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从含铜蚀刻废液中回收硫酸铜 总被引:8,自引:1,他引:8
采用酸性蚀刻液与碱性蚀刻液混合中和沉淀铜的方法生产硫酸铜。试验结果表明,最佳工艺条件为:中和反应pH=6~7,酸解反应每100g滤渣消耗95%(质量分数)硫酸30mL,硫酸铜产率为84%,纯度为96%。混合沉淀铜后滤液中仍含有大量的氯化铵和少量的二价铜离子,实验采用水合肼还原除铜,回收滤液用于配制新的蚀刻液。水合肼还原除铜工艺条件:pH为8,滤液与水合肼体积之比为100:3,二价铜离子的去除率达到96.8%。该工艺简单可行,操作方便,成本低,是一种处理印制电路板(PCB)企业蚀刻废水、回收铜的有效方法,有一定的应用价值。 相似文献
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选用LIX-54作为萃取剂从印制板蚀刻废液中回收铜.探讨了萃取系统的一些条件.对含Cu107.39g/L和NH3128.4g/L的蚀刻液,经3级萃取即可达到含Cu约30g/L,并基本不萃氨,萃余液可返回蚀刻液.实验还考察了萃取剂的降解性能. 相似文献
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采用萃取剂N910为萃取剂,磺化煤油为稀释剂,研究了从碱性蚀刻废液中萃取回收铜的单级及多级萃取工艺。结果表明,在Cu2+含量为112 g/L,总氨浓度为5.7 mol/L的蚀刻废液中,单级萃取优化的工艺条件为:N910体积浓度为60%,有机相和水相的相比O/A=2∶1,T=30℃。碱性蚀刻液不需进行酸碱度的调整,萃取时间为3 min即可达到平衡,Cu2+的萃取率为56.73%,N910萃取Cu2+的饱和萃取量为64.03 g/L。萃取热效应△H=8.95 kJ/mol,萃取过程为吸热反应。在此条件下,PCB碱性蚀刻液中Cu2+的四级错流和三级逆流萃取率分别为94.78%和76.01%,蚀刻液中Cu2+浓度降低至37.98 g/L。 相似文献
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文章主要论述一种新型酸性蚀刻废液处理方法,在特制石墨蒸酸釜内加入定量的酸性蚀刻废液及98%硫酸,在蒸汽不断加热下使得反应液内部氯化氢气体不断逸出,通过冷凝回收盐酸,同时所得粗品硫酸铜通过重结晶除杂的方法得到高品味的电镀级硫酸铜。该处理工艺全过程无废水产生,回收盐酸回用于蚀刻液的配制,达到了资源回收利用之目的,所得铜产品提升了其附加值,是当前所有处置工艺中最环保的处理方法之一。 相似文献
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为实现对印刷线路板生产领域高浓度蚀刻废液的高效处理,建立了“膜吸收+Na2S破络+PAC混凝沉淀”工艺,考察其对实际高氨氮蚀刻废液的脱氨除铜效能,并优化了工艺条件。通过单因素实验探究了料液pH和流速、吸收液浓度和流速、膜组件级数与温度等因素对NH4+-N去除率、传质系数和过膜通量的影响,并确定了最佳运行参数:料液pH=10.5、流速3.6 cm/s,吸收液浓度2.0 mol/L、流速1.1 cm/s,膜组件级数为18级,温度为40℃。在该最佳运行条件下,蚀刻废液NH4+-N可由82 000 mg/L降至100 mg/L左右,去除率保持在99.8%以上,膜传质系数为3.38×10-6 m/s,过膜通量为40.7 mg/(m2·s)。同时对Na2S破络及混凝沉淀工艺条件进行了优化,以n(S2-)/n(Cu2+)=1.4投加Na2S... 相似文献
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由高铁低锌萃铟废水制备锌精矿和铁红 总被引:1,自引:0,他引:1
控制pH值,对高铁低锌萃铟废水加入硫精矿直接制备锌精矿和铁红进行了研究. 分析了反应机理,考察了不同硫化物对锌的回收效果,探讨了超声波辅助硫精矿制备锌精矿和高纯铁红的工艺条件,并利用SEM对锌精矿粒度和形貌进行表征. 在萃铟废水中含铁60.47 g/L、锌28.65 g/L时,在常温下调节pH值为2,加入-0.074 mm硫精矿,超声处理50 min的实验条件下,制得了含锌50.36%的锌精矿产品,锌回收率达95.29%,锌含量和回收率分别比未经超声处理提高了18.52%和23.67%. 制得的高纯铁红符合国家SJ/T10383-93标准一等品的要求,铁回收率为92%. 相似文献
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《分离科学与技术》2012,47(5):983-991
Abstract An extraction system for the recovery of boric acid using 2-butyl-2-ethyl-1,3-propanediol (BEPD) as an extractant was studied. Loss of the extractant to the aqueous solution was lowered by using 2-ethylhexanol as a diluent. The extraction equilibrium of boric acid with BEPD was clarified, and the equilibrium constants for various diluents were determined. Furthermore, continuous operation for the recovery of boric acid using mixer-settlers for extraction and stripping was successfully conducted during 100 hours. 相似文献
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The solvent extraction technology was applied to recover Cu2+ and Ni2+ from plating wastewater. Lix984N was chosen as the extractant due to its good extraction performance. The influence parameters were examined. The results show that the separation of Cu2+ and Ni2+ from sulphate medium can be realized by adjusting pH value with the help of Lix984N. For extracting Cu2+ and Ni2+, the optimal pH values are 4 and 10.5, and the maximal extraction percentages are 92.9% and 93.0%, respectively. With recovered Cu2... 相似文献
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为回收废弃LCD面板中的金属铟及高品质玻璃,提出了一种铟锡氧化物(ITO)玻璃资源化回收方法,用HF溶液浸蚀ITO玻璃碎片得富铟溶液和经表面除杂的玻璃基板,富铟溶液经蒸发、浓缩得富铟物,将富铟物溶解并经铝置换、熔炼、提纯得到粗铟,玻璃基板作为配合料进行再生制样. 结果表明,ITO玻璃破碎会造成铟流失,8 mol/L HF在3 h内即可有效回收ITO中的铟,制得纯度达92.3%的粗铟,回收率达89.2%. 再生玻璃试样成型温度为1462℃,热膨胀系数最大为3.2′10-6/℃,维氏硬度平均值为584.9,密度为2.43097 g/cm3,可见光透射比为75.2,部分性能有所下降,可降低配合料用量,以实现ITO玻璃基板的资源化回收. 相似文献
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《分离科学与技术》2012,47(10):2347-2360
Abstract The study on chemical extraction and stripping for the recovery of fumaric acid from low concentration organic acid wastewater has been carried out. The parameters influencing the extraction efficiency were investigated, including extractant concentration, the initial pH, the volume ratio of water to oil (W/O), the extraction temperature, and the concentration of n‐octanol. The heat effect of the extraction process, the formation of acid‐amine complexes, and the corresponding equilibrium constant were determined. In the optimum condition that kerosene/N7301/n‐octanol was 2:2:1, pH was 0.5, W/O was 1:1, and the temperature was 303K, through chemical extraction and stripping, the CODcr value of fumaric acid wastewater decreased from 71040 mg/l to 8411 mg/l, and the overall CODcr removal rate reached 88.16%, and the extraction efficiency of fumaric acid was 70.67%. The extractant was regenerated by a stripping process with 2% NaOH, and the stripping rate almost arrived at 100%. The regenerated extractant was cycled seven times without decreasing extraction efficiency and the stripping rate. And fumaric acid was obtained by adjusting the pH of the salt from stripping. After extraction, the fumaric acid wastewater can be further treated by oxidation or biodegradation to environmentally acceptable levels. 相似文献
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针对本单位采用大孔树脂吸附处理邻甲苯胺废水效果不尽理想的情况,采用邻硝基甲苯作为萃取剂,对吸附进水进行萃取预处理。萃取相直接送还原系统加氢还原生产邻甲苯胺,萃余相送大孔树脂吸附,可以使出水水质稳定,满足排放要求。 相似文献
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以萃取回收甲苯法生产己内酰胺废液中的己内酰胺为目的,选择氯仿作萃取剂,进行了萃取回收己内酰胺的研究。考察了原料液的pH、萃取温度、萃取时间等因素对氯仿萃取己内酰胺过程的影响。结果表明,在酸性条件下该萃取过程分配比随pH的升高而增大,当pH=7时分配比最大;萃取过程为快速过程,20 min即可达到萃取平衡;水相中硫酸铵和1-磺酸基环己烷羧酸对萃取过程有盐析效应,使分配比增大;萃取过程受温度影响不大,焓变值ΔH=2.86 kJ/mol。实验确定了pH=7时己内酰胺在有机相与水相中的分配平衡关系,当有机相和水相体积比为1时,三级错流萃取的萃取率可达到98%以上。同时,进行了工业废水的萃取验证实验,结果表明,氯仿对废水中己内酰胺的萃取效果良好。 相似文献