Critical factors in the design,operation and economics of coal gasification plants: The case of the flexible co-production of hydrogen and electricity

Power generation from wind and solar sources is growing in importance, but requires back up from fossil fuel plants, greatly compromising fossil fuel plant economics. This includes the economics of most proposed IGCC–Hypogen type plant schemes which are intended to produce hydrogen and electricity, as well as capturing CO₂. IGCC–Hypogen plants, however, that are able to change the ratio of hydrogen to electricity will be able to operate at maximum capacity all of the time, switching from power generation to hydrogen production as the demand for these two forms of energy changes. Because of the need to provide power to the IGCC–Hypogen ancillaries, some hydrogen from the plant will have to be utilised to supply some of this power. A preliminary economic study examines how the plant could produce electricity and hydrogen at competitive prices.     

Pathways to a more sustainable production of energy: sustainable hydrogen—a research objective for Shell

Towards a sustainable energy supply is a clear direction for exploratory research in Shell. Examples of energy carriers, which should be delivered to the envisaged sustainable energy markets, are bio-fuels, produced from biomass residues, and hydrogen (or electricity), produced from renewable sources. In contrast to the readily available ancient sunlight stored in fossil fuels, the harvesting of incident sunlight will be intermittent, efficient electricity and hydrogen storage technologies need to be developed. Research to develop those energy chains is going on, but the actual transformation from current fossil fuel based to sustainable energy markets will take a considerable time. In the meantime the fossil fuel based energy markets have to be transformed to mitigate the impact of the use of fossil fuels. Some elements in this transformation are fuels for ultra-clean combustion (hydrocarbons and oxygenates), hydrogen from fossil fuels, fuels for processors for fuel cells, carbon sequestration.     

Life cycle cost analysis: A case study of hydrogen energy application on the Orkney Islands

Hydrogen can compensate for the intermittent nature of some renewable energy sources and encompass the options of supplying renewables to offset the use of fossil fuels. The integrating of hydrogen application into the energy system will change the current energy market. Therefore, this paper deploys the life cycle cost analysis of hydrogen production by polymer electrolyte membrane (PEM) electrolysis and applications for electricity and mobility purposes. The hydrogen production process includes electricity generated from wind turbines, PEM electrolyser, hydrogen compression, storage, and distribution by H₂ truck and tube trailer. The hydrogen application process includes PEM fuel cell stacks generating electricity, a H₂ refuelling station supplying hydrogen, and range extender fuel cell electric vehicles (RE-FCEVs). The cost analysis is conducted from a demonstration project of green hydrogen on a remote archipelago. The methodology of life cycle cost is employed to conduct the cost of hydrogen production and application. Five scenarios are developed to compare the cost of hydrogen applications with the conventional energy sources considering CO₂ emission cost. The comparisons show the cost of using hydrogen for energy purposes is still higher than the cost of using fossil fuels. The largest contributor of the cost is the electricity consumption. In the sensitivity analysis, policy supports such as feed-in tariff (FITs) could bring completive of hydrogen with fossil fuels in current energy market.     

Electric power required in the world by 2050 with hydrogen fuel production—Revised

Since estimation of electric power requirement for large-scale production of hydrogen fuel for the world vehicle fleet based on data through 1995 in 2001, a large increase in available travel data has become available, sufficient to revise the estimates with greater confidence. It is apparent that much more energy will be required, as worldwide demand for electrification and substitution of hydrogen for fossil fuel in transportation grows over the next 50 years. Published forecasts for electricity demand over the next 30 years show mean annual growth rates ranging from 1.7 to 3.4%/a, which when extrapolated from the present consumption of 16 PWh in 2002 to the year 2050 suggests an annual electricity demand in the range of 36–82 PWh. In addition to the business-as-usual growth in demand, estimation of the growth of the world automotive vehicle fleet from about 900 million vehicles in 2010, consuming about 360 billion gallons of petrol, to about 1.5 billion vehicles in 2050, which could be operated with about 260 billion kilogram of hydrogen fuel, would result in additional electricity demand of about 10 PWh annually for replacement of fossil fuels in transportation. With approximately 175 PW of solar power reaching earth and world fossil fuel reserves of 50–200 years remaining at present consumption rates, the question arises of how much of the world's future electric energy supply will be required (if any) from nuclear fuels.     

Preparation of hydrogen from metals and water without CO2 emissions

Considering the high calorific value and low-carbon characteristics of hydrogen energy, it will play an important role in replacing fossil energy sources. The production of hydrogen from renewable energy sources for electricity generation and electrolysis of water is an important process to obtain green hydrogen compared with classic low-carbon hydrogen production methods. However, the challenges in this process include the high cost of liquefied hydrogen and the difficulty of storing hydrogen on a large scale. In this paper, we propose a new route for hydrogen storage in metals, namely, electricity generation from renewable energy sources, electrolysis to obtain metals, and subsequent hydrogen production from metals and water. Metal monomers facilitate large-scale and long-term storage and transportation, and metals can be used as large-scale hydrogen storage carriers in the future. In this technical route, the reaction between metal and water for hydrogen production is an important link. In this paper, we systematically summarize the research progress, development trend, and challenges in the field of metal to hydrogen production. This study aim to aid in the development of this field.     

Appropriate technologies for large-scale production of electricity and hydrogen fuel

Appropriate technology for energy supply requires the use of the most effective energy resources and conversion technologies that will also result in the minimum acceptable impact upon the environment. A useful parameter for evaluation of energy resources for large-scale production of electricity and hydrogen fuel is the specific energy of the appropriate energy resources. Available resources for such large-scale applications must come from some mixture of renewable, fossil, and nuclear energy. Analysis is made of the appropriate use of solar energy, chemical combustion fuels, and nuclear energy on the basis of their specific energy. The results show that the most appropriate resources for large-scale production of electricity and hydrogen are low-specific solar photovoltaic and wind turbine energy for large numbers of distributed small-scale applications and high-specific nuclear energy for smaller numbers of large-scale applications.     

A strategic roadmap for ASEAN to develop hydrogen energy: Economic prospects and carbon emission reduction

The progress of hydrogen energy in terms of technologies and supply chains is appealing to member countries of the Association of Southeast Asian Nations (ASEAN). Countries with the advantages of fossil fuel resources and existing infrastructure can export grey hydrogen energy until 2025. This could help expand hydrogen-related infrastructure and form a certain level of economies of scale to prepare for the next phase of development of blue and green hydrogen energy. From 2026 to 2030, ASEAN could shift to blue hydrogen energy exports with the help of carbon capture, utilization, and storage. However, the domestic applications of hydrogen energy will remain economically uncompetitive in most ASEAN countries. After 2030, as the levelized costs of electricity for renewables decline and the share of renewable energy power increases, the cost of hydrogen energy production from surplus electricity could become even lower. Consequently, green hydrogen energy will dominate domestic downstream energy applications and exports to overseas markets.     

Techno-economic analysis of the integration of hydrogen energy technologies in renewable energy-based stand-alone power systems

A large number of stand-alone power systems that are based on fossil fuel or renewable energy (RE) based, are installed all over Europe. Such systems, often comprising photovoltaics (PV) and/or diesel generators provide power to communities or technical installations, which do not have access to the local or national electricity grid. The replacement of conventional technologies such as diesel generators and/or batteries with hydrogen technologies, including fuel cells in an existing PV-diesel stand-alone power system providing electricity to a remote community was simulated and optimised, using the hybrid optimisation model for electric renewables (HOMER) simulation tool. A techno-economic analysis of the existing hybrid stand-alone power system and the optimised hydrogen-based system was also conducted. The results of the analyses showed that the replacement of fossil fuel based gensets with hydrogen technologies is technically feasible, but still not economically viable, unless significant reductions in the cost of hydrogen technologies are made in the future.     

Helio-hydro and helio-thermal production of hydrogen

Fossil fuels account for about 80% of the world annual energy demands. Renewables contribute 14% and nuclear some 6%. These numbers will soon change as the world's population grows, energy demand rises, cheap oil and gas deplete, global warming effects continue rising and city pollution worsens the living conditions. The development of energy sources and devices will emerge more aggressively to address the world's energy and environmental situation. A concept of using hydrogen as an energy carrier or storage as a fuel, a replacement of burning fluid fossil fuels is presented. Sources of energy from which hydrogen can be produced in a massive quantity and at a low cost are briefly surveyed. A short account of devices to be employed for hydrogen production is given. Primarily the sun, sea, runoff waters, winds and fissionable materials are to be utilized. The discussion on the inexhaustibility of naturally occurring sources utilized and/or harnessed in this process will lead to the low cost for hydrogen production. Some hydrogen rich products including hydrogen sulfide and methane accompany the oil, gas and brine, when they are pumped out of the ground. While methane is used sometimes as fuel; the hydrogen sulfide is disposed off invariably. In principle, hydrogen can be extracted from these waste products. We discuss here to produce hydrogen in economically feasible manner. The use of brine as a means of usable solar energy in the form of heat and electricity was discussed earlier. Here, we aim at discussing the production of hydrogen from the brine and hydrogen sulfide gas. The brine is proposed to be utilized for two purposes: one for salt gradient solar pond to produce usable heat and electricity, and the other as an electrolyte to produce hydrogen out of itself. The hydrogen from hydrogen sulfide can chemically be extracted.     

CO2-free hydrogen production via microwave-driven methane pyrolysis

Hydrogen will play an integral role in achieving net-zero emissions by 2050. Many studies have been focusing on green hydrogen, but this method is highly electricity intensive. Alternatively, methane pyrolysis can produce hydrogen without direct CO₂ emissions and with modest electricity inputs, serving as a bridge from fossil fuels to renewable energies. Microwaves are an efficient method of adding the required energy for this endothermic reaction. This study introduces a new method of CO₂-free hydrogen production via non-plasma methane pyrolysis using microwaves and carbon products of this process. Carbon particles in the fluidized bed absorb microwave energy and create a hot medium (>1200 °C) in contact with flowing methane. As a result, methane decomposes into hydrogen and solid carbon achieving over 90% hydrogen selectivity with ∼500 cumulative hours of experiments This modular pyrolysis system can be built anywhere with access to natural gas and electricity, enabling distributed hydrogen production.     

Critical assessment of the production scale required for fossil parity of green electrolytic hydrogen

Hydrogen produced from renewable electricity through Power-to-Hydrogen can facilitate the integration of high levels of variable renewable electricity into the energy system. An electrolyser is a device that splits water into hydrogen and oxygen using electricity. When electricity is produced from renewable energy sources, electrolytic hydrogen can be considered to be green. At the same time, electrolysers can help integrate renewable electricity into power systems, as their electricity consumption can be adjusted to follow wind and solar power generation. Green hydrogen then also becomes a carrier for renewable electricity. Key green hydrogen production technologies, mostly PEM and alkaline electrolysers, are still further maturing, both in technical (efficiency), economical (CAPEX) and durability (lifetime) performance. Nonetheless, we will show in this contribution how fossil parity for green hydrogen, i.e. a Total Cost of Ownership (TCO) similar to grey H₂ coming from todays CO₂ intensive SMR processes, can already be achieved today. Moreover, this can be realised at a scale which corresponds to the basic units of renewable electricity generation, i.e. a few MW.     

SUNRISE – A caesura after nuclear has gone: Energy in Germany(and in other potentially de-nuclearizing countries)

The German Bundestag decided June 30, 2011 to shut down by 2022 stepwise the complete national nuclear power plant capacity which at the time of decision generated some 22% of the nation’s electricity demand. This presentation tries to present a technology forecast of three potential compensations 1) energy and exergy efficiency gains, 2) renewable energies, and 3) hydrogen energy, thereby bearing in mind that fossil fuels such as coal, mineral oil and natural gas will by no means be gone after that short 10 year transition time. Consequently, not only the three compensations, but also fossil fuels – now efficient to the technological utmost – have to meet the obligation of reducing anthropogenic environmental and climate changing influences, and, in Germany’s case with 75% of its energy demand covered by imports of great importance, try to decrease the almost life risking high import rate by distributing suppliers all over the world and start introducing global clean renewable energies and trade in renewable hydrogen energy. Whether SUNRISE will evolve into a paragon for all those nations thinking of, planning for, or already taking the first steps towards saying farewell to nuclear is too early to determine. The four components of energy sustainability compensating for nuclear – energy and exergy efficiency gains, clean fossil, solar and hydrogen – pluck up courage, make headway and leave nuclear behind. And, in particular, hydrogen energy is and will increasingly become humankind’s common cause!     

Techno-economic assessment of hydrogen production from seawater

Population growth and the expansion of industries have increased energy demand and the use of fossil fuels as an energy source, resulting in release of greenhouse gases (GHG) and increased air pollution. Countries are therefore looking for alternatives to fossil fuels for energy generation. Using hydrogen as an energy carrier is one of the most promising alternatives to replace fossil fuels in electricity generation. It is therefore essential to know how hydrogen is produced. Hydrogen can be produced by splitting the water molecules in an electrolyser, using the abondand water resources, which are covering around ? of the Earth's surface. Electrolysers, however, require high-quality water, with conductivity in the range of 0.1–1 μS/cm. In January 2018, there were 184 offshore oil and gas rigs in the North Sea which may be excellent sites for hydrogen production from seawater. The hydrogen production process reported in this paper is based on a proton exchange membrane (PEM) electrolyser with an input flow rate of 300 L/h. A financially optimal system for producing demineralized water from seawater, with conductivity in the range of 0.1–1 μS/cm as the input for electrolyser, by WAVE (Water Application Value Engine) design software was studied. The costs of producing hydrogen using the optimised system was calculated to be US$3.51/kg H₂. The best option for low-cost power generation, using renewable resources such as photovoltaic (PV) devices, wind turbines, as well as electricity from the grid was assessed, considering the location of the case considered. All calculations were based on assumption of existing cable from the grid to the offshore, meaning that the cost of cables and distribution infrastructure were not considered. Models were created using HOMER Pro (Hybrid Optimisation of Multiple Energy Resources) software to optimise the microgrids and the distributed energy resources, under the assumption of a nominal discount rate, inflation rate, project lifetime, and CO₂ tax in Norway. Eight different scenarios were examined using HOMER Pro, and the main findings being as follows:The cost of producing water with quality required by the electrolyser is low, compared with the cost of electricity for operation of the electrolyser, and therefore has little effect on the total cost of hydrogen production (less than 1%).The optimal solution was shown to be electricity from the grid, which has the lowest levelised cost of energy (LCOE) of the options considered. The hydrogen production cost using electricity from the grid was about US$ 5/kg H₂.Grid based electricity resulted in the lowest hydrogen production cost, even when costs for CO₂ emissions in Norway, that will start to apply in 2025 was considered, being approximately US$7.7/kg H₂.From economical point of view, wind energy was found to be a more economical than solar.     

Steps toward the hydrogen economy

The hydrogen economy is defined as the industrial system in which one of the universal energy carriers is hydrogen (the other is electricity) and hydrogen is oxidized to water that may be reused by applying an external energy source for dissociation of water into its component elements hydrogen and oxygen. There are three different primary energy-supply system classes which may be used to implement the hydrogen economy, namely, fossil fuels (coal, petroleum, natural gas, and as yet largely unused supplies such as shale oil, oil from tar sands, natural gas from geo-pressured locations, etc.), nuclear reactors including fission reactors and breeders or fusion nuclear reactors over the very long term, and renewable energy sources (including hydroelectric power systems, wind-energy systems, ocean thermal energy conversion systems, geothermal resources, and a host of direct solar energy-conversion systems including biomass production, photovoltaic energy conversion, solar thermal systems, etc.). Examination of present costs of hydrogen production by any of these means shows that the hydrogen economy favored by people searching for a non-polluting gaseous or liquid energy carrier will not be developed without new discoveries or innovations. Hydrogen may become an important market entry in a world with most of the electricity generated in nuclear fission or breeder reactors when high-temperature waste heat is used to dissociate water in chemical cycles or new inventions and innovations lead to low-cost hydrogen production by applying as yet uneconomical renewable solar techniques that are suitable for large-scale production such as direct water photolysis with suitably tailored band gaps on semiconductors or low-cost electricity supplies generated on ocean-based platforms using temperature differences in the tropical seas.     

The role of hydrogen in high wind energy penetration electricity systems: The Irish case

The deployment of wind energy is constrained by wind uncontrollability, which poses operational problems on the electricity supply system at high penetration levels, lessening the value of wind-generated electricity to a significant extent. This paper studies the viability of hydrogen production via electrolysis using wind power that cannot be easily accommodated on the system. The potential benefits of hydrogen and its role in enabling a large penetration of wind energy are assessed, within the context of the enormous wind energy resource in Ireland. The exploitation of this wind resource may in the future give rise to significant amounts of surplus wind electricity, which could be used to produce hydrogen, the zero-emissions fuel that many experts believe will eventually replace fossil fuels in the transport sector. In this paper the operation of a wind powered hydrogen production system is simulated and optimised. The results reveal that, even allowing for significant cost-reductions in electrolyser and associated balance-of-plant equipment, low average surplus wind electricity cost and a high hydrogen market price are also necessary to achieve the economic viability of the technology. These conditions would facilitate the installation of electrolysis units of sufficient capacity to allow an appreciable increase in installed wind power in Ireland. The simulation model was also used to determine the CO₂ abatement potential associated with the wind energy/hydrogen production.     

Political,economic and environmental impacts of biomass-based hydrogen

The purpose of this study is to assess the political, economic and environmental impacts of producing hydrogen from biomass. Hydrogen is a promising renewable fuel for transportation and domestic applications. Hydrogen is a secondary form of energy that has to be manufactured like electricity. The promise of hydrogen as an energy carrier that can provide pollution-free, carbon-free power and fuels for buildings, industry, and transport makes it a potentially critical player in our energy future. Currently, most hydrogen is derived from non-renewable resources by steam reforming in which fossil fuels, primarily natural gas, but could in principle be generated from renewable resources such as biomass by gasification. Hydrogen production from fossil fuels is not renewable and produces at least the same amount of CO₂ as the direct combustion of the fossil fuel. The production of hydrogen from biomass has several advantages compared to that of fossil fuels. The major problem in utilization of hydrogen gas as a fuel is its unavailability in nature and the need for inexpensive production methods. Hydrogen production using steam reforming methane is the most economical method among the current commercial processes. These processes use non-renewable energy sources to produce hydrogen and are not sustainable. It is believed that in the future biomass can become an important sustainable source of hydrogen. Several studies have shown that the cost of producing hydrogen from biomass is strongly dependent on the cost of the feedstock. Biomass, in particular, could be a low-cost option for some countries. Therefore, a cost-effective energy-production process could be achieved in which agricultural wastes and various other biomasses are recycled to produce hydrogen economically. Policy interest in moving towards a hydrogen-based economy is rising, largely because converting hydrogen into useable energy can be more efficient than fossil fuels and has the virtue of only producing water as the by-product of the process. Achieving large-scale changes to develop a sustained hydrogen economy requires a large amount of planning and cooperation at national and international alike levels.     

The transition to renewables: Can PV provide an answer to the peak oil and climate change challenges?

This paper explores energy and physical resource limitations to transitioning from fossil fuels to the large-scale generation of electricity with photovoltaic arrays. The model finds that business as usual models, which involve growth rates in world electricity demand of between 2% and 3.2% p.a., exhibit severe material difficulties before the end of this century. If the growth rate is lowered to 1% p.a., then it may be possible to reach the year 2100 before such difficulties, but it is likely that material constraints will occur early the next century. Steady state scenarios show that silicon based photovoltaic panels could, however, displace fossil fuels before the middle of the century, providing around the same order of magnitude as present (2010) world electricity demand. Scenarios also show that outcomes will be highly dependent upon the rate of improvement of photovoltaic technologies. The analysis does not contend that silicon PV technology is the only technology that will or can be adopted, but as the embodied energy content per kWh generated of this technology is similar to other renewable technologies, such as other solar technologies and wind, it can provide a baseline for examining a transition to a mixture of renewable energy sources.     

Hydrogen as an energy carrier in stand-alone applications based on PV and PV–micro-hydro systems

The paper compares two different models of a hypothetical stand-alone energy system based only on renewable sources (solar irradiance and micro-hydro power) integrated with a system for the production of hydrogen (electrolyzer, compressed gas storage and proton exchange membrane fuel cell or PEMFC). The models of both systems have been designed to supply the electricity needs of a residential user in a remote area (a valley of the Alps in Italy) during a complete year of operation, without integration of traditional fossil fuel energy devices. A simulation model has been developed to analyze the energy performance of these systems. The technical feasibility and the behavior of the systems will be evaluated through the analysis of some data (e.g. the production and consumption of electricity along the year by the different components; the heat management; the production, storage and utilization of hydrogen).     

Photovoltaics and hydrogen: Future energy options

Solar power is destined to make a significant contribution to world energy supply for reasons of both the finite amount of fossil fuels and environmental damage consciousness. It is emphasized that the global environmental damage caused thermodynamically is more alarming to life on Earth than the risk of exhausting the finite amount of fossil fuels being consumed at the present rate. Solar power plants can be designed and constructed to convert solar radiation into some concentrated form of useful energy first and then into electricity or directly into electricity. The latter kind is comprised of photovoltaic cells. This paper discusses some of the solar energy options and also presents a historical overview, explains the rudimentary physical principles of the technology, the photovoltaic effect, the process to generate electricity in silicon solar cells, thin-film devices and high efficiency cells, and finally, the state-of-the-art of the latest developments in solar cell technology. Finally, the storing of solar energy, collected by a photovoltaic system, is recommended in the form of hydrogen as a future energy option.