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研究了钴对钼丝的拉伸性能及其加工硬化的影响。对加工态和退火态纯钼丝及掺杂结构钼丝的金相组织、力学性能进行观察和分析,发现钼中加钴提高了钼丝的加工硬化率,降低了再结晶温度,并且明显改善了退火钼丝的室温延性。因此,掺钴钼丝是一种性能优良的丝材。 相似文献
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<正> 高温钼丝是在纯钼中添加了微量硅、铝、钾的新型电光源材料。它具有优异的高温性能,其再结晶温度比纯钼高600℃以上,再结晶组织为长晶且呈燕尾状搭接,故再结晶后的强度、延性远优于纯钼,特别是其抗弯折性能更优,因而它取代纯钼丝作特种灯泡的引出线能使制灯成材率大幅度提高,完全有可能在特灯行业取代纯钼丝。此外,由于高温钼丝的优异性能,它还将在其它领域 相似文献
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本文通过扫描电镜,俄歇谱仪和金相显微镜等手段,对掺杂钼和纯钼的粉,条乃至丝材,进行横、纵向观察,其结果表明,掺杂钼丝的再结晶温度比纯钼丝高,在1800℃以上仍保持着良好的机械性能。文章初步探讨了高温退火处理后,仍具有良好机械性能的机制。研究表明:掺杂钼丝经高温退火后,晶粒表面形成了规则排列的钾泡,阻碍了掺杂钼丝再结晶晶粒的横向长大。使晶粒沿丝轴方向和无钾泡处生长,形成锯齿形长晶,这种晶粒间相互啮合搭接,导致了高温退火后的掺杂钼丝具有良好的塑性和弯曲性能;并且钾泡行密度和长度愈大,则再结晶晶形比值L/W(L为再结晶晶粒长度,W为宽度)愈大,其机械性能也愈好。 相似文献
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据1992第3期《钨钼材料》报道,成都东方电子材料总厂研制出MoG和MoH两种耐高温高强度钼丝.MoG是在纯钼基础上添加微量稀土元素,MoH则添加微量钾等掺杂元素.与纯钼比其特点:具有较高的再结晶温度和良好的再结晶组织结构;经高温处理后有良好的韧性;随退火温度的增加强度下降缓慢;加工性能优良,能承受较大的压缩比拉丝加工.MoG已投入批量生产.(昱中乐) 相似文献
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Si、Al、K掺杂钼丝的组织和性能研究 总被引:1,自引:0,他引:1
通过透射电镜(TEM)、扫描电镜(SEM)、能谱分析(EDS)对Si、Al、K掺杂烧结钼条和退火钼丝的组织形貌进行了跟踪检测分析;通过DSC和硬度试验检测Si、Al、K掺杂钼丝的再结晶温度;通过热模拟试验对纯钼条和Si、Al、K掺杂钼条的高温综合力学性能进行了对比分析.结果表明:Si、Al、K掺杂使钼条的高温综合力学性能得到了明显的改善;在本试验条件下,Si、Al、K掺杂使钼丝的再结晶温度提高约550~600℃,再结晶后由长径比大的晶粒形成燕尾搭接状链锁结构组织;Si、Al、K掺杂钼丝的强化相是K泡和硅酸铝钾颗粒. 相似文献
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本文研究了La2O3对钼烧结坯力学性能的影响。将纯钼及不同La2O3含量的ODS钼合金在1500℃和2050℃真空退火后,测试其力学性能。结果表明,添加La2O3后,无论是轧制状态还是高温退火后,材料的抗拉强度均显著高于相同加工状态的纯钼。La2O3强化钼合金的再结晶温度显著提高,因此具有优异的高温性能,从而改善了材料从高温加热回复至室温的低温脆性。 相似文献
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Siliconnitrideceramichasaseriesofexcellentproperties,forexample,highstrength,highhardness,wear,corrosion,oxidationandshockresistanceetc.,andisakindofhightemperaturestructuralmaterialwithenormouspotentialitiesforfuturedevelopment.Buthighcostfor… 相似文献
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Inviewofenergysavingandenvironmentalpro tection ,magneticrefrigerationnearroomtemperaturehasastrongimpactonconventionalgascompressiontechnology .However ,coolingefficiencyofthesystemformagneticrefrigerationismainlydecidedbythemagnitudeofmagnetocaloriceffectformagneticrefrig eratingmaterialsinthesystemunderacertainmagnet icfieldchange .Therefore ,developmentofnewrefrig eratingmaterialswithgreatmagnetocaloriceffectnearroomtemperatureisespeciallyimportant .Therearetwoparameterswhichareusedtochara… 相似文献
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���� ���ɹ��� 《钢铁研究学报》2013,25(9):19-23
In order to accurately control the rare earth content in liquid steel in electroslag remelting (ESR) process, according to the ion and molecule coexistence theory (IMCT) of slag structure and corresponding phase diagrams, a thermodynamic calculating model for the evaluation of mass action concentrations (designated by Ni for structure unit i) for La2O3-Al2O3-CaF2 slag system was formulated. The results show that the calculated values of NLa2O3 are in good agreement with the reported measured values, indicating that this calculating model can wholly embody the characteristics of the slag system. The activity of La2O3 decreases with the increasing of the Al2O3 and CaF2 content, and Al2O3 is stronger than CaF2 in decreasing the activity of La2O3. But the activity of La2O3 increase with the increasing in temperature at the composition range of 30% La2O3, 20% Al2O3, 50% CaF2. Above all, the activity of La2O3 in La2O3-Al2O3-CaF2 slag system can be quantitatively analyzed by this thermodynamic model, and this model can provide a theoretical basis for precisely controlling the lanthanum content in molten steel in ESR process. 相似文献
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以石英为先驱体,以液态铝为还原剂,在1073~1523 K的温度范围内对原位生成铝/氧化铝复合材料进行了研究,对获得的复合材料的物理和机械性能做了测定,并对材料显微结构进行了观测和分析.在1473K制备的铝/氧化铝复合材料密度为2.95g/cm3,最大弹性模量为130 GPa,最大三点抗弯强度为580 MPa,最大拉伸强度为268 MPa,洛氏硬度为86.产物铝/氧化铝复合材料的形状与作为先驱体的二氧化硅的形状几乎一致.讨论了反应过程的动力学. 相似文献
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Thermodynamic analysis of binary and ternary oxide systems containing the oxide La2O3 permits the formulation of a database of energy parameters in the theory of subregular solutions for oxide melts adjacent to the region of existence of metallic melts in the phase diagram of the system. The temperature dependence of the equilibrium constants for the heterogeneous reduction of steel is established. The solubility surfaces of components in oxygen-bearing steel are plotted for the Fe–Al–La–O–C, Fe–Ca–La–O–C, Fe–Mg–La–O–C, Fe–Si–La–O–C, and Fe–Cr–La–O–C systems. Diagrams are plotted for the complex reduction of steel by alloys and mixtures containing active and alloying elements: Ca, Mg, Si, Al, Cr, and La. Analysis is undertaken for thoroughly reduced and sulfur-free steel. With the usual reduction system, in which rare-earth metals are added to the steel after the introduction of calcium, silicon, and aluminum, the inclusions that form—consisting of a conglomerate of calcium and magnesium aluminates—provide the substrate for the deposition of small fractions, actively interact with the liquid component of the inclusions, and dissolve in the liquid component. Therefore, La2O3 is not present as an independent phase in the metallic inclusions. 相似文献
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Eu2+/Sm3+co-doped dual-emitting Sr4La(PO4)3O phosphors were synthesized through a convenient high temperature solid state reaction in reductive atmosphere.The structure,luminescence,energy transfer and temperature-dependent luminescence properties of Eu2+/Sm3+co-doped Sr4La(PO4)3O phosphors were researched and analyzed in detail.The blue emission of Eu2+and the red emission of Sm3+can work together as FIR signals.Based on the different response characteristics of these two ion emissions to temperature,Sr4La(PO4)3O:Eu2+/Sm^(3+)phosphor achieves the relative sensitivity of0.48384%/K and a wide range of temperature measurements from room temperature to 573 K.The results reveal that the Sr4La(PO4)3O:Eu2+/Sm3+phosphor has application prospect in the field of high temperature optical thermometry.The energy transfer mechanism is proved to be the dipole-dipole interaction between Eu2+and Sm3+ions. 相似文献
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碳热还原氮化制备氮化硅粉体反应条件研究 总被引:1,自引:0,他引:1
对二氧化硅碳热还原氮化合成氮化硅的反应体系进行了热力学和动力学分析,主要研究了反应温度和氮气流量对Si3N4、Si2N2O和SiC生成的影响。热力学研究表明,Si3N4的生成需要足够高的温度(高于1800K)和充足的氮气气氛;Si2N2O的生成条件是较低的温度(低于1700K)和不充足的氮气气氛;SiC的生成条件是更高的温度(高于2000K)和不充足的氮气气氛。试验研究验证了热力学的分析,并确定了碳热还原氮化合成氮化硅的主要工艺条件(氮气流量为3L/min、煅烧温度为1500℃)。在以上工艺条件下,可制备出纯的Si3N4粉体。 相似文献
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为适应精炼钢包用耐火材料轻量化的发展需要,采用两步烧结法向Al_2O_3-MgO-CaO系复相耐火材料中添加La_2O_3,并对该耐火材料的抗LF精炼渣侵蚀性能进行了研究。结果表明,添加的La_2O_3优先固溶入Al_2O_3-MgO-CaO系复相耐火材料的晶相CaO·6Al_2O_3中,促使CaO·6Al_2O_3晶胞产生晶格畸变,有效抑制了CaO·6Al_2O_3晶粒沿基面的异常长大,进而有效地促进了Al_2O_3-MgO-CaO系复相耐火材料的烧结致密化。当添加La_2O_3的质量分数为4%,在1600℃保温2h烧成后,试样的气孔率由占总体积分数的19.2%下降至6.1%,体积密度由2.78g/cm3上升至3.18g/cm3,制得了含MgO·Al_2O_3、CaO·2Al_2O_3、CaO·6Al_2O_3晶相且呈现交织分布、显微结构致密的Al_2O_3-MgO-CaO系复相耐火材料,其抗LF精炼渣侵蚀性能与同等致密度的Al_2O_3-MgO质耐火材料相当。 相似文献