Variation of total column ozone along the monsoon trough region over north India

This study examined the total column ozone (TCO) variations over New Delhi (28.65° N, 77.217° E) and Varanasi (25.32° N, 83.03° E), which lie along the monsoon trough region, and over the tropical station Kodaikanal (10.23° N, 77.46° E), which lies outside the monsoon trough. Monthly, seasonal and annual TCO variations were determined using data from ground-based Dobson spectrophotometers during 2000–2008, Brewer spectrophotometers during 2000–2005 and the satellite-based Scanning Imaging Absorption Spectrometer for Atmospheric Cartography (SCIAMACHY) during 2002–2008. We found that Dobson, Brewer and SCIAMACHY TCO variations showed negative trends, indicating a decreasing tendency during the period studied at all three stations. Over Varanasi, the trend decreased further by about 3 DU year^?1. Quasi-Biennial Oscillation (QBO) influences were seen in the time series of TCO over New Delhi and Varanasi, and weaker QBO signals over Kodaikanal. Comparisons were made between ground-based Dobson and Brewer spectrophotometer and SCIAMACHY satellite monthly mean TCO values. The differences between SCIAMACHY and Dobson TCO were 0.4–4.2% for New Delhi and 2.3–6.2% for Varanasi. The differences between SCIAMACHY and Brewer TCO values were 2.0–6.4% for Kodaikanal. In the peak monsoon months (July and August), decreases in TCO values over New Delhi and Varanasi (the monsoon trough region) may be due to the deep convection present during the monsoon season. During the monsoon season, several intense cyclonic systems appear over the monsoon trough region and may cause lowering of the TCO. Kodaikanal shows opposite features, with high values being observed during the peak monsoon months. TCO values over New Delhi were found to be higher than those over Varanasi and Kodaikanal, and TCO values over Varanasi were higher than over Kodaikanal. It was concluded that TCO values increase with increasing latitude.     

Comparison of total ozone column observations from space-borne Ozone Monitoring Instrument with ground-based Dobson Ozone Spectrophotometer measurements at an urban location in Indo-Gangetic Basin

This article presents a comparison analysis of OMIT (Ozone Monitoring Instrument retrieved overpass total ozone column (TOC)), and DOST (Dobson Ozone Spectrophotometer observed TOC) over Delhi during a period from October 2004 to June 2011. Megacity Delhi, located in Indo-Gangetic Basin, is an important site for comparison of ground-based and satellite retrieved TOCs due to significant anthropogenic emissions of ozone precursors, large shift in seasons, and large-scale crop residue burning in the region. DOST and OMIT data show an overall bias of 3.07% and significant correlation with coefficient of determination R² = 0.73. Large seasonal fluctuations in the biases and correlations have been observed ranging from 2.46% (winter) to 3.82% (spring), and R² = 0.84 (winter) to R² = 0.09 (summer), respectively. The large biases are attributed to changes in temperature, cloud cover, pollutants emissions from urban area, and crop-residue burning events. We also find notable variations in correlations between the datasets due to the varying burden of absorbing aerosols from open field crop-residue burning. The R² has changed from 0.67 (for aerosol optical depth, AOD 1.5–3.5) to 0.77 (for AOD 0–0.99). The dependence of the bias on solar zenith angle, cloud fraction, and satellite distance is also discussed. A simple linear regression analysis is applied to check the linkage between DOST and OMIT. The influence of atmospheric air temperature and relative humidity on OMIT at different pressure levels between 1000 and 20 hPa has been discussed.     

Sulphur dioxide loadings over megacity Lahore (Pakistan) and adjoining region of Indo-Gangetic Basin

This article presents spatial and temporal variations of planetary boundary layer (PBL) sulphur dioxide (SO₂) over megacity Lahore and adjoining region, a typical representative area in the Indo-Gangetic Basin (IGB) largely influenced by transported volcanic SO₂ from Africa, Middle East, and southern Europe, by using data retrieved from satellite-based Ozone Monitoring Instrument (OMI) during October 2004–September 2015. We find a positive trend of 2.4% per year (slope 0.01 ± 0.005 with y-intercept 0.35 ± 0.03 Dobson Unit (DU), correlation coefficient r = 0.55 and 2-tailed p-value at 0.1) of OMI-SO₂ column with the average value of 0.4 ± 0.05 DU. Strong seasonality of OMI-SO₂ column is observed over the region linked with local meteorology, patterns of anthropogenic emissions, crop residue burning, and vegetation cover. There exists a seasonal high value in winter 0.56 ± 0.24 DU with a peak in December 0.67 ± 0.26 DU. The seasonal lowest value is observed to be 0.29 ± 0.11 DU in wet summer with minimum value in July 0.25 ± 0.06 DU. High growth rates of OMI-SO₂ column over the study region have been observed in January, June, October, and December ranging from 5.7% to 11.6% per year. Satellite data show elevated OMI-SO₂ columns in 2007, 2008, 2011, and 2012 largely contributed by trans-boundary volcanic SO₂. A detailed analysis of volcanic SO₂ transported from Africa and Middle East (Jabal Al-Tair, Dalaffilla, and Nabro volcanoes) over the study area is presented. Air mass trajectories suggest the presence of long-range transported volcanic SO₂ at high altitude levels over Lahore and IGB region during the volcanic episodes. The SO₂ enhancements in PBL during winter season are generally due to significant vertical downdraft of high-altitude volcanic SO₂. For the first time, we present significant influence of volcanic SO₂ from southern Europe (Mt. Etna volcano) reaching over the study area. Daily mean OMI-SO₂ levels up to 21.4, 10.0, 5.6, and 2.4 DU have been noticed due to the eruptions from Dalaffilla, Mt. Etna, Nabro, and Jabal Al-Tair volcanoes, respectively.     

Comparison of vertical ozone profiles as deduced from remote and in situ sensing techniques

A number of vertical ozone profiles up to 35 km in height, have been measured using balloon-based sensors at Athens, Greece (38^° N, 24^° E). The measurements were made during the winter of 1991-1992, as part of the European Arctic Stratospheric Ozone Experiment (EASOE). The data collected during the balloon ascents have been compared with those during the balloon descents. Both profiles are compared with the total ozone measurements derived from the TOMS on the Nimbus-7 satellite and the Dobson spectrophotometer.     

Characterization of aerosols and pre-cursor gases over Maitri during 24th Indian Antarctica Expedition

Within the framework of the 24th Indian Antarctica Expedition (IAE), observations of total column aerosol optical depth (AOD), ozone (TCO) and precipitable water content (TCW) using a multi-channel solar-radiometer (MICROTOPS-II: Microprocessor-controlled Total Ozone Portable Spectrometer-II), and observations of short-wave global radiative flux using a wide-band pyranometer have been carried out over the Indian Antarctica station Maitri (70.76° S, 11.74° E) and the southern Indian Ocean during December 2004–February 2005. These extensive datasets have been utilized to investigate the aerosol optical, physical and radiative properties, and their interface with simultaneously measured gases. Data over the Oceanic region have been collected from the ship front deck. The daily mean AOD at a characteristic wavelength of 500 nm was found to be 0.042 with an average Angstrom coefficient of 0.24, revealing an abundance of coarse-mode particles. Interestingly, the January fluxes were found to be less by about 20% compared with those in February. The average short-wave direct radiative forcing due to aerosols showed cooling at the surface with an average value of??0.47 Wm^?2. The TCO increased from about 252 DU around 38° S to about 312 DU at 70° S, showing a gradual increase in ozone with increasing latitude. The TCO measured by the surface-based ozone monitor matched reasonably well with that observed by the Total Ozone Mapping Spectrometer (TOMS) satellite sensor within 5%. Variability in ozone on a daily scale during the study period was less than 4% over the Antarctica region.     

Long-term trends and decadal solar variability in ozone near the tropopause over the Indian region

To investigate the long-term trends and effects of decadal solar variability in the upper tropospheric ozone, data obtained from the Stratospheric Aerosol and Gas Experiment II (SAGE II) aboard the Earth Radiation Budget Satellite (ERBS) during the period 1985–2005 were analysed using a multifunctional regression model over the Indian region (8–40° N; 65–100° E). Analysis of time series spanning these years shows statistically insignificant trends (at the two-sigma level (95% confidence level)) at upper tropospheric pressure levels (10?16 km). This period covers two solar cycles, one lasting from 1985 to 1995 and the other from 1996 to 2005; these are referred to as decade I and decade II, respectively. Since temporal variation in ozone number density indicates 11 year periodicity, trends are statistically significant when calculated separately during each solar cycle. Trend analysis indicates statistically significant positive trends (0.7 ± 1.7% to 3.9 ± 2.9% year^?1 during decade I, and 2.2 ± 1.6% to 4.5 ± 3.0% year^?1 during decade II). In general, higher ozone trends are observed during decade II. Seasonal variation in trends during decade II shows increasing trends during the pre-monsoon (0.8?3.8% year^?1), monsoon (0.8?7.1% year^?1), and post-monsoon (2.8?8.0% year^?1) seasons. The annually averaged solar signal in ozone is found to be of the order of around??5 ± 4.3% to??13.8 ± 6.7%/(100 sfu). Results obtained in the present study are also compared with those obtained by other researchers.     

Improvement of the Umkehr ozone profile by the neural network method: analysis of the Belsk (51.80°N, 20.80°E) Umkehr data

Vertical profiles of atmospheric ozone by the neural network (NN) method are compared with those obtained by the standard Umkehr inversion algorithm – UMK92. Both methods used the same input, the so-called N values, derived from Umkehr measurements at Belsk (51.80°N, 20.80°E), Poland, by the Dobson spectrophotometer No 84. The vertical profiles of ozone from satellite observations, Microwave Limb Sounder (MLS) overpasses for the period 2004–2009, and from ozonesoundings performed at the nearby aerological station, Legionowo (52.4° N, 21.0° E), for the period 2000–2009 provide a reference data set for the NN model building. The NN methodology appears to be a promising tool for extracting information about the vertical ozone profile from ground-based Umkehr measurements, despite some limitations of the NN method itself, such as the results being limited to the analysed station, sensitivity to errors in the reference data sets, and lack of possibility to determine the actual retrieval errors. Accuracy of the NN ozone profiles is better for all Umkehr layers than that by the standard Umkehr inversion algorithm when NN and UMK92 profiles are compared with the reference profiles. It is especially pronounced for comparisons with the ozonesonde profiles for layers 4 and 1, where the absolute error changes from 10.6 Dobson units (DU) (UMK92) to 4.4 DU (NN) and from 6.6 DU (UMK92) to 3.5 DU (NN), respectively (1 Dobson unit is equal to 2.69 × 10²⁰ molecules/m²). The mean (over all Umkehr layers) correlation coefficient between NN-MLS, and NN-ozonesonde profiles is 0.75 and 0.85, respectively. The corresponding correlation coefficients for the comparison with UMK92 profiles are lower, i.e. 0.61 and 0.64, respectively.     

Satellite remote sensing of total ozone column (TOC) over Pakistan and neighbouring regions

Total ozone column (TOC) obtained from the Ozone Monitoring Instrument (OMI) on board the Aura satellite was utilized to examine the spatio-temporal distribution of atmospheric ozone over Pakistan and adjoining regions of Afghanistan, India, and Iran for October 2004 to March 2014. This region has not yet been evaluated in greater detail. A yearly spatial averaged value of 278 ± 2 DU was found over the region. A decadal increase of 1.3% in TOC value over study region was observed for the first time. Large spatial and temporal variability of TOC was found over the study region. Elevated ozone columns were observed over the regions with high NO₂ and CO concentrations. Analysis indicated that Srinagar city has the highest averaged value of 290 ± 3 DU whereas Jodhpur city showed the highest increasing trend of 1.9% per decade. A monthly averaged maximum value of 289 ± 8 DU and a minimum of 264 ± 5 DU were found during April and November, respectively, over the region. January showed a decreasing trend of ?0.8% and February exhibited the highest increasing trend of 5.1% per decade. Forward trajectory analysis showed the possibility of ozone transport from eastern parts of the study region towards the Indian Ocean (Bay of Bengal) through the subtropical jet stream creating low values at higher meridians in October. TOC data deduced from OMI and the Atmospheric Infrared Sounder were compared to check the level of correlation and the results showed significant correlation (r = 0.75) and an acceptable average relative difference of 4.2%.     

Total ozone observations at Athens,Greece by satellite-borne and ground-based instrumentation

A comparison is made of total ozone (TOZ) content observations conducted by the Dobson spectrophotometer No. 118, the SCanning Imaging Absorption SpectroMeter for Atmospheric CHartographY (SCIAMACHY), the Total Ozone Mapping Spectrometer (TOMS) and the Ozone Monitoring Instrument (OMI) over Athens, Greece, during 1991–2008. Spearman's and Wilcoxon's tests were used to determine the measure of the agreement between the ground-based and satellite column ozone data. The correlation coefficient between Dobson and Nimbus-7, ADEOS, Earth Probe, OMI and SCIAMACHY observations was found to be 0.95, 0.96, 0.94, 0.93 and 0.87, respectively, while the correlation coefficient between total ozone observations of SCIAMACHY and Earth Probe-TOMS and OMI is 0.85 and 0.93, respectively. SCIAMACHY overestimates the column ozone with respect to Dobson, Earth Probe-TOMS and OMI by 10, 15 and 3 DU, respectively, while Dobson underestimates the column ozone with respect to Nimbus-7, ADEOS and OMI by 5, 10 and 8 DU. The results obtained confirm that the Athens Dobson station may continue to be considered as a ground-truth total ozone station for the validation of the satellite column ozone observations. In addition, linear regression analysis of the deseasonalized monthly mean column ozone, as derived from Dobson measurements, gives an increase of +0.33 ± 0.07% per year during 1991–2000 and a decrease of –0.33 ± 0.07% per year for the period 2001–2008.     

Aerosol characteristics during the coolest June month over New Delhi,northern India

June 2008, which is also the transition month between two major seasons for Indo-Gangetic Basin (IGB), has been identified the coolest June over New Delhi during the past century, showing mean temperature of 31.6 ± 1.7°C, which was found to be ～2°C less than its climatological mean (33.9°C). Aerosol optical properties for this month and thus obtained physical parameters have been studied using data from the CIMEL sun/sky radiometer, installed in New Delhi under the Aerosol Robotic Network (AERONET) programme. Results reveal bimodal aerosol volume size distribution. The monthly mean values for aerosol optical depth (AOD) at 500 nm (0.96 ± 0.31) and Ångström exponent at the wavelength pair of 440–870 nm (0.79 ± 0.42) show significant lower values whereas single scattering albedo at 675 nm shows a significantly larger value (0.94 ± 0.04) compared with previous measurements over the station. Results suggest dominance of scattering-type particles such as water-soluble aerosols from anthropogenic sources and dust aerosols from natural sources with higher relative humidity over the station. Radiative forcing caused due to the aerosols for the month of June 2008, which have been computed using the radiative-transfer model, informs low forcing at the top of atmosphere (TOA,?+14 W m^?2) as well as at surface (?33 W m^?2). The resultant atmospheric forcing (+47 W m^?2) indicates warming effect that caused heating of lower atmosphere at the rate of 0.89 K day^?1.     

Cover Application of the NOAA-AVHRR images to the study of the large forest fires in Spain in the summer of 1994.

Ozone vertical profiles derived from Umkehr observations by the Dobson spectrophotometer at Belsk (52.50° N, 20.47° E) and from ozone soundings carried out at the nearest aerological station, Legionowo (52.24° N, 20.58° E), have been compared with those measured by the MLS instrument on board the Aura spacecraft during the sites' overpasses for the period 2004–2005. It is assumed that the satellite station distance should be less than 2° and less than 4° for the latitudinal and longitudinal difference, respectively. The bias, RMS error, and the correlation coefficients between the ozone content in the Umkehr layers have been calculated using Dobson/sonde/MLS data. The ozone mixing ratio at selected levels in the lower and mid‐stratosphere (from 215 hPa up to 6.8 hPa) have been compared using the sonde/MLS data. The number of analysed daily values was ～40 (Dobson/MLS), 60 (sonde/MLS), and 60 (Dobson/sonde) since August 2004. The comparisons show a good correspondence (bias ～±5%, RMS <10%, correlation coefficient >0.5) between the ozone content in Umkehr layers 4–8 and ozone mixing ratio at pressures <50 hPa. At lower stratosphere (Umkehr layer 3) and upper stratosphere (Umkehr layer 9), there is also statistically significant relationship between the data, but the biases and RMS are ～2 times larger, while the correlation coefficients are still high (>0.7).     

An investigation of temporal variability of the total column ozone over tropical urban,high altitude,and coastal stations in Western Maharashtra,India

Distribution and variability of ozone are vital to the atmospheric thermal structure as it can exert great influence on climate. In this study, the Microtops II Ozonometer (Microtops)-measured total column ozone (TCO) data archived at the tropical urban, high altitude, and coastal observing sites during 2012–2015 are analysed to investigate the temporal structure of ozone. Results reveal that the TCO exhibits a non-negligible diurnal variability depicting distinct seasonal behaviour, which corroborates well with the Indian as well as the worldwide measurements of TCO. The mean rate of ozone diurnal change (V_s) in winter is found to be maximum (approximately 2.1 DU h^–1) while it is minimum (about 0.53 DU h^–1) in pre-monsoon. In spite of the prevalent variability of the order of about 2–9 DU amongst Microtops channels and Ozone Monitoring Instrument on board the NASA EOS/AURA spacecraft (OMI-AURA) measurements, there exists a strong monthly/seasonal variation in both the ground- and satellite-based TCO measurements. Monthly mean OMI-AURA TCO variation presents a nearly perfect sinusoidal wave with a coefficient of determination (R²) equal to 0.76. Monthly TCO is maximum in May/June and minimum in December/January. The noticeable diurnal and monthly TCO variability could be due to a complex combination of photochemical processes in the lower troposphere and the transport in the middle and upper troposphere. Linear regression technique applied to the Microtops and OMI-AURA data sets show that the two data sets are better correlated with a correlation coefficient (r) taking values 0.71, 0.77, and 0.61 for channels I, II, and III, respectively. The three Microtops channels show the dispersion of about 8–11 DU around 1:1 regression line which is of the order of one standard deviation of the daily mean data set. The TCO data at all Microtops channels either underestimate or overestimate with respect to the OMI-AURA measurements since the values for slopes of the linear regression line for all the three channels are ≤1. Pearson’s product moment correlation analysis indicates that the TCO anti-correlates with ultraviolet-B (UV-B) irradiance (vis-à-vis through UV index) as the Pearson’s product moment correlation coefficients are found to be in the range –0.52 to –0.97.     

Zenith scattered light measurement: observations of BrO and OClO

Stratospheric BrO and OClO observations have been made for the first time over a tropical station, Pune (18° 31′ N, 73° 55′ E) using a Differential Optical Absorption Spectroscopy (DOAS) technique by measuring zenith sky scattered light spectra in the wavelength range of 346–358 nm by ultraviolet (UV)/visible spectrometer. The Differential Optical Density (DOD) fitting technique is applied for the right selection of a suitable spectral region for the analysis to minimize interference and poorly fitting absorption features, and also to minimize the residual of the fit. Observed DODs of O₃, NO_2, BrO, OClO, O₄, Rayleigh and Ring are well fitted with the calculated DODs and the percentage DODs are found to vary up to 0.5%, 0.8%, 0.15%, 0.13%, 1.5%, 1.2% and 1.3% respectively. Chlorine and bromine species play an important role in the ozone depletion, hence O₃, NO₂, BrO and OClO Slant Column Densities (SCDs) are derived between 76° and 94° Solar Zenith Angles (SZAs). The SCDs of O₃ are found to be decreased in the twilight period (i.e. between 90° and 94° SZA) in the presence of sufficient BrO and OClO. Total Column Densities (TCDs) of O₃, NO₂, BrO and OClO are derived by UV/visible spectrometry, Brewer spectrometry and satellite-based Scanning Imaging Absorption spectrometer for Atmospheric Cartography (SCIAMACHY) for Pune and the higher latitude station Kanpur (26° 28′ N, 80° 24′ E) during the period 1 April–31 June 2008. The day-to-day variations in O₃ and NO₂ TCDs over Pune are found to be more than over Kanpur. BrO TCDs vary between 1.9?×?10¹³ and 4?×?10¹³ molecules cm^?2 over Pune, which are derived by UV/visible spectrometry, while they vary for the high-altitude station Kanpur between 0.5?×?10¹³ and 3.5?×?10¹³ molecules cm^?2 derived by SCIAMACHY. The OClO TCDs are found to have an increasing trend with variations between 2?×?10¹³ and 4.5?×?10¹³ molecules cm^?2 during the above period.     

Recent changes in the snout position and surface velocity of Gangotri glacier observed from space

Glacier mass variations have a direct impact on some of the key components of the global water cycle, including sea level rise and freshwater availability. Apart from being one of the largest Himalayan glaciers, Gangotri is one of the sources of water for the Ganges river, which has a considerable influence on the socioeconomic structure of a largely over-populated catchment area accounting for ～26% of India’s landmass. In this study, we present the most recent assessment of the Gangotri glacier dynamics, combining the use of interferometric techniques on synthetic aperture radar data and sub-pixel offset tracking on Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) satellite imagery. Results show that on average, the Gangotri glacier snout has receded at a rate of 21.3 ± 3 m year^?1 over a period of 6 years (2004–2010). While glacier surface velocity near the snout is estimated to be between 24.8 ± 2.3 and 28.9 ± 2.3 m year^?1, interior portions of the glacier recorded velocities in the range of 13.9 ± 2.3 to 70.2 ± 2.3 m year^?1. Further, the average glacier surface velocity in the northern (lower) portions (28.1 ± 2.3 m year^?1) is observed to be significantly lower than in the southern (higher) portions (48.1 ± 2.3 m year^?1) of the Gangotri glacier. These values are calculated with an uncertainty of less than 5 m year^?1. Results also highlight a consistent retreat and non-uniform dynamics of the Gangotri glacier.     

Frontal changes in the Manimahesh and Tal Glaciers in the Ravi basin,Himachal Pradesh,northwestern Himalaya (India), between 1971 and 2013

The Manimahesh and Tal Glaciers are located in the Budhil fifth-order sub-basin of the Ravi, Himachal Himalaya, Northwestern Himalaya (India). These glaciers were analysed using high- (Corona KH-4A) to medium- (Landsat TM/ETM+/OLI, ASTER) spatial resolution satellite data between 1971 and 2013, along with extensive field measurements (2011–2014) of frontal changes. The results show that the Manimahesh and Tal Glaciers retreated by 157 ± 34 m (4 ± 1 m year^–1) and 45 ± 34 m (1 ± 1 m year^–1), respectively, whereas, the total area lost is estimated at 0.21 ± 0.01 km² (0.005 km² year^–1) and 0.010 ± 0.003 km² (0.0002 km² year^–1), respectively, between 1971 and 2013. The rate of retreat is significantly lower than that previously reported. Our field measurements (2011–2014) also suggest a retreating trend and validate the measured glacier changes using remotely sensed temporal data.     

Use of GRACE time-variable data and GLDAS-LSM for estimating groundwater storage variability at small basin scales: a case study of the Nzoia River Basin

This study integrates time-variable Gravity Recovery and Climate Experiment (GRACE) gravimetric measurements and Global Land Data Assimilation System (GLDAS) land surface models (LSM) in order to understand the inter-annual variations and groundwater storage changes (GWSC) in the Nzoia River Basin in Kenya, using the water balance equation and parameters. From averaged GRACE and GWSC data, the results showed that over the 10-year period, the basin experienced a groundwater depth gain of 6.38 mm year^?1, which is equivalent to aquifer recharge of 298 million cubic metres (mcm) year^?1. The deseasonalized groundwater variation analysis gave a net gain in groundwater storage of 6.21 mm year^?1 that is equal to a groundwater recharge gain of 290 mcm year^?1. The observed results are comparable to the groundwater safe yield of 330 mcm year^?1 as estimated by the Water Resource Management Authority in Kenya. Through cross-plotting and analysis with averaged satellite altimetry data and in situ measurements from rainfall and streamflow discharge, the total water storage change (TWSC) and GWSC in the basin were consistent and closely correlated in variation trends. The inter-annual standard deviation of groundwater change was determined as ±0.24 mm year^?1, which is equivalent to 85% degree of confidence in the obtained results. The results in this study show that GRACE gravity-variable solutions and GLDAS-LSM provide reliable data sets suitable for the study of small to large basin groundwater storage variations, especially in areas with scarce and sparsely available in situ data.     

Annual and seasonal variations in tropospheric ozone concentrations around Varanasi

This study examines the annual, seasonal and diurnal variations in the ambient concentrations of ozone at a suburban site of Varanasi, India, during 2002–2006. Prominent seasonal variations in ozone concentrations were recorded. Ozone concentrations were higher during the warmer months. Daytime 12‐hourly mean monthly ozone concentrations varied from 45.18 to 62.35 ppb during summer, from 28.55 to 44.25 ppb during winter and from 24 to 43.85 ppb during the rainy season from 2002 to 2006. Distinct diurnal variations in ozone concentrations were also observed. Daytime maxima in ozone concentration were recorded between 1200 and 1400 h, whereas morning and evening hours showed lower concentrations of ozone. Ozone concentrations in the atmosphere depended on several meteorological factors. Monthly average ozone concentration was significantly correlated with maximum temperature (p<0.001) and mean monthly temperature (p<0.05), maximum relative humidity (p<0.001), minimum relative humidity (p<0.001) and mean monthly relative humidity (p<0.001), and sunshine hours (p<0.001). Ozone concentrations in the ambient air have shown an increase in the past decade that was more in the winter and rainy seasons than in the summer. This study suggests that ozone concentrations around Varanasi were sufficiently high to cause significant damage to agricultural production. The present work can be extended to a regional level by incorporating modelling studies using recent remote sensing tools.     

Satellite and ground-based monitoring of smoke in the atmosphere during the summer wildfires in European Russia in 2010 and Siberia in 2012

Using Moderate Resolution Imaging Spectroradiometer (MODIS) (Aqua and Terra satellites) and in situ observations, a comparative analysis of two large-scale smoke events caused by the summer wildfires in European Russia (ER) in 2010 and Western Siberia (WS) in 2012 was carried out. In the 5-day periods of the extreme smoke pollution (5–9 August 2010 in ER and 27–31 July 2012 in WS), the number of active fires in the equal territories, confined by the coordinates 47°–65° N, 25°–55° E and 51°–70° N, 71°–104° E, was found to be 4754 for ER and 3823 for WS. With this, the regional mean aerosol optical depths (AODs) were found to be (1.02 ± 0.02) and (1.00 ± 0.04), not much differing for both the events. The regional mean aerosol radiative forcing effects at the top (R₁) and the bottom (R₂) of the atmosphere over ER/WS according to MODIS observations were estimated to be (?61 ± 1) and (?54 ± 2) W m^?2, and (?107 ± 2) and (?96 ± 3) W m^?2, respectively. At the same time, the local values of AOD and the local absolute values of R₁ and R₂ over WS were considerably higher than those over ER. MODIS AOD (L3) data during the wildfires of 2010 were validated by AOD data obtained by the sun-sky photometer CIMEL, operating at the AERONET station Zvenigorod. The rates of radiative heating of the smoky atmosphere over ER and WS were also estimated and compared with the existed temperature anomalies, obtained using National Centers for Environmental Prediction National Center for Atmospheric Research reanalysis data. Optical and microphysical properties of smoke aerosols during the wildfires in ER and WS also revealed some similar characteristics. The aerosols were mostly found in the submicron-size fraction and characterized by very high single-scattering albedos (0.95–0.98). In the dense smoke conditions, the degree of linear polarization at the scattering angle 90° during both the events decreased to negative values ranging between ?0.1 and ?0.15. The optical properties of smoke aerosols were mainly conditioned by unusually narrow particle size distribution.     

Study of aerosol optical depth,ozone, and precipitable water vapour content over Sinhagad,a high-altitude station in the Western Ghats

This article reports the results of a study related to variations in columnar aerosol optical depth (AOD), total column ozone (TCO), and precipitable water content (PWC) over a high-altitude station, Sinhagad (18° 21′ N, 73° 45′ E, 1450 m above mean sea level (AMSL)), employing a microprocessor-based total ozone portable spectrometer, MICROTOPS-II, comprising both a sun photometer and ozonometer, during November 2009–April 2010. The aerosol optical depth at 500 nm (AOD_{500 nm}) portrayed seasonal variation with higher values (0.39) in summer and lower values (0.15) in winter. The TCO and PWC also exhibited lower values in winter and started increasing by the pre-monsoon season. The Ångström wavelength exponent, α, was found to be high (1.79) during February, indicating the relative dominance of accumulation-mode particles. During the summer season, the lower value (0.94) of the Ångström wavelength exponent indicates the relative dominance of coarse-mode particles. The ground-based observations from MICROTOPS-II revealed good correlation with satellite observations of the Moderate Resolution Imaging Spectroradiometer (MODIS) and Ozone Monitoring Instrument (OMI). The observed short-wave solar flux at the bottom of the atmosphere decreased due to aerosol extinction and was found to be 19 and 78 W m^–2 for the winter and pre-monsoon seasons, respectively. This implies that greater concentrations of accumulation-mode particles – which are due to local anthropogenic sources – affected the down-welling radiation than those from natural sources – which are due to long-range transport processes – over the experimental location.     

John G. Fox (1931-2004)

The effectiveness of intermittent, microclimate cooling for men who worked in US Army chemical protective clothing (modified mission-oriented protective posture level 3; MOPP 3) was examined. The hypothesis was that intermittent cooling on a 2 min on–off schedule using a liquid cooling garment (LCG) covering 72% of the body surface area would reduce heat strain comparably to constant cooling. Four male subjects completed three experiments at 30°C, 30% relative humidity wearing the LCG under the MOPP 3 during 80 min of treadmill walking at 224 ± 5 W · m^?2. Water temperature to the LCG was held constant at 21°C. The experiments were; 1) constant cooling (CC); 2) intermittent cooling at 2-min intervals (IC); 3) no cooling (NC). Core temperature increased (1.6 ± 0.2°C) in NC, which was greater than IC (0.5 ± 0.2°C) and CC (0.5 ± 0.3°C) ( p < 0.05). Mean skin temperature was higher during NC (36.1 ± 0.4°C) than IC (33.7 ± 0.6°C) and CC (32.6 ± 0.6°C) and mean skin temperature was higher during IC than CC ( p < 0.05). Mean heart rate during NC (139 ± 9 b · min^?1) was greater than IC (110 ± 10 b · min^?1) and CC (107 ± 9 b · min^?1) ( p < 0.05). Cooling by conduction (K) during NC (94 ± 4 W · m^?2) was lower than IC (142 ± 7 W · m^?2) and CC (146 ± 4 W · m^?2) ( p < 0.05). These findings suggest that IC provided a favourable skin to LCG gradient for heat dissipation by conduction and reduced heat strain comparable to CC during exercise-heat stress in chemical protective clothing.