液相等离子喷涂制备纳米涂层的研究进展

液相等离子喷涂是当今纳米涂层制备技术的研究热点.根据液相前驱体的特性将其分为悬浮液、有机或无机溶液、溶胶,并比较了它们的优缺点和介绍了其研究进展;综述了该技术在SOFC、光催化、新一代热障涂层和超耐磨耐蚀涂层等方面的应用进展.机理研究、前驱体的制备和工艺优化将是该技术今后主要的研究方向.     

利用反应等离子喷涂制备TiCN涂层的研究

TiCN作为一种新型高硬耐磨材料,在生产的诸多领域得到了广泛的应用.主要介绍了首次采用反应等离子喷涂的方法,以Ti粉作为反应粉体,在氮气和乙炔混合气体为反应气氛的反应室中充分反应,制备出以TiCN为主相的涂层;分析了反应气体流量对涂层的影响;并用SEM和XRD对涂层的组织形貌与相组成进行了分析.     

冷喷涂制备复合材料涂层研究现状

鉴于目前冷喷涂技术制备复合材料涂层受到国内外越来越多学者的关注,本文在大量文献分析的基础上对冷喷涂制备复合材料涂层进行了分类和总结。首先,探讨了喷涂前粉末准备和喷涂工艺参数对复合材料涂层的影响;其次,归纳了冷喷涂制备的金属-金属、金属-陶瓷、金属-金属间化合物以及纳米复合材料涂层等研究成果;最后,分析了冷喷涂制备复合材料涂层的应用前景和当前存在的主要问题。     

Ti—Ni涂层的研制进展

NiTi合金具有超弹性和优良的耐磨耐蚀性能,是理想的抗空泡腐蚀材料。但NiTi合金制备成本高、加工难度大、可焊性差,这使其应用受到很大的限制。采用涂层技术沉积Ti—Ni涂层可以大大降低成本和加工难度。本文综述了国内外Ti—Ni涂层的研制现状,并重点阐述了复合涂层工艺对涂层性能的影响。     

Ni60优化高铝青铜SAPS—感应重熔涂层组织结构的研究

采用超音速等离子喷涂技术在45#钢基体上制备Ni60/高铝青铜梯度涂层,并进行高频感应重熔处理。通过SEM、XRD等手段分析了感应重熔前后涂层的组织结构特征、相结构变化以及界面元素扩散情况。结果表明,超音速等离子喷涂层在基体/Ni60结合面处以机械咬合为主,在Ni60/高铝青铜涂层界面处有轻微熔结特性,形成了机械结合和轻微冶金结合的混合结合方式。感应重熔后,Ni60中间层分别与基体、高铝青铜涂层进行充分的双向扩散熔合。在Ni60和基体间形成结构致密、无孔隙的冶金扩散带,元素扩散迁移后不同元素呈现梯度或均匀分布形式。在Ni60和高铝青铜涂层之间分层界面基本消失,形成了完全的一体化涂层,涂层中元素扩散呈现梯度形式。     

Ni—Mo—S复合金属涂层水电解制氢节能新技术研究及其现状

本文展示了Ni—Mo—S复合金属涂层水电解制氢节能新技术可行性研究报告部分内容，并简要总结了两年来研究概况及取得的突破性进展。     

等离子喷涂制备热障涂层的研究进展

等离子喷涂是制备热障涂层最常用的技术。综述了大气等离子喷涂、超音速等离子喷涂、低压等离子喷涂制备热障涂层的研究进展,分析了这3种制备技术的优缺点,并对等离子喷涂制备热障涂层的发展趋势进行了展望。     

C/C复合材料表面Ni涂层的制备及性能研究

石墨材料作为单晶炉热场常用材料，直接影响单晶硅的生长速率和质量。采用C/C复合材料代替单晶炉中石墨材料存在易氧化的缺陷，为此，利用电镀法在C/C复合材料表面制备了Ni涂层。利用正交试验确定最优电镀试验参数，通过X射线衍射仪、扫描电子显微镜、EDS等测试手段分析涂层的相组成、微观形貌和化学组成，并采用热冲击试验和热震性试验对所制备的涂层的抗热冲击性能进行研究。结果表明：电流密度0.4 A/dm²,电镀时间40 min,镀液温度55℃,pH值6条件下制备的涂层的耐磨性最佳。电镀处理后C/C复合材料表面形成了一层均匀、与纤维表面结合紧密的镀层，镀层比较圆整。膜层成分中有大量Ni元素存在。Ni镀层提高了C/C复合材料的抗高温氧化性能。     

超音速火焰喷涂Ni基涂层性能的研究

采用超音速火焰喷涂技术方法制备三种镍基涂层，并研究了涂层的显微组织和性能。结果表明：使用烧结粉末Ni60制备的涂层结合强度、显微硬度均高于包覆粉末Ni包C、Ni包MoS2制备的涂层，Ni包C涂层中产生大量的气体并含有许多的未熔软质相，使得其结合强度、显微硬度最4g；镍在涂层中起粘结作用，镍含量的增加能显著提高涂层的结合强度和显微硬度；涂层中的MoS2和C相明显降低涂层的摩擦系数。     

等离子喷涂液相溶胶制备纳米ZrO2涂层的结构

采用等离子喷涂液相溶胶制备了氧化锆纳米结构涂层。用X射线衍射仪、扫描电镜观察了溶胶干燥粉末和涂层的物相组成及显微结构。结果表明,溶胶自然干燥后为非晶态,通过加热可以得到晶体结构,等离子喷涂形成的涂层为单斜相与立方相的混合晶体结构。涂层由致密的熔化较好的颗粒和微裂纹组成。该方法能够得到晶粒很细的纳米结构涂层。     

热喷涂技术的研究进展与应用

本文叙述了热喷涂技术的研究进展及涂层的应用情况，从而展示了热喷涂技术作为一门新的学科所具有的广阔前景。     

Preparing of nanostructured Al2O3–TiO2–ZrO2 composite powders and plasma spraying nanostructured composite coating

Nanostructured Al₂O₃–TiO₂–ZrO₂ composite powders for plasma spraying were prepared by spray drying granulation technology. The effects of processing parameters on the microstructure and properties of composite powders were investigated. The results show that with increasing the slurry solid content, the particle size of powders increases, and the bulk density of powders increases, and the flowability of powders increases firstly and then decreases. With increasing the binder content, the particle size of powders increases, and the bulk density of powders increases, and the flowability of powders increases firstly and then decreases. With increasing the spray drying temperature, the particle size of powders increases, and the bulk density and flowability of powders increases firstly and then decreases. The most appropriate spray drying parameters are the slurry solid content of 40 wt.%, the binder content of 2.0 wt.% and the spray drying temperature of 250 °C. The nanostructured composite coating was successfully prepared by using the as-prepared nanostructured Al₂O₃–TiO₂–ZrO₂ composite powders as feedstocks. The nanostructured coating possessed higher hardness and toughness compared with the conventional microstructured one, which was attributed to the use of the nanostructured composite powders feedstocks.     

Electrolytic Co-deposition of Ni-CrAlY Composite Coatings Using Different Deposition Configurations

With the aim of seeking an alternative low-cost process for the fabrication of MCrAlY coatings, an electrolytic co-deposition process was employed to form a composite coating consisting of a Ni matrix and CrAlY particles. Three configurations were investigated in the co-deposition process, including a vertical setup, a horizontal arrangement, and a rotating barrel. The CrAlY volume fractions in the resultant composite coatings were compared. The advantages and disadvantages of each configuration were discussed. Among the three configurations studied in this paper, the rotating barrel demonstrated the best overall performance, with the capability of producing coatings with more uniform CrAlY particle incorporation of up to 40 vol.%.     

冷喷涂NiCoCrAlY高温合金防护涂层性能研究

在600℃、2.3 MPa压力和氦气环境下用冷喷涂技术制备了NiCoCrAlY涂层。在600℃下对涂层进行了热处理,用扫描电镜(带能谱仪)、显微硬度测试仪分析了热处理前后涂层微观形貌及显微硬度。结果表明,用冷喷涂技术可以制备出结构致密的NiCoCrAlY涂层,热处理后的涂层变得更加致密,显微硬度有了明显的提高。     

Development and Characterization of Cr3C2–NiCr Coated Superalloy by Novel Cold Spray Process

The coating deposition by cold spray process depends upon the mechanical properties of both the coating and substrate materials. This results in variation of the coating microstructure for different coating–substrate system materials. In this study cold sprayed 75%Cr₃C₂–25%(Ni–20%Cr) coating–superalloy system is developed. The microstructure of the coating obtained is suitable for restricting the penetration of corrosive species toward the substrate. The techniques of X-ray diffraction (XRD), scanning electron microscopy (SEM)/energy-dispersive X-ray spectroscopy (EDX), and elemental X-ray analysis were used for characterization of the newly developed cold spray coated superalloy.     

Characteristics of gas-tunnel plasma-sprayed coatings

The quality of Al₂O₃ coatings formed by gas-tunnel plasma-spraying apparatus has been evaluated with respect to hardness and porosity under various spraying conditions. The deposit characteristics of Al₂O₃ powder sprayed onto a substrate by this type of plasma spraying were also studied and the relation between the deposit characteristics and the spraying distance was investigated. Estimation of the deposit characteristics was found to be a very effective method for determining the proper spraying conditions under which a good quality coating can be obtained.     

我国纳米涂料的研究进展与产业化现状

综述了我国纳米涂料工业科学研究的最新进展,分析了我国纳米涂料产业化的现状和存在的问题.研究认为,我国在纳米涂料的概念、标准、生产技术、研究领域等方面还存在问题,制约了我国纳米涂料的研究与产业化发展.提出了我国纳米涂料研究与产业化的建议.     

石墨烯及其复合材料导热性能的研究现状

阐述了单层石墨烯、石墨烯带及石墨烯复合材料的导热性能。介绍了各种测试模型,综述了石墨烯的层数、纵横比、几何结构、边缘粗糙度、衬底耦合作用、温度等因素对其导热性能的影响。提出了石墨烯及其复合材料导热性能可深入研究的方面。     

喷墨打印基材表面纳米涂层的研究进展

目的综述了目前喷墨打印基材表面纳米涂层的研究成果和发展趋势。方法基于对近年国内外关于表面纳米涂层的研究成果,介绍喷墨打印表面纳米涂层的组成、固化机理及其物化性能和光学性能,进一步对喷墨打印涂层的发展趋势及挑战进行总结与分析。结果表面纳米涂层能够改变材料及其制件表面的物理结构和化学组成。在喷墨打印过程中,喷墨打印基材表面纳米涂层质量直接影响印品的质量,文中通过对喷墨打印纳米涂层的性能、研究现状、发展趋势及挑战等方面的论述,为未来的喷墨打印纳米涂层相关研究和应用提出了建议。结论喷墨打印技术作为数字成像技术的典型代表,可实现印刷品的种类多样化、个性化,想要得到复制完美的制品,需优化基材表面的化学组成或物理结构,而表面涂层技术能够改变材料及其制件表面成分和组织结构,所以对喷墨打印基材表面纳米涂层的研究至关重要。