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导电聚合物复合材料的发展 总被引:4,自引:0,他引:4
综述了有关导电聚合物复合材料的研究。讨论了不同导电聚合物复合材料的导电性、光学特性、电化学特性、力学性能以及它们的不同结构形貌。分析了复合材料制备工艺对其结构及性能的影响。 相似文献
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炭黑填充聚合物导电复合材料的研究和应用概术 总被引:1,自引:0,他引:1
概述了目前国内外炭黑填充聚合物导电复合材料的研究现状及应用。主要对炭黑填充聚合物复合材料的导电性能、正负温度效应尤其是低碳含量炭黑填充聚合物抗静电材料进行了讨论。 相似文献
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影响填充型导电聚合物复合材料导电性的诸因素 总被引:4,自引:0,他引:4
填充型导电聚合物复合材料的导电性受许多因素的影响。本文对这些因素,如导电填料的添加量、材料形态和类型、填料在聚合物中的分散状态、聚合物母体的性能、材料的制备方法等均作了简要的介绍。 相似文献
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填充型导电高分子材料的研究进展 总被引:6,自引:0,他引:6
简要介绍了导电聚合物的分类及特点.重点论述了填充型导电高分子材料的分类、导电机理以及提高其导电稳定性的方法,并对填充型导电复合材料的发展方向提出了建议。 相似文献
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从聚合物/碳黑(CB)气敏导电复合材料的研究体系、气敏响应性能的影响因素、气敏响应机理三方面综述了近年来聚合物/CB气敏导电复合材料研究的新进展,讨论了目前研究尚存在的一些不足之处,并展望了聚合物/CB气敏导电复合材料的今后研究发展方向。 相似文献
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文章综述了导电聚合物/无机纳米复合材料最新研究进展,全面介绍了导电聚合物/无机纳米复合材料的制备方法、材料性能及应用,并对此类复合材料将来的研究方向和发展趋势进行了展望. 相似文献
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石墨烯/导电聚合物复合材料不仅具有石墨烯优异的屏蔽性能和导电聚合物良好的氧化还原特性,还能协同发挥二者的功能,在金属防腐蚀领域有着巨大的应用潜力。本文综述了石墨烯/导电聚合物复合防腐蚀材料的制备方法,包括电化学方法、化学氧化法、分散液混合法和化学气相沉积法(CVD);并全面总结了石墨烯/导电聚合物复合材料在防腐蚀涂层中的应用及性能。制备的石墨烯/导电聚合物复合材料可以通过电化学方法、溶剂挥发法制成石墨烯/导电聚合物防腐蚀薄膜涂层,还可以混入成膜物树脂中制备树脂复合防护涂层。讨论了石墨烯/导电聚合物在制备过程、薄膜涂层和树脂复合涂层应用中的优势与不足,提出了构建结构可控、综合性能好的复合防腐涂层是石墨烯/导电聚合物复合防腐蚀材料的未来主要发展趋势。 相似文献
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C.-M. Chan 《Polymer Engineering and Science》1996,36(4):495-500
A novel method was developed for the preparation of high-resistivity conductive polymer composites reproducibly. The conventional method which involves the simple mixing of a conductive filler and a polymer usually produces a conductive polymer composite having a loading curve with a region in which the resistivity changes rapidly as the filler concentration changes. Hence, it is very difficult to obtain reproducible materials in that region. This newly developed method involves the preparation of a conventional conductive polymer composite, which is prepared by the simple mixing of carbon black and a polymer as the first step. The resulting compound, which is crosslinked by either electron-beam radiation or a chemical-crosslinking agent, is ground into a fine powder (composite filler) with the particle size less than 250 microns. The composite filler is mixed with another polymer to form a conductive particulate composite which has a loading curve showing a more gradual change of resistivity as a function of filler concentration. The modification of the loading curve is controlled by the resistivity, the shape, and the size of the composite filler. 相似文献
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The rise of miniaturized, integrated, and functional electronic devices has intensified the need for heat dissipation. To address this challenge, it is necessary to develop novel thermally conductive polymer composites as packaging materials. In this paper, a number of factors for the construction and design of thermally conductive polymers are concluded. Special attention is focused on the analysis and comparison of the thermally conductive composites prepared by various fillers or strategies to provide guidelines and references for future design of composite materials. The current commonly used preparation strategies of thermally conductive polymer are summarized, such as using a variety of fillers, vacuum filtration, template method, and so on. The challenges of thermally conductive polymer composites are finally sketched. This review can inspire the design of polymer composites with brilliant thermal conductivity. 相似文献
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以EVA为高分子聚合物,采用不同级别的导电炭黑,研究了导电炭黑填充高分子聚合物的导电性,讨论了不同级别和不同用量的导电炭黑在聚合物中的分散性,以及对高分子聚合物导电性的影响。实验结果表明,导电炭黑高分子聚合物的导电性主要取决于不同级别的导电炭黑的表面性和结构等特性、炭黑的不同用量以及导电炭黑的聚集体在高分子聚合物的分散程度。 相似文献
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Anion conductive polymer nanofiber composite membrane: effects of nanofibers on polymer electrolyte characteristics
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Polymer composite membranes composed of anion conductive polymer nanofiber mats and the corresponding polymer matrix were prepared and characterized for future alkaline fuel cells. In this paper, electrospinning was attempted to fabricate anion conductive nanofiber mats. The anion conductivity of the composite membrane was higher than the corresponding membrane without nanofibers under all conditions due to outstanding anion conductive characteristics of the nanofibers. In addition, because of the rigid and anisotropic structure of the nanofibers, membrane stabilities such as reductive degradation resistance and mechanical strength were very much improved. The gas permeability and excessive hydration swelling that will degrade fuel cells after long‐term operation were suppressed in the nanofiber composite membrane. These results indicated that excellent properties of the anion conductive nanofibers were demonstrated even in the composite membrane, leading to the potential application of anion conductive nanofibers in future fuel cells. © 2016 Society of Chemical Industry 相似文献