Main aspects of geothermal energy in Mexico

With an installed geothermal electric capacity of 853 MW_e, Mexico is currently the third largest producer of geothermal power worldwide, after the USA and the Philippines. There are four geothermal fields now under exploitation: Cerro Prieto, Los Azufres, Los Humeros and Las Tres Vírgenes. Cerro Prieto is the second largest field in the world, with 720 MW_e and 138 production wells in operation; sedimentary (sandstone) rocks host its geothermal fluids. Los Azufres (88 MW_e), Los Humeros (35 MW_e) and Las Tres Vírgenes (10 MW_e) are volcanic fields, with fluids hosted by volcanic (andesites) and intrusive (granodiorite) rocks. Four additional units, 25 MW_e each, are under construction in Los Azufres and due to go into operation in April 2003. One small (300 kW) binary-cycle unit is operating in Maguarichi, a small village in an isolated area with no link to the national grid. The geothermal power installed in Mexico represents 2% of the total installed electric capacity, but the electricity generated from geothermal accounts for almost 3% of the national total.     

Fluid chemistry and temperatures prior to exploitation at the Las Tres Vírgenes geothermal field,Mexico

Generation of electricity at the Las Tres Vírgenes (LTV) geothermal field, Mexico, began in 2001. There are currently nine geothermal wells in the field, which has an installed electricity generating capacity of 10 MW_e. The chemical and temperature conditions prevailing in the field prior to its exploitation have been estimated, including their central tendency and dispersion parameters. These conditions were computed on the basis of: (i) geochemical data on waters from springs and domestic wells, and on geothermal well fluids (waters and gases); most of the sampling took place between 1995 and 1999; (ii) fluid inclusion studies; (iii) geothermometric data; and (iv) static formation temperatures computed using a modified quadratic regression Horner method.Fluid inclusion homogenization temperatures (in the 100–290 °C range) suggest that there is a high-temperature fluid upflow zone near wells LV3 and LV4 in the southern part of the field. Computed average chemical equilibrium temperatures for the geothermal fluids are ∼260 °C, based on the Na/K and SiO₂ geothermometers, and ∼265 °C, based on the H₂/Ar, and CO₂/Ar geothermometers. In general, the fluid inclusion homogenization temperatures are consistent with geothermometric data, as well as with static formation temperatures. Some of the observed differences could be related to well interference effects and different fluid production/sampling depths. The deeper geothermal waters show higher concentrations of Cl, Na, K, B, Ba, but lower concentrations of SO₄, Ca, and Mg than the shallower waters. Fluid inclusion salinities are also higher in the deeper rocks. The measured Na/Cl ratios of the geothermal well waters are more or less uniform throughout the field and are very similar to that of seawater, strongly suggesting a seawater component in the fluid of the LTV system.The heat stored in the LTV geothermal system was estimated to be at least 9 × 10¹² MJ, of which some 4 × 10¹¹ MJ (equivalent to about 148 MW_e for 30 years of operation, assuming a conversion efficiency of ∼35%) might be extracted using wells. These results indicate that the installed capacity at LTV could be safely increased from the current 10 MW_e.     

Study on the flow production characteristics of deep geothermal wells

This paper describes a study on the potential flow production characteristics of three non-producing, deep (average depth 4000 m) geothermal wells in the Cerro Prieto geothermal field. The expected production characteristics of these wells were computed in order to determine whether their inability to sustain flow was due to: (1) heat loss effects in the well; (2) the influence of casing diameters; (3) transient temperature effects during the first days of well discharge, and/or (4) the effects of secondary low-enthalpy inflows. For the study, the conservation equations of mass, momentum and energy for two-phase homogeneous flow were solved for the wellbore, since homogeneous flow provides the simplest technique for analyzing two-phase flows when the flow patterns are not well established. The formation temperature distribution was computed assuming radial transient heat conduction. The numerical model was validated by comparison with analytical solutions and with measured pressure and temperature profiles of well H-17 from the Los Humeros geothermal field, Mexico. It was found that the wells should have sustained production. The early heat losses were so large that the flow needed to be induced, and flow will be sustained only after a few days of induced discharge. For well M-202, the analysis suggests that the inflow of secondary colder fluids was responsible for stopping the flow in this well.     

Oxygen isotopic ratios of sulfate ions-water pairs as a possible geothermometer

In this paper a brief review is given of the dependence of the oxygen isotopic fractionation of the sulfate ions-water system on temperature and the pH. From the available experimental data some relationships have been elaborated, which show that the isotopic exchange time is strongly temperature and pH dependent. The times for 97 per cent of isotopic exchange (near equilibrium conditions) at pH 7.0 are about 9 years at 200°C and 0.6 years at 330°C, while at pH 3.8 and at the same temperatures the times of exchange are 1.5 years and 0.08 years respectively. Thus, at the temperatures and pH of geothermal reservoirs the sulfate could be in isotopic equilibrium with environmental water, and the oxygen isotopic fractionation factors of sulfate-water geothermal pairs, being temperature dependent, can be used as geothermometers.Also reported here are some results on the O¹⁸ content of sulfate-water pairs from some wells on the edge of and outside the Larderello geothermal basin. The estimated isotopic temperatures are not very significant for the deep reservoir temperatures due to the geological features of the Larderello area which show important outcropping and deep anhydrite layers. Furthermore, as regards the wells outside the Larderello basin (Travale wells) some mixing of the geothermal water with colder underground water has been proved. However, the isotopic temperatures are generally higher than those measured at the well-head, and the highest ones are close to those estimated for the geothermal reservoir.In other geothermal areas more convenient from a geological point of view, the O¹⁸ content of the sulfate-water pair can be a useful and accurate thermometer.The O¹⁸/O¹⁶ ratios of several other sulfates (surface and deep anhydrite samples, sulfate ions in thermal springs) from the same area were also determined and differ substantially from borehole sulfate values.     

Geochemistry in geothermal exploration

Techniques based on the variations in composition of water, gas and stable isotopes in the liquid and gas phases of the geothermal fluids have been applied for some time now in the major geothermal fields and are now also used regularly in geothermal exploration. There are numerous processes capable of modifying isotopic composition after infiltration of water from the surface, such as water-rock exchanges, formation of secondary minerals and exchange with the gaseous phase (CO₂ and H₂S). During ascent to the surface, the two main processes are steam separation and dilution and mixing with shallower waters. This paper also deals with the chemical characteristics of the waters, their classification and the water-rock interaction producing hydrothermal alteration. During exploration the chemical and isotopic geothermometers represent a unique method for investigating the deep system. The choice of geothermometer and interpretation of geothermometric data are two crucial steps in geothermal exploration. Finally, the paper discusses the geochemistry of gas mixtures, especially the origin of the gas species and the main chemical reactions that produce semi-empirical geothermometers and some recent non-empirical geothermometers based on models of a two-phase system in the reservoir. Gas-geothermometers can be developed to calculate the reservoir temperature for natural manifestations.     

Chemical variations in hydrothermal minerals of the Los Humeros geothermal system, Mexico

The Los Humeros geothermal system is composed of more than 2200 m of Quaternary altered volcanic rocks and an underlying Cretaceous sedimentary sequence. The low salinity of the fluids discharged at present (Na⁺ and Cl⁻ concentrations <500 ppm), and the excess steam, indicate that the reservoir contains a mixture of steam and dilute groundwater. Water-rock equilibrium is not attained. Hydrothermal minerals are present in veinlets, vugs, and replacing primary minerals. Three mineral zones are recognized: 1) a shallow argillic zone (<400 m depth), 2) a propylitic zone (ranging between 500 and 1800 m) and 3) a skarn zone (>1800 m). Petrographic examination of cuttings from five wells and temperature data indicate at least two stages of hydrothermal activity. Temperature is the main factor that affects the chemical composition of chlorite, epidote and biotite. Fe²⁺ and Al^IV increase in chlorite with temperature [from 1.4 formula position unit (fpu) to 2.8, and from 0.7 to 2.4 fpu, respectively]. The pistacite content of epidote varies from 18 to 33 mol% in high-temperature regions (>270 °C) and from 13 to 26 mol% in low-temperature regions (<250 °C). Biotite displays a slight increase in Al^IV contents (1.55–2.8) and octahedral occupancy (5.93–6.0 fpu) with temperature. Whole rock composition and variations in oxygen fugacity conditions are factors that also affect the concentrations of Fe, Al and Mg in the octahedral sites of chlorite, epidote, biotite and amphiboles. Chemical variations observed in alteration minerals at different depths in the Colapso Central-Xalapazco region could be used as indicators of relict physico-chemical conditions in the reservoir, before the present economic exploitation.     

Temperature field distribution from cooling of a magma chamber in La Primavera Caldera, Jalisco, Mexico

The temperature field distribution in La Primavera geothermal area, Jalisco, located in the western part of the Mexican Volcanic Belt (MVB), has been simulated from cooling of a shallow magma chamber (assumed as the primary heat source) during the entire volcanic history of the caldera. Similar to the other two geothermal fields of the MVB (Los Humeros and Los Azufres), it is considered that the evolution of the magma chamber is controlled by the processes of fractional crystallization as well as magma recharge. Besides these processes, heat contribution is also taken into account from decay of natural radioactive elements, U, Th, and K, present in all geological materials. In some models presented in this work, convection in the geothermal reservoir is simulated by assigning higher values of thermal conductivities (up to 20 times the rock conductivities) to respective geologic units. The heat transfer equation has been solved by a finite element implicit method. The results of temperature simulations from the magma chamber are compared with undisturbed formation temperatures in three drill wells. The subsurface depth of the top of the magma chamber is varied from 5 to 7 km. Similarly, the horizontal dimensions of the chamber are varied from 12 km (which is approximately the diameter of the La Primavera caldera) to 10 km. The thermal effects of this change in depth and horizontal dimensions of the magma chamber are readily seen in the predicted temperature distribution for this rather young caldera.     

Temperature evaluation of the Bugok geothermal system, South Korea

Using a variety of chemical geothermometers and statistical analysis, we estimate the temperature of a possible deeper geothermal reservoir at Bugok, Southern Korea. Shallow thermal aquifers (down to about 400 m depth) are under exploitation in this area; the temperatures (up to 78 °C) of the produced fluids are the highest found in South Korea. Based on hydrochemical data and occurrence, the groundwaters at Bugok can be classified under three groups: Na-SO₄ thermal groundwaters (CTGW) occurring in the central (about 0.24 km²) part of the area; Ca-HCO₃ cold groundwater (SCGW) found in shallow peripheral parts of the CTGW; the intermediate-type groundwater (STGW). The CTGW type is typical of the Bugok thermal waters; they have the highest discharge temperatures and contain very high concentrations of Na (75.1–101.0 mg/L), K (2.9–6.9 mg/L) and SiO₂ (62.0–84.5 mg/L) and are rich in sulfates.The major ion composition of the CTGW suggests that these waters are in partial equilibrium with rocks at depth. The application of various alkali-ion geothermometers yields temperature estimates in the 88–198 °C range for the thermal reservoir. Multiple-mineral equilibrium calculations indicate a similar but narrower temperature range (from about 100 to 155 °C). These estimates for CTGW are significantly higher than the measured discharge temperatures. Considering the heat losses occurring during the ascent of the waters, one can infer the presence of a deeper (around 1.8 km) thermal reservoir in the Bugok area that could be developed for district heating or other direct applications of geothermal heat.     

The Iceland Deep Drilling Project: a search for deep unconventional geothermal resources

The Iceland Deep Drilling Project (IDDP) is a long-term program to improve the economics of geothermal energy by producing supercritical hydrous fluids from drillable depths. Producing supercritical fluids will require the drilling of wells and the sampling of fluids and rocks to depths of 3.5–5 km, and at temperatures of 450–600 °C. The IDDP plans to drill and test a series of such deep boreholes in the Krafla, Nesjavellir and Reykjanes geothermal fields in Iceland. Beneath these three developed high-temperature systems frequent seismic activity continues below 5 km, indicating that, even at supercritical temperatures, the rocks are brittle and therefore likely to be permeable, even where the temperature is assumed to exceed 550–650 °C. Temperature gradients are greater and fluid salinities smaller at Nesjavellir and Krafla than at Reykjanes. However, an active drilling program is underway at Reykjanes to expand the existing generating capacity and the field operator has offered to make available one of a number of 2.5 km deep wells to be the first to be deepened to 5 km by the IDDP. In addition to its potential economic significance, drilling deep at this location, on the landward extension of the Mid-Atlantic Ridge, is of great interest to the international science community. This paper examines the prospect of producing geothermal fluids from deep wells drilled into a reservoir at supercritical temperatures and pressures. Since fluids drawn from a depth of 4000–5000 m may prove to be chemically hostile, the wellbore and casing must be protected while the fluid properties are being evaluated. This will be achieved by extracting the fluids through a narrow retrievable liner called the “pipe”. Modelling indicates that if the wellhead enthalpy is to exceed that of conventionally produced geothermal steam, the reservoir temperature must be higher than 450 °C. A deep well producing 0.67 m³/s steam (2400 m³/h) from a reservoir with a temperature significantly above 450 °C could, under favourable conditions, yield enough high-enthalpy steam to generate 40–50 MW of electric power. This exceeds by an order of magnitude the power typically obtained from a conventional geothermal well in Iceland. The aim of the IDDP is to determine whether utilization of heat from such an unconventional geothermal resource at supercritical conditions will lead to increased productivity of wells at a competitive cost. If the IDDP is an economic success, this same approach could be applied in other high-temperature volcanic geothermal systems elsewhere, an important step in enhancing the geothermal industry worldwide.     

Application of the computer code TOUGH2 to the simulation of supercritical conditions in geothermal systems

At the high pressures and temperatures found in deep geothermal systems, supercritical conditions can occur. Current numerical geothermal simulators are either not capable of modelling these conditions, or can do so only at significantly reduced computation speed. This paper describes modifications to the TOUGH2 simulator to extend its applicability. It employs the updated IAPWS-97 thermodynamic formulation, and uses density and temperature as primary thermodynamic variables under supercritical conditions. Results from test problems are in agreement with results produced by other simulators, giving confidence that the simulator can be used for modelling deep geothermal reservoirs.     

Temperature–depth relationships based on log data from the Los Azufres geothermal field,Mexico

Equilibrium temperatures based on log data acquired during drilling stops in the Los Azufres geothermal field were used to study the relationship between temperature, depth and conductive heat flow that differentiate production from non-production areas. Temperature and thermal conductivity data from 62 geothermal wells were analyzed, displaying temperature–depth, gradient–depth, and ternary temperature–gradient–depth plots. In the ternary plot, the production wells of Los Azufres are located near the temperature vertex, where normalized temperatures are over 0.50 units, or where the temperature gradient is over 165°C/km. In addition, the temperature data were used to estimate the depth at which 600°C could be reached (5–9 km) and the regional background conductive heat flow (≈ 106 mW/m²). Estimates are also given for the conductive heat flow associated with the conductive cooling of an intrusive body (≈ 295 mW/m²), and the conductive heat flow component in low-permeability blocks inside the reservoir associated with convection in limiting open faults (from 69 to 667 mW/m²). The method applied in this study may be useful to interpret data from new geothermal areas still under exploration by comparing with the results obtained from Los Azufres.     

Low enthalpy geothermal energy utilisation schemes for greenhouse and district heating at Traianoupolis Evros, Greece

A socio-economic study has been made of the possible use of low enthalpy geothermal resources for district and greenhouse heating in the Traianoupolis Evros region. The thermal energy potential of the Aristino-Traianoupolis geothermal field has been estimated at 10.8 MW_th (discharge temperature of 25 °C). Geothermal wellhead water temperatures range from 53 to 92 °C, from 300 m deep wells yielding over 250 m³/h. Our conclusions show, amongst the different scenarios examined and on the basis of a market study, that utilisation of this geothermal energy capacity for district heating of nearby villages, and/or greenhouse heating directed at serving local vegetable markets, would be an attractive investment.     

Development of a numerical hydraulic model of the Los Azufres steam pipeline network

The development and documentation of a hydraulic model of the steam pipeline network at the Los Azufres geothermal field is presented, as well as the results obtained using one- and two-phase numerical simulators. Flow simulations were performed to determine pressure and heat losses, flow directions and velocities in that network. Computed well pressures agree within ±10% with measured values, except in three of the 41 wells in the system where the differences are between 10% and 13%. Computed and measured steam flow rates entering the Los Azufres geothermal power plants agree within 10%, with the exception of one that showed a 26.7% difference. This is most likely due to a mismatch between the reported and actual flow rates delivered by the pipeline network. The computed results are considered highly satisfactory given the complexity of the Los Azufres network.     

Isotopic (δO, δD) patterns in Los Azufres (Mexico) geothermal fluids related to reservoir exploitation

Isotopic patterns for the year 2000 in the Los Azufres geothermal reservoir were related to injection of a condensed steam–water–air mixture as well as to the occurrence of reservoir physical processes resulting from exploitation. Reservoir boiling and mixing of reservoir fluids with cooler fluids were the most important processes identified. Boiling takes place in two zones of the field. In the north, the boiling area includes wells AZ-13, AZ-28, AZ-48, AZ-43 and AZ-32, while, in the south, boiling affects wells AZ-16AD, AZ-22, AZ-18, AZ-26 and AZ-36. Mixing of reservoir fluids with cooler waters was identified in wells AZ-2, AZ-33, AZ-16 and AZ-46 located in the southern zone and in well AZ-4 in the north. The isotopic (oxygen-18 and deuterium) patterns of fluids collected in September 2000 show that the original convective process found in the unperturbed reservoir is still taking place, although mixing of reservoir and reinjected fluids is also indicated. According to N₂ data, the effects of reinjection on the physical and chemical characteristics of the reservoir fluids can be observed in the northern part of the field. Until now, however, only a steam phase, resulting from boiling and steam separation of the re-injected mixture, is evident in the fluids discharged by the northern wells.     

Hydrothermal alteration and fluid inclusion geothermometry of los humeros geothermal field, Mexico

The Los Humeros geothermal field, located in Puebla State, Mexico, occurs in a caldera; drillholes to 3000 m depth encountered a sequence of Quaternary lavas and pyroclastic rocks that range in composition from rhyolite to basalt but are dominantly andesitic. These rest upon the local basement comprising limestone and siltstone of Cretaceous age, which was encountered below 2500 m in the northern part of the field and 1000 m in its southern part.Examination of 29 cores, mostly from below 900 m depth, from 14 wells show that the hydrothermal minerals that occur in the volcanic host rocks include quartz, calcite, epidote, amphibole, sericite, smectite, illite, chlorite, biotite, pyrite and hematite. Their distribution mainly reflects the prevailing hydrological and thermal regime where temperatures locally exceed 300°C. The limestone basement rocks, however, have altered to an assemblage that includes calcite, quartz, wairakite, garnet, wollastonite, parawollastonite, sericite and fluorite.The homogenization temperatures of 356 fluid inclusions were measured and the freezing temperatures of 200 determined. All except two sets of inclusions homogenized into the liquid phase and neither daughter minerals nor a clathrate phase were seen. The homogenization temperatures mostly match measured bore temperatures that range from 250 to 360°C and the apparent salinities are from 0.2 to 2.7 weight per cent NaCl equivalent, but some contribution to freezing point depression by CO₂ is likely.A preliminary model for the hydrology of the field based upon the hydrothermal alteration mineralogy and fluid inclusion data suggests that dilute hot water ascends via faults in the Central Caldera collapse area of the field and moves laterally outward to elsewhere within the caldera.     

Application of fluid inclusions to the study of Bagnore geothermal field (Tuscany, Italy)

A fluid inclusion study of the hydrothermal minerals in two breccias from two wells in the Bagnore geothermal field (Italy) has provided information on the evolution of the fluids, and has also demonstrated that fluid inclusions can be utilized as geothermometers in this geothermal field. Both breccias come from reservoir zones: one (Bagnore 3bis (Bg 3bis)) was cored at a depth of 3111 m below ground level (b.g.l.), whereas the other (Bagnore 22 (Bg 22)) was ejected during a blow-out, probably from a fractured zone present between 2200 and 2300 m b.g.l. The hydrothermal cement of the breccias is mostly made up of quartz, K-feldspar, Na-rich plagioclase, calcite, chlorite and illite. Fluid inclusion studies were carried out on quartz (Bg 3bis and Bg 22 breccias) and adularia (Bg 22 breccia). Three types of fluid inclusions were recognized in the Bg 3bis breccia. Type I (liquid-rich) inclusions trapped an aqueous fluid with a CO₂ concentration (1.7–2.7 mol/kg) that is significantly higher than present-day fluids (0.5 mol/kg). Type II (liquid-rich) inclusions formed after type I, and trapped a fluid with less CO₂ (0.6–1.0 mol/kg). Type III (vapor-rich) coexist with type I inclusions, and record an early fluid circulation under boiling conditions. The decrease of the CO₂ (and total gas) concentrations from type I inclusions to type II inclusions, and on to present-day conditions can be related to boiling with gas loss and/or mixing. Only one type of fluid inclusion (type II), with moderate CO₂ concentration (0.7–0.3 mol/kg), was found in the Bg 22 breccia. Boiling and/or mixing explain the variation of the CO₂ content in the Bg 22 reservoir fluid from inclusion formation to modern CO₂ concentration (0.3 mol/kg). The absence of any type I inclusions in Bg 22 breccia may be related to non-uniform CO₂ concentrations in different parts of the field. Present-day temperatures (295±10 °C for Bg 3bis and 320±10 °C for Bg 22) are close or equal to fluid inclusion average total homogenization temperatures (around 290 °C for Bg 3bis and 320 °C for Bg 22), suggesting that fluid inclusions can be useful for estimating local temperatures when direct measurements are not available or dubious.     

The shallow structure of Los Humeros and Las Derrumbadas geothermal fields, Mexico

Los Humeros caldera and Las Derrumbadas rhyolitic domes located in the State of Puebla (Mexico) are being extensively studied by Comisión Federal de Electricidad (CFE) to assess the geothermal potential of that area. Both geothermal sites have been locally studied with geological, geochemical and geophysical methods. In order to get a geological picture of the sub-surface of the area comprising both sites, a regional structural survey was conducted together with gravity and magnetics studies. These studies showed a regional weakness zone (the Libres-Oriental depression), where the volcanic activity related to the geothermal manifestations took place.The tectonic events in the area are represented by two systems of structures. The first one (N140°–N170°) gave rise to the folds and overthrusts affecting the sequence of calcareous rocks resting upon the basement. This system is affected by a second system (N40°–70°E). Regionally these tectonic events remodelled the sedimentary sequence giving rise to a series of topographic highs that constitute the core of several ranges, and to depressions that were filled with volcano-sediments during the ensuing volcanic activity.The rhyolitic domes of Las Derrumbadas are emplaced in a regional NW-SE lineament, which reflects clearly on the Bouguer anomaly, and is interpreted as a front of overthrust affecting the marine sedimentary sequence. Estimations of depths to the basement, based on magnetic data, showed that the basement under Los Humeros caldera is shallower than in Las Derrumbadas. The gravity data were interpreted in terms of tabular bodies associated to calcareous rocks, of igneous intrusions, and of depressions filled with volcano-sediments. A joint interpretation of the geological and geophysical data led to a model of the structure of the shallow crust in the area.     

Application of chemical geothermometers to thermal springs of the Maghreb,North Africa

In order to assess the geothermal potential in the Maghrebian region, several studies have been undertaken in the three countries concerned, Morocco, Algeria and Tunisia, during the past decade. Research programmes have considered the surface evidence (thermal springs) and underground thermal information from deep and shallow wells. The main chemical characteristics of the sampled thermal springs and the results of the application of geothermometers as result from these studies are presented. Of the 238 inventoried thermal springs, 169 have been selected, on the basis of complete water analyses and acceptable ionic balances. Measured temperatures range from 22.5 to 98°C, thermal indexes from 0.5 to 78°C and salinities from 0.13 to 52.5 g/L. Most studied springs are sodium-chloride type waters. These basic data allow identification of the main thermal anomalies in the Maghrebian zone, which are located in regions of the Libyan-Tunisian, Algerian-Moroccan and Algerian-Tunisian frontiers, of northern Tunisia, the Eastern Rif and the northern part of the Saharan Atlas.Several chemical geothermometers have been applied to selected springs: NaK, NaKCa, NaKCaMg, Na/Li, Mg/Li, K²/Mg, quarts, chalcedony (Fournier) and chalcedony (Arnorsson). The NaK, NaKCa, NaKCaMg, Na/Li and Mg/Li geothermometers seem to give unreliable results, while K²/Mg and silica temperatures are apparently reasonable. However, dissolved silica seems to be governed by quartz solubility for some thermal springs and by chalcedony solubility for others. The results are tentatively compared with known geothermal gradients and geological features.     

Basement structure, lithology and permeability at Kawerau and Ohaaki geothermal fields, New Zealand

Poorly permeable basement rocks commonly occur in geothermal regions around the world, and the Quaternary Taupo Volcanic Zone (TVZ) of New Zealand is no exception. Production from basement terrane requires detailed knowledge of its geological and geophysical parameters, as shown by the history of Kawerau and Ohaaki, the only geothermal fields in the TVZ where Mesozoic Torlesse terrane greywacke (litharenite) basement is commonly penetrated at drilled depths of 1–2.5 km. In both fields the basement is step-faulted down into the TVZ. Although hot and hydrothermally altered, the greywackes have little permeability. Some production wells feed from elusive basement faults at Kawerau, but rarely at Ohaaki. Greywackes at Ohaaki are of “granite-rhyolite” provenance, and have more interbedded argillite than the “andesite-dacite” derived Kawerau greywackes. In consequence, the Kawerau basement may sustain brittle fracture at higher temperatures and depths than the more ductile Ohaaki basement, allowing convective circulation of higher enthalpy fluids into permeable Quaternary aquifers.     

New geothermometers for carbonate—evaporite geothermal reservoirs

Two new Ca/Mg and SO₄/F geothermometers specific for carbonate-evaporite geothermal reservoirs are proposed. General considerations on waters interacting with such rocks suggest that Ca²⁺, Mg²⁺, CO²⁻₃, SO²⁻₄, F⁻ and SiO₂ are compatible components of the pertinent thermodynamic system and, therefore, their activities are fixed by five solid phases at equilibrium conditions. Geothermometric elaboration is based on the assumption that the five solid phases are represented by pure calcite, dolomite, anhydrite, fluorite and an SiO₂ mineral, e.g. quartz or chalcedony or amorphous silica. Pressure and ion association effects are not taken into consideration. Preliminary applications both to thermal waters and geothermal wells are promising. These new geothermometers could be widely used in the geothermal exploration of areas with carbonate-evaporite reservoirs, such as the two main geothermal fields of Italy, Larderello and Mt. Amiata. Further calibration by experimental studies and additional data from geothermal boreholes is needed, however, to test the practical reliability of the new geothermometers.