Antioxidant Depletion from a High Density Polyethylene Geomembrane under Simulated Landfill Conditions

Accelerated aging tests to evaluate the depletion of antioxidants from a high density polyethylene geomembrane are described. The effects of temperature, high pressure, and continuous leachate circulation on the aging of geomembranes in composite liner systems are examined. The antioxidant depletion rates (0.05, 0.19, and 0.41?month?1 at 55, 70, and 85°C, respectively) obtained for the simulated landfill liner at 250 kPa vertical pressure are consistently lower than that obtained from traditional leachate immersion tests on the same geomembrane (0.12, 0.39, and 1.1?month?1 at 55, 70, and 85°C). This difference leads to a substantial increase in antioxidant depletion times at a typical landfill liner temperature (35°C) with 40 years predicted based on the data from the landfill liner simulators tests, compared to 15 years predicted for the same geomembrane based on leachate immersion tests. In these tests, the crystallinity and tensile yield strain of the geomembrane increased in the early stages of aging and then remained relatively constant over the testing period. There was no significant change in other geomembrane properties within the testing period.     

Aging of HDPE Geomembrane in Three Composite Landfill Liner Configurations

Laboratory-accelerated aging experiments conducted to examine the depletion of antioxidant from a geomembrane (GM) underlain by a geosynthetic clay liner (GCL) are described. Three different “protection” layers between the GM and overlying gravel and leachate are examined: (1) A traditional nonwoven geotextile (GT); (2) a GT-GCL; and (3) a GT-sand-GT layer. The GT-GCL protection layer gives an antioxidant depletion rate 0.59 to 0.66 times slower than the GT layer alone. The GT-sand-GT layer gives depletion rates 0.72–0.75 times that of the conventional GT alone. Based on Arrhenius modeling, the time required for depletion of antioxidants at 35°C is estimated to be 65 years for a GM with a GT-GCL protection layer, 50 years for a GT-sand-GT layer, and 40 years for a conventional GT protection layer. These times are all significantly greater than the depletion time for GM immersed in leachate (10 years) for the geomembrane tested.     

Effects of Thickness on the Aging of HDPE Geomembranes

The results of an accelerated aging test program to evaluate the effect of thickness on the depletion of antioxidants from high-density polyethylene (HDPE) geomembranes and subsequent degradation of the physical properties are reported. Three commercially available HDPE geomembranes having nominal thicknesses of 1.5, 2.0, and 2.5 mm were examined. The geomembranes were immersed in a synthetic leachate at 85, 70, 55, and 22°C and tested for oxidative induction time, crystallinity, melt index (MI), tensile properties, and stress-crack resistance. The antioxidant depletion rate for the 1.5 mm geomembrane was faster than for the 2.0 and 2.5 mm geomembranes. Antioxidant depletion time was predicted at representative landfill temperatures of 20–60°C using Arrhenius modeling and was found to increase with geomembrane thickness for the three geomembranes examined. Based on the results of crystallinity, MI, and stress-crack resistance, the degradation of the geomembrane was slowest for the thickest geomembrane. These results suggest that a thicker geomembrane may have a longer service life (other things being equal).     

Comparison of Solute Transport in Three Composite Liners

Three composite landfill liners were compared in this study based on leakage rate, mass flux, and sorptive capacity. One composite liner consisted of a geomembrane and a geosynthetic clay liner (GCL). The other two had a geomembrane and a thicker soil barrier (61 or 122 cm). The analyses employed one- and three-dimensional numerical models that were developed for analyzing contaminant transport through defects in the geomembrane component of composite liners and diffusion of volatile organic compounds through intact composite liners (i.e., composite liners without holes in the geomembrane). Cadmium was used to represent inorganic leachate constituents and toluene was used to represent organic leachate constituents. The composite liner, having a GCL had the lowest leakage rate of the three composite liners. For cadmium, the mass flow rate and sorptive capacity for the three composite liners varied within an order of magnitude. However, for toluene, the mass flux from the GCL composite liner was two to three orders of magnitude greater than that through composite liners having a thicker soil liner. Additionally, for leachate having similar concentrations of cadmium and toluene, the mass flux of toluene can be as much as seven orders of magnitude greater than that for cadmium. For toluene, the sorptive capacity of thicker liners was an order of magnitude greater than that for the GCL composite liner. Similar behavior is expected for other inorganic and organic solutes.     

Modeling of Clay Liner Desiccation

The potential for the desiccation of clay liner component of composite liners due to temperature field generated by breakdown of organic matter in municipal solid waste landfills is examined using a model proposed by Zhou and Rowe. In these analyses, a set of fully coupled governing equations expressed in terms of displacement, capillary pressure, air pressure, and temperature increase are used, and numerical results are solved by using finite element method with a mass-conservative numerical scheme. The model results are shown to be in encouraging agreement with experimental data for a problem involving heating of a landfill liner. The fully coupled transient fields (temperature, horizontal stress change, suction head, and volumetric water content) are then examined for two types of composite liner system, one involving a geomembrane over a compacted clay liner (CCL) and the other involving a geomembrane over a geosynthetic clay liner (GCL). It is shown that there can be significant water loss and horizontal stress change in both the CCL and GCL liner even with a temperature increase as small as 20°C. The time to reach steady state decreases as boundary temperature increases. Under a 30°C temperature increase, it takes 5 years to reach the steady state water content with a GCL liner but 50 years with a CCL liner. The effects of various parameters, such as hydraulic conductivity and thickness of the liner, on the performance of the liner are discussed.     

Permeation of BTEX through Unaged and Aged HDPE Geomembranes

The effects of aging of high-density polyethylene (HDPE) geomembranes on the diffusion and partitioning of a group of volatile organic compounds (VOCs) are examined. Two different 1.5?mm thick HDPE geomembranes were aged in the laboratory at 85°C by immersing in a synthetic leachate for up to 32?months. The results of partitioning and diffusion tests performed at room temperature on both unaged and aged geomembranes using a dilute aqueous solution containing four VOCs commonly found in landfill leachates [benzene, toluene, ethylbenzene, and xylenes (BTEX)] are reported. The diffusion and partitioning coefficients decreased with increased aging. The calculated permeation coefficients decreased by 36–62% after aging the geomembrane for about 10–32?months. This decrease in diffusion, partitioning, and permeation coefficients is related to the increase in geomembrane crystallinity during aging. A relationship between partitioning, diffusion, and permeation coefficients with the geomembrane crystallinity is established and could potentially be used to evaluate the migration of VOCs through HDPE geomembranes. Aging of HDPE geomembrane did not increase diffusive transport of organic contaminants.     

Durability of Fiberglass Composite Sheet Piles in Water

The durability of fiberglass composite sheet piles in water was studied through the specimens cut from flanges and webs of pultruded sheet pile sections. The experiments were performed to evaluate the water absorption at ambient temperature in complete immersion, and its effect on the tensile properties and the freeze-thaw resistance of the saturated composites. The high temperature at 70°C was used to accelerate the tests, and 100°C (boiling water) to verify the state of saturation. The non-Fickian absorption behavior of the pultruded composites was modeled based on the Berens and Hopfenberg two-phase absorption theory to predict the long-term performance and the change in mechanical properties of saturated composites. The results indicated that the water absorption process of the pultruded sheet pile composites followed a combination of Fickian diffusion and polymeric relaxation. The percent absorption at saturation was about 1.72% for the flange and 3.11% for the web. The water absorption model predicted that saturation would be reached after 5.8 years for the flange and after 14.5 years for the web immersed in tap water at ambient temperature. The tensile strength was found to decrease initially with the increase in the percent water absorption, and finally stabilize at the state of saturation. On the other hand, there was no noticeable change in the tensile modulus of elasticity during the entire water-aging period. The saturated composites showed excellent resistance to freeze-thaw cycling from 4.4 to ?17.8°C.     

Estimation of Mass Transport Parameters of Organic Compounds through High Density Polyethylene Geomembranes Using a Modifield Double-Compartment Apparatus

A modified double-compartment apparatus (MDCA) is used to estimate mass transport parameters of organic compounds through high density polyethylene (HDPE) geomembranes and to investigate the effects of aging and external tension of HDPE geomembranes on the mass transport of organic compounds. A developed one-dimensional partition–diffusion mass transport model successfully explains the mass transport of the organic compounds through the HDPE geomembranes in a dilute aqueous solution–geomembrane system. Similar to batch immersion tests, the HDPE–water partition coefficient (KHDPE–W) values of organic compounds are found to have close relationships with the octanol–water partition coefficient and the aqueous solubility; furthermore, the diffusion coefficient (D) values decrease with the increase of their molecular diameter. For HDPE geomembranes served in the landfill liner for 5 years and stretched by 8% of their initial length, KHDPE–W values for organic compounds increase by 5–58%, D values for organic compounds increase by 10–86%, and breakthrough times are faster, indicating more amounts of organic compounds may break through the HDPE geomembrane in fields than expected. The mass transport parameters from MDCA tests could be used with those from batch immersion tests interchangeably after mass loss and immobilization of organic compounds in MDCA tests are considered.     

Analytical Solution for Diffusion of VOCs through Composite Landfill Liners

Analytical solutions are presented for analyzing volatile organic compound (VOC) diffusion through intact composite landfill liners for two scenarios with boundary conditions at the base of either a VOC concentration of zero or a VOC mass flux of zero. A time-dependent concentration top boundary condition is included in the presented analytical solutions to model typical variations of VOC concentration in the leachate over time. The presented solutions are verified against alternative numerical solutions and applied to analyze dichloromethane diffusion through a composite liner. The analytical solutions are found to provide useful predictions of VOC concentration and mass flux for the design of composite liners. VOC concentrations and fluxes at the base of the composite liner at 30?years predicted by consideration of representative transient variation in leachate concentration, for an example problem, are nearly half of those when a constant leachate concentration assumed.     

Hydraulic Conductivity of MSW in Landfills

This paper presents a laboratory investigation of hydraulic conductivity of municipal solid waste (MSW) in landfills and provides a comparative assessment of measured hydraulic conductivity values with those reported in the literature based on laboratory and field studies. A series of laboratory tests was conducted using shredded fresh and landfilled MSW from the Orchard Hills landfill (Illinois, United States) using two different small-scale and large-scale rigid-wall permeameters and a small-scale triaxial permeameter. Fresh waste was collected from the working phase, while the landfilled waste was exhumed from a borehole in a landfill cell subjected to leachate recirculation for approximately 1.5 years. The hydraulic conductivity tests conducted on fresh MSW using small-scale rigid-wall permeameter resulted in a range of hydraulic conductivity 2.8×10?3–11.8×10?3?cm/s with dry unit weight varied in a narrow range between 3.9–5.1?kN/m3. The landfilled MSW tested using the same permeameter produced results between 0.6×10?3–3.0×10?3?cm/s for 4.5–5.5?kN/m3 dry unit weights. The hydraulic conductivity obtained from large-scale rigid-wall permeameter tests decreased with the increase in normal stress for both fresh and landfilled waste. The hydraulic conductivity for fresh MSW ranged from 0.2 cm/s for 4.1?kN/m3 dry unit weight (under zero vertical stress) and then decreased to 4.9×10?5?cm/s for 13.3?kN/m3 dry unit weight (under the maximum applied normal stress of 276 kPa). The hydraulic conductivity of the landfilled MSW decreased from 0.2 cm/s to 7.8×10?5?cm/s when the dry unit weight increased from 3.2 to 9.6?kN/m3. The results clearly demonstrated that the hydraulic conductivity of MSW can be significantly influenced by vertical stress and it is mainly attributed to the increase in density leading to low void ratio. In small-scale triaxial permeameter, when the confining pressure was increased from 69 to 276 kPa the hydraulic conductivity decreased from approximately 10?4?to?10?6?cm/s, which is much lower than those determined from rigid-wall permeameter tests. The published field MSW hydraulic conductivities are found to be higher than the laboratory results. Landfilled MSW possesses lower hydraulic conductivity than fresh MSW due to increased finer particles resulting from degradation. The decreasing hydraulic conductivity with increasing dry unit weight is expressed by an exponential decay function.     

Shear Strength of Municipal Solid Waste

A comprehensive large-scale laboratory testing program using direct shear (DS), triaxial (TX), and simple shear tests was performed on municipal solid waste (MSW) retrieved from a landfill in the San Francisco Bay area to develop insights about and a framework for interpretation of the shear strength of MSW. Stability analyses of MSW landfills require characterization of the shear strength of MSW. Although MSW is variable and a difficult material to test, its shear strength can be evaluated rationally to develop reasonable estimates. The effects of waste composition, fibrous particle orientation, confining stress, rate of loading, stress path, stress-strain compatibility, and unit weight on the shear strength of MSW were evaluated in the testing program described herein. The results of this testing program indicate that the DS test is appropriate to evaluate the shear strength of MSW along its weakest orientation (i.e., on a plane parallel to the preferred orientation of the larger fibrous particles within MSW). These laboratory results and the results of more than 100 large-scale laboratory tests from other studies indicate that the DS static shear strength of MSW is best characterized by a cohesion of 15?kPa and a friction angle of 36° at normal stress of 1?atm with the friction angle decreasing by 5° for every log cycle increase in normal stress. Other shearing modes that engage the fibrous materials within MSW (e.g., TX) produce higher friction angles. The dynamic shear strength of MSW can be estimated conservatively to be 20% greater than its static strength. These recommendations are based on tests of MSW with a moisture content below its field capacity; therefore, cyclic degradation due to pore pressure generation has not been considered in its development.     

某固体废弃物填埋场续建工程的防渗处理

简要介绍了深圳市下坪固体废弃物填埋场（以下简称下坪场）续建工程的概况以及目前国内外填埋场防渗技术应用现状，通过方案比较，确定了该工程采用双层复合衬层水平防渗系统。     

Transit-Time Design for Diffusion through Composite Liners

Transit-time design methods are presented in this paper for determining the design thickness for composite liners consisting of a geomembrane and a compacted soil liner or geosynthetic clay liner. The design methods are based on a closed-form analytical solution for transient solute diffusion of volatile organic compounds in a composite liner and results from a numerical model. An analytical solution for diffusion in a two-layer soil profile, which is useful for transit-time design of composite liners, is also presented. The analytical solutions are used to develop graphical solution charts that can be used to design composite liners for which the effluent concentration and contaminant flux are less than a specified value. Design examples are included for a composite liner having a compacted soil liner and a composite liner having a geosynthetic clay liner. The method is relatively simple to apply and can be used for preliminary design of composite liners, evaluating experimental results, and verifying more complex numerical models.     

Pilot-Scale Simulation of Landfill Bioreactor and Controlled Dumping of Fresh and Partially Stabilized Municipal Solid Waste in a Tropical Developing Country

Four pilot-scale lysimeters were used to study the benefits of landfill operation with and without leachate recirculation in tropical weather conditions. Young and old landfills were simulated by filling lysimeters with a segregated fraction of fresh municipal solid waste (MSW) and MSW mined from an open dump site, respectively, and periodically monitoring leachate quantity and quality and biogas quality. For each substrate, one lysimeter was operated as a bioreactor with leachate recirculation and another lysimeter was operated as a controlled dump, for a period of 10 months. Densities between 652 and 825??kg/m3 could be achieved with fresh and mined MSW. Despite such compaction during waste placement, bioreactor technology helps in leachate management, especially in the case of the young landfill lysimeter operated in tropical weather. The benefits of leachate recirculation in the young landfill lysimeter were evident from the significant decrease in chemical oxygen demand (COD) (86%), biochemical oxygen demand (BOD) (82%), dissolved organic carbon (DOC) (85%), and volatile solids (75%) in leachates. However, ammonia nitrogen (amm-N) and chlorides in the leachates accumulated in bioreactor landfills. Operating an old landfill lysimeter as a bioreactor seemed to have no exceptional advantage in the context of leachate management, although leachate recirculation enhanced the methane potential of both fresh and mined MSW.     

Evaluation of Multidimensional Transport through a Field-Scale Compacted Soil Liner

A field-scale compacted soil liner was constructed at the University of Illinois at Urbana-Champaign by the U.S. Environmental Protection Agency (USEPA) and Illinois State Geological Survey in 1988 to investigate chemical transport rates through low permeability compacted clay liners (CCLs). Four tracers (bromide and three benzoic acid tracers) were each added to one of four large ring infiltrometers (LRIs) while tritium was added to the pond water (excluding the infiltrometers). Results from the long-term transport of Br? from the localized source zone of LRI are presented in this paper. Core samples were taken radially outward from the center of the Br? LRI and concentration depth profiles were obtained. Transport properties were evaluated using an axially symmetric transport model. Results indicate that (1) transport was diffusion controlled; (2) transport due to advection was negligible and well within the regulatory limits of ksat ? 1×10?7?cm/s; (3) diffusion rates in the horizontal and vertical directions were the same; and (4) small positioning errors due to compression during soil sampling did not affect the best fit advection and diffusion values. The best-fit diffusion coefficient for bromide was equal to the molecular diffusion coefficient multiplied by a tortuosity factor of 0.27, which is within 8% of the tortuosity factor (0.25) found in a related study where tritium transport through the same liner was evaluated. This suggests that the governing mechanisms for the transport of tritium and bromide through the CCL were similar. These results are significant because they address transport through a composite liner from a localized source zone which occurs when defects or punctures in the geomembrane of a composite system are present.     

Deflection Response of Glass Fiber-Reinforced Pultruded Components in Hot Weather Climates

Presented in this paper are the experimental results pertaining to the deflection response of E-glass/polyester pultruded structural elements when subjected to bending and temperature profiles comparable to those encountered in hot weather conditions. Experiments were conducted on tubular components subjected to an applied force resulting in a maximum stress corresponding to 4% of the composite material strength. In one case, five component tests were carried out in an environmental condition in which the air temperature was first gradually increased from 20°±2°C?to?72°±2°C, then decreased to 60°±2°C in 1?h. In another case, one component was tested under an air temperature that was first gradually increased from 20?to?60°C, then kept at 60°±2°C for 215?h. Test results are compared with those obtained in another study at laboratory conditions (22°±2°C). It is concluded that the increase in the deflection of glass-reinforced pultruded components in hot climates is substantial and must always be accounted for in the design of pultruded structures.     

Leachate Recirculation in Bioreactor Landfills Using Geocomposite Drainage Material

The key purpose of this study was to test the use of a permeable blanket made up of a geocomposite drainage layer (GDL) for leachate recirculation in municipal solid waste (MSW) landfills and to predict the observed leachate travel in the blanket using a numerical model. A 34?m long by 12?m wide permeable blanket made up of GDL was constructed at an active MSW landfill located in Michigan. Leachate was injected in the GDL using a perforated pipe placed centrally above the GDL along its length. Moisture content sensors, pressure transducers, thermistors, thermocouple sensors, and a vertical load sensor were embedded immediately below the GDL blanket to monitor the flow of injected leachate. After the blanket was covered with waste, leachate was injected into the blanket at rates ranging from 0.9 to 2.6?m3/h per meter length of the blanket. Data collected from the embedded sensors indicated that the injected leachate traveled at rates ranging from 5 to 18?m/h through the blanket depending upon the leachate injection rate. Only pressure transducers and thermistors were consistently able to detect migration of injected leachate once the blanket got saturated. Moisture content sensors could not register any change in readings once the blanket became saturated. Leachate injection pressure monitored over a period of about 12 months indicated no signs of clogging of the blanket. The leachate pressures measured immediately below the blanket were less than the net leachate injection pressure indicting that there was a head loss in the GDL blanket. Numerical modeling of liquid flow in the blanket indicated that predicted leachate travel in the blanket was consistent with the field data for assumed values of the waste hydraulic conductivity. In the absence of measured representative hydraulic properties of the waste, absolute verification of the field data was not possible.     

Predicting Leakage through Composite Landfill Liners

Leakage through composite landfill liners having various characteristics was analyzed using existing analytical and numerical models developed for the study. Three-dimensional numerical models were used to analyze leakage through circular defects and two-dimensional numerical models were used to analyze leakage from defective seams. Leakage rates predicted with the numerical models were compared to leakage rates predicted using existing equations and analytical models currently being used. These comparisons show that existing equations and analytical models all have limitations and no universal equation or method is available for predicting leakage rates. To overcome some of the deficiencies in the existing equations and models, new equations were developed based on results from the numerical models. Recommendations are made for using the new equations, existing equations, and analytical models to predict leakage rates in thick composite liners having a geomembrane overlaying a compacted soil liner and thin composite liners having a geomembrane overlaying a geosynthetic clay liner.     

Hydraulic Performance of Geosynthetic Clay Liners in a Landfill Final Cover

Percolation from a landfill final cover containing a geosynthetic clay liner (GCL) as the hydraulic barrier is described. The GCL was covered with 760?mm of vegetated silty sand and underlain with two gravel-filled lysimeters to monitor percolation from the base of the cover. Higher than anticipated percolation rates were recorded in both lysimeters within 4–15?months after installation of the GCL. The GCL was subsequently replaced with a GCL laminated with a polyethylene geofilm on one surface (a “composite” GCL). The composite GCL was installed in two ways, with the geofilm oriented upwards or downwards. Low percolation rates (2.6–4.1?mm/year) have been transmitted from the composite GCL for more than 5?years regardless of the orientation of the geofilm. Samples of the conventional GCL that were exhumed from the cover ultimately had hydraulic conductivities on the order of 5×10?5?cm/s. These high hydraulic conductivities apparently were caused by exchange of Ca and Mg for Na on the bentonite combined with dehydration. The overlying and underlying soils likely were the source of the Ca and Mg involved in the exchange. Column experiments and numerical modeling indicated that plant roots and hydraulic anomalies caused by the lysimeters were not responsible for the high hydraulic conductivity of the GCL. Despite reports by others, the findings of this study indicate that a surface layer 760?mm thick is unlikely to protect conventional GCLs from damage caused by cation exchange and dehydration. Accordingly, GCLs should be used in final covers with caution unless if cation exchange and dehydration can be prevented or another barrier layer is present (geomembrane or geofilm).     

Fiber-Sizing-Based Enhancement of Materials Durability for Seismic Retrofit

E-glass/epoxy-based jackets have been demonstrated to be an effective means of providing lateral confinement for the seismic retrofit and strengthening of concrete columns. When fabricated using appropriate procedures and covered with a protective coating these materials show good environmental durability. However, E-glass fibers are susceptible to attack and degradation by moisture and alkalis, causing concern for their use in humid and very moist climates or in applications where the jacketed columns are immersed in water. This paper describes the enhancement of durability through change in the sizing used on the fibers. Results of ring burst tests on three differently sized systems after immersion in a severe environment [water at 60°C (140°F)] are detailed, and it is shown that the use of the appropriate sizing can significantly reduce moisture-related degradation.