Exhaust Gas Recirculation Cooler Fouling in Diesel Applications: Fundamental Studies of Deposit Properties and Microstructure

This article reports on the results of experimental efforts aimed at improving the understanding of the mechanisms and conditions at play in the fouling of exhaust gas recirculation coolers. An experimental apparatus was constructed to utilize simplified surrogate heat exchanger tubes in lieu of full-size heat exchangers. The use of these surrogate tubes allowed removal of the tubes after exposure to engine exhaust for study of the deposit layer and its properties. The exhaust used for fouling the surrogate tubes was produced using a modern medium-duty diesel engine fueled with both ultra-low-sulfur diesel and biodiesel blends. At long exposure times, no significant difference in the fouling rate was observed between fuel types and hydrocarbons levels. Surface coatings for the tubes were also evaluated to determine their impact on deposit growth. No surface treatment or coating produced a reduction in the fouling rate or any evidence of deposit removal. In addition, microstructural analysis of the fouling layers was performed using optical and electron microscopy in order to better understand the deposition mechanism. The experimental results are consistent with thermophoretic deposition for deposit formation, and van der Waals attraction between the deposit surface and exhaust-borne particulate.     

Two- and four-way coupling of cohesive poly-disperse particulate foulants on a metal foam fibre immersed in quiescent fluid

The ubiquity and complexity of the unsteadiness of fouling and multiphase flows in various engineering systems signify the need to develop advanced numerical methods to study the underlying phenomena of two-phase particle-laden fluid flows in heat exchanger systems such as, compact electronics cooling (i.e. heat sinks) and HVAC&R systems. Fouling is omnipresent in many industries such as power generation, chemical, petroleum, among others. The mechanisms governing fouling coupled with multiphase foulant-laden fluid flow in porous heat exchangers, such as metal foams, are very complex and poorly understood. This investigation forms the basis for addressing the implications of fouling for a myriad of industrial processes. This study will discuss the development of a coupled finite volume method and discrete element method (FVM-DEM) numerical framework to investigate the mechanisms governing particulate fouling in an idealized metal foam heat exchanger. This study resolves four-way and two-way coupled interactions based on poly-disperse cohesive foulants in fluid-saturated foam. The significance stems from the inclusion of cohesiveness between particle-particle and particle-wall contacts which play a decisive role in the foulant aggregation process prevalent in particles with a diameter smaller than 50 μm. The present results show that the cohesive foulants exhibit strong tendency to aggregate with time and form chain-like projections. A rigid aggregate stack is formed which alters the fluid velocity of the fluid-filled foam. Quantitative analysis of the foulant count and time-averaged aggregate count is discussed. The presented results and the numerical framework could potentially be used to optimize heat exchanger designs by considering operating conditions and foam morphology (i.e. pore diameter, ligament thickness, porosity) that is most susceptible to particulate fouling.     

Mitigation of Soot Deposition on Modified Surfaces of Exhaust Gas Recirculation Coolers

Abstract

A common approach for lower emission of NO_x from diesel engines is to use exhaust gas recirculation (EGR) coolers where part of the exhaust gas is returned to the cylinder to reduce the combustion temperature. Nonetheless, the deposition of various species, i.e. soot particles, on surfaces deteriorates the thermal efficiency of EGR coolers. This study investigated the impact of surface treatment on particulate fouling of a rectangular EGR cooler. An experimental setup was assembled through which the uncoated and coated plates were exposed to the flow of exhaust flue gases. The cooler surfaces were coated by ceramic-based materials with resistance to high temperatures by spraying. The results showed that surface modification abated soot deposition to some extent and the deposit layer was easily flaked off with a force of 0.8 N when it was scratched with a nano-intender. Contrariwise, the deposit formed on the uncoated surface did not result in similar propensity and instead it required a larger force of 2.25 N. This implies weaker stickiness of soot deposit on the investigated coatings compared to baseline stainless steel surface. It was also found that the electron donor component of surface energy would determine the tendency of a surface to foul or not.     

Influence of gas velocity on particulate fouling of exhaust gas recirculation coolers

The objective of this research is to study the influence of gas flow velocity on particulate fouling of exhaust gas recirculation (EGR) coolers. An experimental setup has been designed and constructed to simulate particulate fouling in EGR coolers in diesel engines. The setup consists of soot generator, gas/particle flow heater, testing section for EGR coolers and finally an exhaust system. Two sets of fouling experiments have been performed with and without water injection, and the gas velocity in each set has varied between 30, 70 and 120 m/s. The concentration of soot particles in the gas flow is 100 mg/m³, and the average diameter of the particles is 130 nm with a standard deviation of 55 nm. It has been found that the thermal resistance and thickness of the fouling layer and the fouling rate decrease as the gas velocity in the EGR cooler increases. If EGR coolers are operated with a gas velocity, which is just lower than the critical flow velocity for the largest particle in the flow, quick deterioration of the thermal performance of the heat exchanger will nevertheless occur. This strongly indicates that the gas velocity should exceed a certain critical flow velocity in order to prevent particulate fouling. In addition, the presence of water vapour in the gas flow improves the thermal performance of the cooler and decreases the fouling rate, and its influence decreases as the gas velocity increases.     

Fouling Problems in Exhaust Gas Recirculation Coolers in the Automotive Industry

Transportation is responsible for approximately 20% of global greenhouse gas emissions, such as CO₂, NO_x, and hydrocarbons that have not been burned completely in the engine. In particular, 55% of globally emitted NO_x, which is more harmful to the environment than CO₂, is produced by the automotive industry alone. Strict emission standards are now in place that set specific limits to the amount of pollutants that can be released into the environment. The widely used measure to reduce NO_x emissions in diesel engines is to return part of the exhaust gas to the intake of the engine. This is usually done through a heat exchanger known as an exhaust gas recirculation (EGR) cooler. However, EGR coolers are subject to severe fouling such that their thermal efficiency can drop by as much as 30% within a very short period of time. More importantly, the deposit layer is a blend of particulate matter and sticky heavy hydrocarbons that are very difficult to remove from the heat exchanger surfaces. The present study addresses this problem and provides a review on required research and development (R&D) activities to mitigate fouling of EGR coolers.     

Influence of sintering on the growth rate of particulate fouling layers

This article addresses the question; why the gas-side temperature affects the rate of particulate fouling of heat exchangers? An experiment was carried out in a gas-cooler of a full-scale biomass gasifier to investigate the influence of the gas-side temperature on the strength, structure and growth rate of particulate fouling layers. It is observed that the particulate fouling rate in the gas cooler decreases with sintering, which is a function of the gas-side temperature. Detailed impaction experiments are carried out to investigate the influence of sintering on the removal of particles from a particulate fouling layer due to an incident particle impact as well as the sticking of an incident particle to a particulate fouling layer. Sintering of a fouling layer lowers significantly the ability of an incident particle to stick to the fouling layer or to remove particles out of the layer. However, particles that are still able to deposit on the sintered fouling layer will not sinter immediately, and can be removed due to the incident particles impact. The removal of newly deposited particles on a fouling layer due to incident particles becomes easier as sintering of the fouling layer takes place. Accordingly, it may be stated that sintering reduces the fouling rate of heat exchangers by lowering the deposition of new particles and increasing the removal rate of newly deposited particles. This explains why the growth rate of particulate fouling layers decreases with the gas-side temperature.     

Development of a Computational Fluid Dynamics Model for Predicting Fouling Process Using Dynamic Mesh Model

Abstract

This article presents a comprehensive computational model capable of simulating fouling layer thickness evolution using dynamic mesh model. This computational methodology has been developed to reproduce the deposit generation during fouling process with an innovated work method. Dynamic mesh model, from Ansys Fluent software, and external routines have been used to implement this advanced numerical model which allows to move the boundaries of a region relative to other boundaries of the zone. The displacement of the nodes of the mesh is the mechanism that this model uses to adjust the geometry according to the fouling layer evolution. During the simulation process, the geometry under investigation is modified to reproduce the emergence and gradual change of the fouling layer. Different rules of deposition and removal of the fouling process can be implemented in the proposed algorithm. The direct interaction between fouling expressions and governing equations of the main flow is used to predict deposits formation and growth. In this article, numerical simulations of soot fouling layer formation have been presented. Deposit evolution has been calculated inside different heat exchanger technologies used in exhaust gas recirculation systems to analyze fouling process and to verify the advantages of this new computational strategy.     

Compact potential of exhaust heat exchangers for engine waste heat recovery using metal foams

To improve the practicability of the waste heat recovery system for internal combustion engines, the compact potential of exhaust heat exchangers using metal foams is investigated. In the present study, the performance of compact exhaust heat exchangers is compared with that of a conventional shell and tube heat exchanger in a real test bench. Both heat transfer and pressure drop performance are considered when assessing the performance of heat exchangers because these two factors normally show a trade‐off relationship when designing exhaust heat exchangers. Compared with the conventional heat exchanger, the compact heat exchanger can achieve a similar pressure drop, and at the same time the heat transfer is increased by 30%, whereas the volume and the weight are each reduced by 2/3. The performance of compact heat exchangers with six types of Ni metal foams is also investigated under different mass flow rates and thicknesses of the porous layer. Results show that the optimum compact heat exchanger enhances the comprehensive performance 1.9 times compared with original one. This study shows that metal foams have great potential in realizing a compact exhaust heat exchanger for engine waste heat recovery.     

Fouling Management of Thermal Cracking Units

ABSTRACT

Visbreakers and other thermal cracking units are thermal process units in crude oil refineries that upgrade heavy petroleum, usually residual oils produced from atmospheric or vacuum distillation of crude oil. The associated process streams of these units consist of heavy hydrocarbons with very high viscosities and impurities, resulting in fouling of the heat exchangers used to cool or heat these streams. This paper presents a practical fouling analysis for thermal cracking units in a refinery in Germany. Fouling management at this refinery was initiated as part of the refinery energy-saving program. Following similar analysis of the refinery's crude preheat trains, heat exchanger networks associated in the thermal cracking units were modeled by entering the plant monitoring data, network topology, and heat exchanger geometries into a commercial heat exchanger network simulator, SmartPM. Fouling behaviors of vacuum residue streams and thermal cracker residue streams were identified and quantified. Both chemical reaction fouling and particulate fouling mechanisms were identified to be responsible for the fouling in these streams. Dynamic fouling models were fitted and used to predict fouling of these heavy petroleum streams, which fouled on both the shell and tube sides of the shell-and-tube heat exchangers.     

Impact of Nonuniform Fouling on Operating Temperatures in Heat Exchanger Networks

ABSTRACT

Investigations of fouling in heat exchangers are mainly focused on two factors: commercial impact due to energy losses, and environmental impact manifested through higher CO₂ emissions. The purpose of this paper is to introduce a third factor relating to safety in operations. This paper presents two case studies, one for a hydroprocessing unit with feed/effluent heat exchangers and another for preheat train exchangers installed upstream of the atmospheric furnace in a refinery crude unit. Due to a wide range of process temperatures examined in both case studies, the heat exchangers in the network are subject to various fouling mechanisms. As illustrated in the pictures of actual tube bundles, some of the exchangers within the network are heavily fouled, while the other exchangers operate in nearly clean conditions. Detailed simulations indicate that nonuniform fouling results in heat exchanger operating temperatures that are significantly higher than those predicted by conventional analyses using uniform fouling. Higher than anticipated process fluid temperatures may result in exceeding the threshold limits for certain corrosion mechanisms and/or significantly higher than expected rates of corrosion.     

A review of heat exchanger fouling in the context of aircraft air-conditioning systems,and the potential for electrostatic filtering

This paper presents a focused literature review to understand the common problem of fouling of air-conditioning heat exchangers aboard aircraft, with the academic consideration to employ electrostatic precipitation to remove airborne particulate matter.Particulate matter suspended in air, is carried through the matrices of aircraft environmental cooling systems. The deposition and build up of such contaminants affects the thermal performance of cooling systems and leads to component failure, expensive repairs and loss of service of an aircraft.Although there have been many publications of material pertaining to heat exchangers and fouling, very little publications specifically to aircraft air-conditioning systems or failures have been published. Nonetheless, the literature review indicates that sizes and distribution of particulate matter including Reynolds numbers and rates of deposition have been established in previous papers.The novel approach to this industrial problem has been to evaluate the operational problem of aircraft air-conditioning systems, identify local factors, and to consider the use of means of protection employed in other non-aerospace industries. It is believed the application of electrostatic precipitation could potentially aid prevention of fouling particulate matter on aircraft air-conditioning heat exchangers.     

Numerical Simulations of Fluid Flow and Heat Transfer through Aluminum and Copper Metal Foam Heat Exchanger – A Comparative Study

Abstract

This article discusses about a numerical simulation of a metal foam heat exchanger system carried out by a commercial software. A metal foam layer is attached to the bottom of the heat exchanger to absorb heat from the exhaust hot gas leaving the system. Two types of metal foams with two different pores per inch (PPI) values are considered for heat transfer enhancement. Similarly, two different materials Aluminum and copper, that poses high thermal conductivity, metal foams are considered for the present numerical simulations. The heat exchanger system is simulated over a range of 6–30?m/s fluid velocity. The proposed simulations are compared with theoretical and experimental data available in the literature. The goal is to improve the thermal performance of the heat exchanger by decreasing the pressure drop and maximizing the heat transfer rate. Finally, it has been noticed that the velocity of the fluid decreases as PPI increases at the expense of its pressure drop. The copper metal foam gives a maximum increase of 4–10% heat transfer rate compared to aluminum metal foams for a fluid velocity of 30?m/s.     

Numerical Simulation of Crystallization Fouling: Taking into Account Fouling Layer Structures

ABSTRACT

The fouling layers on heat exchanger surfaces exhibit complicated structures, which essentially affect flow hydrodynamics, fouling kinetics, and hence the heat transfer performance. Numerical models developed so far for the fouling process, however, are based exclusively on the assumption of an impermeable fouling layer with a uniform porous structure. In order to quantitatively evaluate the effect of fouling layer structure on fouling dynamics, this work systematically investigated four representative schemes for fouling layer characterization: a homogeneous porous medium that is impermeable to water (HoIm), a heterogeneous porous medium that is impermeable to water (HeIm), a homogeneous porous medium that is permeable to water (HoPe), and a heterogeneous porous medium that is permeable to water (HePe). Under the same operational conditions, four models offer significantly different prediction results on the fluid velocity, temperature distribution, and fouling resistance. It is concluded that numerical model development should take the fouling layer structure into account, and the scheme of HePe that best resembles a real fouling layer structure should be a promising option.     

Deposition of Nanosized Soot Particles in Various EGR Coolers Under Thermophoretic and Isothermal Conditions

This study investigates the performance of various types of exhaust gas recirculation (EGR) coolers, that is, smooth tube, corrugated tube, and plate–fin, when subjected to particulate fouling by soot particles. Experiments were carried out for different temperature gradients of 170 and 320°C (thermophoretic) and 0°C (isothermal). Soot particles with an average diameter of 130 nm were produced by a soot generator. Experimental results showed that generally soot deposition under isothermal conditions is negligible compared to thermophoresis for any given cooler geometry, but is not universal. It may become appreciable when complex coolers with extended surfaces, that is, plate–fin type, are used due to impaction and settlement of soot particles onto the extended surfaces, which act as barrier to the flow. Contrariwise, under thermophoretic conditions, the plate–fin cooler performed best, followed by the corrugated tube and smooth tube cooler. Coolers with larger heat transfer surface area are also found to be less sensitive to the loss in effectiveness, but show a higher pressure drop.     

Modelling and analyses of heat exchangers in a biomass boiler plant

A boiler plant is presented, in which the fuel is dried before combustion in a silo with air. The drying air is heated in a recuperative heat exchanger by the heat of flue gases. Hot air is then blown through the bed of fuel in the drying silo, while the fuel dries and the air cools down and becomes humidified. Heat of the moist exhaust air of the silo is recovered for the drying air and combustion air by a recuperative heat exchanger. Modelling of the thermal behaviour of the plant helps in understanding complex interdependencies of the two heat exchangers, the boiler and the dryer. The models of the heat exchangers and applications in analysing the boiler system are described in this paper. Calculating the combinations of extreme operational conditions gives the input data needed in comparing different types of heat exchangers, dimensioning the heat transfer area, choosing the control strategy and selecting the operating parameters and set‐values of the control system. Results of verification measurements and practical operation at a 40 kW_th pilot plant and a 500 kW_th demonstration plant are also discussed. Using engineering correlation formulas for heat and mass transfer, an adequate accuracy between the model and the measurements was achieved. Fouling was detected to be a major problem with the flue gas heat exchanger. However, in absence of condensation, the increase of a fouling layer with respect to time was observed to be low. Fouling was also a problem with the drying exhaust gas heat exchanger, but after the installation of a simple dust collector, a reasonable cleaning period was achieved. A mixed‐flow configuration was found to be the most appropriate for the flue gas heat exchanger. In order to avoid condensation of the flue gas the drying exhaust gas heat exchanger is indispensable in Finnish climate in the considered system. In addition to this, it decreases the need of fuel. A parallel‐flow type was found the most appropriate as the drying exhaust gas heat exchanger. Copyright © 2004 John Wiley & Sons, Ltd.     

三维变形管管内积灰特性数值模拟研究

烟气中的高灰分、高黏度、高腐蚀性成分不可避免地造成换热器烟气侧换热面积灰结垢的问题,如何有效解决这些问题一直是烟气换热器研究的焦点之一.三维变形管内的螺旋流增强了管内流体的湍动程度从而实现强化传热,基于其内部灰尘受气流携带而处于湍动便不易沉积的特点,本文通过数值模拟的方法探讨了三维变形管几何参数、粒径、气体流速对灰尘颗...     

Influence of the Apex Angle of Cone-Shaped Tubes on Particulate Fouling of Heat Exchangers

A two-dimensional (2D) cone shape has been added to the normal circular tubes of heat exchangers to minimize the area of stagnation and to streamline the air flow around the heat exchanger tubes. An experimental setup has been developed to study the influence of the apex angle of the cone-shaped tubes on particulate fouling of heat exchangers. Fouling experiments have been performed in which calcium carbonate particles are injected during the experiments and the deposition of particles on the tubes of the heat exchanger is monitored. Four sets of experiments have been performed, in which normal cylindrical tubes and coned tubes with an apex angle of 60°, 90°, and 120° are examined. It was found that particulate fouling ceased if the apex angle of the cone-shaped tubes is smaller than 90°. The attached cones enhance the flow around the tubes of the heat exchanger, by minimizing the stagnation area and keeping the flow attached to the tubes starting from the tip of the attached cone until separation, such that particles that deposit on the top of the tubes of the heat exchanger can be removed by the air flow.     

Management of Acute Particulate Fouling in a Titanium Dioxide Reactor System

ABSTRACT

The gas-phase manufacture of titanium dioxide is subject to acute fouling in the cooler unit located directly downstream of the reactor which quenches the reaction. A model of the cooler system was constructed, incorporating aspects of compressible flow, multimode heat transfer, fouling, and changes in geometry. This indicated that deposition could be very rapid. The effect of deposit layer buildup required measurement of the thermal conductivity of the porous layer; this was achieved using a novel testing device similar to that reported by Tan et al. (2006), for measuring the thermal conductivity of surface coatings. Active mitigation techniques are employed to reduce the effect of rapid fouling. The effectiveness of adding an erodent, in this case sand, to the flow was appraised by studying the breakup of deposit layers by impinging particles. The experimental conditions (high-temperature chlorine gas, high flow velocities) were simulated in cold experiments by matching the inertia and size of test particles to those of the sand. These studies showed that sand at the feed size would detach deposits, but could result in breakage of the sand particles. Mitigation efficiency is then determined by sand distribution and redistribution.     

Particulate Fouling and On-Line Cleaning of Ferric Oxide Particles in Internally Enhanced Tubes

This paper describes the results of accelerated particulate fouling tests performed on three enhanced tubes and a plain tube. The tests were performed using ferric oxide as the foulant material. Three enhanced tubes included 25 start, 10 start helically ribbed tube and a ripple tube. Effect of the water velocity (1.2–1.7 m/s) on fouling resistance was investigated. The maximum fouling resistance occurred in the 25 start helically ribbed tube (about 8.0 × 10^?5 m²K/W after 100 hours). For the 10 start helically ribbed tube, the fouling resistance was relatively small (less than 1.8 × 10^?5 m²K/W). The rippled and plain tubes show almost negligible fouling resistance. High velocity flushing was effective for all the tubes except for the 25 start helically ribbed tube. On-line brush cleaning maintained the fouling resistance below 1.8 × 10^?5 m²K/W for all tubes. The fouling concentrations used in the tests were significantly higher than would be expected in commercial heat exchangers. Also, the velocity range investigated was lower than would be expected in heat exchanger operation.     

Assessment of the Superheater Ash Fouling Using a Numerical Model of the Superheater

ABSTRACT

Superheaters are high-temperature cross-flow heat exchangers. Steam flows inside the tubes, and the flue gas outside in a direction perpendicular to the axes of the tubes. However, they differ very substantially from the other heat exchangers operating at low temperatures. Superheaters are characterized by complex flow system and high tube walls temperature. Superheaters are among the most exposed to damaging pressure elements of steam boilers. Damage to the superheater causes about 40% of emergency shutdowns of boilers. The paper presents the boiler superheater model with distributed parameters, which is used to determine on-line the degree of superheater fouling by ash.