LAP降烯烃助剂的工业应用

文章介绍了洛阳石油化工工程公司炼制研究所开发的LAP降低催化裂化烯烃助剂在北海石化厂的工业应用。结果证实了LAP助剂具有良好的降烯烃活性,当LAP助剂占装置催化剂藏量的5％时,催化裂化汽油烯烃降低了5－11个百分点,汽油收率下降0．15个百分点,柴油收率下降2．26个百分点;同时,液化石油气上升3．91个百分点,其中丙烯、丁烯产率增加。     

ZCAT-HP丙烯增产助剂在重油催化裂化装置的工业应用

ZCAT-HP丙烯增产助剂是一种可有效提高液化石油气中丙烯含量增产丙烯收率的催化添加剂，该剂在福建炼化公司重油催化裂化装置工业应用结果表明：ZCAT-HP丙烯增产助剂在占系统催化剂藏量2．4％时，催化裂化的丙烯产率可提高0．83个百分点，液化石油气收率可提高1．51个百分点，液化石油气中的丙烯含量显著提高。同时该剂可有效降低汽油烯烃含量、减少新鲜催化剂单耗0．11kg／t，且对产品其它性质无不良影响。     

XB-01催化助剂在RFCC装置的应用

金陵分公司RFCC装置通过使用XB-01催化助剂。在加入量占原料90μg／g时，使装置的油浆产率降低了1．2个百分点。目的产品的收率提高1个百分点，初步核算可使每吨原料增效10元，有良好的经济效益。同时，该助剂对产品质量及装置操作没有不利影响，而且加注方便、调节简单，不需增加设备投资。     

TOM OPAL 878L型降烯烃催化剂的工业应用

介绍了洛阳分公司I套催化裂化装置使用TO MOPAl．878L．降汽油烯烃催化剂的情况。该剂在占系统催化剂藏量46％时进行的标定结果表明：该剂具有比较明显的降汽油烯烃效果，汽油烯烃体积分数由49．7％降到42％，下降了7．7个百分点，汽油辛烷值没有降低；产品分布得到改善，重油裂化能力强，干气和焦炭选择性好，干气产率降低了0．16个百分点，焦炭产率降低了0．81个百分点，轻质油收率增加了1．58个百分点，轻液体收率增加了2．36个百分点。     

催化裂化增产丙烯助剂(LPI-1)对原料适应性的研究

介绍了催化裂化增产丙烯助剂(LPI-1)对原料适应性的实验室研究结果。研究表明，LPI-1对长庆常压渣油、九江管输混合油和茂名加氢渣油均具有很好的适应性。该助剂不仅可以用于炼油企业催化裂化装置增产丙烯，而且在已应用助气剂的催化裂化装置上仍可有效增产丙烯。使用该助剂后，液化石油气产率增加2．31个百分点以上，丙烯产率增加1．51个百分点以上，增产丙烯的选择性均在59％以上。于气和焦炭产率略有增加，总液体收率基本不变；汽油研究法辛烷值略有提高，同时汽油烯烃含量有所降低。     

提高催化裂化液化石油气中丙烯浓度助剂的工业应用浅析

介绍了提高催化裂化液化石油气中丙烯浓度的助剂(MP031)的工业应用结果，并对在工业装置上由于加剂速度、原料性质、系统催化剂品质、反应温度和其它操作参数等因素变化对助剂使用效果造成的影响进行了分析和讨论。从工业应用结果看，当MP031助剂在反应再生系统中占系统催化剂藏量的比例为4％左右时，液化石油气中丙烯体积分数可提高约4个百分点，丙烯产率增加0．62个百分点，而液化石油气的产率增加值不大于0．5个百分点。     

酸性助剂对催化裂化催化剂活性的影响

利用杂多酸 (盐 )具有质子酸的特点 ,合成了油溶性的杂多酸助剂Ⅰ及与其盐的混合助剂Ⅱ。该酸性助剂与原料油直接混合进入提升管 ,与平衡剂接触明显改善了平衡剂的B酸酸性 ,提高了催化剂的裂化活性。当助剂Ⅰ用量为 40 μg/g时 ,酸性提高 3个单位 ,轻油收率提高 1.3 6个百分点 ,总液体收率提高 2 .3 4个百分点。当使用酸性助剂Ⅱ时 ,轻油收率、总液体收率分别提高 1.90和 2 .5 0个百分点     

提高渣催化裂化轻质油收率的助剂研究

为适应渣油催化裂化原料的多样化和劣质化,研制开发了少量添加于催化剂中的助剂。该助剂的载体包含AI、Si、Mg、P四组分,活性组分选用稀土金属和过渡金属两组分,用喷雾干燥法制备。该助剂经固定流化床试验装置与小型提升管试验装置评定结果表明,它具有较好的渣油裂化活性和较强的水热稳定性;在基础剂中加入5％的助剂,可使轻质油收率提高3．4个百分点,气体收率提高0．7个百分点,重油产率减少约4个百分点,焦炭产率基本不变。助剂的使用对油品质量基本上没有影响。     

提高液化气中丙烯含量助剂MP031的开发和应用

以特种活性组元改性MFI结构沸石为主活性组元开发了提高液化气中丙烯含量的催化裂化助剂MP031。中试评价结果表明，以大庆减压蜡油掺30％减压渣油为原料，以降烯烃催化剂为主剂，掺入8％的MP031助剂，丙烯产率增加1．54个百分点，液化气中丙烯含量增加4．11个百分点。开发的助剂对丙烯的选择性明显优于常规助气剂，并且助剂对主剂具有很好的适应性。该助剂在中国石化洛阳分公司和金山分公司的工业应用结果表明，MP031助剂占催化剂藏量约5％，液化气产率增加1个百分点以下时，丙烯产率增加0．6个百分点以上。     

新型催化裂化轻质油收率助剂的工业应用

介绍了WD0 1 0 0 2油溶性催化助剂在长岭炼化有限责任公司重油催化裂化装置上的工业应用情况。该助剂通过减缓催化剂在提升管内活性衰减 ,提高催化剂裂化活性、选择性 ,优化提升管内催化裂化反应。该装置使用助剂 36 μg/g ,装置渣油掺炼率由 30 .81%提高到35 .15 %,轻质油收率提高 0 .8个百分点 ,总液体收率提高 0 .6 7个百分点 ,对产品质量无不良影响。加剂调整作用时间短 ,操作灵活、方便。     

New Modifications Bart,Bdchamp, Mayer,Rosenmund, Scheller,Sherlyn-Braz Reactions with Halides of Arsenic,Antimony and Bismuth

It was discovered a new approach modification Bart, Beschamp, Mayer, Rosenmund, Scheller, Sherlyn-Braz reactions with of arsine, stibine and bismuthine in organometallic chemistry. The authors have proposed a new mechanism for possible reactions.     

Search for New Three-, Four-Component Petasis,Passerini, Hantzsch,Kabachnic-Fields,Ugi Reactions with Organic Compounds of Phosphorus,Arsenic, Antimony and Bismuth

It is discovered a new three-, four-component Petasis, Passerini, Hantzsch, Kabachnic-Fields, Ugi reactions with of arsine, stibine and bismuthine in organometallic chemistry. Modifications were replaced to a nitrogen atom of classical reactions of atoms of phosphorus, arsenic, antimony and bismuth. It has been proposed a new mechanism for possible reactions.     

Compatibility of 2, 4, 6, 8, 10,12-Hexanitrohexaazaisowurtzitane with a Selection of Insensitive Explosives

Thermal techniques (differential scanning calorimetry (DSC) and the vacuum stability test (VST)), according to STANAG 4147, and non-thermal techniques (Fourier transform infrared (FTIR) spectrometry and X-ray diffractometry (XRD)) were used to examine compatibility issues for 2,4,6,8,10,12-hexanitrohexaazaisowurtzitane (CL-20) with a selection of insensitive explosives, including nitroguanidine (NQ), 2,4,6-trinitrotoluene (TNT), 2,6-diamino-3,5-dinitropyridine-1-oxide (ANPyO), 2,4,6-triamino-1,3,5-trinitrobenzene (TATB), 3-nitro-1,2,4-triazol-5-one (NTO) and 2,6-diamino-3,5-dinitropyrazine-1-oxide (LLM-105). DSC measurements showed that ANPyO, TATB, NTO and LLM-105 were compatible with CL-20. The compatibility of CL-20/NQ, CL-20/TNT, CL-20/ANPyO, CL-20/TATB, CL-20/NTO and CL-20/LLM-105 mixtures was further explored using the VST, which revealed that all the selected insensitive explosives were compatible with CL-20. Possible chemical interactions were suspected for CL-20/TATB from the FTIR results and for CL-20/NTO from XRD analysis. In summary, ANPyO and LLM-105 demonstrated the optimal compatibility with CL-20.     

The Petrography,Mineralogy, and Hydrocarbon Potential of the Shales of the Duwi Formation,Abu Tartur,South Western Desert,Egypt

Abstract

Eight shale samples related to the Duwi Formation (Campanian-Maastrichtian) of the Abu Tartur mines of the southwestern desert of Egypt were petrographically, mineralogically, and geochemically studied. The study results indicate that the detrital material of these shales were derived mainly from mafic to ultramafic components of the basement rocks under intensive chemical weathering and deposited in an alkaline reducing marine environment of low energy and these shales do not attain the requirements of hydrocarbon production.     

QPQ表面处理技术及提高工具耐冲蚀性能试验研究

为了提高海洋石油用井下工具的耐磨和耐冲蚀性能,采用理论和试验方法,开展了4145材质的QPQ表面处理技术的应用研究和耐冲蚀性能试验研究。结果表明:在模拟现场压裂作业工况(高砂比、大排量)下,QPQ处理工具的平均冲蚀厚度约3 mm,QPQ处理的工具较磷化处理的工具有较高的耐腐蚀性能和良好的自润滑性能。QPQ处理后的整套压裂工具在渤海油田某井成功应用,满足压裂作业的要求。     

ICP-AES法测定聚丙烯中钙、镁、铁、铝、钛的含量

应用ICP -AES分析方法测定聚丙烯中钙、镁、铁、铝、钛的含量。研究了酸度及共存元素对被测元素的影响 ,选择了合适的分析谱线及ICP -AES工作参数。同时进行了方法精密度试验 ,相对标准偏差小于 5 % ,标准加入回收率 91%～ 10 7%。本法简单、快速、准确     

Bulk Compositions,Genetic Origin,Classifications, and Maturation of Crude Oils in the Gulf of Suez,Egypt

Abstract

API gravity, sulfur content, gas chromatography, and gas chromatography-mass spectrometry analyses were carried out for eight oil samples collected from different wells in the Gulf of Suez. The results showed that two types of oils could be recognized: (a) heavy oils, which are oils from Zafarana, Rahmi, West Bakr, and Ras Gharib wells, are of low maturation and originated mainly from terrestrial organic sources; and (b) light oils, which are oils from Um El Yuser, Ras El Ush, Gemsa-SE, and Hurghada wells, have a high level of maturation and orginate mainly from marine organic sources.     

Preparation,Characterization, Evaluation,and Regeneration of a Novel Hydro-upgrading Catalyst

A non–noble metal hydro-upgrading catalyst was prepared using modified zeolites as acidic component, and catalytic performance evaluation was also carried out between the hydro-upgrading catalyst and the reference catalyst, which is a commercial catalyst. The evaluation results revealed that under the pressure of 8.0 MPa, the diesel product yield of the hydro-upgrading catalyst was 98.8 m%, cetane index increment was 7.3 units, diesel yield of the reference catalyst was 98.3 m%, and the cetane index increment was 7.2 units; under the pressure of 6.0 MPa, the diesel product yield of the hydro-upgrading catalyst was 99.1 m%, cetane index increment was 6.1 units, diesel yield of the reference catalyst was 98.7m%, and the cetane index increment was 5.3 units. In addition, preparation repeatability, activity stability, and regeneration performance tests of the hydro-upgrading catalyst were carried out.     

Stratigraphy,Petrography, and Petrophysical Properties of the Subsurface Upper Cretaceous Sediments,Northwestern Desert,Egypt

Abstract

In this article, 33 core samples and 160 ditch samples of Upper Cretaceous age were studied at different depths from Horus well 1. Stratigraphic, petrographic, and petrophysical studies and well log analysis are used to study and evaluate the rock units. The studied core samples are dolomite (Abu Roash formation), shaly limestone, and argillaceous sandstone (Bahariya formation). The depositional environments of the studied rock units vary from deltaic to deltaic-marine. The effective porosity of the studied core samples is low and may be of secondary origin. The upper part of low Bahariya is considered a high category of reservoir. The stratigraphic significance of some benthonic foraminifera (Thomasinella, Nezzazata, and Nezzatine) furnishes new information on the age determination. Cenomanian-Santonian time is suggested for the studied interval (Bahariya and Abu Roash formations).