DRYING KINETICS OF A MULTICOMPONENT MIXTURE OF ORGANIC SOLVENTS

Drying kinetics of volatile organic solvents have been examined during the drying process of a pharmaceutical coating containing a multicomponent mixture of ethyl acetate, n-heptane, propanol-2, and toluene. A complete set of experiments was performed in two drying apparatuses, a laboratory air-dryer and an oven dryer, for a wide range of drying temperature, air velocity, initial coating thickness and drying time. An empirical kinetic model is used to predict the concentration of each organic solvent in the mixture during the drying process. The results show that both drying conditions and sample characteristics affect significantly the drying rate of solvents.     

PEEL ADHESION PROPERTIES OF AIR-DRIED PHARMACEUTICAL PRESSURE SENSITIVE ADHESIVE

ABSTRACT

The performance of a pharmaceutical pressure sensitive adhesive, whose liquid formulation is based on a multicomponent mixture of solvents, has been examined during two peel adhesion types of tests (90° dynamic adhesive strength peel test and 180° release liner peel test). The experiments were carried out under various drying temperatures, initial coating thickness, and types of backing film and release liner. The results show that the peel force depends mainly on the dry film weight of the tested adhesive. The type of the backing film which is used to form the adhesive also affects its peel adhesion properties.     

STABILITY OF THE DYNAMICAL SYSTEM DESCRIBING ISOTHERMAL GAS-PHASE-CONTROLLED DRYING OF TERNARY MIXTURES

ABSTRACT

A stability analysis of the ordinary differential equations describing the process of convective gas-phase-controlled evaporation during drying of ternary mixtures was performed. The case considered was that of a gas flowing parallel to the surface of a flat solid, wetted with a liquid mixture, during drying at constant gas conditions. If evaporation is isothermal, the solutions of a system of ODEs are the trajectories in the phase plane represented by a triangular diagram of compositions. Analysis of the ternary mixture showed that the predicted ternary dynamic azeotropes were unstable nodes and composition trajectories moved away from them. On the other hand, some of the binary azeotropes could be stable nodes. Nodes represented by pure components could be either stable or unstable. Loading the gas with one of the components might give rise to additional critical points and might reverse or change the stability of the previous ones. The present stability analysis permits the prediction of the trajectories and final state in a gas-phase-controlled drying process. It is of great importance due to the critical influence of the composition of the remaining moisture on the quality and properties of the final product.     

R&D Needs in the Drying of Coatings

ABSTRACT

The key technologies involved in the drying of coatings are first reviewed and then the factors that influence the drying process are identified, leading to a discussion uf future R&D needs. The drying mechanisms in the constant and falling rate periods are discussed. Present and nticipated estrictions on the use of solvents will result in aqueous systems replacing some solvent systems. and in wider use of high solids coatings and 100% solids coatings. Cross-linking reactions to solidify monomers and low-molecular polymers now become important. Dryers will become chemical reactors. Further development of models of drying, of diffusion, of surface solvent levels, and of solvent vapor pressures will be needed, along with those of dryer defects and drying stresses. To accurately simulate a wide range of coating systems more physical property data is needed. Nan-convection heating and environmental concerns complete the discussion.     

FLUID1ZED BED SPRAY GRANULATION AND FILM COATING A NEW METHOD FOR THE INVESTIGATION OF THE COATING PROCESS ON A SINGLE SPHERE

ABSTRACT

The coating and granulation of solid particles in a fluidized bed is a process which converts pumpable and atomizable liquids (solutions, slurries, melts) into granular solids in one step through drying. Although this process has been applied in industry for several years, there is still a lack of understanding the physical fundamentals and the mechanisms by which spherical granules are formed. Hence a new method was developed which allows the direct observation of the subsequent particle-forming mechanisms such as droplet deposition, spreading, wetting and drying. The authors will present a laboratory scale apparatus in which a single freely suspended particle can be coated under well defined and constant coating and drying conditions. With this device, particle-growth-rate and the development of particle morphology were measured and investigated under various experimental conditions.     

THE RELEASE OF MONOTERPENES DURING CONVECTIVE DRYING OF WOOD CHIPS

ABSTRACT

The release of volatile organic components (VOC) during high temperature convective drying of wood chips was studied experimentally and theoretically. The drying medium was superheated steam with a pressure of two bar. Two different temperature levels of the drying medium, 160 and 180 °C, and two different materials, Scots Pine and Norway Spruce, were investigated. It was found that the main components released consist of various types of monoterpenes, with α-pinene dominating in each of the two materials. The amount released is dependent on the drying temperature as well as the time of the drying process.

In order to describe the release rate of monoterpenes during drying, two separate models, called the communicating and the non-communicating model respectively, were developed. The mechanisms included for the transport of monoterpenes are, in the communicating model, transport by diffusion and with the advective gas and liquid flow within the tracheids and, in the non-communicating model, diffusion within the resin canal system.

The results obtained using the communicating model largely overpredict the experimental results. To avoid this rapid release, additional mass transfer resistance for the transport of monoterpenes between the two canal systems could be introduced. The non-communicating model was found to be useful in explaining the release rate when drying spruce. This model, however, can not distinguish between the two temperature levels studied.     

HEAT AND MASS TRANSFER DURING DRYING OF A LIQUID FILM FROM THE SURFACE OF A SINGLE INERT PARTICLE

ABSTRACT

This paper presents the results of theoretical and experimental studies on drying of aqueous suspensions of finely dispersed solids sprayed over the surface of an inert ceramic sphere. The effects of temperature and air velocity on kinetics of heat and mass transfer as well as peeling off the layer of a dry material from the sphere surface are described. The mathematical model of a drying process based on simplified ?gradientless? approach to transfer phenomena is proposed. The adequacy of the model developed for drying of the wet coat from a single sphere to the real drying process taking place in a bed of particulate carrier is confirmed by results of drying of several organic dyestuffs in an industrial spouted bed dryer with inert particles.     

OPTIMIZATION OF SINGLE-ZONE DRYING OF POLYMER SOLUTION COATINGS TO AVOID BLISTER DEFECTS

ABSTRACT

The optimal conditions for drying polymer-solvent coatings result from a trade-off between minimizing the residual solvent level and creating defects. Blistering defects can be caused by boiling the solvent within the coating. In this paper, we use a detailed drying model with automated constrained optimization to find optimal drying conditions for prototypical coatings that minimize the residual solvent without blistering the coating. The drying oven is assumed to have a single zone with fixed residence time. The optimal drying conditions include the oven air temperature and substrate-side and coating-side heat transfer coefficients The latter are constrained to physically reasonable values. According to our results, the optimal coating-side heat transfer coefficient is always equal to or greater than the optimal substrate-side heat transfer coefficient.     

STUDY AND MODELLING OF COATED CAR PAINTING FILM BY INFRARED OR CONVECTIVE DRYING

Abstract

In this study, we described and modelled some coupled material transformations with heat and mass transfer phenomena which occur during the convective or the infrared drying of coated films of model car paintings. For these very complex reactive systems -highly shrinking, hygroscopic, semi-transparent (infrared)- the vaporization process is coupled with the polymerization reaction itself which determines significantly the material properties of the dry paint coating. Three model systems (paint + support) were successively defined and investigated by association of five supports of different radiative or adhesive properties -polish aluminium, blackened aluminium, glass, galvanized iron and composite plastic (SMC)- with three model paintings : epoxy-amine system, polyurethane system and polyvinylalcohol (PVA). Two laboratory combined dryers (convective or infrared) were set up in order to control and regulate precisely the main process parameters: aerothermic conditions (temperature and velocity), spectrum (NIR or MIR) and flux density of infrared radiation.

Firstly, the kinetics of the polymerization were followed all along the process by three different techniques : DSC (Differential Scanning Calorimetry), SEC (Size Exclusion Chromatography), FT-ERS (FOURIER Transform Infrared Spectroscopy). The glass transition temperature of the material during the drying process was deduced from DSC data with the fractional conversion of the monomer. These two parameters were well correlated by the DI BENEDETTO'S relationship, thus defining some characteristic curve of the painting system. Drying curves -temperature profiles and drying rates- were determined for PVA systems for many operating conditions, principally infrared flux density, spectra type or air velocity. The two main coating properties necessary for the modeling were deduced from drying experiments 1: the mean radiative absorptivity as a function of the mean moisture content, 2: the water apparent mass diffusivity as a function of the temperature and of the local moisture content. A diffusive model - written with a mobile frame of coordinates (lagrangian coordinates)- associated with an overall heat balance of the support + coating system, has proved capable of predecting very well the drying curves and the temperatures profiles So, this whole set of results -associated with other material properties (rheological, adhesive, color, etc ?)- will be useful to rationally optimize the industrial dryers operating in the car manufactories.     

TWO-SIDED DRYING OF COATINGS ON POROUS WEBS

ABSTRACT

A relatively simple spreadsheet-based model of the drying of coated webs has been extended to cover coatings on porous webs Two cases have been modeled. In one the coating is assumed to fully saturate the porous web, with the drying being completely symmetrical about the center plane except for differences in the air velocities and temperatures. The drying rate in the constant rate period is then increased, but because of the greater thickness that the coating now occupies, diffusion is much slower and the falling rate drying can be slower, even though it takes place on both sides. In the other case the coating is assumed to lie on top of the porous web, with solvent vapor diffusing through the web. Here the constant rate drying is only slightly faster than in the base case, but in the falling rate period the drying can be greatly accelerated Both models predict the temperatures and solvent levels throughout the length of the dryer.     

PEEL ADHESION PROPERTIES OF AIR-DRIED PHARMACEUTICAL PRESSURE SENSITIVE ADHESIVE

The performance of a pharmaceutical pressure sensitive adhesive, whose liquid formulation is based on a multicomponent mixture of solvents, has been examined during two peel adhesion types of tests (90° dynamic adhesive strength peel test and 180° release liner peel test). The experiments were carried out under various drying temperatures, initial coating thickness, and types of backing film and release liner. The results show that the peel force depends mainly on the dry film weight of the tested adhesive. The type of the backing film which is used to form the adhesive also affects its peel adhesion properties.     

STRUCTURE FORMATION OF COATED FILMS WITH DISPERSED PIGMENTS DURING DRYING

ABSTRACT

In the drying of coated films with dispersed pigments, such as floppy disks, the structure of the film is formed during the drying process and depends on the drying condition. It is important to understand the structure formation during drying for the design of the dryer and die better quality of the product. We measured die drying characteristics of the film and determined the structure of dried film experimentally. A qualitative model for the structure formation during drying of the coated film is suggested.     

SOME THEORETICAL AND EXPERIMENTAL CONSIDERATIONS ON THE THIN-LAYER DRYING OF FISH CRACKERS: PRODUCT EXPANSION ASSESSMENT

ABSTRACT

Fish crackers are semi-prepared starch-based products which must be expanded just prior to consumption. This work aims at the experimental and theoretical study of the thin-layer drying process of fish crackers in a thin disc geometry. The process was carried out in an insulated cabinet dryer and the experimental kinetic drying data were fitted using the analytical solutions resulting from both a drying model governed by the Fick' s second law and a model based on the lumped system, highlighting the adequacy of each of them. Therefore, it was possible to calculate the mass transfer coefficients for seven different blends offish crackers. Also, the effect of the drying time on the bulk density of the puffed product was evaluated for these seven blends. Both the kinetic drying parameters and the optimal bulk density responses were analyzed using the Simplex-Lattice Design over a mixture triangle within a minimal number of experiments.     

Three-Layer Model for Drying of Coating Applied on Silicone-Coated Paper

Abstract

Upon application of water based coating onto silicone-coated paper and during the subsequent drying process, the water permeates through the silicone layer into the paper substrate. At the same time, water evaporates from both the surface of the coated layer and throughout the paper layer. Initially, the evaporation rate from the wet coating surface may be dominant, but at longer times the bulk evaporation from the paper can dominate. Here a three-layer diffusion model for such a system is developed. Solutions obtained by Galerkin's method with finite element basis functions show that the hygroscopic nature of the paper leads to low drying rates at low moisture contents. Further, the model predicts that initially the coating dries to a moderately low residual moisture concentration faster than a coating applied on an impermeable substrate. However, at longer times, the predicted residual moisture of coatings applied on silicon-coated paper is higher than for a coating applied on an impermeable substrate.     

AN ANALYTICAL SOLUTION OF THE GRANULAR PRODUCT IN DEEP-BED FALLING RATE DRYING PROCESS

Abstract

According to analysis of drying characteristics of granular product, the paper describes analytical solutions on a single grain with two falling rale drying stages during corresponding period of deep-bed drying process. Changes of drying and physical parameters and their correlation were discussed. A mathematical model was developed and solved numerically. The application of this analytical solution is also given.     

NUMERICAL SIMULATION OF DRYING IN A CYCLONE

ABSTRACT

This work presents a complete improved mathematical model of drying in cyclone. The slip condition of the particles on the wall, the heat transfer wall-panicle and the shrinkage of the panicles during the drying process were considered. The mathematical model considers a two-dimensional turbulent gas-particle flow where the panicle phase is treated as a continuum. The momentum equations of both particle and gas phases were written in cylindrical coordinates. The discretized equations were solved by the SIMPLE algorithm. Considering the slip condition to the panicle phase and the shrinkage of the material during the drying process it was revealed a better fitness between numerical and experimental results than the previous model.     

THE INFLUENCE OF AIR TEMPERATURE ON EFFECTIVE DIFFUSION COEFFICIENT OF MOISTURE IN THE FALLING RATE PERIOD

ABSTRACT

The convection drying of spheres of Al-Ni catalyst and thin clay plate was investigated on a laboratory scale. The aim of the investigation was to determine the mechanism of moisture transfer within the firm sample skeleton.

By measuring the mass loss and the surface temperature of the samples during the drying process, basic dependencies necessary to describe the process kinetics was obtained. Found functional dependencies show high level of correlation with experimental data. Exponential model parameters are dependent of air temperature and velocity, and the type of the examined material.

The applicability of the chosen model to describe the drying kinetics is proven regardless of drying material origin and geometry, The comparison of different drying experiment and determination of the average diffusional coefficient at given experimental conditions is enabled.     

OVERVIEW AND SYSTEM ANALYSIS OF VARIOUS SEWAGE SLUDGE DRYING PROCESSES

ABSTRACT

An incineration process is routinely used in Japan to treat nearly all the generated sewage sludge. The drying process now is recognized to play an important role as a pretreatment process of a incineration process.

This paper provides a brief introduction to the conventionally utilized drying methods/equipment (i.e, hot gas drying, fluidized bed drying, pneumatic conveyor drying, and steam drying( for treating dewatered sludge cakes.     

Extraction and Liquid Membrane Preconcentration of Rosmarinic Acid from Lemon Balm (Melissa Officinalis L.)

Abstract

Liquid membrane separation technique was applied for the recovery and preconcentration of rosmarinic acid from aqueous extract of dried leaves of Balm lemon (Melissa officinalis L.). Among several studied organic solvents, diisopropyl ether and ethylacetate appeared to be appropriate membrane liquids for recovery and selective preconcentration of the acid. The difference in pH values between the two aqueous solutions was the driving force in this case. An integrated process coupling the extraction of rosmarinic acid from ground Melissa leaves with a simultaneous stripping of membrane and accumulation of the extracted solute was demonstrated using a laboratory bulk liquid membrane contactor. The process provided an almost complete (96 percent) exhaustion of the herbal mass and highly enriched final extract, containing 87 percent RA after strip solution drying.