Simulation of Drying on the Basis of Nonequilibrium Thermodynamics of Beterogeneous Multiphase Polydispersed Systems.Formation of the Morphological Structure of Emulsive Elastomers Using Method of Spray - Drying for Latexes

The process and the technology of fine - dispersed rubber powder production on the basts of spray - drying for latexes were considered. The practical recommendations on usage of physical modification method for elastomers on the basis of interaction mechanism between solid -phase dispersed filler and polymeric panicles were given.

The mathematical model for latex drops during drying in the presence of structured adsorptive layer of surface active substances on the surface of drops was worked out, that allowed us to give the recommendations for production of monolithic particles.     

Food Drying and Dewatering

ABSTRACT

Food drying and dewatering raises a growing interest because of increasing requirements in quality, specially in the production of ingredients and additives for food formulation. Heat and mass transfers, as well as mechanical phenomena and reactions kinetics induced by these transfers must be more and more carefully controlled during drying and storage.

This chapter relates recent advances in

- drying of solids

- spray-drying

- drum-dryine

- superheateded steam drying

- osmotice dehydration

- hot oil immersion drying     

The Effect of Particle Size on the Drying of Milled Peat

ABSTRACT

Milled peat production involves the atmospheric drying of a 20-30mm deep layer of milled peat (i.e. peat in a powder or crumb form) on the surface of the bog. Research from various sources indicates that the drying of rate of this layer is highly dependent upon its particle size distribution. Experiments were conducted to confirm this phenomenon for Irish peats.

A drying chamber was constructed that enabled both climatic and material variables to be controlled. Three peat types were evaluated (viz. low (150 g/l), medium (240 g/l), and high (330 g/l) bulk density peats)for three particle size distributions (i.e. small (2.0-5.6 mm), medium (5.6-9.5 mm) and large (9.5-16mm)) diameter particles.

Results showed that large diameter particles (viz 9.5-16 mm) dry some 10-25 % faster than smaller particles.     

Effects of Surface Concentration on Drying Behavior of Carbohydrate Solutions

ABSTRACT

As the surface properties of the drying materials are very important not only for the drying rate but also for the quality change during drying, the effects of surface concentration on the drying behavior of liquid foods (sugar solutions) were investigated by isothermal drying experiments and by numerical calculation experiments. The isothermal drying experiments with gelled sugar solution systems (sucrose and maltodextrin) were carried out at various relative humidity (RH) values (RH = 0 to 84%). Separate experiments were carried out for determination of the desorption isotherms.

The isothermal drying curves of sugar solutions at RH = 0 to 51% were very similar. Numerical simulations also showed that the drying curves of these sugars at the surface concentration = 0 and 0.1 are almost the same, although the concentration distributions are different.

When a small amount of gelatin was added to sugar solutions, the drying rate decreased remarkably as the gelatin might form a thin film (skin) near the surface, and consequently the retention of ethanol increased.     

Surface Stickiness of Drops of Carbohydrate and Organic Acid Solutions During Convective Drying: Experiments and Modeling

Abstract

Drying kinetics of low molecular weight sugars such as fructose, glucose, sucrose and organic acid such as citric acid and high molecular weight carbohydrate such as maltodextrin (DE 6) were determined experimentally using single drop drying experiments as well as predicted numerically by solving the mass and heat transfer equations. The predicted moisture and temperature histories agreed with the experimental ones within 6% average relative (absolute) error and average difference of ± 1°C, respectively. The stickiness histories of these drops were determined experimentally and predicted numerically based on the glass transition temperature (T _g ) of surface layer. The model predicted the experimental observations with good accuracy. A nonsticky regime for these materials during spray drying is proposed by simulating a drop, initially 120 µm in diameter, in a spray drying environment.     

FACTORS GOVERNING SURFACE MORPHOLOGY OF SPRAY-DRIED AMORPHOUS SUBSTANCES

ABSTRACT

Changes in particle morphology (size, shape, and appearance) have been monitored during drying of drops of foods and food-related materials. The apparatus produces a single stream of drops of uniform size, using a vibrating-orifice device for drop production. The drop size and the time-temperature history of the drops as they fall can be varied and controlled.

Qualitative observations are reported for drying of aqueous solutions of lactose, maltodextrin, skim milk, and coffee extract, with different feed concentrations. Particular emphasis is placed upon the tendency for development of folds upon the particle surface. A mechanistic model is developed, relating the tendency for folding to the extent of viscous flow of surface material in response to a surface-energy driving force. This model gives semi-quantitative agreement with observations for solutes of different molecular weight (and hence different viscosity) and for different feed concentrations.     

Effect of Humidity on NPK Fertilizer Drying

ABSTRACT

The drying process within rotary coolers during the manufacture of granular NPK fertilizer plays an important role in the production of fertilizer granules possessing both a low moisture content and low caking propensity. A theory for fertilizer drying has been developed which takes into account the low critical relative humidity of complex fertilizer found at high temperature. The theory proposes that the gradient between the partial vapour pressure of moisture in the air and the vapour pressure moisture adjacent to the surface of the fertilizer granule, is the rate controlling stage in the drying of hot granular fertilizer rather than the internal diffusion of moisture within the particle.     

Drying Foodstuffs with Superheated Steam

Abstract

A thin-layer superheated steam drier was constructed with the objective of determining the drying characteristics, drying rates, and the effect of superheated steam on product quality in thin-layers. Results from superheated steam drying experiments with sugar-beet pulp, potatoes, Asian noodles, and spent grains indicate that drying times and rates increase with increasing steam temperature. For sugar-beet pulp it was also found that these changes were more significant than increases seen by hot-air drying under the same conditions and that drying rates were not affected by velocity for hot air but were increased for superheated steam. When quality aspects were examined, superheated steam dried Asian noodles saw both beneficial changes to recovery, adhesiveness, and gumminess while parameters of maximum cutting stress, resistance to compression, and surface firmness saw deleterious effects. Spent grains saw high levels of starch gelatinization and retention of fibre content.

     

Drying of Transformer Board

ABSTRACT

The internal insulation in shell type power transforms is usually ensured by the stacking of plates of board impregnated with oil. A board is in equilibrium with the atmosphere at a moisture content varying from seven to eight percent by weight, but, when the insulating function is required, the water content must be lower than 0.5 %. The aim of the present work is the understanding and the modelling of transformer boards drying.

The first part of this work presents experimental studies showing that the drying of transform board follows two regimes :

- a fast regime in the fim period

- a slow regime, up to 99 percent of dryness.

The effect of heating and the influence of the board thickness on the drying rate also studied. In the second part of this paper, we presnt a model capable to represent the observed kinetics of transformer board drying. This model is based on the diffusion of water vapour in the gaseous phases combined with the transfer of water vapor from the fibres to the -us phase. The due of the average global transfer coefficient can be deduced from the slope of the curve 1 f(drying time), where x     

A Study of the Boundary Layer Flow Through a Lumber Drying Stack

ABSTRACT

Experiments were performed to investigate the boundary layer flow over rough surfaces of sawn boards in a lumber drying stack. The measurements were conducted with hot-wire anemometry in a range of free-stream velocities of from 0.6 to 7.0 m/ over the rough surface of sawn boards. Boundary layer properties were calculated to demonstrate the development and structure of the flow for various free-stream velocities. The effect of the boundary layer flaw on the drying of lumber was discussed.     

Vacuum Drying of Oak Wood

ABSTRACT

Vacuum drying, j,e drying under absolute gas pressure of about 10? Pa. is an efficient means of reducing the process period and of producing good quality wood. We will examine here continuous vacuum drying where the plank surfaces are kept at a constant temperature, which remains above the boiling point, and moisture flowing to the surface is extracted from the kiln.

We have carried out an experimental study of oak drying under such conditions. The drying rate and moisture content profile of the sample (40 mm thick) are recorded during the whole drying period.

A model of continuous drying is established from general conservation equations with the main approximation that the air is rapidly extracted. The two constitutive equations of the model which describe temperature and water content fields are of a diffusive type and coupled through coefficients. The adequate boundary equation is not a convective one, but expresses a hygroscopic equilibrium between the vapour in the chamber and the wood surface. The mass diffusive coefficient can be adjusted to the drying rates through capillary pressure and bound water diffusion functions. The wood heterogeneity (seasonal growth) is the main factor of discrepancy in these functions. The simulated drying rates correspond with the experimental ones.     

Deformation Behavior of Ceramic Slabs by Nonuniform Drying

ABSTRACT

The presenr paper is to study the transient deformation characteristics of molded ceramics undergoing nonunifom drying. The linear viscoelasticity was assumed for the strain-stress analysis. Three dimensional equations of the strain-stress as well as heat and moisture transfer werc solved numerically by the Galerkln finlle element melhod using isoparametric parameters of twenty-nodes so to allow easily the application to any feature of ceramics. Both the analysis and experiments were carried out to be compared on the behavior of drying and deformation for a slab clay in preheating and constant drying rare periods. When the bottom surface of the slab uras shielded to model the nonuniform drying. a warp phenomrnon to the opposite side of the shielded surface was observed experimentally as drying by hot air heating proceeds. The behavior could be successively simulaled by the present theoretical model. The degree of warp became rcmarkabel with a rise in air temperature or nonuniformity of drying. The surface area exposed to the atmosphere was subjected to a comparatively large tensional stress through drying. The tensile sltresses on the top surface were significantly larger than on the bottom surface.     

Drying behavior of sludge with drying accelerator

Abstract

For fuelization of high moisture content sludge, efficient sludge drying technique using a drying accelerator was investigated. In the experiment, drying accelerator types and drying conditions were changed and the effect of accelerator type and/or drying condition on sludge drying behavior was evaluated by analyzing drying characteristic curve. Depending on drying accelerator type, the addition of drying accelerator did not always exert superiority in drying rate, but sludge with added acrylic resin having low glass transition temperature (DA10) demonstrated significantly enhanced drying rate. Addition of surface activating agent (SAA) instead of resin type drying accelerator also enhanced the sludge drying rate. The highest drying rate was obtained by addition of DA10 and SAA together, and the sludge drying rate has significantly been augmented at the high drying temperature condition.     

Drying Characteristics In Superheated Steam Drying at Reduced Pressure

Abstract

The superheated steam drying at reduced pressure is performed, and the effects of operational conditions such as drying pressure and temperature on the drying characteristics are examined. In order to obtain the basic guideline for the design of the superheated steam dryer at reduced pressure, the heat flux to sample was calculated and the optimal conditions were estimated.

After the sample temperature reached at the boiling point, the temperature was maintained at the boiling point and the drying rate became almost constant. Once the sample was dried out, the temperature suddenly increased up to the drying gas temperature. From the calculation of combined heat flux, the followings were found. The contribution of radiative heat transfer to the combined heat flux became larger as the drying pressure was lower. The combined heat flux had a maximum value against the drying pressure. The optimum drying pressure, which gave the maximum heat flux, became lower as the drying gas temperature decreased. It was found that reduction in the drying pressure is effective for the enhancement in drying performance.     

Microwave Drying of Porous Materials

Abstract

Experimental results on microwave drying of the porous particles exposed to air stream at 40°C are presented. The temperature and moisture distribution inside a particle were measured for gypsum spheres of 9, 18, 28, and 38 mm. The mass reduction was monitored during the drying process. The rate of drying and changes in temperature and moisture profiles for different drying conditions were analyzed and compared with the ones for convective drying.     

Steam Drying of Products Containing Solvent Mixtures

ABSTRACT

Drying experiments with single, porous spheres wetted with mixtures of 2- propanol and water were performed using superheated steam, air, or steam-air mixtures as drying agent. Both the drying rate and the moisture composition were determined experimentally for different temperatures and compositions of the drying agent and for different initial compositions of the moisture. It is shown that evaporation of 2-propanol is enhanced by using superheated steam as drying agent instead of air due to steam condensing on the sample. While the overall drying rate increases with rising steam temperature, the evaporation rate of 2-propanol is hardly affected. When drying samples containing mixtures of 2- propanol and water, internal boiling can occur depending on the vapor–liquid equilibrium. Vapor generated inside the sample may cause mechanical dewatering of the sample which greatly increases the drying rate.     

R & D Needs - Drying of Ceramics

ABSTRACT

New research and development needs for the drying of ceramics are prooosed. The researches on the ceramic drying are briefly reviewed and the role of the drying in the ceramic production process iS summarized. The drying must deal with molded materials and the problem is of significant difference from another drying with particulate materials. It means that the drying must be performed with keeping the molded feature and the insufficient completion of drying and the careless operation influence directly on the product quality The importnance of the R & D on the heat and moisture transfer. shrinking mechanism. the deformation behavior and the strain-stress formation in the molded clay issuggested. The subjects are also pointed out for the further improvement of the ceramic drying process and the precise design of molding with high quality.     

Numerical Simulation of the Drying of a Deformable Material : Evaluation of the Diffusion Coefficient

ABSTRACT

We are interested in the simulation of heat and mass transfer processes accompanying the drying of a deformable agricultural product. We have used an implicit method with classical finite differences to resolve the set of equations. The identification of the diffusion coefficient within a thin carrot layer is carried by trial and error on two analytical forms. These two forms take into account moisture content, temperature and shrinkage of the product.

The drying rates of thin layer of carrot pieces are measured in a laboratory tunnel dryer. These drying curves are established by varying some airflow parameters such as velocity, temperature and relative humidity. The internal and surface temperature of the slab were recorded by means of therrnosensors. The simulated solutions are in agreement with the experimental results.     

Control of Drying Process in Mechanically Spouted Bed Dryer

ABSTRACT

The continuously operated Mechanically Spouted Bed (MSB) dryer of high evaporative capacity can be advantageously used to produce fine powder from paste-like materials, slurries, suspensions and sludges. Due to the thin layer formed on the surface of the spherical inert particles intensive heat and mass transfer occur and the drying process takes place in the constant rate period. Steady state drying conditions can be achieved when the total operational time of partial processes of inert bed drying does not exceed the cycle time of the inert particles.

A laboratory scale MSB dryer has been equipped with a computerised measuring, data acquisition and control system. In the knowledge of the hydrodynamic characteristics of the MSB and giving the enthalpy and mass balances over the dryer a calculation method has been developed for control of drying process.     

Structure of Drying Costs

ABSTRACT

Cost structures of lumber and coal drying processes together with an application of the factor method for prediction of the drying cost are presented.