Probing of a random phase object by a focused spatially modulated laser beam. Integral scanning method

A telescope system incorporating an illuminating spatially modulated laser beam, a diffuser in the entry plane, and a random phase screen in the spatial frequency plane was used to analyze the formation of average-intensity interference fringes in the image plane of the diffuser. It is shown that the system can operate as a shift interferometer where the contrast of the fringes is independent of the diffuser characteristics. Analytic expressions are obtained for the contrast of the fringes as a function of the parameters of the screen and the illuminating beam and it is established that the statistical anisotropy of the screen influences the contrast of the fringes. Pis’ma Zh. Tekh. Fiz. 25, 5–10 (December 26, 1999)     

Determination of correlation properties of moving diffuser by spectral analyses of the scattered light emerging from two pinholes

Abstract

Correlation properties of light scattered by a moving diffuser are determined by studying the spectral characteristics of the light that emerges from two pinholes placed after the diffuser. These properties are used to determine the correlation functions of the heights of diffuser surface and the speed of the diffuser. The phase of the light on the two pinholes after it has passed through the moving diffuser, is also determined.     

Coherence of two interfering beams modulated by a uniformly moving diffuser

Abstract

Coherence properties are discussed of light which emerges from two pinholes after it has passed through a moving diffuser. The results are used to show how the correlation function of the heights of the diffuser surface and the speed with which the diffuser is moving may be determined from simple interference experiments.     

Transformation of coherence and of the spectrum of light by a moving diffuser

Abstract

Effects of a diffuser on the spectral degree of coherence and on the spectrum of light produced by transmitting light through the diffuser are described. Both stationary and uniformly moving diffusers are considered and the analysis applies to dielectric as well as to absorbing diffusers. The results are illustrated by numerical examples.     

Gas dynamic analysis of the performance of diffuser augmented wind turbine

A diffuser augmented wind turbine (DAWT) is considered an important application of the advanced concepts to improve the attractiveness of wind energy. The present paper aims to find a theoretical demonstration of DAWT by using theoretical analysis, mathematical models, assumptions, estimations and maximization of power coefficients and augmentation ratios, in addition to computer programs for calculations and drawings. The final results show that the maximum power coefficient (Cpd ₀) and augmentation ratio (R _b-) relative to Betz — are directly proportional to pressure recovery factor(Cr), turbine factor (Ct), and maximum velocity ratio(No), but inversely proportional to overall recovery factor (Co) of diffuser. The power coefficient(Cpd ₀ ) of DAWT reaches 1.5 at C₀ ≃ -0.5,No ≃ 1.0 andCr ≃ 0.5, but the augmentation ratio(R _b ) reaches 6.0 at C₀ ≃ -0.5,Cr ≃ 0.9, and reaches 7.0 atNo ≃ 1.0 and Ct ≃ 1.0, which gives a good application for DAWT systems.     

Composite Displacement Measurement by Speckle Technique

Abstract

We present a simple method for measuring composite movements which comprise a longitudinal displacement and a rotation of a rough surface. The method is based on the direct analysis of the double exposure photographic recording obtained from two speckle patterns produced by the diffuser, before and after it is translated and rotated.     

Complex Degree of Coherence Due to Tilted Planar Sources

Abstract

The complex degree of coherence (CDC) due to a quasi-monochromatic spatially incoherent source can be displayed by performing a two-step procedure. The CDC information is encoded in the spectral content of the speckle pattern produced via a diffuser placed at the plane where the CDC is to be studied. In a second step, the recorded speckle is Fourier analysed. We apply this method to the study of tilted incoherent sources, for which the CDC is no longer an homogeneous function. A relationship is found that links the size of the speckle halo in the Fourier plane (where CDC information exists), and the tilt angle of the source plane. Some experimental results are shown in order to illustrate the method. Finally, some possible extensions and applications of our study are mentioned.     

Inhomogeneous deformation of crystalline skeleton of syndiotactic polypropylene under uniaxial stretching

Structure changes of syndiotactic polypropylene (sPP) under uniaxial stretching are studied with the combination of micro-tensile tester and in situ wide angle X-ray diffraction (WAXD) measurement. Lamellae stacked “vertically” and “parallel” to the stretching direction (defined as “V” and “P” part) are separated on the basis of two-dimensional WAXD patterns. For all samples with different lamellar thickness, two critical points named as b ₁ and b ₂ were found in the stress–strain curves, while b ₁ and b ₂ points are the onsets of the rotation for the lamellae of “V” part and “P” part, respectively. The corresponding true stress and true strain for b ₂ point are bigger than that of b ₁ , demonstrating that for samples with initial isotropic lamellar orientation, inhomogeneous deformation of crystalline skeleton induced by uniaxial stretching is universal. And after b ₁ point, “stress-induced melting” always occurs simultaneously with lamellar slips. Furthermore, the relationship between lamellar thickness and the true stress for b ₁ and b ₂ point was also studied, illustrating a linear correlation between ln σ and 1/l (σ is the corresponding true stress, l is the lamellar thickness), consistent with Young’s model. However, the critical true strains for these two points did not change with the varying thickness.     

Optical properties of lead-bismuth cuprous glasses

The optical transmission and absorption spectra in UV- VIS were recorded in the wavelength range 350–800 nm for different glass compositions in the system (CuO) _x (PbO) ₅₀−x(Bi₂O₃)₅₀ (x = 2.5, 5.0, 7.5, 10.0, 12.5, 15.0, 20.0). Absorption coefficient (α), optical energy gap (E_opt), refractive index (n_D), optical dielectric constant (ε′_∞), measure of extent of band tailing (ΔE), constant (β) and ratio of carrier concentration to the effective mass (N/m*) have been reported. The effects of compositions of glasses on these parameters have been discussed. It has been indicated that a small compositional modification of the glasses lead to an important change in all the optical properties including non-linear behaviour. The optical parameters were found to be almost the same for different glasses in the same family.     

Chemical synthesis and characterization of hydrous tin oxide (SnO<Subscript><Emphasis Type="Bold">2</Emphasis></Subscript>:H<Subscript><Emphasis Type="Bold">2</Emphasis></Subscript>O) thin films

In the present investigation, we report chemical synthesis of hydrous tin oxide (SnO ₂ :H ₂ O) thin films by successive ionic layer adsorption and reaction (SILAR) method at room temperature ( \thicksim \thicksim 300 K). The films are characterized for their structural and surface morphological properties. The formation of nanocrystalline SnO ₂ with porous and agglomerated particle morphology is revealed from X-ray diffraction (XRD) and scanning electron microscopy (SEM) studies, respectively. The Fourier transform infrared spectroscopy (FTIR) study confirmed the formation of Sn–O phase and hydrous nature of the deposited film. Static water contact angle studies showed the hydrophilic nature of SnO ₂ :H ₂ O thin film. Electrical resistivity showed the semiconducting behaviour with room temperature electrical resistivity of 10 ⁵  W\boldsymbol\Omega cm. The electrochemical properties studied in 0·5 M Na ₂ SO ₄ electrolyte showed a specific capacitance of 25 F g ^− 1 at 5 mVs ^− 1 scan rate.     

Inhibition effects of acetyl coumarines and thiazole derivatives on corrosion of zinc in acidic medium

The corrosion inhibition characteristics of acetyl coumarine (AC), bromo acetyl coumarine (BAC) and thiazole derivatives (BTMQ and BTCQ) on the corrosion of zinc in 0·1 M HCl solution were investigated by weight loss, potentiodynamic polarization and impedance techniques. The inhibition efficiency increased with increase in inhibitor concentration upto 5 ×10^− 4  M, then gave almost same inhibition efficiency. The polarization measurements indicated the mixed nature of inhibitors. The adsorption of compounds obeyed Langmuir’s adsorption isotherm. The thermodynamic functions for adsorption processes were evaluated.     

Bilateral bounds for the shear and torsion factors: comments on elementary derivations

This paper proposes a new simple derivation of bilateral bounds for the strain energy–based shear and torsion factors, χ _i , of an elastic beam together with some comments about the coherence of the current formulations. A rearrangement of the definition as a mean over the cross-section and an original decomposition of the shear stress in two parts—τ _eqv that is equivalent to the external force and a residual Δτ—allow (i) to interpret (χ − 1) as the mean quadratic deviation of the shear field with respect to the distribution τ _eqv and (ii) to easily evaluate an upper bound, using minimal information about the stress field. In this formulation, the lower bound becomes trivial. Several numerical examples illustrate the accuracy and suitability of the results obtained.     

Systematic hardness measurements on mixed and doped crystals of rubidium halides

Efforts are made to improve the hardness of rubidium halide crystals by (i) solid solution hardening and (ii) impurity hardening. Systematic microhardness measurements have been made on rubidium halide mixed crystals (RbBr-RbI and KI-RbI) and rubidium halide crystals doped with Sr²⁺ ions. The composition dependence of the hardness of mixed crystals follows the law ΔH _v =K x (1− x),where ΔH _v is the enhancement in hardness,K a constant andx and (1 −x) the concentrations of the first and second component of the mixed crystals, respectively. The hardness of doped crystals increases with the concentrationC of the dopant according to the law, ΔH _v+6 =k C ^m ,wherek andm are constants. The relative efficacy of the two methods of hardening is discussed.     

One-dimensional diffuser based on a thick layer of dichromated gelatin

A new diffuser capable of scattering light in one direction (one-dimensional diffuser) has been developed and experimentally tested. The diffuser is formed in a thick layer of dichromated gelatin. The scattering indicatrices of the diffuser measured in two mutually perpendicular directions are presented. It is demonstrated that the indicatrix width in one direction is significantly greater than that in the perpendicular direc-tion. However, no zero-order diffraction has been observed. The proposed one-dimensional diffuser exhibits close scattering indicatrices for reading at a wavelength of 0.44 and 0.63 μm.     

Synthesis and nonlinear optical properties of novel Y-type polyurethanes with high thermal stability of dipole alignment

2,3-Di-(2′-hydroxyethoxy)benzylidenemalononitrile (3) was prepared and condensed with 2,4-toluenediisocyanate and 3,3′-dimethoxy-4,4′-biphenylenediisocyanate to yield novel Y-type polyurethanes 4–5 containing 2,3-dioxy benzylidenemalononitrile group as a nonlinear optical (NLO)-chromophore, which constituted parts of the polymer backbones. Polyurethanes 4–5 were soluble in common organic solvents such as acetone and N,N-dimethylformamide. They showed a thermal stability up to 270 °C in thermogravimetric analysis thermograms and the glass-transition temperatures (T _g) obtained from differential scanning calorimetry thermograms were around 116–135 °C. The second harmonic generation (SHG) coefficients (d ₃₃) of poled polymer films at 106.4 mm⁻¹ fundamental wavelength were around 9.07 × 10⁻¹⁹ C (2.72 × 10⁻⁹ esu). The dipole alignment exhibited high thermal stability up to 10 °C higher than T _g, and there was no SHG decay below 145 °C due to the partial main-chain character of the polymer structure, which was acceptable for nonlinear optical device applications.     

Uncatalyzed synthesis of polypyrrole with viologen side groups and its chemical properties

A substituted polypyrrole (PPr) with viologen side groups (polymer-1) was obtained from the reaction of N-aminopyrrole with 1-hexyl-1′-(2,4-dinitrophenyl)-4,4′-bipyridinium dihalide (salt-1). A model compound (model-1) was synthesized by the reaction of N-aminopyrrole with N-(2,4-dinitrophenyl)-4-(4-pyridyl)pyridinium chloride (salt-2). UV–vis spectra revealed that polymer-1 had an expanded π-conjugation system along the polymer chain: the polymer showed an onset position of absorption at a wavelength approximately 200 nm longer than the corresponding wavelength of model-1. Polymer-1 received an electrochemical oxidation of the pyrrole ring and reduction of the viologen group within the polymer.     

Efficient triphenylamine photosensitizers with alkoxy- or fluorine-substituted phenylene spacer for dye-sensitized solar cells

Two new organic sensitizers (TP1–2) containing triarylamine donor and a cyanoacrylic acid acceptor bridged by alkoxy- or fluorine-substituted phenylene spacer have been synthesized and explored as a sensitizer in dye-sensitized solar cells (DSCs). The absorption spectra, electrochemical and photovoltaic properties of TP1–2 are extensively investigated. The DSC based on dye TP1 shows the best photovoltaic performance: a short-circuit photocurrent density (J _SC) of 13.5 mA cm⁻², an open-circuit photovoltage (V _OC) of 702 mV, and a fill factor (ff) of 0.68, corresponding to an overall conversion efficiency of 6.4% under standard global AM1.5 solar light conditions. The results demonstrate that structural modification of substituting groups on π-spacer is importance for realizing a high efficiency DSC.     

ζ-potential characterization of collagen and bovine serum albumin modified silica nanoparticles: a comparative study

In this study, bovine serum albumin (BSA) and collagen (COLL) were adsorbed independent of one another, onto the surface of silica nanoparticles (SNPs) at pH’s where the ζ-potential of the proteins were equal in magnitude, but opposite to the SNP surface to ascertain the differences in surface coverage and conformation in the adsorbed layer. In both systems, increasing the concentration of free protein resulted in an increase in protein surface coverage and ζ values, with ζ values approaching that of native protein at high surface coverage. However, a lower critical charge reversal concentration range was measured for COLL relative to BSA (COLL: 0–25 μg/mL, BSA: 25–90 μg/mL). Additionally, a considerable difference in ζ for adsorbed protein versus free protein was observed. These results when interpreted in terms of the theory of Ottewill and Watanabe indicate a higher Gibbs energy of association for COLL versus BSA on SNP surfaces, accompanied by perturbation in protein structure.     

Correlated one-body density matrix of boson superfluids

The correlated density matrix theory is employed and further developed to analyze the one-body density matrix ρ₁(|r ₁-r ₂|) of the normal and superfluid phases of a strongly interacting Bose system at non-zero temperature. The approach continues the formal development described in an earlier article and is based on a suitable trial ansatz for the many-body density matrixW(R, R′)∼Φ(R) Q(R, R′) Φ(R′) with the wave function Φ and incoherence factorQ incorporating the essential statistical and dynamical correlations. Special attention is given to the appearance of off-diagonal long-range order in function ρ₁(|r ₁-r ₂|) and its relation to the condensation strength B_cc characterizing the degree of coherence in the superfluid phase. We derive a number of structural relations that have counterparts in known results on ρ₁ in the Jastrow variational theory of the Bose ground state. We discuss Bose-Einstein condensation and make contact to Landau's phenomenological theory of continuous phase transitions. Numerical estimates are presented on the condensation strength and the condensate fraction of liquid⁴He as functions of the temperature.     

Optical characterization of a new donor–acceptor type conjugated polymer derived from 3,4-diphenylthiophene

A new donor–acceptor type poly{2-(3,4-didecyloxythiophen-2-yl)-5-[3,4-diphenyl-5-(1,3,4-oxadiazol-2-yl)thiophen-2-yl]-1,3,4-oxadiazole} (P1) has been designed and synthesized starting from thiodiglycolic acid, 1,2-diphenylethane-1,2-dione, and diethyl oxalate through multi-step reactions using precursor polyhydrazide route. The charge-transporting and linear optical property of the polymer has been investigated by cyclic voltammetric, UV–visible, and fluorescence emission spectroscopic studies. The UV–visible absorption spectrum of polymer in thin film form showed maxima at 420 nm. The polymer displayed bluish-green fluorescence both in solution and thin film form. The optical band gap is determined to be 2.27 eV. Third-order nonlinear optical property of the new polymer has been investigated at 532 nm using single beam Z-scan and degenerate four wave mixing (DFWM) techniques with nanosecond laser pulses. The absorptive nonlinearity observed for the polymer P1 is of optical limiting type, which arises due to an “effective” three-photon absorption (3PA) process. The third-order nonlinear optical susceptibility (χ⁽³⁾) of the polymer is found to be 0.831 × 10^–12 esu. Both linear and nonlinear optical studies revealed that the new polymer (P1) is a promising material for applications in photonic devices.