粉煤灰势能等级系统的认证技术

粉煤灰势能等级系统的认证技术沈旦申，瞿秋云，黄治祥上海市建筑科学研究院１前言当前，国内外粉煤灰混凝土科学技术研究和发展的焦点，较多地聚集于粉煤灰势能的有序和有效的利用，要求理性地和充分地发挥粉煤灰内在势能的价值和实现粉煤灰与其它混凝土组分互补和交融而...     

粉煤灰海工高性能混凝土的应用研究

针对粒化高炉矿渣粉和硅灰存在的缺陷。研究采用粉煤灰替代粒化高炉矿渣粉配制混凝土,进而观察其力学性能、抗氯离子渗透性以及胶凝材料的水化热。研究结果表明,所配制的混凝土能满足海工高性能混凝土高耐久性的需要,粉煤灰替代粒化高炉矿渣粉胶凝材料具有较低的水化热,有利于大体积混凝土的施工。     

粉煤灰超量取代技术在水利工程混凝土中的研究与应用

在拌合混凝土时加入适量粉煤灰取代水泥，是化废为利、节约水泥、降低成本、改进混凝土性能的简便措施。国外研究工作始于３０年代，４０～７０年代推广应用，８０年代进入了粉煤灰资源化、产品化、商品化研究利用新时期。普遍开展了粉煤灰的分选利用；高性能粉煤灰作为功能材料，已为配制高强、高性能混凝土（ＨＰＣ）的重要组成材料。本项研究始于１９７３年，是在建设广西大化水电站时，由北京水利水电科学院、广西水电工程局、广西电力工程勘察设计研究院等合作完成。以往在混凝土中掺用粉煤灰，普遍采用容易获得的原状普通粉煤灰，并据…     

粉煤灰和矿粉对混凝土力学与耐久性能的影响研究

粉煤灰和矿粉加入混凝土中可以有效消耗工业固体废弃物,保护环境.基于此,利用室内试验方法采用粉煤灰和矿粉取代部分水泥,制备了不同粉煤灰以及矿粉掺量的混凝土材料,测试了这些材料的抗压强度、抗氯离子侵蚀性能、抗冻性能以及抗碳化性能.结果表明:双掺粉煤灰和矿粉条件下混凝土的抗压强度和抗冻性能均要优于单掺粉煤灰或矿粉;当粉煤灰或矿粉单掺量为24％时,混凝土的电通量最小,其抗氯离子侵蚀能力最强;双掺粉煤灰和矿粉混凝土的28 d碳化深度比素混凝土小39.4％～53.5％.     

粉煤灰和矿粉对混凝土力学与耐久性能的影响研究

粉煤灰和矿粉加入混凝土中可以有效消耗工业固体废弃物,保护环境.基于此,利用室内试验方法采用粉煤灰和矿粉取代部分水泥,制备了不同粉煤灰以及矿粉掺量的混凝土材料,测试了这些材料的抗压强度、抗氯离子侵蚀性能、抗冻性能以及抗碳化性能.结果表明:双掺粉煤灰和矿粉条件下混凝土的抗压强度和抗冻性能均要优于单掺粉煤灰或矿粉;当粉煤灰或矿粉单掺量为24％时,混凝土的电通量最小,其抗氯离子侵蚀能力最强;双掺粉煤灰和矿粉混凝土的28 d碳化深度比素混凝土小39.4％～53.5％.     

桩身材料用低钙Ⅲa分煤灰与高钼粉煤灰素混凝土的力学性能试验研究

通过室内材料实验，对低钙Ⅲａ「１」顷粉煤灰与高钙为分煤灰素混凝土的ＣＦＧ桩桩身材料配合比和力学性能（抗压强度和弹性模量）进行了试验对比分析，主要探讨了两种粉煤灰素混凝土满足一定和易性、稠度要求时的需水量、抗中度、强度增长和弹性模量之间的差别。实验结果表明，在弹性模量方面，粉煤灰素混凝土的ＣＦＧ桩桩身材料趺半刚性；并且高钙粉煤灰素混凝土的需水性与力学性能指标均优于低钙Ⅲａ级粉煤灰素混凝土。     

夹芯型免烧结粉煤灰轻集料及其制品的试验研制

本文介绍一种由聚苯乙烯球与粉煤灰为主要材料复合的免烧结粉煤灰轻集料，并对其生产工艺，主要技术性能，以及用其配制轻混凝土，生产小型轻混凝土砌块进行了试验研究。     

粉煤灰质量控制的几点意见

粉煤灰作为混凝土组成的主要掺加材料，其质量的好坏对混凝土性能有一定的影响。粉煤灰的组成和化学成分对粉煤灰在混凝土中三大效应的发挥有直接的影响，只有充分保证粉煤灰的原材料质量的稳定性，才能最大限度的发挥粉煤灰对混凝土的性能改善的积极作用。     

粉煤灰沥青混凝土的性质

粉煤灰沥青混凝土的性质粉煤灰沥表混凝土是用粉煤灰替代矿粉配制的混凝土，众所周知，沥青混凝土的质量在很大程度上取决于矿粉的性质。而符合标准的粉煤灰则是制备沥青混凝土混合料的廉价材料。保加利亚波夫·道尔电厂将电除尘设备Ⅱ、Ⅲ电场的干粉煤灰和从Ⅰ、Ⅱ、Ⅲ电...     

粉煤灰高聚物混凝土的强度研究

研究了以ＡＰＡＯ（ＡｍｏｒｐｈｏｕｓＰｏｌｙＡｌｐｈａＯｌｅｆｉｎｅ）改性沥青、酚醛树脂为粘结剂,粉煤灰为填料制高聚物混凝土的可行性以及粉煤灰表面活化、粉煤灰掺量及粒径对材料强度的影响,结果表明粉煤灰具有增加材料强度的作用,而且高聚物混凝土的掺灰比例高于硅酸盐粉煤灰水泥的掺灰量时,材料强度依然较高。     

Electrical resistivity and corrosion potential of reinforced concrete: influencing factors and prediction models

Abstract

This paper presents two models: one for predicting the electrical resistivity of concrete and the other for the corrosion potential of reinforcing steel. The prediction models were developed based on experimental results, considering various influencing factors. The experiment approach included the concrete mix proportion, chloride content, concrete cover thickness and time of exposure as the parameters. The results revealed that fly ash concrete showed significantly high electrical resistivity even in the presence of chloride ions. The effects of fly ash became more significant when the water to binder ratio was lower. Chloride ions also decreased the corrosion potential of steel in both the OPC and fly ash concrete. The corrosion potential was found less negative for fly ash concrete due to higher electrical resistivity. The prediction results show good agreement with the experimental results of this study and some other researchers.     

粉煤灰对脱硫石膏-矿渣-粉煤灰复合胶凝材料力学性能的影响

通过研究粉煤灰自身在硫酸盐和石灰双重激发下产生的活性、粉煤灰的碱性以及颗粒Zeta（电位）等,分析不同粉煤灰对脱硫石膏-矿渣-粉煤灰复合胶凝材料力学性能的影响。结果表明,粉煤灰的种类对复合胶凝材料的力学性能影响很大,粉煤灰本身活性的差异不是造成这种影响的主要原因,其主要原因是粉煤灰对矿渣粉的激发程度。粉煤灰的碱性对矿渣粉的激发影响很大,对于普通含钙粉煤灰,碱性越强,激发越好,复合胶凝材料力学性能越好。矿渣粉颗粒的Zeta电位为负,因此粉煤灰颗粒表面的正电荷密度过高,不利于矿渣粉活性的激发。     

Electrochemical studies on the corrosion performance of steel embedded in activated fly ash blended concrete

The use of fly ash to replace a portion of cement has resulted significant savings in the cost of cement production. Fly ash blended cement concretes require a longer curing time and their early strength is low when compared to ordinary Portland cement (OPC) concrete. By adopting various activation techniques such as physical, thermal and chemical methods, hydration of fly ash blended cement concrete was accelerated and thereby improved the corrosion-resistance of concrete. Concrete specimens prepared with 10-40% of activated fly ash replacement were evaluated for their open circuit potential measurements, weight loss measurements, impedance measurements, linear polarization measurements, water absorption test, rapid chloride ion penetration test and scanning electron microscopy (SEM) test and the results were compared with those for OPC concrete without fly ash. All the studies confirmed that up to a critical level of 20-30% replacement; activated fly ash cement improved the corrosion-resistance properties of concrete. It was also confirmed that the chemical activation of fly ash yielded better results than the other methods of activation investigated in this study.     

Effects of fly ash on the properties of environmentally friendly dam concrete

The utilization of a solid waste – fly ash (FA) in the construction of concrete dams was investigated in this paper, which contained its effects on the strength, shrinkage and expansion strain of dam concrete with and without 8% of a novel MgO-bearing expansive agent. The results are shown a relationship between the content of fly ash replacing cement and the above properties of dam concrete.The compressive strengths of dam concrete with 50% fly ash in 90 d are higher than that of dam concrete with 30% fly ash or without fly ash slightly. Fly ash may decrease the deformation of dam concrete in that with 50% fly ash, and the shrinkage and expansive strain was reduced significantly – about 33% and 40% less than that of the specimens without fly ash respectively.     

大掺量粉煤灰对混凝土渗透性的影响

以粉煤灰代替３０％的水泥，在水胶比为０．３０、０．３３、０．３６及０．３９的情况下，分别试验了用水量及胶凝材料用量变化下混凝土的强度和渗透性。试验结果表明，与不掺粉煤灰的混凝土比较，掺粉煤灰混凝土的渗透性都明显降低，３０天龄期时最大可降低至５０．７％，７０天时可降低至２２．３％；为了获得较低的渗透性而采取较低的水胶比时，不掺粉煤灰的混凝土应用降低用水量的办法有利，掺粉煤灰的混凝土用提高总胶凝材料用量的办法更好     

粉煤灰对碾压混凝土耐久性的影响

用于大体积混凝土工程的碾压混凝土，其耐久性好坏直接关系到重大工程的使用及寿命。从抗渗性、抗冻性、抗冲磨性、抗碳化性及抗化学侵蚀性等方面研究了粉煤灰对碾压混凝土耐久性的影响。结果表明：（1）粉煤灰能提高碾压混凝土后期的抗渗性；（2）在碾压混凝土中增加粉煤灰的用量，提高胶凝材料的总量，从而降低混凝土的水灰比，能提高碾压混凝土抗冻性：（3）粉煤灰掺量不大于15％时，粉煤灰掺量对碾压混凝土的抗冲磨性能影响甚微；（4）粉煤灰掺量不大于50％时，经碳化后混凝土的抗压强度反而有所提高；（5）碾压混凝土的水化产物长期稳定性较好，且因有粉煤灰的二次水化消耗了部分Ca（OH）2，故其抗镁盐及硫酸盐侵蚀的能力较强。     

等强度条件下粉煤灰对补偿收缩混凝土变形性能的影响

通过测定水中限制膨胀率和水养7d转干空后的限制膨胀率,计算干燥收缩落差,讨论粉煤灰在等强度条件下对补偿收缩混凝土变形性能的影响.结果表明:等强度条件下掺加适量粉煤灰可以明显地促进限制膨胀率的增长;掺量过大容易导致早期约束不足,降低对限制膨胀的促进作用.粉煤灰可以明显降低混凝土转干空后早期的干燥收缩落差.随着粉煤灰掺量增加,干燥收缩落差进一步降低,空气中放置28 d后均表现为膨胀.对于硫铝酸钙-氧化钙类膨胀剂和粉煤灰复掺的补偿收缩混凝土,膨胀剂最小用量的要求可以适当降低.     

粉煤灰及沙漠砂对混凝土抗碳化性能的影响

通过进行单掺粉煤灰、单掺沙漠砂、双掺粉煤灰和沙漠砂混凝土3d、7d、14d、28d和56d抗碳化性能试验,分析了粉煤灰掺量和沙漠砂替代率对混凝土抗碳化性能的影响,建立了混凝土28 d碳化深度与粉煤灰掺量及沙漠砂替代率之间回归关系模型.试验结果表明:对于单掺粉煤灰混凝土,随着粉煤灰掺量增加,混凝土碳化深度逐渐增大,且碳化早期比后期增长较快;对于单掺沙漠砂混凝土,随着沙漠砂替代率增加,混凝土碳化深度呈先减小后增大趋势,沙漠砂替代率20%时混凝土碳化深度最小;对于双掺粉煤灰和沙漠砂混凝土,粉煤灰掺量10%,沙漠砂替代率20%时混凝土碳化深度最小.     

Durability of biomass fly ash concrete: Freezing and thawing and rapid chloride permeability tests

Strict interpretation of ASTM C 618 excludes non-coal fly ashes, such as biomass fly ashes from addition in concrete. Biomass fly ash in this investigation includes (1) cofired fly ash from burning biomass with coal; (2) wood fly ash and (3) blended fly ash (wood fly ash mixing with coal fly ash). A set of experiments conducted on concrete from pure cement and cement with fly ash provide basic data to assess the effects of several biomass fly ashes on the performances of freezing and thawing (F-T) and rapid chloride permeability test (RCPT). The F-T tests indicate that all fly ash concrete has statistically equal or less weight loss than the pure cement concrete (control). The RCPT illustrate that all kinds of fly ash concrete have lower chloride permeability than the pure cement control concrete.     

粉煤灰混凝土抗酸雨侵蚀的研究

不同粉煤灰掺量(0,20%,40%,60%)高性能混凝土经不同pH值(1、2、4)硫酸溶液浸泡后,研究其相对动弹性模量和质量损失规律.试验表明,随着溶液酸性的增加,混凝土破坏严重;粉煤灰掺量为20%～60%时,混凝土抗酸性能有所增加;高掺量粉煤灰混凝土在酸性环境中浸泡,当粉煤灰掺量为60%时,混凝土以相对动弹性模量损失...