共查询到20条相似文献,搜索用时 93 毫秒
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将纯丙乳液和苯丙乳液通过乳液共混制备出丙烯酸酯共混乳液,探讨了共混比例、共混温度、共混pH值和共混工艺对丙烯酸酯共混乳液的粒径及其分布的影响,并进一步研究了共混乳液粒径大小及分布对其流变性能的影响。结果表明:共混乳液为假塑性流体;随着共混比例和共混温度的升高,共混乳液粒径减小,黏度增大;随着共混pH值的升高,乳液粒径先增大后减小,黏度总体上呈增大趋势;半连续工艺制备的共混乳液粒径分布最窄、黏度最大,连续工艺制备的共混乳液粒径分布最宽、黏度最小,间歇工艺制备的共混乳液粒径分布和黏度居中。 相似文献
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微乳液技术制备纳米微粒的研究进展 总被引:19,自引:2,他引:19
综述了微乳液技术制备纳米微粒的研究现状,并对微乳液的配制及制备中影响纳米微粒的主要因素进行了讨论,提出了这一研究领域的发展方向。 相似文献
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传统上以聚乙烯醇(PVA)为乳化剂所制备的聚醋酸乙烯酯(PVAC)乳液存在黏度大、耐水性差等问题,在PVAC乳液的聚合过程中加入AMPS,研究了在无PVA条件下AMPS对乳液的聚合过程及性能的影响,并对相关性能进行了检测和对比分析。结果表明,AMPS可以明显提高PVAC乳液的贮存稳定性和电解质稳定性,与采用PVA为乳化剂制得的PVAC乳液相比,黏度由2600mPa·s下降到了97mPa·s以下、胶膜的吸水率由210%下降到了32.7%以下;使用无皂聚合方法制备PVAC乳液时,添加AMPS可以迅速减小乳胶粒的尺寸,提高乳液的稳定性和收率。 相似文献
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利用聚乙二醇和二异氰酸酯聚合,并以酚类物质为链封端剂合成了缔合型增稠剂,检测和对比该产品与一支国外同类产品在乳液及乳胶涂料中的一些相关应用性能,结果显示,该产品与同类产品性能接近,具有一定的市场前景。 相似文献
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Heterocoagulation as an Inclusion Coating Technique for Ceramic Composite Processing 总被引:3,自引:0,他引:3
Terry Garino 《Journal of the American Ceramic Society》1992,75(3):514-518
Colloidal heterocoagulation in aqueous media was used to form coatings of alumina or polystyrene latex particles on alumina spheres and of alumina or latex particles on silicon carbide whiskers. The polyelectrolyte dispersants poly-(ammonium methacrylate) and poly(ethylenimine) were used to alter the inherent surface potentials of the materials to increase the applicability of this technique. In most cases, the coatings formed were partial monolayers, although thicker coatings of alumina were formed on the SiC due to aggregation of the alumina. The oxide coatings were relatively well adhered while the latex coatings were easily removed in aqueous media. The adherence of the latex coatings was improved by adding low alcohols to the heterocoagulating suspension. 相似文献
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This study applied redispersible powder into wall coatings and compared the film microstructure and properties of dry-mixed coatings and corresponding latex coatings. It could be found that the dry-mixed coatings film had loose and uniform structure, while the latex coatings film was dense and had two-layered microstructure. Through the UV–vis spectra and dynamic light scattering, we found that the different microstructures of both coatings films were resulted from the different stability of reconstituted emulsion and original polymer emulsion, and one model was set up to demonstrate this process. The performance of dry-mixed coatings was worse compared with latex coatings, which was due to the weakened stability and adhesive ability of reconstituted emulsion after spray drying. 相似文献
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The role of pigment particle size distribution on stress and microstructure development was studied for coatings prepared from aqueous suspensions of ground calcium carbonate (GCC) and latex binder. Stress development was monitored using a modified beam deflection technique under controlled environment. Microstructure was characterized by scanning electron microscopy (SEM) and cryogenic SEM. For coatings containing only GCC particles and no latex, a wide particle size distribution resulted in a significant particle size gradient in the cross-sectional microstructure and irregular stress development. With latex addition, uniform microstructures were observed in coatings with either wide or narrow GCC particle size distribution. GCC/latex coatings prepared using GCC with a wide particle size distribution developed a higher stress than those prepared using GCC with a similar average particle size but a narrow particle size distribution. The higher stress is related to the particle packing that results in smaller pore sizes and larger capillary pressures that drive compaction. In coatings prepared with the same GCC particles but different latex binders, the stress and cracking behavior of the coating depends on the latex properties. 相似文献
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颜料对乳胶漆耐洗刷性能的影响 总被引:1,自引:1,他引:1
乳胶漆的耐洗擦性能反映乳胶漆的综合性能。本试验系统研究了颜料体积浓度、填料用量、乳液聚合物、成膜助剂对乳胶漆耐洗擦性能的影响。试验发现增加颜料和填料用量,降低乳胶漆的耐洗擦性能,使用玻璃化温度低,弹性大,极性低的乳液聚合物,乳胶漆耐洗擦性能提高越明显;同时还发现使用成膜助剂可以显著改善乳胶漆的耐洗擦性能。 相似文献
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乳液聚合法制备全氟碳涂料及性能的研究 总被引:2,自引:0,他引:2
以自制的全氟丙烯酸酯单体 ,经乳液聚合的全氟丙烯酸酯乳液共聚物配制的全氟碳乳液涂料 ,其耐水性、耐碱性等均优于传统的丙烯酸酯乳液涂料 相似文献
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建筑反射隔热保温涂料的研制 总被引:1,自引:1,他引:1
介绍了以有机硅改性丙烯酸乳液为基料,不透明聚合物、空心微珠和红外辐射功能颜填料制备建筑反射隔热保温涂料的工艺技术,研究了几种功能颜填料及涂料体系的PVC值对涂料隔热保温性能的影响,乳液T_g值及阻燃剂对涂料耐沾污性和阻燃性能的影响。 相似文献
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The light-scattering coefficient S of coatings formulated from a mixture of an inorganic pigment and polystyrene latex particles may be enhanced significantly when the dry coating is heated in order to cause sintering of the polystyrene spheres. The relative increase in S depends on the size and the amount of the latex particles and the type of the inorganic pigment. Of the latexes examined (0.5, 0.2, 0.1, and 0.03 μm in diameter) the 0.2μm latex is the most effective in blends with platelike delaminated clay. The coatings based on spherelike precipitated calcium carbonate are less responsive to the heat treatment. The gloss of the clay–latex coatings is not significantly altered by the heat treatment up to 20 pph of latex; the gloss of the calcium carbonate coatings generally decreases upon heating. 相似文献