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SBS/蒙脱土复合材料的制备及其性能Ⅱ.复合材料的性能 总被引:3,自引:0,他引:3
分别采用大分子溶液插层法和大分子熔融插层法制备了苯乙烯-丁二烯-苯乙烯共聚物(SBS)/蒙脱土纳米复合材料.研究了材料的力学性能。纳米结构的形成对复合材料的性能产生显著影响,少量蒙脱士的引入可以明显改善SBS/蒙脱土复合材料的力学性能。无论溶液插层法制备的星型SBS/蒙脱土纳米复合材料,还是熔融插层法制备的线型SBS/蒙脱土纳米复合材料,其拉伸强度和断裂伸长率都同时增加。其中,溶液插层法制备的纳米复合材料的拉伸强度和断裂伸长率分别较纯SBS增加了75%和55%;熔融法制备的纳米复合材料的托伸强度和断裂伸长率分别较纯SBS增加了70%和18%。 相似文献
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采用阳离子交换的方法对蒙脱土进行了有机化处理,使蒙脱土由亲水性变成亲油性,并且使其层间距由原来的1.48nm扩大到2.33nm。采用X射线衍射仪研究了有机蒙脱土在酚醛树脂中的剥离行为,制备了酚醛树脂/蒙脱土纳米复合材料并测试了其层间剪切性能和烧蚀性能。实验结果表明,酚醛树脂与有机蒙脱土的相容性好,蒙脱土在酚醛树脂中完全剥离;酚醛树脂/蒙脱土纳米复合材料的层间剪切性能和烧蚀性能与纯酚醛树脂固化物相比有不同程度的提高和改善。 相似文献
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环氧树脂/蒙脱土纳米复合材料的制备与剥离机理研究进展 总被引:2,自引:0,他引:2
阐述了蒙脱土的性质及其在基体树脂中的剥离机理、环氧树脂/蒙脱土纳米复合材料的制备方法。原位插层复合法是制备环氧树脂/蒙脱土纳米复合材料最常用的方法;有机改性剂、固化剂及固化条件会对蒙脱土在环氧树脂中的剥离与插层行为产生影响;环氧单体聚合过程中产生的弹性力是使蒙脱土片层发生剥离的主要原因。重点介绍了近几年来制备高度剥离型纳米复合材料的方法和工艺,指出蒙脱土在复合材料中的完全均匀剥离仍然是现阶段有待解决的关键问题。 相似文献
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SBS纳米复合材料的制备研究现状 总被引:4,自引:2,他引:4
介绍目前国内外SBS纳米复合材料的研究现状,重点介绍用蒙脱土和白泥制备SBS纳米复合材料的原理和方法,包括蒙脱土和白泥的精制改性、蒙脱土与高聚物的复合方法、复合熔融插层法和溶液插层法蒙脱土/SBS纳米复合材料的制备以及改性白泥和改性纳米层状白泥/SBS纳米复合材料的制备。指出制备耐热聚合物纳米粒子对SBS进行填充改性或采用纳米复合技术在SBS中引入纳米无机相进行增强反应是SBS纳米复合材料的研究方向。 相似文献
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The epoxy resin/curing agent/montmorillonite nanocomposite was prepared by a casting and curing process. The intercalation and exfoliation behaviors of epoxy resin in the presence of organophilic montmorillonite were investigated by X‐ray diffraction (XRD) and dynamic mechanical thermal analysis (DMTA). For the diethylenetriamine curing agent, the intercalated nanocomposite was obtained; and the exfoliated nanocomposite would be formed for tung oil anhydride curing agent. The curing condition does not affect the resulting kind of composite, both intercalation or exfoliation. For intercalated nanocomposite, the glass transition temperature Tg, measured by DMTA and affected by the curing temperature of matrix epoxy resin is corresponded to that of epoxy resin without a gallery. The α′ peak of the loss tangent will disappear if adding montmorillonite into the composite. It was also found that the Tg of the exfoliated nanocomposite decreases with increasing montmorillonite loading. © 2002 John Wiley & Sons, Inc. J Appl Polym Sci 84: 842–849, 2002; DOI 10.1002/app.10354 相似文献
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运用自制的有机蒙脱土,采用浇模固化成型法制备环氧树脂/二乙烯三胺/有机蒙脱土纳米复合材料,对固化产物利用XRD(X射线衍射)分析有机蒙脱土的层间距变化,确定产物为插层型的纳米复合材料,并用DSC(差示扫描量热法)跟踪环氧树脂固化行为。运用Kissinger,Flynn-Wall-Ozawa,Crane方法对环氧树脂的固化反应过程进行分析,求出活化能和反应级数等动力学以在数。结果发现,加入有机化蒙脱土后使固化反应活化能和频率下降,从而有利于固化工艺的实现,便于纳米复合材料实际应用。 相似文献
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通过原位插层聚合方法在苯酚与甲醛缩合反应过程中引入层状钠基硅酸盐粘土,得到1种纳米粘土改性酚醛树脂的结合剂。通过X-射线衍射、透射电子显微镜等手段表征了所制备的纳米粘土改性酚醛树脂结合剂中粘土片层的分散状态。采用这种结合剂所制得的无定形捣打料和铝碳砖的耐压强度以及抗弯刚度均得到较大提高。 相似文献
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环氧树脂/蒙脱土纳米复合材料的制备及性能 总被引:4,自引:0,他引:4
实验采用长链烷基胺对原始蒙脱土进行有机化处理,再利用环氧树脂对有机蒙脱土插层,制得环氧树脂,蒙脱土纳米复合材料。实验表明,改性环氧树脂的冲击强度有所提高。 相似文献
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Structure and properties of phenolic resin/nanoclay composites synthesized by in situ polymerization
An in situ semibatch polymerization process for making phenolic resin/montmorillonite clay nanocomposites is developed. It is found that auxiliary mixing in phenol allows intercalation of the monomer and polymer between montmorillonite clay layers. At 2.7% clay by mass the montmorillonite is predominantly exfoliated (fully dispersed). At higher clay loading, a substantial amount of the clay remains in aggregate or intercalated form. When the montmorillonite is exfoliated, the material is mechanically superior. The composite has a tensile modulus that is 21% higher than the neat resin and has 87% improved fracture strength, 100% larger fracture energy, and strain to failure 13% above the pure resin. Thermogravimetric analysis shows the montmorillonite system maintains its thermal stability up to 200°C. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 95: 1169–1174, 2005 相似文献
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剥离型酚醛树脂/蒙脱土纳米复合材料研究 总被引:8,自引:0,他引:8
用十六烷基三甲基溴化铵(CTAB)对蒙脱土进行了有机化处理,使蒙脱土由亲水性变成亲油性。采用XRD、FTIR及TEM研究了有机蒙脱土及其在酚醛树脂中的剥离行为,制备了酚醛树脂/蒙脱土纳米复合材料并测试了其层间剪切性能和烧蚀性能。实验结果表明,经CTAB处理的蒙脱土与酚醛树脂具有良好的相容性,且CTAB的含量较多时所制得的有机蒙脱土的结构较好,根据Bragg方程计算,CTAB用量超过蒙脱土量50%时,蒙脱土的片层间距由原来的1.48 nm增加到2.33 nm;有机蒙脱土用量小于5%时生成完全剥离型酚醛树脂/蒙脱土纳米复合材料;与碳布增强酚醛树脂复合材料相比,碳布增强酚醛树脂/蒙脱土纳米复合材料的力学性能和烧蚀性能均有一定的提高和改善,层间剪切强度随蒙脱土含量的增多而增大,蒙脱土用量为15%时,层间剪切强度提高了27.1%,线烧蚀率在用量为3%时降低了48.5%,质量烧蚀率变化不明显。 相似文献
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Organoclays assisted vat and disperse dyeing of poly(ethylene terephthalate) nanocomposite fabrics via melt spinning
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Abdalla A. Mousa Yehya A. Youssef Wael S. Mohamed Reham Farouk Elisabeth Giebel Michael R. Buchmeiser 《Coloration Technology》2018,134(2):126-134
Polyethylene terephthalate nanocomposites containing six modified montmorillonite nanoclays were prepared by a melt compounding technique. The effect of intercalated compounds of montmorillonite on textile mechanical properties of resultant polyethylene terephthalate nanocomposite fabrics was investigated. Winding was not possible, when the polymers were first compounded with the desired amount of montmorillonite and then spun, as filament breakage occurred. Spinable polymer were only obtained by mixing polyethylene terephthalate master batches with 4 wt% montmorillonite, which contained tallow intercalating compound with pure untreated polyethylene terephthalate to a montmorillonite content of 0.5 wt%, thus decreasing the concentration of thermally degraded polymer chains. After spinning the fibres were drawn and knitted into fabric samples for further testing. The prepared polyethylene terephthalate nanocomposite fabrics using montmorillonite exhibited higher colour strength using vat and disperse dyes compared with those of the reference fabrics made from fibres spun without montmorillonite clay content and regular fabrics. The carbocyclic‐based vat dyes have higher colour strength values on polyethylene terephthalate nanocomposite fabrics if compared with heterocyclic‐based vat dyes. The colour fastness ratings for both vat and disperse dyeings secured very good to excellent washing and perspiration fastness on polyethylene terephthalate nanocomposite fabrics. All dyed fabrics showed excellent light fastness using vat and disperse dyes. The preparation of polyethylene terephthalate nanocomposite fabrics with improved textile mechanical and vat dyeing properties needs further investigations. 相似文献