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聚氨酯反应注射成型固化过程数值模拟 总被引:2,自引:0,他引:2
依据反应动力学和能量守恒方程的基本理论,对聚氨酯反应注射成型的固化过程进行了合理的假设和必要的简化,建立了体系反应程度和温度的数学模型。采用显示有限差分法并结合数学软件Matlab对固化过程进行了动态模拟.结果表明:固化初始的20s内交联反应剧烈。体系迅速升至最高温度,交联度达到80%所需时间与经验值一致.约为17s。同时为优化反应注射成型工艺因素,探讨了催化剂浓度、原料初始温度和模具温度等对体系的影响。结果表明:催化剂浓度增加,使体系固化周期缩短,制品内部交联度的变化减小,但延长了制品处于高温部分的时间;模具温度主要影响制品壁面附近的反应,而物料初始温度则能影响到体系的最高温度,尤其是在低模温情况下更加明显. 相似文献
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气体辅助注射成型过程的数值模拟技术 总被引:4,自引:0,他引:4
本文描述了气体辅助注射成型过程中熔体充填及气体穿入的数学模型,采用有限元/控制体积法计算充填阶段的压力场,确定两类移动边界,熔体前沿和熔体-气体边界。并对典型制件进行模拟验证了模型的可行性。对不同成型参数如熔体充填百分比及气道直径的影响进行了研究,结果表明熔体充填百分比不够,使气体吹入薄壁,较高的充填比又会阻止气体进入气道;较大直径的气道较小直径的气体不易进入薄壁处。 相似文献
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庄俭;张亚军;吴大鸣;董鹏伟 《中国塑料》2011,25(3):61-64
以生物测试上广泛使用的微流控芯片为研究对象,研究使用聚合物微型注塑方法进行类似产品大规模、批量化生产的可能性。在建立微流控芯片结构模型的基础上,运用聚合物成型分析软件Moldllow对其在不同工艺参数下的成型过程进行了系统研究。结果表明,熔体温度的改变对充填时间的影响甚微,充填时间随着注射速度的增加而明显缩短,注射压力随熔体温度的增加而减小,随注射速度的增加而增加。增加熔体温度和注射速度可以降低翘曲变形。 相似文献
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A mathematical formulation and numerical simulation for non‐isothermal cell growth during the post‐filling stage of microcellular injection molding have been developed. The numerical implementation solves the energy equation, the continuity equation, and a group of equations that describe the mass diffusion of dissolved gas and growth of micro‐cells in a microcellular injection molded part. The “unit‐cell” model employed in this study takes into account the effects of injection and packing pressures, melt and mold temperatures, and super‐critical fluid content on the material properties of the polymer‐gas solution and the cell growth. The material system studied is a microcellular injection molded polyamide 6 (PA‐6) resin. Two Arrhenius‐type equations are used to estimate the coefficients of mass diffusion and solubility for the polymer‐gas solution as functions of temperature. The dependence of the surface tension on the temperature is also included in this study. The numerical results in terms of cell size across the sprue diameter agree fairly well with the experimental observation. The predicted pressure profile at the sprue location has also been found to be in good agreement with the dynamics of the cell growth. Whereas for conventional injection molding the pressure of the system tends to decay monotonously, the pressure profile in microcellular injection molding exhibits an initial decay resulting from cooling and the absence of packing followed by an increase due to cell growth that expands the polymer‐gas solution and helps to pack out the mold uniformly. Polym. Eng. Sci. 44:2274–2287, 2004. © 2004 Society of Plastics Engineers. 相似文献
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A two dimensional finite element model for the simulation of the advancing front in reaction injection molding (RIM) is presented. The model is based on the solution of the full Navier-Stokes equation for the computation of the velocity and pressure. The arbitrary Lagrange-Euler method is used for the moving front. The method of characteristics is used for the solution of the mass-and energy equations. An automatic remeshing algorithm is used to prevent element distortion and to optimize element size and number. Numerical results are presented for flow into a complex domain in order to illustrate the versatility of the method. 相似文献
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B. Abbgs R. Ayad J.-C. Prudhomme J.-P. Onteniente 《Polymer Engineering and Science》1998,38(12):2029-2038
A numerical study is carried out on the thermoplastic wheat starch injection molding process. The simulation is performed using currently available molding software to determine optimal molding parameters. The molding of a standardized sample for tensile test is considered. It is shown that the conventional continuum mechanics equations can be used for modeling the injection molding of thermoplastic starch. These equations are solved using the finite element method. Comparisons with some experimental results are presented, indicating good agreement. Data on the processing of thermoplastic starch and several other basic aspects are also provided. 相似文献
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Processing of microcellular foam was investigated for the feasibility of production of tough and lightweight polyurethanes. To increase the nucleation rate in a gas-supersaturated resin, ultrasonic excitation was applied to the mixture of polyol(polyether-based polyol) and isocyanate(diphenyl methane diisocyanate). A microcellular structure was produced by two sequential steps, i.e., supersaturationof the polyol resin with nitrogen gas at elevated pressure and ultrasonic bubble nucleation right after the impingement mixing of two components of the polyurethane system. Theoretical analyses based on nucleation theories were employed to predict the rate of nucleation in the gas-supersaturated polyurethane. The rate of nucleatio in the resin was predicted by classical nucleation and cluster theories. In the experimental investigation, ultrasonic excitation was applied to increase the nucleation rate in the resin that had been saturated by nitrogen at a saturation pressure < 2.0 MPa. 相似文献
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气辅成型技术能够有效地改善产品力学性能、提高产品的质量,因此在注射成型生产中应用广泛,与之相应的气辅成型CAE技术也得到了快速发展。当前的气辅成型CAE技术中假定空气为不可压缩流体,忽略了空气的可压缩性,因此研究气辅成型过程中可压缩空气的流动行为具有一定的实际意义。针对气辅成型过程中可压缩空气流动的复杂行为,基于假设将复杂的三维(3D)流动问题转化为二维(2D)。采用 CBS方法建立2D瞬态可压缩空气流动的有限元分析模型,求解算法采用预共轭梯度法,并用VC++完成了算法编制,实现了可压缩空气流动过程的数值模拟,其压力结果可作为充填流动分析的基础数据。 相似文献
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The linear low‐density polyethylene melt is described by the modified Cross model, the dependence of melt viscosity on temperature incorporated with the Arrhenius equation, and the Moldflow second‐order model in this investigation. The mass, momentum conservation, and constitutive equations are discretized and solved by using the iterative stabilized fractional step algorithm along with the Crank–Nicolson implicit difference scheme. The energy conservation equation is discretized with the characteristic Galerkin approach. The free surface of molten polymer flow front is tracked by the arbitrary Lagrangian–Eulerian (ALE) method. It is demonstrated that good agreement of the numerical predictions given by the proposed ALE method with the results obtained by the injection short‐shot experiments is achieved in the locations and shape of the melt front. Furthermore, when the melt front completely reaches the wall of the mold cavity, the horizontal velocity distribution of counterflow at the section near the finally filling wall is exhibited in the present simulation. POLYM. ENG. SCI., 2012. © 2011 Society of Plastics Engineers 相似文献
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The present study develops a numerical simulation program to predict the transient behavior of fiber orientations together with a mold filling simulation for short-fiber-reinforced thermoplastics in arbitrary three-dimensional injection mold cavities. The Dinh-Armstrong model including an additional stress due to the existence of fibers is incorporated into the Hele-Shaw equation to result in a new pressure equation governing the filling process. The mold filling simulation is performed by solving the new pressure equation and energy equation via a finite element/finite difference method as well as evolution equations for the second-order orientation tensor via the fourth-order Runge-Kutta method. The fiber orientation tensor is determined at every layer of each element across the thickness of molded parts with appropriate tensor transformations for arbitrary three-dimensional cavity space. 相似文献
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The radial flow of a chemically reactive fluid between two parallel circular disks during the process of Reactive Injection Molding (RIM) has been simulated in a decelerative, non-isothermal, transient flow environment. The effects of key operating and system parameters (feed temperature, volumetric flow rate, reaction rate, and cavity thickness) on velocity, conversion, and temperature profiles which occur in this decelerative flow environment were determined. A catalyzed, unfilled polyurethane RIM system was modeled by a linear step polymerization scheme using average literature values for the reaction rate, and thermodynamic and constitutive parameters. The numerical solution was achieved using the method of lines and upwind approximations of the spatial derivatives. The geometry studied (two parallel, center gated circular disks) models flow patterns in commercial RIM processes more realistically than the rectangular flow between two parallel surfaces (studied by previous workers) in which the average velocity is constant along the length of the mold. This simulation predicts the accumulation of high polymer near the entrance to the mold and near the outer edge of the cavity in fast reactive systems. The accumulation of material near the gate results in viscous heat generation and a maximum in temperature in the region immediately downstream from the restriction. 相似文献
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The injection-molding process consists of three consecutive stages: filling, packing, and cooling. In order to obtain some insight into the phenomena involved in the process, and particularly in order to evaluate the moldability of certain resins and to predict the microstructure and properties of products molded therefrom, a number of workers have employed a variety of techniques based on mathematical simulation of the process. Mathematical simulation involves writing the relevant continuity, momentum, and energy equations governing the system, with appropriate boundary and initial conditions representing the prevailing conditions in the cavity and delivery channels. In order to obtain meaningful solutions to the above equations, detailed information is required regarding the thermodynamic, thermal, and rheological properties of the resin. Moreover, the prediction of the microstructure and ultimate properties of the molded article requires a knowledge of the morphological, crystallization, and orientation phenomena that take place under the influence of the thermo-mechanical history experienced by the resin. The complexity of the equations involved results in the utilization of a number of simplifying assumptions and the resort to computer simulation and numerical solutions of these equations. A variety of numerical schemes based on finite difference and finite element methods has been employed by various researchers. 相似文献