CeO_2缓冲层对蓝宝石基Ba_(0.6)Sr_(0.4)TiO_3薄膜结构和介电性能的影响

利用磁控溅射法制备Ce O_2缓冲层,通过脉冲激光沉积法制备Ba_(0.6)Sr_(0.4)TiO_3(BST)薄膜,在Al_2O_3(11—02)蓝宝石基片上构架了Pt/BST/Ce O_2/Al_2O_3和Pt/BST/Al_2O_3叉指电容器,对比研究了Ce O_2缓冲层对BST薄膜结构和叉指电容器介电性能的影响。通过X射线衍射仪、原子力显微镜和LCR表分别对叉指电容器的结构、表面形貌和介电性能进行了表征。实验发现,直接沉积在蓝宝石上的BST薄膜为多晶结构,生长在Ce O_2缓冲层上的BST为(001)取向的高质量外延薄膜。生长在Ce O_2缓冲层上的BST薄膜相对于没有缓冲层的BST薄膜具有更小的晶粒和均方根粗糙度。在40 V偏置电压下,Pt/BST/Al_2O_3和Pt/BST/Ce O_2/Al_2O_3叉指电容器的调谐率分别是13.2%和25.8%;最小介电损耗为0.021和0.014。结果表明Ce O_2缓冲层对生长在蓝宝石基片上的BST薄膜结构和介电性能具有重要影响。     

BST溶胶及其纳米晶铁电薄膜特性研究

考察了在溶胶-凝胶(Sol-Gel)工艺中化学添加剂对钛酸锶钡(BST)溶胶的粒度分布的影响。通过对化学添加剂的优选,制备出具有优异电性能的BST薄膜。X-射线衍射(XRD)表明在Pt/Cr/SiO2/Si衬底上制备的BST薄膜具有完整的钙钛矿结构,AFM表面形貌显示BST薄膜表面致密、平整、无裂纹,平均晶粒尺寸约50 nm。漏电流测试表明BST薄膜在0~9 V的外加偏压下始终保持着较低的漏电流,在外加偏压为8.8 V时,漏电流密度为2.9×10-6A/cm2。     

钛酸锶钡热释电薄膜及其非制冷红外探测器研究

开展了钛酸锶钡(BST)热释电薄膜材料制备工艺研究,及其在单元器件和焦平面器件中的应用研究.在删Pt/Ti/SiO2/Si衬底上,用倒筒靶射频溅射方法制备了BST热释电薄膜.通过低温缓冲层技术和调控自偏压的方法,降低了BST薄膜的生长温度,提高了BST薄膜的c轴取向度和耐压特性,解决了薄膜制备的均匀性和一致性问题,使薄膜热释电系数达到6.7×10-7Ccm-2K-1.利用微细加工的方法,制备出全集成的BST薄膜单元红外探测器,抗过载能力强,探测器达到8×107cmHz1/2W-1,可以满足"灵巧弹药"的使用要求.实验表明,制备BST热释电薄膜的工艺不会对新型的耐高温读出电路造成破坏,为研制高性能的BST薄膜型焦平面探测器奠定了基础.     

LSMCD法制备梯度BST铁电薄膜的工艺研究

研究了利用液态源雾化化学沉积(LSMCD)法制备梯度钛酸锶钡(BST)薄膜的工艺。该方法既可以较精确的控制薄膜的化学计量比及掺杂浓度,又可采用控制超声雾化沉积的时间和次数来有效的控制膜厚及晶粒的大小。X-射线衍射(XRD)和扫描电镜(SEM)分析表明:沉积8次,采用常规退火方式,在Pt/Ti/SiO2/Si衬底上能成功制备出具有钙钛矿结构的、晶粒粒径约80 nm、厚约850 nm的梯度BST薄膜。该BST梯度薄膜在常温下介电常数达526,介电损耗约为0.06,矫顽场强约为100 kV/cm,剩余极化强度约为10μC/cm2,饱和极化强度约为20μC/cm2,在各个领域都具有广阔的应用前景。     

退火温度对铁电薄膜钛酸锶钡的影响

用醋酸盐和钛酸酯为原料，采用改进的Sol—gel工艺在Pt／Ti／SiO2／Si基片上制备出Ba0.6Sr0.4TiO3(BST)铁电薄膜，然后进一步对薄膜进行退火实验：对(110)方向生长BST薄膜在550～750℃进行恒温退火。X射线衍射分析表明：退火温度在650℃以上时，BST薄膜转变为较为完整的ABO3型钙钛矿晶体结构，更高的退火温度将提高晶体的取向度。     

利用Ba0.65Ru0.35TiO3缓冲层制备高热释电系数的Ba0.65Sr0.35TiO3薄膜

采用射频溅射,在Ba0.65Sr0.35TiO3(BST)薄膜和Pt/Ti/SiO2/Si衬底之间制备10 nm的Ba0.65Ru0.35RUO3 (BSR)缓冲层,研究了BSR缓冲层对BST薄膜结构和性能的影响.与没有BSR缓冲层的BST薄膜相比,BSR缓冲层可使BST薄膜呈高度a轴择优取向生长,改善了薄膜的介电常数,降低了薄膜的漏电流密度,使其热释电系数达到7.45×10-1 C cm-2 K-1.表明利用BSR缓冲层可以制备高热释电性能的BST薄膜.     

溶胶–凝胶法制备BST薄膜的结晶特性研究

采用改进的溶胶–凝胶(sol-gel)工艺配制了(Ba0.65,Sr0.35)TiO3(BST)溶胶。利用旋转涂覆工艺将BST溶胶涂覆在SiO2/Si衬底上,在不同的热处理条件下制备出BST薄膜。XRD分析结果表明:制得的BST薄膜形成了单一钙钛矿结构;AFM测试结果表明,BST薄膜表面平整致密,无裂纹。表面均方根粗糙度为3~6nm,晶粒大小分布均匀,直径约为40~100nm。随着热处理温度的提高,BST薄膜的晶粒变大,表面粗糙度变大。     

化学溶液法制备的Ba0.9Sr0.1TiO3薄膜的结构及光学特性研究

采用高度稀释的前驱体溶液在LaNiO3(LNO)薄膜上沉积了Ba0.9Sr0.1TiO3(BST)薄膜。X-射线衍射分析表明BST薄膜呈高度的（100）择优取向。原子力显微镜测量发现制备的BST薄膜具有大的晶粒尺寸80-200nm。用椭偏光谱仪测量了光子能量为0.7-3.4eV范围内BST薄膜的椭偏光谱，用Cauchy模型描述BST薄膜的光学性质，获得了BST薄膜的光学常数谱和禁带宽度Eg=3.36eV。     

倒筒式射频溅射频偏压对Ba0.65Sr0.35TiO3热释电薄膜结构及性能的影响

采用倒筒式射频溅射方法,在Pt、Ti/SiO2/Si基片上制备了Ba0.65Sr0.35TiO3(简称BST)薄膜.研究了自偏压对BST薄膜结构及电学性能的影响.在较高自偏压下制备的BST薄膜具有高度的(100)择优取向,且结晶性好,表面平整,耐压能力强.在25℃时薄膜的热释电系数高达6.73×10-7C.cM-2.K-7.研究结果表明,利用倒筒式射频溅射方法适当提高自偏压,可以制备出热释电性能优良的BST薄膜.     

Mn掺杂BST薄膜的制备与表征

采用醋酸水溶液体系溶胶－凝胶法制备了未掺杂和掺Mn(II）钛酸锶钡（BST）薄膜。用这种方法。可在BST体系中容易地加入任何浓度的金属离子，并可在室温下长期保存，根据X－射线衍射图（XRD）和表面形貌，薄膜的晶化温度取为650－750℃，根据掺Mn BST的Mn2p3/2X－射线光电子能谱（XPS）图中Mn2p3/2的峰位置，显示出薄膜中Mn的价态与加入Mn(II)离子价态相同，根据结合能的峰移，可以得到掺Mn BST的费密能级降低0．7eV.I-V特性和介电特性测试表明，掺Mn(II)BST的漏电流明显降低，相对的介电常数增加，损耗角正切降低0．01，根据漏电性质，介电常数和损耗的关系，2％（摩尔分数）的Mn掺杂的BST薄膜适合于低频小信号（2V以下，约500kHz)应用，而高浓度的Mn掺杂适合于大信号较高频率（1MHz以上）应用。     

Dielectric Characteristics of Ba0.65Sr0.35TiO3 Thin Films by Sol-Gel Method

Ferroelectric Ba0.65Sr0.35TiO3 (BST) thin films on the Pt/Ti/SiO2/Si substrate have been successfully prepared by sol-gel. Such films have approximately 300 nm thicknesses with a remnant polarization of about 2.95 C/cm2 and a coercive field of about 21.5 kV/cm. The investigations of X-ray diffraction and atomic force microscopy show that the BST films annealed at 650 ℃ exhibit a tetragonal structure and that the films dominantly consist of large column or grains of about 89 nm in diameter. The curves of the temperature dependence of dielectric coefficient in different frequencies display the curie transition at the temperature around 23 ℃. The dielectric loss tangent of BST thin films at 100 kHz is less than 0.04. As a result, the BST thin films are more applicable for fabrication of infrared detector compared with the BST thin films reported previously.     

Dielectric Characteristics of Ba_(0.65)Sr_(0.35)TiO_3 Thin Films by Sol-Gel Method

Ferroelectric Ba0.65Sr0.35TiO3(BST) thin films on the Pt/Ti/SiO2/Si substrate have been successfully prepared by sol-gel. Such films have approximately 300 nm thicknesses with a remnant polarization of about 2.95 μC/cm2 and a coercive field of about 21.5 kV/cm. The investigations of X-ray diffraction and atomic force microscopy show that the BST films annealed at 650 °C exhibit a tetragonal structure and that the films dominantly consist of large column or grains of about 89 nm in diameter. The curves of the temperature dependence of dielectric coefficient in different frequencies display the curie transition at the temperature around 23 °C. The dielectric loss tangent of BST thin films at 100 kHz is less than 0.04. As a result,the BST thin films are more applicable for fabrication of infrared detector compared with the BST thin films reported previously.     

BST铁电薄膜的制备及介电性能研究

通过射频磁控溅射法,采用高温溅射、低温溅射高温退火两种不同的工艺制备了钛酸锶钡（BST）薄膜。分析两种不同的工艺对BST薄膜的结构、微观形貌及介电性能的影响。采用X线衍射（XRD）分析了样品的微观结构。采用扫描电镜（SEM）和台阶仪分别测试了样品的微观形貌和表面轮廓。通过能谱分析（EDS）得到了薄膜均一性的情况。最后通过电容 电压（C V）曲线测试得到BST薄膜的介电常数偏压特性。结果表明,与低温溅射高温退火工艺制备的BST 薄膜相比,高温溅射制备的BST薄膜结晶度好,致密性高,表面光滑,薄膜成分分布较均一。因此,采用高温溅射得到的BST薄膜性能较好。在频率300 kHz时,采用高温溅射制备的BST薄膜介电常数为127.5~82.0,可调谐率为23.86%~27.9%。     

Low-Dielectric-Loss Barium Strontium Titanate Thin Films with MgO Buffer Layer for Tunable Microwave Devices

The dielectric and microwave properties of Ba_0.6Sr_0.4TiO₃ (BST60) thin films with a MgO buffer layer deposited on Al₂O₃ substrates were investigated. Insertion of the MgO buffer layer is demonstrated to be an effective approach to fabricate low-dielectric-loss BST thin films. x-Ray pattern analysis indicates that the thin films exhibit good crystalline quality with a pure perovskite phase and that insertion of the MgO buffer layer does not change the crystal structure of BST. The nonlinear dielectric properties of the BST films were measured by using an interdigital capacitor (IDC). At room temperature, the tunability of the BST films with a MgO buffer layer was 24.1% at a frequency of 1 MHz with an applied electric field of 80 kV/cm. The dielectric loss of the BST thin films is only 0.005 to 0.007 in the frequency range from 20 Hz to 2 MHz, the same as for BST films prepared on single-crystal MgO substrates. The microwave dielectric properties of the BST thin films were also measured by a vector network analyzer from 50 MHz to 10 GHz.     

Zn掺杂对BST薄膜介电调谐性能的影响

用sol-gel法在Pt/SiO2/Si基片上制备了未掺杂和掺杂Zn的钛酸锶钡(BST)薄膜。用XRD对BST薄膜进行了物相分析,研究了Zn掺杂对薄膜的表面形貌和介电调谐性能的影响。结果表明:室温下,随着Zn加入量的增加,BST薄膜的介电常数减小,介质损耗降低,介电调谐量增加。x(Zn)为0.025的BST薄膜具有最大的优越因子(FOM),其值为29.28。     

高度(100)取向的BST薄膜及其高介电调谐率

用脉冲激光沉积法制备(Ba1-xSrx)TiO3(x=0.35,0.50简称BST35和BST50)介电薄膜。在650℃原位退火10min,获得高度(100)取向柱状生长的晶粒。BST35薄膜的平均晶粒尺寸为50nm,BST50薄膜的晶粒尺寸为150~200nm。在室温和1MHz条件下,BST35的最大εr和调谐率分别达到810和76%,其介电调谐率高于国内外同类文献报道的数据;BST50的εr和调谐率最大分别达到875和63%。薄膜为(100)取向生长,因为薄膜沿平面c轴极化而产生应力,在电场作用下,而获得高介电调谐率。     

BST薄膜的反应离子刻蚀研究

钙钛矿结构的钛酸锶钡(BST)薄膜作为优良的介电、铁电材料在新一代的微机械系统(MEMS)、动态存储器(DRAM)及其他器件上的广泛应用,使得BST薄膜的刻蚀特性越来越重要。该文利用反应离子刻蚀装置,研究了溶胶-凝胶工艺制备的钛酸锶钡薄膜在CHF3/Ar等离子气体中的刻蚀情况。通过分析刻蚀速率及薄膜刻蚀前后表面形貌的变化,结果表明,刻蚀过程是离子轰击、离子辅助化学反应和化学反应刻蚀共同作用的结果。刻蚀速率为5.1 nm/min。Sr元素较难去除,成为阻碍刻蚀的重要因素。     

Structural and Electrical Characters of Ba0.6Sr0.4TiO3/La0.5Sr0.5CoO3 Thin Films by Plus Laser Deposition

Epitaxial Ba0.6Sr0.4TiO3 (BST) thin films were deposited on LaAlO3 (LAO) substrates with the conductive metallic oxide La0.5Sr0.5CoO3 (LSCO) film as a bottom electrode by pulsed laser deposition (PLD). X-ray diffraction ~2 and Ф scan showed that the epitaxial relationship of BST/LSCO/LAO was [001] BST//[001] LSCO//[001] LAO. The atomic force microscope (AFM) revealed a smooth and crack-free surface of BST films on LSCO-coated LAO substrate with the average grain size of 120 nm and the RMS of 1.564 nm for BST films. Pt/BST/LSCO capacitor was fabricated to perform CapacitanceVoltage measurement indicating good insulating characteristics. For epitaxial BST film, the dielectric constant and dielectric loss were determined as 471 and 0.03, respectively. The tunabilty was 79.59% and the leakage current was 2.6310-7 A/cm2 under an applied filed of 200 kV/cm. Furthermore, it was found that epitaxial BST (60/40) films demonstrate well-behaved ferroelectric properties with the remnate polarization of 6.085 C/cm2 and the coercive field of 72 kV/cm. The different electric properties from bulk BST (60/40) materials with intrinsic paraelectric characteristic are attributed to the interface effects.