Comparative assessment of greenhouse gas mitigation of hydrogen passenger trains

This paper examines a comparative assessment in terms of CO₂ emissions from a hydrogen passenger train in Ontario, Canada, particularly comparing four specific propulsion technologies: (1) conventional diesel internal combustion engine (ICE), (2) electrified train, (3) hydrogen ICE, and (4) hydrogen PEM fuel cell (PEMFC) train. For the electrified train, greenhouse gases from electricity generation by natural gas and coal-burning power plants are taken into consideration. Several hydrogen production methods are also considered in this analysis, i.e., (1) steam methane reforming (SMR), (2) thermochemical copper–chlorine (Cu–Cl) cycle supplied partly by waste heat from a nuclear plant, (3) renewable energies (solar and wind power) and (4) a combined renewable energy and copper–chlorine cycle. The results show that a PEMFC powertrain fueled by hydrogen produced from combined wind energy and a copper–chlorine plant is the most environmentally friendly method, with CO₂ emissions of about 9% of a conventional diesel train or electrified train that uses a coal-burning power plant to generate electricity. Hydrogen produced with a thermochemical cycle is a promising alternative to further reduce the greenhouse gas emissions. By replacing a conventional diesel train with hydrogen ICE or PEMFC trains fueled by Cu-Cl based-hydrogen, the annual CO₂ emissions are reduced by 2260 and 3318 tonnes, respectively. A comparison with different types of automobile commuting scenarios to carry an equivalent number of people as a train is also conducted. On an average basis, only an electric car using renewable energy-based electricity that carries more than three people may be competitive with hydrogen trains.     

Coal gasification system using nuclear heat for ammonia production

Utilization of nuclear energy is an effective way of solving the global warming resulting from CO₂ emissions. Thermal energy accounts for more than two thirds of total energy utilization at present and therefore it is significant to extend the utilization of nuclear heat for the effective reduction of CO₂ emissions in the world. This paper describes a coal gasification system using HTGR nuclear heat in an ammonia production plant in terms of industrial utilization of the nuclear heat. The system uses the nuclear heat directly in addition to generating electricity. A steam reforming method using a two-stage coal gasifier is employed: it improves the heat utilization efficiency of the secondary helium gas from the HTGR. Finally, the paper clarifies that the nuclear gasification system can reduce CO₂ emissions by about five hundred thousand tons per year from that of a conventional system using fossil fuel.     

Dynamics of hydrogen powered CAES based gas turbine plant using sodium alanate storage system

Typical compressed air energy storage (CAES) based gas turbine plant operates on natural gas or fuel oils as fuel for its operation. However, the use of hydro-carbon fuels will contribute to carbon emissions leading to pollution of the environment. On the other hand, the use of hydrogen as fuel for the gas turbine will eliminate the carbon emissions leading to a cleaner environment. Hydrogen can be produced using renewable energy sources like wind, solar etc. Storage of hydrogen is a bottleneck for such a system. A high capacity sodium alanate metal hydride bed is used in this study to store the hydrogen. The dynamics of the CAES based gas turbine plant operating with hydrogen fuel is presented along with discharge dynamics of the metal hydride bed. The heat required for desorbing the hydrogen from the metal hydride bed is provided partly by the hot flue gas exiting from the low pressure turbine and partly by external heating. Thus some of the heat from the flue gas is extracted. A novel multiple bed strategy is employed for efficient desorption. Each bed consists of a shell and tube, with alanate in the shell and heating fluid flowing through the helical coiled tube. Hydrogen combustor is modeled using a simplified Continuous Stirred Tank Reactor (CSTR) assumption in CANTERA. The NO_x emissions in the low pressure turbine exhaust stream are presented.     

Greenhouse gas emissions reduction by use of wind and solar energies for hydrogen and electricity production: Economic factors

This study addresses economic aspects of introducing renewable technologies in place of fossil fuel ones to mitigate greenhouse gas emissions. Unlike for traditional fossil fuel technologies, greenhouse gas emissions from renewable technologies are associated mainly with plant construction and the magnitudes are significantly lower. The prospects are shown to be good for producing the environmentally clean fuel hydrogen via water electrolysis driven by renewable energy sources. Nonetheless, the cost of wind- and solar-based electricity is still higher than that of electricity generated in a natural gas power plant. With present costs of wind and solar electricity, it is shown that, when electricity from renewable sources replaces electricity from natural gas, the cost of greenhouse gas emissions abatement is about four times less than if hydrogen from renewable sources replaces hydrogen produced from natural gas. When renewable-based hydrogen is used in a fuel cell vehicle instead of gasoline in a IC engine vehicle, the cost of greenhouse gas emissions reduction approaches the same value as for renewable-based electricity only if the fuel cell vehicle efficiency exceeds significantly (i.e., by about two times) that of an internal combustion vehicle. It is also shown that when 6000 wind turbines (Kenetech KVS-33) with a capacity of 350 kW and a capacity factor of 24% replace a 500-MW gas-fired power plant with an efficiency of 40%, annual greenhouse gas emissions are reduced by 2.3 megatons. The incremental additional annual cost is about $280 million (US). The results provide a useful approach to an optimal strategy for greenhouse gas emissions mitigation.     

Potential importance of hydrogen as a future solution to environmental and transportation problems

Air pollution is a serious public health problem throughout the world, especially in industrialized and developing countries. In industrialized and developing countries, motor vehicle emissions are major contributors to urban air quality. Hydrogen is one of the clean fuel options for reducing motor vehicle emissions. Hydrogen is not an energy source. It is not a primary energy existing freely in nature. Hydrogen is a secondary form of energy that has to be manufactured like electricity. It is an energy carrier. Hydrogen has a strategic importance in the pursuit of a low-emission, environment-benign, cleaner and more sustainable energy system. Combustion product of hydrogen is clean, which consists of water and a little amount of nitrogen oxides. Hydrogen has very special properties as a transportation fuel, including a rapid burning speed, a high effective octane number, and no toxicity or ozone-forming potential. It has much wider limits of flammability in air than methane and gasoline. Hydrogen has become the dominant transport fuel, and is produced centrally from a mixture of clean coal and fossil fuels (with C-sequestration), nuclear power, and large-scale renewables. Large-scale hydrogen production is probable on the longer time scale. In the current and medium term the production options for hydrogen are first based on distributed hydrogen production from electrolysis of water and reforming of natural gas and coal. Each of centralized hydrogen production methods scenarios could produce 40 million tons per year of hydrogen. Hydrogen production using steam reforming of methane is the most economical method among the current commercial processes. In this method, natural gas feedstock costs generally contribute approximately 52–68% to the final hydrogen price for larger plants, and 40% for smaller plants, with remaining expenses composed of capital charges. The hydrogen production cost from natural gas via steam reforming of methane varies from about 1.25 US$/kg for large systems to about 3.50 US$/kg for small systems with a natural gas price of 6 US$/GJ. Hydrogen is cheap by using solar energy or by water electrolysis where electricity is cheap, etc.     

System-level energy efficiency is the greatest barrier to development of the hydrogen economy

Current energy research investment policy in New Zealand is based on assumed benefits of transitioning to hydrogen as a transport fuel and as storage for electricity from renewable resources. The hydrogen economy concept, as set out in recent commissioned research investment policy advice documents, includes a range of hydrogen energy supply and consumption chains for transport and residential energy services. The benefits of research and development investments in these advice documents were not fully analyzed by cost or improvements in energy efficiency or green house gas emissions reduction. This paper sets out a straightforward method to quantify the system-level efficiency of these energy chains. The method was applied to transportation and stationary heat and power, with hydrogen generated from wind energy, natural gas and coal. The system-level efficiencies for the hydrogen chains were compared to direct use of conventionally generated electricity, and with internal combustion engines operating on gas- or coal-derived fuel. The hydrogen energy chains were shown to provide little or no system-level efficiency improvement over conventional technology. The current research investment policy is aimed at enabling a hydrogen economy without considering the dramatic loss of efficiency that would result from using this energy carrier.     

Life cycle environmental impact comparison of solid oxide fuel cells fueled by natural gas,hydrogen, ammonia and methanol for combined heat and power generation

This study aims to provide a comprehensive environmental life cycle assessment of heat and power production through solid oxide fuel cells (SOFCs) fueled by various chemical feeds namely; natural gas, hydrogen, ammonia and methanol. The life cycle assessment (LCA) includes the complete phases from raw material extraction or chemical fuel synthesis to consumption in the electrochemical reaction as a cradle-to-grave approach. The LCA study is performed using GaBi software, where the selected impact assessment methodology is ReCiPe 1.08. The selected environmental impact categories are climate change, fossil depletion, human toxicity, water depletion, particulate matter formation, and photochemical oxidant formation. The production pathways of the feed gases are selected based on the mature technologies as well as emerging water electrolysis via wind electricity. Natural gas is extracted from the wells and processed in the processing plant to be fed to SOFC. Hydrogen is generated by steam methane reforming method using the natural gas in the plant. Methanol is also produced by steam methane reforming and methanol synthesis reaction. Ammonia is synthesized using the hydrogen obtained from steam methane reforming and combined with nitrogen from air in a Haber-Bosch plant. Both hydrogen and ammonia are also produced via wind energy-driven decentralized electrolysis in order to emphasize the cleaner fuel production. The results of this study show that feeding SOFC systems with carbon-free fuels eliminates the greenhouse gas emissions during operation, however additional steps required for natural gas to hydrogen, ammonia and methanol conversion, make the complete process more environmentally problematic. However, if hydrogen and ammonia are produced from renewable sources such as wind-based electricity, the environmental impacts reduce significantly, yielding about 0.05 and 0.16 kg CO₂ eq., respectively, per kWh electricity generation from SOFC.     

Comparison of well-to-wheels energy use and emissions of a hydrogen fuel cell electric vehicle relative to a conventional gasoline-powered internal combustion engine vehicle

The operation of hydrogen fuel cell electric vehicles (HFCEVs) is more efficient than that of gasoline conventional internal combustion engine vehicles (ICEVs), and produces zero tailpipe pollutant emissions. However, the production, transportation, and refueling of hydrogen are more energy- and emissions-intensive compared to gasoline. A well-to-wheels (WTW) energy use and emissions analysis was conducted to compare a HFCEV (Toyota Mirai) with a gasoline conventional ICEV (Mazda 3). Two sets of specific fuel consumption data were used for each vehicle: (1) fuel consumption derived from the U.S. Environmental Protection Agency's (EPA's) window-sticker fuel economy figure, and (2) weight-averaged fuel consumption based on physical vehicle testing with a chassis dynamometer on EPA's five standard driving cycles. The WTW results show that a HFCEV, even fueled by hydrogen from a fossil-based production pathway (via steam methane reforming of natural gas), uses 5%–33% less WTW fossil energy and has 15%–45% lower WTW greenhouse gas emissions compared to a gasoline conventional ICEV. The WTW results are sensitive to the source of electricity used for hydrogen compression or liquefaction.     

US electric industry response to carbon constraint: a life-cycle assessment of supply side alternatives

This study explores the boundaries of electric industry fuel switching in response to US carbon constraints. A ternary model quantifies how supply side compliance alternatives would change under increasingly stringent climate policies and continued growth in electricity use. Under the White House Climate Change Initiative, greenhouse gas emissions may increase and little or no change in fuel-mix is necessary. As expected, the more significant carbon reductions proposed under the Kyoto Protocol (1990—7% levels) and Climate Stewardship Act (CSA) (1990 levels) require an increase of some combination of renewable, nuclear, or natural gas generated electricity. The current trend of natural gas power plant construction warrants the investigation of this technology as a sustainable carbon-mitigating measure. A detailed life-cycle assessment shows that significant greenhouse gas emissions occur upstream of the natural gas power plant, primarily during fuel-cycle operations. Accounting for the entire life-cycle increases the base emission rate for combined-cycle natural gas power by 22%. Two carbon-mitigating strategies are tested using life-cycle emission rates developed for US electricity generation. Relying solely on new natural gas plants for CSA compliance would require a 600% increase in natural gas generated electricity and almost complete displacement of coal from the fuel mix. In contrast, a 240% increase in nuclear or renewable resources meets the same target with minimal coal displacement. This study further demonstrates how neglecting life-cycle emissions, in particular those occurring upstream of the natural gas power plant, may cause erroneous assessment of supply side compliance alternatives.     

Efficient utilization of waste heat from molten carbonate fuel cell in parabolic trough power plant for electricity and hydrogen coproduction

Direct steam generating parabolic trough power plant is an important technology to match future electric energy demand. One of the problems related to its emergence is energy storage. Solar-to-hydrogen is a promising technology for solar energy storage. Electrolysis is among the most processes of hydrogen production recently investigated. High temperature steam electrolysis is a clean process to efficiently produce hydrogen. In this paper, steam electrolysis process using solar energy is used to produce hydrogen. A heat recovery steam generator generates high temperature steam thanks to the molten carbonate fuel cell's waste heat. The analytical study investigates the energy efficiency of solar power plant, molten carbonate fuel cell and electrolyser. The impact of waste heat utilization on electricity and hydrogen generation is analysed. The results of calculations done with MATLAB software show that fuel cell produces 7.73 MWth of thermal energy at design conditions. 73.37 tonnes of hydrogen and 14.26 GWh of electricity are yearly produced. The annual energy efficiency of electrolyser is 70% while the annual mean electric efficiency of solar power plant is 18.30%.The proposed configuration based on the yearly electricity production and hydrogen generation has presented a good performance.     

A cost-effective approach for optimal energy management of a hybrid CCHP microgrid with different hydrogen production considering load growth analysis

An optimum design and energy management of various distributed energy resources is investigated in a hybrid microgrid system with the examination of electrical, heating, and cooling demand. This paper suggested an optimal approach to design and operate a microgrid incorporating with battery energy storage, thermal energy storage, photovoltaic arrays, fuel cell, and boiler with minimization of the total operational cost of the hybrid microgrid. Two different hydrogen production methods are considered to assure the advantage of the developed proposed methodology. Furthermore, besides natural gas, residential and municipal wastes are collected and are utilized to produce electricity in fuel cell units. Load growth for different type of loads is also considered. The new number of households are added to the proposed system in different years and the proposed program is determined the optimum size of each employed resources to add each year for satisfying the total demand. To find out the optimum energy management and the optimum capacity of each employed distributed energy resources, a meta-heuristic Particle Swarm Optimization Algorithm is utilized. It is concluded from the results that by utilizing residential waste, the amount of natural gas consumption by fuel cells is reduced about 6.2%, and by utilizing residential plus municipal waste, the reduction is about 26.7%. It is also observed that the amount of CO₂ emission is reduced significantly (46.8%) in the case of utilization of produced heat by fuel cells. Finally, the results confirmed the efficacy of the suggested optimal energy management of the hybrid microgrid.     

An investigation of a household size trigeneration running with hydrogen

This study examined the performance and emission characteristics of a household size trigeneration based on a diesel engine generator fuelled with hydrogen comparing to that of single generation, cogeneration using ECLIPSE simulation software. In single generation simulation, the engine genset is used to produce electricity only and the heat from the engine is rejected to the atmosphere. In cogeneration and trigeneration, in addition to the electricity generated from the genset, the waste heat rejected from the hot exhaust gases and engine cooling system, is captured for domestic hot water supply using heat exchangers and hot water tank; and a part of the waste heat is used to drive absorption cooling in trigeneration. Comparisons have been made for the simulated results of these three modes of operation for hydrogen and diesel. The results prove that hydrogen is a potential energy vector in the future which is a key to meeting upcoming stringent greenhouse gases emissions. The study show that hydrogen has very good prospects to achieve a better or equal performance to conventional diesel fuel in terms of energetic performance, and a near zero carbon emission, depending on the life cycle analysis of the way the hydrogen is produced. The results also show enormous potential fuel savings and massive reductions in greenhouse gas emissions per unit of useful energy outputs with cogeneration and trigeneration compared with that of single generation.     

Carbon black and hydrogen production process analysis

The adoption of new environmentally responsible technologies, as well as, energy efficiency improvements in equipment and processes help to reduce CO2 rate emission into the atmosphere, contributing in delaying the consequences of intensive use of fossil fuels. For more effective actions, it is necessary to make the transition from the fossil-based to the renewable source economy. In this context, hydrogen fuel has a special role as clean vector of energy. Hydrogen has the potential to be decisive in mitigating greenhouse gas emissions, but fossil fuels high profitability due to global energy dependency actually drives the global economy.While renewable energy sources are not worldwide fully established, new technologies should be developed and used for the recovery of energetic streams nowadays wasted, to decarbonize hydrocarbons and to improve systems efficiency creating a path that can help nations and industries in the needed energy economy transition. Hydrogen gas can be generated by various methods from different sources such as coal and water. Currently, almost all of the hydrogen production is for industrial purpose and comes from the Steam Reforming, while the use of hydrogen in fuel cells is only incipient.The article analysis the plasma pyrolysis of hydrocarbons as a decarbonization option to contribute as a step towards hydrogen economy. It presents the Carbon Black and Hydrogen Process (CB&H Process) as an alternative option for hydrogen generation at large scale facility, suitable for supplying large amounts of high-purity carbon in elemental form. CB&H Process refers to a plant with hydrogen thermal plasma reactor able to decompose Hydrocarbons (HC's) into Hydrogen (H2) and Carbon Black (CB), a cleaner technology than its competing processes, capable of generating two products with high added value. Considering the Brazilian context in which more than 80% of the generated electricity comes from renewable sources, the use of electricity as one of the inputs in the process does not compromise the objective of reducing greenhouse gas emissions. It is important to consider that the use of renewable energy to produce two products derived from fossil fuels in a clean way represents integration of technologies into a more efficient system and an arrangement that contributes to the transition from fossil fuels to renewables.The economic viability of the CB&H process as a hydrogen generation unit (centralized) for refining applications also depends on the cost of hydrogen production by competing processes. Steam Methane Reforming (SMR) is a widespread method that produces twice the amount of hydrogen generated by natural gas plasma pyrolysis, but it emits CO2 gas and consumes water, while CB&H process produces solid carbon. For this reason, the paper seeks the carbon production cost by plasma pyrolysis as a breakeven point for large-scale hydrogen generation without water consumption and carbon dioxide emissions.     

Ecological and economic efficiency of the use of alternative energy technologies including hydrogen to reduce of the anthropogenic load in the central ecological area of the Baikal natural territory

The central ecological area of the Baikal natural territory covers some districts of the Irkutsk oblast and the Republic of Buryatia, located on the coast of the Lake Baikal. Due to the natural uniqueness and special status of doing economic activity, the assessment of the impact on the environment in this territory is very importance.An analysis of the functioning of energy objects showed that a significant part of the territory is provided with a centralized electricity supply with developed electric grid infrastructure. There are only a few remote settlements with autonomous electricity supply from diesel power plants.The main sources of pollution are numerous boiler houses that provide heat to the population, social and administrative institutions. In all, there are 98 heat energy sources in the territory, of which 66 (or 70%) use coal.The problems of environmental pollution are mainly caused by the use of coal in a small boiler house, worn-out equipment, and the lack of an appropriate level of flue gas treatment. The total estimated emission of pollutants into the atmosphere from heat energy sources is estimated at 20–25 thousand tons per year.In order to reduce the anthropogenic impact from energy objects, it is advisable to use renewable energy sources, hydrogen technologies, coal substitution with environmentally friendly fuels, use of electricity for heat energy supply, installation of environmental protection equipment and the implementation of energy-saving measures.The methodological approach and simulation models developed at MESI SB RAS were used to determine the competitiveness conditions of alternative technologies and energy carriers.The studies evaluated the environmental and economic efficiency of energy production technologies by using specific indicators: the capital intensity of reducing 1 ton of emissions and environmental capital return by 1 million rubles for the conditions of the central ecological area.The potential for reducing emissions into the atmosphere by use of renewable energy sources in autonomous energy supply areas is less than 1% of the current level of total emissions from energy objects. The potential for reducing emissions by replacing boiler houses with a capacity of less than 0,2 Gcal/h by a heat pump units is no more than 12%.The biggest environmental effect can be achieved by using alternative energy carriers including hydrogen instead of coal. Moreover, the potential for reducing emissions is 60% of the total emissions. In addition to these activities are the least capital intensive.The most effectively is the replacement of coal with natural gas. Rational gas consumption in the coastal areas of Lake Baikal is estimated at 175–190 thousand tons of equivalent fuel. The real possibility of transferring small boiler houses to gas arises during the construction of an export gas pipeline from Russia (through the territory of the Irkutsk oblast) to China via Mongolia, or by the small-scale production of liquefied natural gas.The most currently implemented direction is the use of electricity for heat energy supply. The potential volume of electricity to replace coal in boiler houses of the central ecological area is 1,3 TWh per year, however, the competitive electricity tariff is estimated less than 2 US c/kWh, which is several times lower than current tariffs.Hydrogen technology is currently very capital-intensive, but using it in a way similar to using electricity for heat eliminates pollutant and greenhouse gas emissions.Now days, there are no effective financial mechanisms aimed at stimulating the reduction of the anthropogenic pressure on the environment from existing energy sources, including for the use of alternative technologies. As the result, significant financial support is required in the form of special cost compensation mechanisms for energy producers and/or consumers.     

Estimates of inter-fuel substitution possibilities in Chinese chemical industry

The chemical sector is a key driver of China's remarkable growth record and accounts for about 10% of the country's GDP. This has made the industry energy-intensive and consequently a major contributor to greenhouse gas emissions (GHG) and other pollutants. This study has attempted to investigate the potential for inter-fuel substitution between coal, oil, natural gas and electricity in Chinese chemical sector by employing a translog production and cost function. Ridge regression procedure was adopted to estimate the parameters of the function. Estimation results show that all energy inputs are substitutes. In addition, the study produces evidence that the significant role of coal in the Chinese chemical fuel mix converges over time, albeit slowly. These results suggest that price-based policies, coupled with capital subsidy programs can be adopted to redirect technology use towards cleaner energy sources like electricity and natural gas; hence, retaining the ability to fuel the chemical sector, while also mitigating GHG emissions. Notwithstanding, one must understand that the extent to which substituting electricity for coal will be effective depends on the extent to which coal or oil is used in generating electricity. The findings of this study provide general insights and underscore the importance of Chinese government policies that focus on installed capacity of renewable electricity, energy intensity targets as well as merger of enterprises.     

World energy analysis: H2 now or later?

This is a study of world energy resource sustainability within the context of resource peak production dates, advanced energy use technologies in the transportation and electricity generation energy use sectors, and alternative fuel production including hydrogen. The finding causing the most concern is the projection of a peak in global conventional oil production between now and 2023. In addition, the findings indicate that the peak production date for natural gas, coal, and uranium could occur by 2050. The central question is whether oil production from non-conventional oil resources can be increased at a fast enough rate to offset declines in conventional oil production. The development of non-conventional oil production raises concerns about increased energy use, greenhouse gas emissions, and water issues. Due to the emerging fossil fuel resource constraints in coming decades, this study concludes that it is prudent to begin the development of hydrogen production and distribution systems in the near-term. The hydrogen gas is to be initially used by fuel cell vehicles, which will eliminate tailpipe greenhouse gas emissions. With a lowering of H₂ production costs through the amortization of system components, H₂ can be an economic fuel source for electricity generation post-2040.     

The pollutant discharge improvement by introducing HHO gas into biomass boiler

Biomass fuel has been widely concerned because its net CO₂ emission is close to zero. Biomass boilers are known to have lower pollutant emissions than fossil fuel boilers, but in some applications, they also release high-level CO and NO. We developed a medium-sized hydrogen and oxygen (HHO) generator, with high energy conversion rate and adjustable output gas. The HHO gas was then introduced into a biomass hot air generator for mixed combustion. The experimental results showed that based on the electricity consumption of gas production and biomass fuel price, the total cost during preheating reduced. In addition, the average concentrations of CO, NO and smoke decreased by 93.0%, 22.5% and 80%, respectively. Integration of biomass fuel and HHO gas can effectively reduce pollutant emissions and save fuel, especially in areas rich in renewable energy.     

Improving the technical, environmental and social performance of wind energy systems using biomass-based energy storage

A completely renewable baseload electricity generation system is proposed by combining wind energy, compressed air energy storage, and biomass gasification. This system can eliminate problems associated with wind intermittency and provide a source of electrical energy functionally equivalent to a large fossil or nuclear power plant. Compressed air energy storage (CAES) can be economically deployed in the Midwestern US, an area with significant low-cost wind resources. CAES systems require a combustible fuel, typically natural gas, which results in fuel price risk and greenhouse gas emissions. Replacing natural gas with synfuel derived from biomass gasification eliminates the use of fossil fuels, virtually eliminating net CO₂ emissions from the system. In addition, by deriving energy completely from farm sources, this type of system may reduce some opposition to long distance transmission lines in rural areas, which may be an obstacle to large-scale wind deployment.     

An experimental investigation on hydrogen as a dual fuel for diesel engine system with exhaust gas recirculation technique

With higher rate of depletion of the non-renewable fuels, the quest for an appropriate alternative fuel has gathered great momentum. Though diesel engines are the most trusted power sources in the transportation industry, due to stringent emission norms and rapid depletion of petroleum resources there has been a continuous effort to use alternative fuels. Hydrogen is one of the best alternatives for conventional fuels. Hydrogen has its own benefits and limitations in its use as a conventional fuel in automotive engine system.In the present investigation, hydrogen-enriched air is used as intake charge in a diesel engine adopting exhaust gas recirculation (EGR) technique with hydrogen flow rate at 20 l/min. Experiments are conducted in a single-cylinder, four-stroke, water-cooled, direct-injection diesel engine coupled to an electrical generator. Performance parameters such as specific energy consumption, brake thermal efficiency are determined and emissions such as oxides of nitrogen, hydrocarbon, carbon monoxide, particulate matter, smoke and exhaust gas temperature are measured. Usage of hydrogen in dual fuel mode with EGR technique results in lowered smoke level, particulate and NO_x emissions.     

Non-catalytic plasma-arc reforming of natural gas with carbon dioxide as the oxidizing agent for the production of synthesis gas or hydrogen

The world's energy consumption is increasing constantly due to the growing population of the world. The increasing energy consumption has a negative effect on the fossil fuel reserves of the world. Hydrogen has the potential to provide energy for all our needs by making use of fossil fuel such as natural gas and nuclear-based electricity. Hydrogen can be produced by reforming methane with carbon dioxide as the oxidizing agent. Hydrogen can be produced in a Plasma-arc reforming unit making use of the heat energy generated by a 500 MWt Pebble Bed Modular Reactor (PBMR). The reaction in the unit takes place stoichiometrically in the absence of a catalyst. Steam can be added to the feed stream together with the Carbon Dioxide, which make it possible to control the H₂/CO ratio in the synthesis gas between 1/1 and 3/1. This ratio of H₂/CO in the synthesis gas is suitable to be used as feed gas to almost any chemical and petrochemical process. To increase the hydrogen production further, the Water–Gas Shift Reaction can be applied. A techno-economic analysis was performed on the non-catalytic plasma-arc reforming process. The capital cost of the plant is estimated at $463 million for the production of 1132 million N m³/year of hydrogen. The production cost of hydrogen is in the order of $12.81 per GJ depending on the natural gas cost and the price of electricity. The purpose of this study is to demonstrate that plasma-arc reforming is competitive with SMR for synthesis gas production and to reduce CO₂ discharge at the same time.