Lauric and myristic acids eutectic mixture as phase change material for low‐temperature heating applications

Lauric acid (m.p.: 42.6°C) and myristic acid (m.p.: 52.2°C) are phase change materials (PCM) having quite high melting points which can limit their use in low‐temperature solar applications such as solar space heating and greenhouse heating. However, their melting temperatures can be tailored to appropriate value by preparing a eutectic mixture of lauric acid (LA) and myristic acid (MA). In the present study, the thermal analysis based on differential scanning calorimetry (DSC) technique shows that the mixture of 66.0 wt% LA forms a eutectic mixture having melting temperature of 34.2°C and the latent heat of fusion of 166.8 J g^?1. This study also considers the experimental establishment of thermal characteristics of the eutectic PCM in a vertical concentric pipe‐in‐pipe heat storage system. Thermal performance of the PCM was evaluated with respect to the effect of inlet temperature and mass flow rate of the heat transfer fluid on those characteristics during the heat charging and discharging processes. The DSC thermal analysis and the experimental results indicate that the LA–MA eutectic PCM can be potential material for low‐temperature solar energy storage applications in terms of its thermo‐physical and thermal characteristics. Copyright © 2005 John Wiley & Sons, Ltd.     

Numerical and experimental investigation for heat transfer in triplex concentric tube with phase change material for thermal energy storage

This paper addresses a numerical and experimental investigation of a thermal energy storage unit involving phase change process dominated by heat conduction. The thermal energy storage unit involves a triplex concentric tube with phase change material (PCM) filling in the middle channel, with hot heat transfer fluid (HHTF) flowing outer channel during charging process and cold heat transfer fluid (CHTF) flowing inner channel during discharging process. A simple numerical method according to conversation of energy, called temperature & thermal resistance iteration method has been developed for the analysis of PCM solidification and melting in the triplex concentric tube. To test the physical validity of the numerical results, an experimental apparatus has been designed and built by which the effect of the inlet temperature and the flow rate of heat transfer fluid (HTF, including HHTF and CHTF) on the thermal energy storage has been studied. Comparison between the numerical predictions and the experimental data shows good agreement. Graphical results including fluid temperature and interface of solid and liquid phase of PCM versus time and axial position, time-wise variation of energy stored/released by the system were presented and discussed.     

Numerical and experimental investigation of heat transfer in a shell and tube thermal energy storage system

A numerical and experimental investigation of phase change process dominated by heat conduction in a thermal storage unit is presented in this paper. The thermal energy storage involves a shell and tube arrangement where paraffin wax as phase change material (PCM) is filled in the shell. Water as heat transfer fluid (HTF) is passed inside the tube for both charging and discharging cycles. According to the conservation of energy, a simple numerical method called alternative iteration between thermal resistance and temperature has been developed for the analysis of heat transfer between the PCM and HTF during charging and discharging cycles. Experimental arrangement has been designed and built to examine the physical validity of the numerical results. Comparison between the numerical predictions and the experimental data shows a good agreement. A detailed parametric study is also carried out for various flow parameters and system dimensions such as different mass flow rates, inlet temperatures of HTF, tube thicknesses and radii. Numerical study reveals that the contribution of the inlet temperature of HTF has much influence than mass flow rate in terms of storage operating time and HTF outlet temperature. Tube radius is a more important parameter than thickness for better heat transfer between HTF and PCM.     

Thermal Performance of a Phase Change Material‐Based Latent Heat Thermal Storage Unit

An experimental analysis is presented to establish the thermal performance of a latent heat thermal storage (LHTS) unit. Paraffin is used as the phase change material (PCM) on the shell side of the shell and tube‐type LHTS unit while water is used as the heat transfer fluid (HTF) flowing through the inner tube. The fluid inlet temperature and the mass flow rate of HTF are varied and the temperature distribution of paraffin in the shell side is measured along the radial and axial direction during melting and solidification process. The total melting time is established for different mass flow rates and fluid inlet temperature of HTF. The motion of the solid–liquid interface of the PCM with time along axial and radial direction of the test unit is critically evaluated. The experimental results indicate that the melting front moves from top to bottom along the axial direction while the solidification front moves only in the radial direction. The total melting time of PCM increases as the mass flow rate and inlet temperature of HTF decreases. A correlation is proposed for the dimensionless melting time in terms of Reynolds number and Stefan number of HTF. © 2013 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley Online Library ( wileyonlinelibrary.com/journal/htj ). DOI 10.1002/htj.21120     

Eutectic compound (KNO3/NaNO3 : PCM) quasi‐encapsulated into SiC‐honeycomb for suppressing natural convection of melted PCM

The phase change eutectic compound, KNO₃/NaNO₃ (50/50 mol%) (phase change material (PCM)), which is used as the thermal energy storage material in the solar thermal power plant, was quasi‐encapsulated into the SiC‐honeycomb (SCH) for suppressing the natural convection occurring at the liquid state of PCM. The performance of the SCH as the material suppressing natural convection of PCM was investigated experimentally. PCM with three kinds of mixing ratios of SCH of 10%, 20%, and 30%, was prepared and packed in their respective stainless can with oil‐flowing pipe in the center, which is called thermal energy storage unit (TESU). Three units were linked together and stacked vertically by the connector at the inlet/outlet oil pipe. The time variation of temperature at the fixed positions inside the TESU in charging/discharging process and temperature gradient in the radial direction inside TESU when PCM was liquid state were investigated. It is concluded that the natural convection is suppressed by mixing the SCH with PCM up to around 30% in weight, because the PCM is quasi‐encapsulated into cell holes and porous structures of SCHs. And thus, the heat transfer of the PCM + 30%SCH composite is controlled mainly by its thermal conduction, which is also supported through comparison of simulation result with experimental one. And so, we conclude that SCH has a function as the quasi‐encapsulating material for suppressing the natural convection of PCM. Copyright © 2015 John Wiley & Sons, Ltd.     

Performance analysis on industrial refrigeration system integrated with encapsulated PCM‐based cool thermal energy storage system

Cool thermal energy storage (CTES) is an advanced energy technology that has recently attracted increasing interest for industrial refrigeration applications such as process cooling, food preservation and building air conditioning systems. An experimental investigation on the performance of an industrial refrigeration system integrated with encapsulated phase change material (PCM)‐based CTES system is carried out in the present work. In the experimental set‐up a vertical storage tank is integrated with the evaporator of the vapour compression refrigeration system. Effect of the inlet temperature of heat transfer fluid (HTF) on the temperature variation of the PCM and the HTF in the storage tank and the performance parameters namely average rate of charging, energy stored, specific energy consumption (SEC) of the chiller with and without storage system are studied in detail. The effect of porosity variation in the storage tank is also studied. A 1°C decrease in evaporator temperature results in about 3–4% increase in SEC and 1°C decrease in condensing temperature leads to 2.25–3.25% decrease in SEC. The range of HTF inlet temperature and porosity values for optimum performance is reported. Copyright © 2007 John Wiley & Sons, Ltd.     

Experimental investigation of an adsorptive thermal energy storage

A zeolite‐water adsorption module, which has been originally constructed for an adsorption heat pump, has been experimentally investigated as an adsorptive thermal energy storage unit. The adsorber/desorber heat exchanger contains 13.2 kg of zeolite 13X and is connected to an evaporator/condenser heat exchanger via a butterfly valve. The flow rate of the heat transfer fluid in the adsorber/desorber unit has been changed between 0.5 and 2.0 l min^?1, the inlet temperature to the evaporator between 10 and 40°C. It turned out that the higher the flow rate inside the adsorber/desorber unit the faster and more effective is the discharge of heat. However, at lower flow rates higher discharge temperatures are obtained. Storage capacities of 2.7 and 3.1 kWh have been measured at the evaporator inlet temperatures of 10 and 40°C, respectively, corresponding to thermal energy storage densities of 80 and 92 kWh m^?3 based on the volume of the adsorber unit. The measured maximum power density increases from 144 to 165 kWh m^?3 as the flow rate in the adsorber increases from 0.5 to 2 l min^?1. An internal insulation in form of a radiation shield around the adsorber heat exchanger is recommended to reduce the thermal losses of the adsorptive storage. Copyright © 2006 John Wiley & Sons, Ltd.     

Thermal performance enhancement of melting and solidification process of phase‐change material in triplex tube heat exchanger using longitudinal fins

Efficient application of intermittent renewable energy sources, like solar, waste heat recovery, and so forth, depends on a large extent on the thermal energy storage methods. Latent heat energy storage with the use of phase‐change material (PCM) is the most promising one because it stores large energy in the form of latent heat at a constant temperature. The current study investigates melting and solidification of PCM in the triplex tube heat exchanger (TTHX) numerically. The two‐dimensional numerical model has been developed using Ansys Fluent 16.2, which considers the effects of conduction as well as natural convection. To overcome the limitation imposed by the poor thermal conductivity of PCM, use of fins is the better solution. In the current study, longitudinal fins are used for better performance of TTHX, which increases heat‐transfer area between PCM and heat‐transfer fluid. The effects of location of fins, that is, internal, external, and combined internal‐external fins, are observed. All three configurations improve melting as well as solidification process. During the melting process, internal and combined internal‐external fins are equally efficient, in which maximum 59% to 60% reduction in melting time is achieved. For solidification, internal‐external fins combination gives maximum 58% reduction in solidification time.     

Thermal response of a packed bed of spheres containing a phase-change material

A computational model of the transient thermal response of a packed bed of spheres containing a phase-change material (PCM) is presented. A one-dimensional separate phases formulation is used to develop a numerical analysis of the dynamic response of the bed which is subject to the flow of a heat transfer fluid, for arbitrary initial conditions and inlet fluid temperature temporal variations. Phase-change models are developed for both isothermal and nonisothermal melting behaviours. Axial thermal dispersion effects are modelled, including intraparticle conduction (Biot number) effects. Regenerative thermal storage applications involve flow reversals to recover the stored energy; this aspect of operation is included in the present model. Results from the model for a commercial sized thermal storage bed for both the energy storage and recovery periods are presented. Experimental measurements of transient temperature distributions in a randomly packed bed of uniform spheres containing a PCM for a step-change in inlet air temperature are reported for a range of Reynolds number.     

Exergy‐based performance analysis of packed‐bed solar air heaters

This paper presents an experimental investigation of the thermal performance of a solar air heater having its flow channel packed with Raschig rings. The packing improves the heat transfer from the plate to the air flow underneath. The dimensions of the heater are 0.9 m wide and 1.9 m long. The aluminium‐based absorber plate was coated with ordinary black paint. The characteristic diameter of the Raschig rings, made of black polyvinyl chloride (PVC) tube, is 50 mm and the depth of the packed‐bed in flow channel is 60 mm. Energy and exergy analyses were applied for evaluating the efficiency of the packed‐bed solar air heater. The rate of heat recovered from the packed‐bed solar air heater varied between 9.3 and 151.5 W m^?2, while the rate of thermal exergy recovered from the packed‐bed solar air heater varied between 0.04 and 8.77 W m^?2 during the charging period. The net energy efficiency varied from 2.05 to 33.78%, whereas the net exergy efficiency ranged from 0.01 to 2.16%. It was found that the average daily net energy and exergy efficiencies were 17.51 and 0.91%, respectively. The energy and exergy efficiencies of the packed‐bed solar air heater increased as the outlet temperature of heat transfer fluid increased. Copyright © 2004 John Wiley & Sons, Ltd.     

Parametric analysis of space cooling systems based on night ceiling cooling with PCM‐embedded piping

A parametric analysis is conducted for space cooling systems based on cold water flowing, during the night, within regularly arranged pipes embedded in a layer of phase change material (PCM), located among the structural layers of the ceiling. The introduced PCM layer in conjunction with night cooling add to the usual ceiling cooling systems offers the advantages of low energy consumption, high cool storage capacity, operation under reduced night electricity price, smoothing of electricity consumption by eliminating daily peak loads, improved thermal comfort and elimination of ceiling dripping. Our parametric analysis is based on a transient three‐dimensional finite‐difference solution of the related heat‐transfer problem for various values of all the main system parameters. PCM phase change process is simulated by using the effective thermal capacity function, which is determined experimentally for PCM suitable for air‐conditioning applications. Our tests showed that the main parameters of the system are pipe spacing, PCM layer thickness, pipe depth within the ceiling, cooling water inlet temperature, night cooling duration and PCM properties (thermal conductivity, phase change heat and ends of phase change temperature range). The effect of all the above parameters is analysed and suggestions are made for selecting the proper combinations of their values in order to obtain the lowest energy consumption in conjunction with the highest level of thermal comfort. Copyright © 2010 John Wiley & Sons, Ltd.     

Analysis of an encapsulated phase change material‐based energy storage system for high‐temperature applications

The capability of an encapsulated phase change material (EPCM)‐based thermal energy storage (TES) system to store a large fraction of latent energy at high temperatures was examined. A 3‐dimensional simulation of a prototype heat exchanger was conducted employing sodium nitrate as the phase change material (PCM). The k‐ω SST model was used to capture the turbulent flow of the HTF, while the melting front was tracked using the enthalpy‐porosity method. The results show that the use of metal deflectors yields a nearly constant heat transfer coefficient over the capsule's surface. Despite this, the presence of the void in the capsule and natural convection within the molten PCM influenced the storage characteristics of the system affecting the shape of the isotherms and melting front. Furthermore, the EPCM capsules consecutively undergo the same heat transfer starting from the capsule closest to the inlet. The EPCM capsules store 80% of the energy lost by the HTF. The 17.7 kg of sodium nitrate stores 14.5 MJ of energy where 20% of the energy stored is via latent heat. Of the energy released by the heat transfer fluid, 80% was absorbed by the EPCM capsules with the remaining energy going into the test section walls. A total of 14.5 MJ of energy was stored by the 17.7 kg of NaNO₃, of which 20% is attributed to the latent heat. The fraction of energy stored as latent heat would be larger if a smaller operating temperature range was used. Thus, an EPCM‐based latent heat TES system is capable of storing a large fraction of the supplied energy and presents efficient means of storing thermal energy for high‐temperature applications. Additionally, the strong agreement between the numerical and experimental works demonstrates that the numerical methods employed can predict the behavior of an EPCM capsule not only within a single capsule but on the system scale as well. Therefore, the applied numerical methods can be used for further design and optimization of EPCM‐based latent heat TES systems.     

Melting of PCM in a thermal energy storage unit: Numerical investigation and effect of nanoparticle enhancement

The present paper describes the analysis of the melting process in a single vertical shell‐and‐tube latent heat thermal energy storage (LHTES), unit and it is directed at understanding the thermal performance of the system. The study is realized using a computational fluid‐dynamic (CFD) model that takes into account of the phase‐change phenomenon by means of the enthalpy method. Fluid flow is fully resolved in the liquid phase‐change material (PCM) in order to elucidate the role of natural convection. The unsteady evolution of the melting front and the velocity and temperature fields is detailed. Temperature profiles are analyzed and compared with experimental data available in the literature. Other relevant quantities are also monitored, including energy stored and heat flux exchanged between PCM and HTF. The results demonstrate that natural convection within PCM and inlet HTF temperature significantly affects the phase‐change process. Thermal enhancement through the dispersion of highly conductive nanoparticles in the base PCM is considered in the second part of the paper. Thermal behavior of the LHTES unit charged with nano‐enhanced PCM is numerically analyzed and compared with the original system configuration. Due to increase of thermal conductivity, augmented thermal performance is observed: melting time is reduced of 15% when nano‐enhanced PCM with particle volume fraction of 4% is adopted. Similar improvements of the heat transfer rate are also detected. Copyright © 2012 John Wiley & Sons, Ltd.     

Experimental and numerical study on heat transfer and flow characteristics in an alternating cross‐section flattened tube

An experimental and numerical study on convection heat transfer of water flowing through an alternating cross‐section flattened (ACF) tube are investigated in this paper. The thermal‐fluid characteristics were evaluated by numerical simulation. The test run conditions covered a mass flux of 200 to 800 kg m^?2 s^?1, a heat flux of 10 kW/m², and an inlet temperature of 40°C. The results showed that the Nusselt number increased with the increase in mass flux. Moreover, the heat transfer was also affected by the flow characteristics. Vortices were formed at the curved wall, and their intensities were increased along the flow direction. It was also found that the heat transfer and pressure drop were larger than that of the circular tube. However, the thermal performance was greater than the pressure loss penalty. The comparison results showed that the ACF tube had better performance than the circular tube. Further, the details of heat transfer, flow resistance, and fluid behavior were investigated and discussed in this study.     

Experimental investigation on a combined sensible and latent heat storage system integrated with constant/varying (solar) heat sources

The objective of the present work is to investigate experimentally the thermal behavior of a packed bed of combined sensible and latent heat thermal energy storage (TES) unit. A TES unit is designed, constructed and integrated with constant temperature bath/solar collector to study the performance of the storage unit. The TES unit contains paraffin as phase change material (PCM) filled in spherical capsules, which are packed in an insulated cylindrical storage tank. The water used as heat transfer fluid (HTF) to transfer heat from the constant temperature bath/solar collector to the TES tank also acts as sensible heat storage (SHS) material. Charging experiments are carried out at constant and varying (solar energy) inlet fluid temperatures to examine the effects of inlet fluid temperature and flow rate of HTF on the performance of the storage unit. Discharging experiments are carried out by both continuous and batchwise processes to recover the stored heat. The significance of time wise variation of HTF and PCM temperatures during charging and discharging processes is discussed in detail and the performance parameters such as instantaneous heat stored and cumulative heat stored are also studied. The performance of the present system is compared with that of the conventional SHS system. It is found from the discharging experiments that the combined storage system employing batchwise discharging of hot water from the TES tank is best suited for applications where the requirement is intermittent.     

Numerical study on thermal energy storage performance of phase change material under non-steady-state inlet boundary

Due to the solar radiation intensity variation over time, the outlet temperature or mass flow rate of heat transfer fluid (HTF) presents non-steady-state characteristics for solar collector. So, in the phase change thermal energy storage (PCTES) unit which is connected to solar collector, the phase change process occurs under the non-steady-state inlet boundary condition. In present paper, regarding the non-steady-state boundary, based on enthalpy method, a two dimensional physical and mathematical model for a shell-and-tube PCTES unit was established and the simulation code was self-developed. The effects of the non-steady-state inlet condition of HTF on the thermal performance of the PCTES unit were numerically analyzed. The results show that when the average HTF inlet temperature in an hour is fixed at a constant value, the melting time (time required for PCM completely melting) decreases with the increase of initial inlet temperature. When the initial inlet temperature increases from 30 °C to 90 °C, the melting time will decrease from 42.75 min to 20.58 min. However, the total TES capacity in an hour reduces from 338.9 kJ/kg to 211.5 kJ/kg. When the average inlet mass flow rate in an hour is fixed at a constant value, with the initial HTF inlet mass flow rate increasing, the melting time of PCM decreases. The initial inlet mass flow rate increasing from 2.0 × 10⁻⁴ kg/s to 8.0 × 10⁻⁴ kg/s will lead to the melting time decreasing from 37.42 min to 23.75 min and the TES capacity of PCM increasing from 265.8 kJ/kg to 273.8 kJ/kg. Under all the studied cases, the heat flux on the tube surface increases at first, until it reaches a maximum then it decreases over time. And the larger the initial inlet temperature or mass flow rate, the earlier the maximum value appearance and the larger the maximum value.     

Numerical analysis of latent heat thermal energy storage using encapsulated phase change material for solar thermal power plant

Thermal energy storage improves the load stability and efficiency of solar thermal power plants by reducing fluctuations and intermittency inherent to solar radiation. This paper presents a numerical study on the transient response of packed bed latent heat thermal energy storage system in removing fluctuations in the heat transfer fluid (HTF) temperature during the charging and discharging period. The packed bed consisting of spherical shaped encapsulated phase change materials (PCMs) is integrated in an organic Rankine cycle-based solar thermal power plant for electricity generation. A comprehensive numerical model is developed using flow equations for HTF and two-temperature non-equilibrium energy equation for heat transfer, coupled with enthalpy method to account for phase change in PCM. Systematic parametric studies are performed to understand the effect of mass flow rate, inlet charging system, storage system dimension and encapsulation of the shell diameter on the dynamic behaviour of the storage system. The overall effectiveness and transient temperature difference in HTF temperature in a cycle are computed for different geometrical and operational parameters to evaluate the system performance. It is found that the ability of the latent heat thermal energy storage system to store and release energy is significantly improved by increasing mass flow rate and inlet charging temperature. The transient variation in the HTF temperature can be effectively reduced by decreasing porosity.     

Modeling of the melting characteristics of commercial paraffin wax in an inverted equilateral triangular enclosure: Effect of convective heat transfer boundary conditions

A horizontal double-pipe heat exchanger with an inverted outer equilateral triangular tube is modeled to numerically investigate the low-temperature thermal energy storage capability of an impure phase change material (PCM). The energy source fluid (hot water) flows through the inner tube and transfers heat to the PCM (heat sink) residing in the annular gap. The results show that the inlet temperature of the heat transfer fluid (HTF) has a significant effect on the melting process compared with the mass flow rate (MFR). The configuration, as well the concentricity/eccentricity of the inner tube has a great influence on the energy storage.     

A study on latent heat storage exchangers with the high‐temperature phase‐change material

This paper presents a theoretical analysis and an experimental test on a shell‐and‐tube latent heat storage exchanger. The heat exchanger is used to recover high‐temperature waste heat from industrial furnaces and off‐peak electricity. It can also be integrated into a renewable energy system as an energy storage component. A mathematical model describing the unsteady freezing problem coupled with forced convection is solved numerically to predict the performance of the heat exchanger. It provides the basis for an optimum design of the heat exchanger. The experimental study on the heat exchanger is carried out under various operating conditions. Effects of various parameters, such as the inlet temperature, the mass flow rate, the thickness of the phase‐change material and the length of the pipes, on the heat transfer performance of the unit are discussed combined with theoretical prediction. The criterion for analyzing and evaluating the performance of heat exchanger is also proposed. Copyright © 2001 John Wiley & Sons, Ltd.     

A comparative study on the performances of different shell-and-tube type latent heat thermal energy storage units including the effects of natural convection

Numerical modeling was performed to simulate the melting process of a fixed volume/mass phase-change material (PCM) in different shell-and-tube type latent thermal energy storage units with identical heat transfer area. The effect of liquid PCM natural convection (NC) on the latent heat storage performance of the pipe and cylinder models was investigated using a 3D numerical model with FLUENT software. Result shows that NC can cause a non-uniform distribution of the solid–liquid interface, which accelerates PCM melting rate. The PCM melting rate and heat storage rate in the horizontal cylinder model are higher than those in the horizontal pipe model because of the combined effects of heat conduction and NC. A comparative study was conducted to determine the effects of horizontal and vertical shell-and-tube models with different heat transfer fluid (HTF) inlets including the effects of NC. The results indicate that the vertical model with an HTF inlet at the bottom exhibits the highest PCM melting rate and heat storage rate for the pipe models. For the cylinder models, the horizontal model and the vertical model with an HTF inlet at the bottom can achieve nearly the same completed melting time. In addition, NC has minimal effect on any model with an HTF inlet at the top.