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用复合乳化剂(Span 80/OP-10)制备了稳定的丙烯酰胺(AM)反相微乳液,研究了温度、复合乳化剂的配比及浓度对单体增溶量的影响,并通过紫外分光光度计、乌氏黏度计等对微乳液体系的微观结构和特征进行了分析和表征. 相似文献
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以CTAB/正丁醇/正庚烷/NH.3H2O和CTAB/正丁醇/正庚烷/TiCl4反相双微乳液方式制备纳米TiO2,且采用SEM和FI-IR等分析手段对纳米TiO2的粒径、物相等方面进行分析。结果表明,在CTAB6.83g,正丁醇8.54mL,正庚烷30mL,2.4mo.lL-1的NH.3H2O6mL,0.6mo.lL-1的TiCl43mL的条件下,可以制备纳米TiO2。 相似文献
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反相微乳液法制备糊精纳米微球 总被引:1,自引:0,他引:1
以正己烷为油相,去离子水为水相,Span 60和Tween 60为表面活性剂,正戊醇为助表面活性剂配制微乳液,对影响微乳液特性的各因素做了分析。并以糊精为原料,三偏磷酸钠为交联剂,制备糊精纳米微球。结果表明,在微乳液体系中,表面活性剂的量与体系溶水能力在一定范围内正向相关,而助表面活性剂正戊醇对溶水能力则具有逆向作用。红外光谱测试证实糊精与三偏磷酸钠发生交联,经扫描电镜观察,糊精微粒纳米形态均一,粒径在500~600 nm之间。 相似文献
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螺旋霉素的油/水界面循环伏安法测定韩玉洁,杨文友,徐忠CYCLICVOLTAMETRYDETERMINATIONOFSPANMYCINATWATERLOILINTERFACES1前言油/水界面循环伏安法是近年来发展起来的一种新的电化学分析方法。并且已... 相似文献
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以次亚磷酸钠还原剂,采用反相微乳液法制备纳米银粉;并借助TEM、X射线衍射和粒度分析仪研究了反应温度、水和表面活性剂的摩尔比、Ag+浓度和助表面活性剂对纳米银粉的粒径大小的影响。结果表明:随着水和表面活性剂的摩尔比的增加,纳米银粉的粒径尺寸随之变大;随着银离子浓度的增大,纳米银粉的粒径变小,当银离子浓度超过0.1 mol/L时,纳米银粒子出现团聚明显的现象,且粒径大小分布范围变大;随着助表面活性剂用量的增加,纳米银粉的粒径先降低,当正己醇的用量超过0.2 mol时,粒径大小反而缓慢增大;反应温度不太高时(20℃,40℃),纳米银粉的粒径分布大致都在20~40 nm之内,当温度高于60℃时,纳米银粉粒径分布不均匀且形状不规则,且出现明显的团聚现象。适宜工艺为:温度为40℃,水和表面活性剂的摩尔比ω=1,Ag+浓度为0.1 mol/L,助表面活性剂(正己醇)的用量为0.2 mol;制备的纳米银粉为面心立方晶系纯相银、分散性好、规则球形形状、粒径分布均匀、平均粒径为22 nm。 相似文献
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The application of cyclic voltammetry to the evaluation of the platinum content of carbon-supported platinum catalysts was investigated. The results were compared to those obtained by INAA and FAAS. A good linear relationship between the hydrogen deposition charge and platinum loading in the catalyst was found for platinum of different particle size. This method has the advantage of being readily available in many laboratories in addition to providing the real surface area of the metal at the same time. 相似文献
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In this work, electropolymerization of sulfonated phenol were performed by cyclic voltammetry (CV) on planar or nano‐architecture substrates. The corresponding CV curves were analyzed and compared. The obtained polymer was characterized by SEM, EDX, and FTIR. The results suggested that it was feasible to electropolymerize sulfonated phenol on different substrates. The facility of electropolymerization on different substrates was as follows: graphite carbon > stainless steel plate > ZrO2 nanotube. The peak current density of CV curve on stainless steel kept constant from the second cycle possibly attributed to the promoting effects of sulfonic acid groups: improving the ionic conductivity, changing the packing mode of polymer chains, and enhancing the permeability of the film to monomers. This work offered some insights into electrochemical synthesis of proton‐conducting membrane for varied special applications, such as micro‐sized fuel cell, sensor, battery, and other solid‐state ionic devices. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
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SUMMARY The polymer-metal ion interactions were studied by cyclic voltammetry. These were carried out with poly(acrylic acid)-Cu(II) and poly(vinylsulfonic acid)-Cu(II) systems at different pH. At low pH, the polymer was adsorbed on the electrode surface increasing the irreversibility of the Cu2+/Cu(s) redox system. At pH 2.7, it was possible to demonstrate that the interaction between Cu(II) and poly(vinylsulfonic acid) is basically electrostatic and with poly(acrylic acid) a complex formation also exists. Received: 5 April 2000/Accepted: 16 August 2000 相似文献
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Y.A. Yaraliyev 《Electrochimica acta》1984,29(9):1213-1214
From chronovoltammetric and cyclovoltammetric polarization curves three mechanisms of iodide ions have been established: 3I? = I?3 + 2e,2I?3 = 3I2 + 2e and 2I? = I2 + 2e under certain conditions of scan rate, concentration of iodide ions and area of electrode in the aqueous solutions KI (background solution 1 N Na2SO4) with half-wave potentials of 0.428, 0.489 and 0.507 V by silver/silver chloride electrode. 相似文献
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通过Span80-Tween80/异辛烷/FM(4-甲氧基-N-(2-N′,N′-二甲基氨基乙基)萘二甲酰亚胺烯丙基氯化铵)-AM(丙烯酰胺)-H2O反相微乳液聚合,制备了AM和FM的荧光高分子聚合物(F-PAM).采用透射电镜(TEM)、原子力显微镜(AFM)、激光纳米粒度仪、荧光分光光度计等测试手段,测定了荧光高分子聚合物(F-PAM)的粒子形态、粒径和粒径分布等微观结构及其荧光性能.试验结果表明:所制备的F-PAM为单分散、球形的纳米材料,平均粒径(D)在60~145 nm之间;F-PAM的激发波长和发射波长分别为381 nm和462 nm.F-PAM激发光谱与发射光谱呈较好的镜像对称关系;F-PAM的相对荧光强度随着其质量浓度的增加而增加,且F-PAM的浓度与其荧光强度呈很好的线性关系,其线性相关系数(R)为0.9953,F-PAM的检测下限为1.83 mg·L-1. 相似文献
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A semi-analytical method of modelling cyclic voltammetry is described, derived, exemplified, verified, and advocated. A listing of the mechanistic schemes that can be addressed by the procedure includes E, EE, CE, EC and ECE, all with various degrees of reversibility. The approach has advantages and disadvantages when compared with digital simulation. 相似文献
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采用反相(W/O)微乳液法制备负载型Pt基催化剂,以间氯硝基苯(m-CNB)选择加氢反应为探针,考察微乳液组成、助表面活性剂和油相种类、还原剂用量及载体种类等制备参数对催化剂活性的影响,并对Pt粒子及催化剂进行TEM表征。结果表明:选择十六烷基三甲基溴化胺(CTAB)/正丁醇/环己烷/H2PtCl6溶液的W/O微乳体系,m(CTAB)∶m(正丁醇)=3∶7,m(CTAB+正丁醇)∶m(环己烷)=3∶7,H2PtCl6溶液含量3.6%,N2H4·H2O用量100 μL时制备的Pt/γ-Al2O3催化剂对m-CNB选择加氢活性最高。TEM分析表明催化剂中Pt粒子均匀分散在载体上。 相似文献