Movement and transformations of fertigated nitrogen below trickle emitters and their effects on pH in the wetted soil volume

The movement and transformations of ammonium-, urea- and nitrate-N in the wetted volume of soil below the trickle emitter was studied in a field experiment following the fertigation of N as ammonium sulphate, urea and calcium nitrate. Effects on soil pH in the wetted volume were also investigated.During a fertigation cycle (emitter rate 2lh^–1) applied ammonium was concentrated in the surface 10 cm of soil immediately below the emitter and little lateral movement occurred. In contrast, because of their greater mobility in the soil, fertigated urea and nitrate were more evenly distributed down the soil profile below the emitter and had moved laterally in the profile to 15 cm radius from the emitter. The conversion of applied N to nitrate-N was more rapid when urea rather than ammonium-N was applied suggesting that the accumulation of large amounts of ammonium below the emitter in the ammonium sulphate treatment probably retarded nitrification.Following their conversion to nitrate-N, both fertigated ammonium sulphate and urea caused acidification in the wetted soil volume. Acidification was confined to the surface 20 cm of soil in the ammonium sulphate treatment, however because of its greater mobility, fertigation with urea (2lh^–1) resulted in acidification occurring down to a depth of 40 cm. Such subsoil acidity is likely to be very difficult to ameliorate. Increasing the trickle discharge rate from 2lh^–1 to 4lh^–1 reduced the downward movement of urea and encouraged its lateral spread in the surface soil. As a consequence, acidification was confined to the surface (0–20 cm) soil.     

The effect of fertiliser type and application rate on denitrification losses from cut grassland in Northern Ireland

Denitrification losses were measured using the acetylene inhibition technique adapted for a coring procedure. Two soils under a cut ryegrass sward were used. One soil was a freely-drained clay loam receiving under 900 mm rainfall annually, the other soil being a poorly-drained silty clay receiving over 1100 mm rainfall annually. Swards at each site received up to 300 kg N ha^–1 yr^–1 of calcium ammonium nitrate (CAN), urea or a new fertiliser mixture GRANUMS (30% ammonium nitrate, 30% urea, 10% ammonium sulphate, 30% dolomite). For both soils the rate of denitrification exceeded 0.1 kg N ha^–1 day^–1 only when the air-filled porosity of the soil was < 30% v/v and soil nitrate was > 2 mg N kg^–1 in the top 10cm of the profile and when soil temperature at 10 cm was > 4°C. When the soils dried such that their air-filled porosity was > 30% v/v, denitrification rates decreased to < 0.08 kg N ha^–1 day^–1. Highest rates (up to 3.7 kg N ha^–1 day^–1) were observed on the clay soil following application of 94 kg N ha^–1 CAN to soil near field capacity in early summer 1986. Losses from CAN were approximately 3 times those from urea for a given application. Denitrification losses from the GRANUMS treatment were, overall, intermediate between those from CAN and urea but the daily losses more closely resembled those from the CAN treatment. The impeded drainage on the clay soil, where soil moisture contents remained close to field capacity throughout the year, showed denitrification losses roughly 3 times those observed on the more freely drained clay-loam for any given treatment. Over a 12-month period, N losses arising from denitrification were 29.0 and 10.0 kg N ha^–1 for plots receiving 300 kg N ha^–1 CAN and urea, respectively, on the well drained clay-loam and 79.0 and 31.1 kg N ha^–1 respectively, for identical plots on the poorly drained clay soil. Annual denitrification losses from control plots were < 1 kg N ha^–1 on both soils.     

Calculated rates of soil acidification of intensively used grassland in the Netherlands

The major processes involved in acidification of soils under intensively managed grassland are the transformation and subsequent leaching of applied nitrogen (N), assimilation of excess cations in herbage and acidic atmospheric deposition. Carbonates from fertilizers and excess cations in purchased concentrates are the most important proton (H⁺) neutralizing agents applied to grassland. In this study, the effects of grazing, cutting and N application on the net proton loading from each of the main processes were calculated, using a simple model.On mown swards, simulated excess cation uptake by the sward released 4.5–9.3 kmol_c H⁺ ha^–1 yr^–1. The total proton loading on mown grassland decreased from about 8.0 to 5.3 kmol_c ha^–1 yr^–1 when fertilizer N input as CAN-27 increased from 0 to about 400 kg ha^–1 yr^–1. Contributions from atmospheric deposition ranged from 2.2 kmol_c ha^–1 yr^–1 when herbage yield exceeded 10 Mg ha^–1 yr^–1 to 3.0 kmol_c ha^–1 yr^–1 when herbage production was only 5.5 Mg ha^–1 yr^–1.On grazed swards, transformation of organically bound N from urine and dung to nitrate (NO ₃ ^- ) and the subsequent leaching of excess NO ₃ ^- was the main source of protons. Application of 400 kg N ha^–1 yr^–1 to grazed swards increased the proton loading from transformed N from 3.9 to 16.9 kmol_c ha^–1 yr^–1. The total proton loading on grazed swards exceeded that of mown swards when the input of fertilizer N exceeded 150 kg ha^–1 yr^–1.Underestimation of the amount of N immobilized in the soil biomass and lost by denitrification may have resulted in a slight overestimation of the amount of N lost by leaching and thereby also the simulated total proton loading.     

Response to fertilization and nutrient deficiency diagnostics in peach palm in Central Amazonia

Peach palm (Bactris gasipaes Kunth) is increasingly grown in the tropics for its heart-of-palm and fruit. Determining fertilization response and diagnosing nutrient status in peach palm may require methods that consider the particularities in nutrient acquisition and recycling of perennial crops. Responses to nutrient additions, and the diagnostic value of soil and foliar analyses were examined in three field experiments with three-year old peach palm stands on Oxisols in Central Amazonia. To diagnose P-deficiency levels in soils, samples from 0–5 cm and 5–20 cm depth were analyzed for available P by different methods (Mehlich-1, Mehlich-3 and Modified Olsen). The second and fifth leaves were analyzed to assess N, P and K deficiencies. Field experiments involved several combinations of N (from 0 to 225 kg ha^–1 yr^–1), K (from 0 to 225 kg ha^–1 yr^–1) and P (from 0 to 59 kg ha^–1 yr^–1). Palms on control plots (unfertilized) and those receiving 225 kg ha^–1 yr^–1 N and 2 Mg ha^–1 of lime yielded between 4 and 19% of the maximum growth which was obtained with N, P and K applications. In one of the experiments, yield of heart-of-palm was positively related to N additions at the lowest levels of P (8.6 kg ha^–1 yr^–1) and K (60 kg ha^–1 yr^–1) additions. In one experiment, critical leaf N level was 2.5% for the second leaf and 2.2% for the fifth leaf. Some growth responses to P additions at constant N and K levels were observed (e.g., 797 kg ha^–1 yr^–1 of heart-of-palm with 39.3 kg ha^–1 yr^–1 of applied P, and 632 kg ha^–1 yr^–1 of heart-of-palm with 10.9 kg ha^–1 yr^–1 of applied P in one experiment, and 2334 kg ha^–1 yr^–1 of heart-of-palm with 39.3 kg ha^–1 yr^–1 of P and 1257 kg ha^–1 yr^–1 of heart-of-palm with 19.7 kg ha^–1 yr^–1 of P in another trial). In the experiment for fruit production from peach palm, total plant height did not respond to P additions between 19.7 and 59 kg ha^–1 yr^–1 and K additions between 75 and 225 kg ha^–1 yr^–1. Leaf P levels were found to be above the proposed critical levels of 0.23% for the third leaf and 0.16% for the fifth leaf. Plants in this experiment, however, showed evident symptoms of Mg deficiency, which was associated with a steep gradient of increasing Mg concentration from the fifth leaf to the second leaf. Standard leaf diagnostic methods in most cases proved less useful to show plant N and P status and growth responses to N and P additions. Soil P determined by common extractions was in general too variable for prediction of growth.     

Potential impact of agroforestry on soil nutrient balances at the farm scale in the East African Highlands

There is much current interest in the potential role of agroforestry in the mitigation of nutrient depletion in Sub-Saharan Africa. Using data from farm surveys and trials, a static model of N and P flows was constructed for a standard farm system, representative of typical subsistence farms in humid parts of the East African Highlands. The model was used to explore the possible impact of improved agroforestry systems on nutrient budgets, to identify priorities for research.Soil nutrient balances in the standard farm system were - 107 kg N and - 8 kg P ha^–1 yr^–1. Agroforestry systems did not significantly reduce the N deficits except when a high proportion of the total biomass was returned to the soil, rather than removed from the farm. Agroforestry increased N input through biological N fixation and deep N uptake, but this was offset by a larger nutrient removal from the farm in harvested products, which increased from 38 kg N in the standard system to 169 kg N ha^–1 yr^–1 in an intensive dairy-agroforestry system. Agroforestry did not increase P inputs, and harvested P increased from 6 kg P in the standard farm system to 29 kg P ha^–1 yr^–1 in the dairy-agroforestry system. Thus, moderate P inputs, of 20 kg P ha^–1 yr^–1 were required to maintain soil P stocks.N leaching from the field was the most significant nutrient loss from the farm system, with a range of 68 to 139 kg N ha^–1 yr^–1. The capture of subsoil N by deep-rooted trees in agroforestry systems substantially increased N-use efficiency, providing 60 kg N ha^–1 yr^–1 in the dairy-agroforestry system. The budgets were sensitive to N mineralization rates in subsoils, N losses from soils and manures, and effectiveness of deep-rooted plants in subsoil N capture, for which there is little data from the region. Therefore, high priority should be given to research in these areas.The current model can not account for important feedback mechanisms that would allow analysis of the long-term effects of nutrient budgets on nutrient availability and plant productivity. Dynamic models of farm nutrient budgets that include such interactions are needed to further assess the sustainability of farming systems.     

Distribution of acid extractable P and exchangeable K in a grassland soil as affected by long-term surface application of N, P and K fertilizers

Information on the fate and distribution of surface-applied fertilizer P and K in soil is needed in order to assess their availability to plants and potential for water contamination. Distribution of extractable P (in 0.03 M NH₄F + 0.03 M H₂SO₄ solution) and exchangeable K (in neutral 1.0 M ammonium acetate solution) in the soil as a result of selected combinations of 30 years (1968–1997) of N fertilization (84–336 kg N ha^–1), 10 years of P fertilization (0–132 kg P ha^–1), and 14 years of K fertilization (0 and 46 kg K ha^–1) was studied in a field experiment on a thin Black Chernozem loam under smooth bromegrass (Bromus inermis Leyss.) at Crossfield, Alberta, Canada. Soil samples were taken at regular intervals in October 1997 from 0–5, 5–10, 10–15, 15–30, 30–60, 60–90 and 90–120 cm layers. Soil pH decreased with N rate and this declined with soil depth. Increase in extractable P concentration in the soil reflected 10 years of P fertilization relative to no P fertilization, even though it had been terminated 20 years prior to soil sampling. The magnitude and depth of increase in extractable P paralleled N and P rates. The extractable P concentration in the 0–5 cm soil layer increased by 2.2, 20.7, 30.4 and 34.5 mg P kg^–1 soil at 84, 168, 280 and 336 kg N ha^–1, respectively. The increase in extractable P concentration in the 0–15 cm soil depth was 1.5 and 12.8 mg P kg^–1 soil with application of 16 and 33 kg P ha^–1 (N rate of 84 N ha^–1 for both treatments), respectively; and it was 81.6 and 155.2 mg P kg^–1 soil with application of 66 and 132 kg P ha^–1 (N rate of 336 N ha^–1 for both treatments), respectively. The increase in extractable P at high N rates was attributed to N-induced soil acidification. Most of the increase in extractable P occurred in the top 10-cm soil layer and almost none was noticed below 30 cm depth. Surface-applied K was able to prevent depletion of exchangeable K from the 0–90 cm soil, which occurred with increased bromegrass production from N fertilization in the absence of K application. As only a small increase of exchangeable K was observed in the 10–30 cm soil, 46 kg K ha^–1 year^–1 was considered necessary to achieve a balance between fertilization and bromegrass uptake for K. The potential for P contamination of surface water may be increased with the high N and P rates, as most of the increase in extractable P occurred near the soil surface.     

Cadmium concentration in vegetable crops grown in a sandy soil as affected by Cd levels in fertilizer and soil pH

Field trials were conducted over a three-year period with chinese cabbage (Brassica pekinensis Rupr.) and carrots (Daucus carota L.) grown in a sandy soil with pH adjusted to 5.5 and 6.5. The NPK fertilizers containing 1, 30, 90, and 400 mg Cd kg^–1 P were applied at the rate of 0.07, 2.1, 6.3 and 28 g Cd ha^–1 yr^–1. The amounts of Cd added through phosphate rock also ranged between 0.1 and 28 g ha^–1 yr^–1. The increased Cd application rates through NPK fertilizers increased the Cd concentration in both vegetables but the differences among treatments were not found to be significant. The Cd uptake by both crops was significantly (p<0.01) higher at pH 5.5 than at pH 6.5. Chinese cabbage exhibited lower Cd concentration than carrots. Carrot leaves contained higher Cd than its roots. Cadmium removals by chinese cabbage and carrot were about 0.7 and 1.3 g ha^–1 yr^–1, respectively. At pH 5.5, Cd concentrations in the two crops, based on a three-year average, were 23 and 46% higher than at pH 6.5. Cadmium uptake by chinese cabbage from different sources of phosphate rock was affected to a very limited extent. Cadmium concentration generally increased over the years. Cadmium extracted by ammonium nitrate after harvest of the crops was closely related with soil pH and Cd concentration in the plants.     

Changes in quantity of mineral nitrogen in three grassland soils as affected by intensity of nitrogen fertilization

Changes in quantity of soil mineral nitrogen down to a depth of 1 m in cloverfree grassland were monitored within one growing season and over successive growing seasons. Accumulation of mineral nitrogen in the soil occurred on permanent grassland with split application of nitrogen totalling more than 400 kg N ha^–1 yr^–1 and on young grassland, sown after arable crops, with applications of more than 480 kg N ha^–1 yr^–1. The relationship between the rate of nitrogen application minus nitrogen uptake, and accumulation of mineral nitrogen in the upper 50 cm of soil during each growing season is described.     

Carbon sequestration in soil aggregates under different crop rotations and nitrogen fertilization in an inceptisol in southeastern Norway

Effects of crop rotation and fertilization (nitrogen and manure) on concentrations of soil organic carbon (SOC) and total soil nitrogen (TSN) in bulk soil and in soil aggregates were investigated in a long-term field experiment established in 1953 at Ås, Norway. The effect of these management practices on SOC sequestration was estimated. The experiment had three six-course rotations: (I) continuous spring grain, (II) spring grain for 3 years followed by root crops for 3 years, and (III) spring grain for 2 years followed by meadow for 4 years. Three fertilizer treatments compared were: (A) 30–40 kg N ha^–1; (B) 80–120 kg N ha^–1; and (C) a combination of B and 60 Mg farmyard manure (FYM) ha^–1. All plots received a basal rate of PK fertilizer. Soil samples from these treatments were collected in autumn 2001 and analyzed for aggregate size, SOC and TSN concentrations. There were significant increases in 0.6–2 mm and < 0.6 mm aggregate size fractions, and reduction in the 6–20 mm and the > 20 mm sizes for rotation III only. There were also significant differences among rotations with regard to water stable aggregation. The order of increase in stability was II < I < III. Fertilizer treatment had no effect on aggregation or aggregate size distribution, but there was a slight tendency of increased stability with the application of FYM. Aggregate stability increased with increasing concentration of SOC (r2 = 0.53). The SOC and TSN concentrations in bulk soil were significantly higher in rotation III than in rotations II and I. Application of FYM increased SOC and TSN concentrations significantly in the 0–10 cm soil depth, but there were few significant differences between fertility treatments A and B. There was a trend of increase in concentration of SOC and TSN with decreasing aggregate size, but significant differences in these parameters in different aggregate size fractions were found only in few cases. The SOC and TSN concentrations were higher in >0.25 mm than in < 0.25 mm aggregates. The SOC sequestration rate was 77–167 kg SOC ha^–1 yr^–1 by increasing the N rate and 40–162 kg SOC ha^–1 yr^–1 by applying FYM. The SOC sequestration rate by judicious use of inorganic fertilizer was the greatest in the grain–meadow rotation, while that by application of FYM was the greatest in the all grain rotation.     

Total and light fraction organic C in a thin Black Chernozemic grassland soil as affected by 27 annual applications of six rates of fertilizer N

Maintenance and sequestration of C is important to sustain and improve the quality and productivity of soils. The objective of this study was to determine the effects of 27 annual applications of six N rates (0, 56, 112, 168, 224 and 336 kg N ha^–1 yr^–1) on total organic C (TOC) and light fraction organic C (LFOC) in a thin Black Chernozemic loam soil. Nitrogen (ammonium nitrate) was surface-applied to bromegrass (Bromus inermis Leyss) managed as hay near Crossfield, Alberta, Canada. The concentration and mass of TOC and LFOC in the 0–5, 5–10, 10–15 and 15–30 cm soil layers increased with N rate and showed a quadratic response to N rate with significant R² values, with their maximum values at 336 kg N ha^–1 in the 0–5 cm layer and at 224 kg N ha^–1 in other layers. But the increase in TOC and LFOC per kg of N addition was maximized at 56 kg N ha^–1 and declined with further increase in N rate. These trends indicated that higher N rates would cause a faster build up of soil C, whereas lower N rates would achieve a greater increase in soil C per unit of N addition. Response of C mass to N application was much greater for LFOC (range of 697 to 156% increase) than for TOC (range of 67 to 17% increase). Percentage of LFOC in TOC mass increased with N rate. At the 168 to 336 kg N ha^–1 rates, almost all of the increase in TOC in the surface 10 cm soil occurred as LFOC. Thus, LFOC was more responsive to N application and was a good indicator of N effect on soil C. The trend of change in soil TOC and LFOC was similar to hay yield and C removal in hay, which suggests that increasing hay yield with N application concurrently also increases soil organic C. In conclusion, long-term annual applications of N fertilizer to bromegrass resulted in a substantial increase in TOC and LFOC in the soil, thereby indicating that N fertilization can be used to sequester more atmospheric C in prairie grassland soils.     

Effect of rates and sources of nitrogen application on yield and nutrient uptake of Citronella Java (Cymbopogon winterianus Jowitt)

Two field experiments were conducted for two crop cycles each of two years (1985–87 and 1986–88) on an entisols to study the effect of rate and sources of N application on yield and nutrient uptake of Citronella Java (Cymbopogon winterianus Jowitt). Fresh herbage and essential oil yields were significantly influenced by application of N up to 200 kg ha^–1 yr^–1, while tissue N concentration and N uptake increased only to 150 kg N ha^–1. The oil yields with Neem cake coated urea (urea granules coated with Neem cake) and urea super granules were 22 and 9% higher over that with prilled urea and urea supergranules were significantly increased up to 200 kg N ha^–1 while with Neem cake coated urea, response was observed only to 150 kg N ha^–1! Estimated recovery of N during two years from Neem cake coated urea, urea supergranules and prilled urea were 38, 31 and 21%, respectively.     

Effect of urea management on yield and N use efficiency of lowland rice on an acid sulfate soil

Field experiments were conducted during 1988–1989 at two adjacent sites on an acid sulfate soil (Sulfic Tropaquept) in Thailand to determine the influence of urea fertilization practices on lowland rice yield and N use efficiency. Almost all the unhydrolyzed urea completely disappeared from the floodwater within 8 to 10 d following urea application. A maximum partial pressure of ammonia (pNH₃) value of 0.14 Pa and an elevation in floodwater pH to about 7.5 following urea application suggest that appreciable loss of NH₃ could occur from this soil if wind speeds were favorable. Grain yields and N uptake were significantly increased with applied N over the control and affected by urea fertilization practices (4.7–5.7 Mg ha^–1 in dry season and 3.0–4.1 Mg ha^–1 in wet season). In terms of both grain yield and N uptake, incorporation treatments of urea as well as urea broadcasting onto drained soil followed by flooding 2 d later were more effective than the treatments in which the same fertilizer was broadcast directly into the floodwater either shortly or 10 d after transplanting (DT). The¹⁵N balance studies conducted in the wet season showed that N losses could be reduced to 31% of applied N by broadcasting of urea onto drained soil and flooding 2 d later compared with 52% loss by broadcasting of urea into floodwater at 10 DT. Gaseous N loss via NH₃ volatilization was probably responsible for the poor efficiency of broadcast urea in this study.     

Nitrate distribution and accumulation in an Ustochrept soil profile in a long term fertilizer experiment

Distribution and accumulation of NO₃—N, down to 210 cm depth, in the soil profile of a long term fertilizer experiment were studied after 16 cycles of cropping (maize-wheat-fodder cowpea). The application of fertilizer N without P and K or in combination with only P resulted in higher NO₃—N concentration in the soil profile than the application of N with P and K. With an annual application of 320 kg N ha^–1 alone, a peak in NO₃—N accumulation occurred at 135 cm soil depth. However, with the application of NPK, no peak in NO₃—N distribution was discernible and its content at most of the sampling depths was either less than or equal to N and NP treatments. The annual application of 10 tons farm yard manure (FYM) per ha along with NPK resulted in a relatively lower NO₃—N content in the sub soil. The amount of NO₃—N accumulation in the soil profile decreased as the cumulative N uptake by the crops increased. Application of fertilizer amounts greater than that of the recommended (100% NPK) resulted in low percent N recoveries in crops and greater NO₃—N accumulation in the soil profile.     

Initial and residual effects of nitrogen fertilizers on grain yield of a maize/bean intercrop grown on a Humic Nitosol and the fate and efficiency of the applied nitrogen

Initial and residual effects of nitrogen (N) fertilizers on grain yield of a maize/bean intercrop grown on a deep, well-drained Humic Nitosol (66% clay, 3% organic carbon) were evaluated. Enriched (¹⁵N) N fertilizer was used to study the fate of applied N in two seasons: using urea (banded) at 50 kg N ha^–1 in one season, and¹⁵N-enriched urea (banded), calcium ammonium nitrate (CAN, banded), and urea supergranules (USG, point placement) were applied in the other season (different field) at 100 kg N ha^–1. Nitrogen fertilizer significantly (P = 0.05) increased equivalent maize grain yield in each season of application with no significant differences between N sources, i.e., urea, CAN, and USG. Profitmaximizing rates ranged from 75 to 97 kg N ha^–1 and value: cost ratios ranged from 3.0 to 4.8. Urea gave the highest value: cost ratio in each season. Most (lowest measurement 81%) of the applied N was accounted for by analyzing the soil (to 150 cm depth) and plant material. Measurements for urea, CAN, and USG were not significantly different. The high N measurements suggest low losses of applied N fertilizer under the conditions of the study. Maize plant recovery ranged from 35 to 55%; most of this N (51–65%) was in the grain. Bean plant recovery ranged from 8 to 20%. About 34–43% of the applied N fertilizer remained in the soil, and most of it (about 70%) was within the top soil layer (0–30 cm). However, there were no significant equivalent maize grain increases in seasons following N application indicating no beneficial residual effect of the applied fertilizers.     

Residual N and P fertilizer effect and fertilizer recovery on intercropped and sole-cropped corn and bean in semiarid northeast Brazil

The effects of a single ¹⁵N and P fertilizer application (16 and 12 kg ha^–1) on intercropped and sole-cropped corn and beans was followed over three consecutive years. Grain (0.1–0.9 ton ha^–1 yr^–1) and straw productions (0.2–2.5 ton ha^–1 yr^–1) were limited by rainfall and showed small responses to fertilizer. In the first year, plant N uptake was more than twice the fertilizer amounts, while P uptake was less than half the fertilizer amounts. Plant N derived from fertilizer was low (9–19%). Sole corn took up more (34%) than beans (16%) and the combined intercrop (26%) and also had higher recovery of fertilizer in the soil than single beans (50% against 28%). The distribution of fertilizer N and P in the soil showed a similar pattern in all treatments, with a high concentration around the application spot and decreasing concentrations at greater distances and above and below this point. Total P increases in a soil volume 10 cm around the application spot corresponded to 60% of the amount applied. Fertilizer contributions to the second crop were < 3% of total plant N and represented <6% of the applied amount. Therefore, the residual fertilizer effect on production was attributable to P. The patterns of fertilizer N and P distribution in the soil remained similar but N recoveries decreased 14–18%. Despite low rainfall, low productivities and reasonable proportions of fertilizer N remaining in the soil, the residual effects of the applied fertilizer N were too low to justify a fertilizer recommendation based on economic returns on the investment.     

Effect of green manuring with Sesbania aculeata and nitrogen fertilization on the performance of direct-seeded flood-prone lowland rice

Green manuring of rice with dhaincha (Sesbania aculeata) is widely practised under irrigated puddle-transplanted conditions. In flood-prone lowlands, the rice is established through direct seeding early in the season and flooding occurs after 1–2 months of crop growth following regular rains. The low yields are due to poor crop stands and difficulty in nitrogen management under higher depths of water. The effect of green manuring with dhaincha intercropped with direct-seeded rice vis-à-vis the conventional practice of incorporating pure dhaincha before transplanting was investigated under flood-prone lowland conditions (up to 50–80 cm water depth) at Cuttack, India. Treatment variables studied in different years (1992, 1994 and 1995) were: rice varieties of different plant heights, crop establishment through direct seeding and transplanting, varying length of periods before dhaincha incorporation, and urea N fertilizer levels. Dhaincha accumulated 80–86 kg N ha^-1 in pure stand and 58–79 kg N ha^-1 when intercropped with direct-seeded rice in alternate rows at 50 days of growth. The growth of rice improved after dhaincha was uprooted manually and buried in situ between the rice rows when water depth was 10–20 cm in the field. The panicle number was lower but the panicle weight was higher with dhaincha green manuring than with recommended level of 40 kg N ha^-1 applied as urea. The grain yield was significantly higher with direct seeding than with transplanting due to high water levels (>60 cm) immediately after transplanting. Dhaincha manuring was at par with 40 kg N ha^-1 as urea in increasing the yield of direct-seeded and transplanted crops. The highest yield of direct-seeded crop was obtained when 20 kg N ha^-1 was applied at sowing and dhaincha was incorporated at 50 days of growth. The results indicate that green manuring of direct-seeded rice with intercropped dhaincha is beneficial for substituting urea fertilizer up to 40 kg N ha^-1 and augmenting crop productivity under flood-prone lowland conditions.     

Nitrogen transformations near urea in soil: Effects of nitrification inhibition,nitrifier activity and liming

A laboratory incubation experiment was conducted to gain a better understanding of N transformations which occur near large urea granules in soil and the effects of dicyandiamide (DCD), nitrifier activity and liming. Soil cores containing a layer of urea were used to provide a one-dimensional approach and to facilitate sampling. A uniform layer of 2 g urea or urea + DCD was placed in the centre of a 20 cm-long soil core within PVC tubing. DCD was mixed with urea powder at 50 mg kg^–1 urea and enrichment of soil with nitrifiers was accomplished by preincubating Conestogo silt loam with 50 mg NH ₄ ⁺ -N kg^–1 soil. Brookston clay (pH 5.7) was limited with CaCO₃ to increase the pH to 7.3. The cores were incubated at 15°C and, after periods of 10, 20, 35 and 45 days, were separated into 1-cm sections. The distribution of N species was similar on each side of the urea layer at each sampling. The pH and NH ₄ ⁺ (NH₃) concentration were very high near the urea layer but decreased sharply with distance from it. DCD did not influence urea hydrolysis significantly. Liming of Brookston clay increased urea hydrolysis. The rate of urea hydrolysis was greater in Conestogo silt loam than limed Brookston clay. Nitrite accumulate was relatively small with all the treatments and occurred near the urea layer (0–4 cm) where pH and NH ₄ ⁺ (NH₃) concentration were high. The nitrification occurred in the zone where NH ₄ ⁺ (NH₃) concentration was below 1000µgN g^–1 and soil pH was below 8.0 and 8.7 in Brookston and Conestogo soils, respectively. DCD reduced the nitrifier activity (NA) in soil thereby markedly inhibiting nitrification of NH ₄ ⁺ . Nitrification was increased significantly with liming of the Brookston soil or nitrifier enrichment of the Conestogo soil. There was a significant increase in NA during the nitrification of urea-N. The (NO ₂ ^– + NO ₃ ^– )-N concentration peaks coincided with the NA peaks in the soil cores.A practical implication of this work is that large urea granules will not necessarily result in NO ₂ ^– phytotoxicity when applied near plants. A placement depth of about 5 cm below the soil surface may preclude NH₃ loss from large urea granules. DCD is a potential nitrification inhibitor for use with large urea granules or small urea granules placed in nests.     

Integrated soil management for the savanna zone of W. Africa: legume rotation and fertilizer N

Integrated soil management with leguminous cover crops was studied at two sites in the northern Guinea savanna zone of northern Nigeria, Kaduna (190 day growing season) and Bauchi (150 days). One-year planted fallows of mucuna, lablab, and crotalaria were compared with natural grass fallow and cowpea controls. All treatments were followed by a maize test crop in the second year with 0, 30, or 60 kg N ha^–1 as urea. Above ground legume residues were not incorporated into the soil and most residues were burned early in the dry season at the Kaduna site. Legume rotation increased soil total N, maize growth in greenhouse pots, and dry matter and N accumulation of maize. Response of maize grain yield to 30 kg N ha^–1 as urea was highly significant at both sites and much greater than the response to legume rotation. The mean N fertilizer replacement value from legume rotation was 14 kg N ha^–1 at Kaduna and 6 kg N ha^–1 at Bauchi. W ith no N applied to the maize test crop, maize grain yield following legume fallow was 365 kg ha^–1 higher than natural fallow at Bauchi and 235 kg ha^–1 higher at Kaduna. The benefit of specific legume fallows to subsequent maize was mostly related to above ground N of the previous legume at Bauchi, where residues were protected from fire and grazing. At Kaduna, where fallow vegetation was burned, maize yield was related to estimated below ground N. The results show that legume rotation alone results in small maize yield increases in the dry savanna zone.     

Very high applications of nitrogen fertilizer on grassland and residual effects in the following season

At very high nitrogen applications (480 and more kg N ha^–1 yr^–1) in field trials on all-grass swards the amount of N applied exceeded the amount of N harvested. In the humid temperate climate of the Netherlands in the subsequent spring approximately 25, 40, and 50% of this excess nitrogen was recovered as accumulated mineral nitrogen in the 0–100 cm layer of sandy, clay and heavy clay soil, respectively. The effect of this excess nitrogen on growth during the subsequent season was measured through the increase in DM and N yield over a reference treatment. In this season all treatments received a uniform application (40 kg N ha^–1 cut^–1). Residual effects were absent on sandy soil but distinct on the clay soils. On the clay soils each accumulated kg soil mineral nitrogen produced 15 kg DM. Assuming a relatively small contribution of residual nitrogen carried over in stubble, roots and organic matter, the accumulated soil mineral nitrogen would seem to be as effective as applied fertilizer nitrogen.     

Nitrogen requirements in young Douglas-fir of the Pacific North-west

A series of fourteen Pacific North-west Douglas-fir installations, ranging in age from 6 to 26 years were analysed with respect to site factors, foliage nutrients, and growth response to applied fertilizer. Unfertilized basal area increment ranged from 1.2 to 3.1 m² ha^–1 yr^–1 with no apparent relationship with soil, stand age or site index. Basal area increment was correlated with foliage N and a critical level for N was calculated as 1.7%. Applications of 220 kg N ha^–1 as urea increased growth between 0 and 95% of the unfertilized basal area growth, with an average of 24.9%. Response could be predicted from foliage N and unfertilized basal area increment. When the same relationships were applied to previously older stand data, results were more variable as elements such as B and S showed evidence of being limiting.