient and sediment loading. Concentrations of NO increased significantly in surface water flowing over the floodplain in three of the four floods, suggesting the floodplain was a source of NO. The upper portion of the floodplain flowpath consistently exported NH, most likely due to the hyporheic flushing of floodplain soil NH, which was then likely nitrified to NO in floodwaters. The floodplain was a sink for particulate organic P (POP) during two floods and particulate organic N and inorganic suspended sediment (ISS) during one flood. Large releases of all dissolved inorganic N and P species occurred following a snowmelt and subsequent cold winter flood. Although there was little consistency in most patterns of nutrient processing among the different floods, this floodplain, characterized by brief inundation, low residence time and low nutrient loading, behaved oppositely from the conceptual model for most floodplains in that it generally exported inorganic nutrients and imported organic nutrients. Published in 2007 by John Wiley & Sons, Ltd.     

Erratum: Predicting the morphological and hydraulic consequences of river rehabilitation

Erratum : Predicting the Morphological and Hydraulic Consequences of River Rehabilitation. S. Schweizer, M. E. Borsuk and P. Reichert . River Research and Applications (23)3: 303–322. Equation 17 on page 313 should read and not as published.     

Nitrogen dynamics in sediment during water level manipulation on the Upper Mississippi River

Nitrogen (N) has been linked to increasing eutrophication in the Gulf of Mexico and as a result there is increased interest in managing and improving water quality in the Mississippi River system. Water level reductions, or ‘drawdowns’, are being used more frequently in large river impoundments to improve vegetation growth and sediment compaction. We selected two areas of the Upper Mississippi River system (Navigation Pool 8 and Swan Lake) to examine the effects of water level drawdown on N dynamics. Navigation Pool 8 experienced summer drawdowns in 2001 and 2002. Certain areas of Swan Lake have been drawn down annually since the early 1970s where as other areas have remained inundated. In the 2002 Pool 8 study we determined the effects of sediment drying and rewetting resulting from water level drawdown on (1) patterns of sediment nitrification and denitrification and (2) concentrations of sediment and surface water total N (TN), nitrate, and ammonium (NH). In 2001, we only examined sediment NH and TN. In the Swan Lake study, we determined the long‐term effects of water level drawdowns on concentrations of sediment NH and TN in sediments that dried annually and those that remained inundated. Sediment NH decreased significantly in the Pool 8 studies during periods of desiccation, although there were no consistent trends in nitrification and denitrification or a reduction in total sediment N. Ammonium in sediments that have dried annually in Swan Lake appeared lower but was not significantly different from sediments that remain wet. The reduction in sediment NH in parts of Pool 8 was likely a result of increased plant growth and N assimilation, which is then redeposited back to the sediment surface upon plant senescence. Similarly, the Swan Lake study suggested that drawdowns do not result in long term reduction in sediment N. Water level drawdowns may actually reduce water retention time and river‐floodplain connectivity, while promoting significant accumulation of organic N. These results indicate that water level drawdowns are probably not an effective means of removing N from the Upper Mississippi River system. Copyright © 2006 John Wiley & Sons, Ltd.     

Evaluation of Owabi Reservoir (Ghana) water quality using factor analysis

The Owabi Reservoir receives water inflows from several streams that drain through the rapidly urbanizing towns in the Kumasi metropolis. The reservoir catchment had been encroached upon by various human activities, resulting in the generation of large volumes of waste water being discharged into streams draining to the reservoir. This study presents a comprehensive evaluation of the water quality of Owabi Reservoir. Water samples from 10 sampling sites within the reservoir were analysed for various water quality parameters; namely, pH, electrical conductivity (EC), sulphate (), phosphate (), chloride (Cl^?), lead (Pb), arsenic (As), zinc (Zn), iron (Fe), copper (Cu), total dissolved solids (TSS), turbidity, faecal coliform and E. coli. The measured water quality parameters were compared to the guidelines proposed by the WHO for drinking water and natural background levels. Mean values for Pb, As, turbidity, TDS, faecal coliform and E. coli were greater than the WHO guidelines. Factor analysis for the measured parameters resulted in the extraction of five factors accounting for 83.13% of the total variance. Factor 1 showed strong loadings for , and TDS, reflecting a negative influence on the water quality by agricultural discharges. Factor 2 showed high loadings for EC, Cl^? and apparent colour, while Factor 3 registered high loadings for colour and faecal coliform, suggesting domestic wastewater discharges and the presence of decaying organic matter. Factors 4 and 5 showed high loadings for copper, lead, turbidity and E. coli, an indication of both organic and inorganic pollution. Accordingly, periodic monitoring of Owabi Reservoir water quality, and the streams draining into it, is recommended as a means of ensuring good water quality, as well as facilitating the identification of the possible types and sources of water pollutants entering the reservoir.     

垃圾渗滤液中好氧反硝化生物脱氮的最佳条件

对垃圾渗滤液间歇曝气(曝气时DO为5.5～7 mg/L;停止时DO为1.1～5.5 mg/L),在仅有有机碳、无机氮的条件下进行好氧反硝化作用.通过正交试验确定了好氧反硝化的最佳条件为水力停留时间168 h,DO为5.5～7 mg/L,有机碳源为乙醇,当有机碳源为乙醇时C/N为10.并得出影响好氧反硝化作用因素的重要性排序依次为C/N＞水力停留时间＞有机碳源＞DO.C/N是影响好氧反硝化的主要因素,对TN去除率有高度显著的影响;水力停留时间对TN去除率有显著影响;有机碳源对TN去除率有一定影响;DO对TN去除率没有显著影响.     

Residues of PCB in a Cladophora Community Along the Lake Huron Shoreline

PCB residues were measured in samples of Cladophora, Ulothrix, net plankton, water, and fish collected in the Harbor Beach area of Lake Huron. The average concentrations of total PCB in each of the sample groups were as follows: water - 0.154 ng/g; Cladophora - 92 ng/g; Ulothrix - 126 ng/g; net plankton - 1,651 ng/g; and fish - 40 to 4,400 ng/g. The PCB patterns in the samples were found to match a mixture of Aroclo6r 1242 and 1254. Aroclor 1242 represented about 60% of the mixture in all the samples except the fish, where Aroclor 1254 represented about 75% of the total PCB measured. The accumulation factors observed in the progression from Cladophora to net plankton to fish were 1:15:30; these were similar to the concentration factors (1:14:44) developed on these ecosystem compartments in Lake Ontario during the 1972 IFYGL program.     

Spatial and seasonal variations and ecotoxicological significance of sediment trace metal concentrations in Kebir-Rhumel basin (Northeast of Algeria)

This study sought to assess sediment contamination by trace metals (cadmium, chromium, cobalt, copper, manganese, nickel, lead and zinc), to localize contaminated sites and to identify environmental risk for aquatic organisms in Wadis of Kebir Rhumel basin in the Northeast of Algeria. Water and surficial sediments (0-5 cm) were sampled in winter, spring, summer and autumn from 37 sites along permanent Wadis of the Kebir Rhumel basin. Sediment trace metal contents were measured by Flame Atomic Absorption Spectroscopy. Trace metals median concentrations in sediments followed a decreasing order: Mn > Zn > Pb > Cr > Cu > Ni > Co > Cd. Extreme values (dry weights) of the trace metals are as follows: 0.6-3.4 microg/g for Cd, 10-216 microg/g for Cr, 9-446 microg/g for Cu, 3-20 microg/g for Co, 105-576 microg/g for Mn, 10-46 microg/g for Ni, 11-167 microg/g for Pb, and 38-641 microg/g for Zn. According to world natural concentrations, all sediments collected were considered as contaminated by one or more elements. Comparing measured concentrations with American guidelines (Threshold Effect Level: TEL and Probable Effect Level: PEL) showed that biological effects could be occasionally observed for cadmium, chromium, lead and nickel levels but frequently observed for copper and zinc levels. Sediment quality was shown to be excellent for cobalt and manganese but medium to bad for cadmium, chromium, copper, lead, nickel and zinc regardless of sites.     

Treatment of linear alkylbenzene sulfonate (LAS) wastewater by internal electrolysis--biological contact oxidation process

Surfactant wastewater is usually difficult to treat due to its toxicity and poor biodegradability. A separate physico-chemical or biochemical treatment method achieves a satisfactory effect with difficulty. In this study, treatment of the wastewater collected from a daily chemical plant by the combination processes of Fe/C internal electrolysis and biological contact oxidation was investigated. For the internal electrolysis process, the optimal conditions were: pH = 4-5, Fe/C = (10-15):1, air-water ratio = (10-20):1 and hydraulic retention time (HRT)= 2 h. For the biological contact oxidation process, the optimal conditions were: HRT = 12 h, DO = 4.0-5.0 mg/L. Treated by the above combined processes, the effluent could meet the I-grade criteria specified in Integrated Wastewater Discharge Standard of China (GB 8978-1996). The results provide valuable information for full-scale linear alkylbenzene sulfonate wastewater treatment.     

Buffer zones as a sink for sediment and phosphorus between the field and stream: Danish field experiences.

Rill erosion, surface runoff and storage of sediment and phosphorus in buffer zones were investigated during three winters on ca. 140 arable field slope units in twenty places in Denmark covering all landscape types, climate gradients and dominant soil types. The dominant soils are Alfisols and Spodosols, with textural composition typically ranging from sand to loam. The average slope is 7% (range: 2-20%) and median buffer zone width was 8.3 m (range: 0.6-125 m). The geometric mean annual rill erosion was 0.33 m3 ha(-1) equalling to 495 kg sediment ha(-1) and 0.25 kg P ha(-1). The deposition of sediment on the field, in the buffer zone and delivery of soil to the stream was surveyed within the 140 slope units following three winters. Deposition of sediment in the buffer zone was observed in 31% (1997/98), 31% (1998/99) and 29% (1999/2000) of the slope units. Delivery of soil across the edge of the stream was observed in 23% (1997/98), 17% (1998/99) and 25% (1999/2000) of the 140 slope units. Median dissolved P concentration in surface runoff was 0.18 mg Pl(-1) (range: 0.029-16.294 mg Pl(-1)). A probability model was developed to predict the efficiency of different widths of buffer zones.     

Selecting Between One‐Dimensional and Two‐Dimensional Hydrodynamic Models for Ecohydraulic Analysis

Aquatic habitat assessment and river restoration design require geospatially explicit maps of hydraulic conditions. Diverse mechanistic ecohydraulic models compute spatially explicit depth and velocity results to evaluate habitat suitability spatially as a function of these abiotic conditions. This study compared depth and velocity results from two‐dimensional (2D) and one‐dimensional (1D) hydraulic models with algorithms that laterally discretize 1D velocity and interpolate depth and velocity spatially based on the Laplacian heat mapping approach. These ‘conveyance distributed’ methods constitute ‘best 1D modelling practice’ and were compared with 2D results for the first time. The 1D and 2D models were applied to three morphologically distinct reaches (leveed, meandering, and anastomosing) for three flows (base, bankfull, and flood flows) of the partially regulated, gravel/cobble lower Yuba River in north–central California. The test metrics were the coefficient of determination (R²) and the median absolute residual ( ). These metrics quantified the incremental uncertainty 1D approximation incurs, results which make explicit cost–benefit processes of model selection possible. Finally, velocity residual maps were analysed to identify regions and processes where residuals were high, indicating divergence from the 1D assumptions. Paired data (1D–2D) fell between 0.94 ≥ R² ≥ 1.00 (R²_mean = 0.98 and R²_median = 0.99) for depth and median absolute residuals were all 3.8 ≤ ≤ 7.2% (i.e. 50% of residuals are approximately within ±1.7 to 3.6%). Higher flows and lower gradient reaches had lower residuals and higher R². Velocity diverged more, particularly for base flow in anastomosing reaches (0.42 < R² < 0.58). One‐dimensional, conveyance distributed, assumptions performed better for other channel types, where 0.69 < R² < 0.81 (R²_mean = 0.75 and R²_median = 0.77), with median absolute residuals between 9.6% > > 22.4% (i.e. ~ ± 4.6 to ±11.2%), where _mean = 14.2% and _median = 13% (~ ±7.1 and 6.5%). The conveyance distributed 1D velocity model performed best, where the orthogonal flow assumptions obtained and where side channels did not transition from backwater to conveying area between flows. Copyright © 2015 John Wiley & Sons, Ltd.     

基于气温链的南水北调中线工程冬季气温等级评价

寒冷区明渠冬季输水结冰是常见的自然现象。南水北调中线工程水面一旦形成冰盖其安全输水流量仅为设计流量的30%~50%,而气温是驱动冰盖形成的主要因子,如何科学评价冬季气温等级是冰期输水面临的关键问题之一。分析了沿线8座气象站1951—2021年冬季日平均气温和日最低气温数据,揭示了总干渠气温沿程和年际变化规律。基于拉格朗日质点跟踪法,结合沿线气温-水温-冰盖生成物理过程,提出了气温链概念并给出通用数学表达式。分别采用国标法、一月平均气温法和气温链法评价冬季气温等级,构建了71 a冬季气温位次。结果表明:①总干渠自南向北气温逐级下降速率为0.48 ℃/(100 km),保定站呈加速下降趋势,对冰盖生成贡献最大。②沿线冬季气温总体呈波动上升趋势,升温速率为0.37 ℃/(10 a),强暖冬出现在最近30 a,强冷冬出现在前30 a,气温的总体上升有利于减缓大范围冰盖生成。③对于冰盖生成预测,气温链法优于一月平均气温法,更优于国标法;不同时间尺度组合评价可获得更优的结果;全球持续变暖背景下,可采用一月平均气温法和北方2站6 d气温链法联合评价。④给出了北方2站6 d气温链法冬季等级的分界阈值,即强暖冬T_C≥-4.0 ℃,弱暖冬-5.7 ℃≤T_C<-4.0 ℃,正常-7.4 ℃<T_C<-5.7 ℃,弱冷冬-9.1 ℃<T_C≤-7.4 ℃,强冷冬T_C≤-9.1 ℃,长系列均值为-6.5 ℃。研究成果可更好地为南水北调中线工程总干渠冰盖生成提供新的参考基准。     

Helsinge sludge reed bed system: reduction of pathogenic microorganisms.

Reduction of pathogenic bacteria: Salmonella, enterococci and Escherichia coli was investigated using the sludge reed bed system. The system at Helsinge was established in 1996 and has a capacity of 630 tonnes dry solids per year and consists of 10 basins. Since 2000 the individual basins have been subjected to an average area-specific loading rate of 46-56 kg dry solids/m2/year. The total sludge residue height in April 2006 was approximately 1.40 m. The sludge (approximately 0.5-0.8% dry solids), with which the individual basins were loaded, contained a large number of bacteria. Salmonella, enterococci and E. coli were found in the sludge in the following quantities: 10-300/100 g (wet weight), 7,000-25,000 CFU/g (wet weight) and 800,000-10,000,000 CFU/100 g (wet weight), respectively. The analysis of the reduction in pathogens in the sludge residue through a period of 3-4 months after the last loading indicated that the pathogen content was reduced down to < 2/100 g (Salmonella), < 10 CFU/g (enterococci) and < 200 number/100 g (E. coli). For enterococci and E. coli the reduction was approximately log 5 and log 6-7, respectively. In the same period the sludge residue achieved a dry solids content of approximately 20-35%.     

三级配大骨料混凝土双轴抗压性能试验分析

利用自行研制的大型混凝土静、动三轴试验系统,完成了5种应力比、4种应变率、3种含水状态（干燥、自然、饱和）的三级配大骨料混凝土双轴动态抗压试验。试验研究了含水率对三级配大骨料混凝土动态极限抗压强度的影响,并在此基础上提出考虑含水率影响的大骨料混凝土动态破坏准则。研究表明,饱和混凝土试件在高应变率下的强度明显提高,而在低应变率下强度则有所降低。在相同应变率下,极限抗压强度在应力比为1∶0.5时达到最大值。影响三级配大骨料混凝土试件破坏形态的主要因素为应力比,其动态极限抗压强度随含水率的增大而增大,而静态极限抗压强度随含水率的增大而减小;单轴受压状态下的变形明显小于双轴受压,试件的峰值应变随应变率的增大而减小。     

NO2-N含量对预臭氧化工艺效果影响研究

探讨了深圳某给水厂原水中NO2--N含量对预臭氧化工艺效果的影响.室内静态试验结果表明,深圳原水的O3消耗量与NO2--N完全去除的比例为51(O3消耗量/NO2--N的理论值约为3.4);当原水NO2--N＜0.1 mg/L时,NO2--N对预臭氧工艺无影响,而当NO2--N＞0.18 mg/L后,预臭氧化工艺去除有机物效果(以UV254表征)明显降低;水厂生产结果表明,NO2--N含量对预臭氧化工艺中的臭氧投加量及处理效果具有显著影响,原水中较高的NO2-N还会对后续混凝沉淀和砂滤工序造成不良影响,原水经生物预处理和封闭管道改造后,NO2--N由0.12～1.85 mg/L降低到0.02～0.14 mg/L,CODMn去除率明显升高.     

Water quality in the southern Tibetan Plateau: chemical evaluation of the Yarlung Tsangpo (Brahmaputra)

Yarlung Tsangpo (Brahmaputra) is the largest river system draining the northern slopes of the Himalayan ranges on the southern Tibetan Plateau. It remains one of only two large non‐regulated rivers in China. In this paper the chemical composition of Yarlung Tsangpo and its major tributaries (Raga Tsangpo, Nyangchu and Lhasa River) are studied. Water samples (n = 55) were collected and measured for major ions, trace elements and nutrients in order to: (1) define the present chemical quality of this water course; (2) address possible mechanisms governing the water chemical compositions, and (3) identify potential sources for contaminants. Multivariable analysis shows that geology and climate are the major explanatory variables for the spatial variation in water chemistry in this river system. In general, water chemistry is mainly controlled by carbonate weathering, with Ca²⁺ and HCO being the dominant ions. In addition, runoff from brackish/saline lakes and geothermal waters, enriched in Na⁺, Cl^?, SO, Mg²⁺ and Li, are major contributors of elevated concentrations of these solutes in the headwater regions resulting in a relatively high loading of total dissolved solids (TDS, 146–397 mg L^?1). Levels of most heavy metals and total dissolved nutrients were generally found to be low. However, elevated As concentration (avg. 95 μg L^?1) in the headwaters and additions from untreated wastewater were evident at some locations. Copyright © 2009 John Wiley & Sons, Ltd.     

Effect of loading rate on performance of constructed wetlands treating an anaerobic supernatant.

The effect of organic loading, season and plant species on the treatment of fish farm effluent was tested using three-year old mesocosm wetland systems. During one year, nine 1 m2 mesocosms (horizontal subsurface flow), located in a controlled greenhouse environment, were fed with a reconstituted fish farm effluent containing a high fraction of soluble components (1,600 microS/cm and in mg/L: 230 +/- 80 COD, 179 +/- 60 sCOD, 100 +/- 40 TSS, 37 +/- 7 TKN, 14 +/- 2 TP). Combinations of three hydraulic loading rates (30, 60 and 90 L.m(-2) d(-1)) and two plant species (Phragmites australis, Typha angustifolia) and an unplanted control were tested for treatment performance and hydraulic behaviour. Loadings higher than 15 g COD m(-2) d(-1) resulted in a net decrease of hydraulic performances (generation of short circuiting) coupled with low TKN removal. Maximal TKN removal rates (summer: 1.2, winter: 0.6 g.m(-2) d(-1)) were reached in planted units. In all mesocosms, phosphorus was removed during summer (maximal removal rate: 0.3 g TP m(-2) d(-1)) and was released in winter (release rate = approximately half of summer removal rate). This study confirmed that constructed wetlands are susceptible to clogging when treating anaerobic storage tank supernatant rich in highly biodegradable compounds. Contributions of plants to hydraulic efficiency were mainly observed in summer, associated with high evapotranspiration rates. Both plant species gave a similar removal efficiency for all pollutants.