Addressing Cu/Low-$k$ Dielectric TDDB-Reliability Challenges for Advanced CMOS Technologies

Low-$k$ dielectrics, which are beneficial for chip resistance–capacitance ($RC$) delay improvement, crosstalk-noise minimization, and power-dissipation reduction, are indispensable for the continuous scaling of advanced VLSI circuits, particularly that of high-performance logic circuits. In this paper, several critical challenges for Cu/low-$k$ time-dependent dielectric-breakdown (TDDB)-reliability qualification will be reviewed. First, a low-$k$ TDDB field-acceleration model and its determination will be discussed. Second, the macroscopic interconnect line-to-line spacing variation across the wafer and the microscopic line-to-line spacing nonuniformity induced by line-edge roughness within the same test structure and their impacts on low- $k$ TDDB reliability will be carefully examined. The Weibull shape-parameter dependence on applied stress voltage due to such global and local spacing variations will be analyzed. Finally, the moisture effect on low-$k$ TDDB and capacitance stability as an example of the impact from process integration will be reported, demonstrating that low-$k$ TDDB is sensitive to back-end-of-the-line integration.      

High-Performance Poly-Silicon TFTs Using a High-$k$ $hbox{PrTiO}_{3}$ Gate Dielectric

In this letter, a polycrystalline-silicon thin-film transistor (poly-Si TFT) with a high- $k$ $hbox{PrTiO}_{3}$ gate dielectric is proposed for the first time. Compared to TFTs with a $hbox{Pr}_{2}hbox{O}_{3}$ gate dielectric, the electrical characteristics of poly-Si TFTs with a $hbox{PrTiO}_{3}$ gate dielectric can be significantly improved, such as lower threshold voltage, smaller subthreshold swing, higher $I_{rm on}/I_{rm off}$ current ratio, and larger field-effect mobility, even without any hydrogenation treatment. These improvements can be attributed to the high gate capacitance density and low grain-boundary trap state. All of these results suggest that the poly-Si TFT with a high- $k$ $hbox{PrTiO}_{3}$ gate dielectric is a good candidate for high-speed and low-power display driving circuit applications in flat-panel displays.      

Cubic-Structured $hbox{HfO}_{2}$ With Optimized Doping of Lanthanum for Higher Dielectric Constant

It is demonstrated that $hbox{HfO}_{2}$ films can have much higher dielectric-constant values than the usual reported value of 20–24 by optimized incorporation of lanthanum element and crystallization to cubic structure. When $hbox{HfO}_{2}$ with 8% La is crystallized into cubic structure, the film exhibits the $kappa$ value of $sim$ 38 which is the highest among ever reported $hbox{HfO}_{2}$ -based high-$kappa$ dielectrics. The increased $kappa$ value of $ hbox{HfO}_{2}$ with 8% La enables the leakage current to be reduced more than one order of magnitude lower, compared to amorphous-phase $hbox{HfO}_{2}$ under the same electric field. The dependence of film thickness and annealing temperature on the cubic crystallization is also reported.      

Reliability of Combined $k{hbox{-out-of-}}n$ and Consecutive $k_{c}{hbox{-out-of-}}n$ Systems of Markov Dependent Components

A combined $k{hbox{-out-of-}}n$ :$F(G)$ & consecutive $k_{c}{hbox{-out-of-}}n{hbox{:}}F(G)$ system fails (functions) iff at least $k$ components fail (function), or at least $k_{c}$ consecutive components fail (function). These models involve two common failure criteria, and can be used in various situations depending on the actual failure criteria involving consecutive components, or all components. Explicit formulas for the reliabilities of these systems are obtained for Markov dependent components using the distribution theory of runs. Some numerical results are also presented.      

Gate-First AlGaN/GaN HEMT Technology for High-Frequency Applications

This letter describes a gate-first AlGaN/GaN high-electron mobility transistor (HEMT) with a W/high- $k$ dielectric gate stack. In this new fabrication technology, the gate stack is deposited before the ohmic contacts, and it is optimized to stand the 870 $^{circ}hbox{C}$ ohmic contact annealing. The deposition of the W/high-$k$ dielectric protects the intrinsic transistor early in the fabrication process. Three different gate stacks were studied: $hbox{W}/ hbox{HfO}_{2}$, $hbox{W}/hbox{Al}_{2}hbox{O}_{3}$ , and $hbox{W}/hbox{HfO}_{2}/hbox{Ga}_{2}hbox{O}_{3}$ . DC characterization showed transconductances of up to 215 mS/mm, maximum drain current densities of up to 960 mA/mm, and more than five orders of magnitude lower gate leakage current than in the conventional gate-last Ni/Au/Ni gate HEMTs. Capacitance–voltage measurements and pulsed-$IV$ characterization show no hysteresis for the $hbox{W}/hbox{HfO}_{2}/ hbox{Ga}_{2}hbox{O}_{3}$ capacitors and low interface traps. These W/high- $k$ dielectric gates are an enabling technology for self-aligned AlGaN/GaN HEMTs, where the gate contact acts as a hard mask to the ohmic deposition.      

$S$ - and $C$ -Band Ultra-Compact Phase Shifters Based on All-Pass Networks

Ultra-compact phase shifters are presented. The proposed phase-shifting circuits utilize the lumped element all-pass networks. The transition frequency of the all-pass network, which determines the size of the circuit, is set to be much higher than the operating frequency. This results in a significantly small chip size of the phase shifter. To verify this methodology, 5-bit phase shifters have been fabricated in the $S$ - and $C$ -band. The $S$ -band phase shifter, with a chip size of 1.87 mm $,times,$0.87 mm (1.63 mm $^{2}$), has achieved an insertion loss of ${hbox{6.1 dB}} pm {hbox{0.6 dB}}$ and rms phase-shift error of less than 2.8$^{circ}$ in 10% bandwidth. The $C$ -band phase shifter, with a chip size of 1.72 mm $,times,$0.81 mm (1.37 mm $^{2}$), has demonstrated an insertion loss of 5.7 dB $pm$ 0.8 dB and rms phase-shift error of less than 2.3 $^{circ}$ in 10% bandwidth.      

2 MHz AO $Q$ -switched ${rm TEM}_{00}$ Grazing Incidence Laser With 3 at.% Neodymium Doped Nd:YVO$_{4}$

We present a detailed experimental and theoretical study of the ultrahigh repetition rate AO $Q$ -switched ${rm TEM}_{00}$ grazing incidence laser. Up to 2.1 MHz $Q$-switching with ${rm TEM}_{00}$ output of 8.6 W and 2.2 MHz $Q$ -switching with multimode output of 10 W were achieved by using an acousto-optics $Q$ -switched grazing-incidence laser with optimum grazing-incidence angle and cavity configuration. The crystal was 3 at.% neodymium doped Nd:YVO$_{4}$ slab. The pulse duration at 2 MHz repetition rate was about 31 ns. The instabilities of pulse energy at 2 MHz repetition rate were less than ${pm}6.7hbox{%}$ with ${rm TEM}_{00}$ operation and ${pm}3.3hbox{%}$ with multimode operation respectively. The modeling of high repetition rate $Q$-switched operation is presented based on the rate equation, and with the solution of the modeling, higher pump power, smaller section area of laser mode, and larger stimulated emission cross section of the gain medium are beneficial to the $Q$-switched operation with ultrahigh repetition rate, which is in consistent with the experimental results.      

Electrical Properties of Amorphous $hbox{Bi}_{5} hbox{Nb}_{3}hbox{O}_{15}$ Thin Film for RF MIM Capacitors

Amorphous $hbox{Bi}_{5}hbox{Nb}_{3}hbox{O}_{15}(hbox{B}_{5} hbox{N}_{3})$ film grown at 300 $^{circ}hbox{C}$ showed a high-$k$ value of 71 at 100 kHz, and similar $k$ value was observed at 0.5–5.0 GHz. The 80-nm-thick film exhibited a high capacitance density of 7.8 fF/$muhbox{m}^{2}$ and a low dissipation factor of 0.95% at 100 kHz with a low leakage-current density of 1.23 nA/ $hbox{cm}^{2}$ at 1 V. The quadratic and linear voltage coefficient of capacitances of the $hbox{B}_{5}hbox{N}_{3}$ film were 438 ppm/$hbox{V}^{2}$ and 456 ppm/V, respectively, with a low temperature coefficient of capacitance of 309 ppm/$^{circ}hbox{C}$ at 100 kHz. These results confirmed the potential of the amorphous $hbox{B}_{5}hbox{N}_{3}$ film as a good candidate material for a high-performance metal–insulator–metal capacitors.      

An FIR-Embedded Noise Filtering Method for $Delta Sigma$ Fractional-N PLL Clock Generators

This paper describes a noise filtering method for $Delta Sigma$ fractional- $N$ PLL clock generators to reduce out-of-band phase noise and improve short-term jitter performance. Use of a low-cost ring VCO mandates a wideband PLL design and complicates filtering out high-frequency quantization noise from the $Delta Sigma$ modulator. A hybrid finite impulse response (FIR) filtering technique based on a semidigital approach enables low-OSR $Delta Sigma$ modulation with robust quantization noise reduction despite circuit mismatch and nonlinearity. A prototype 1-GHz $Delta Sigma$ fractional-$N$ PLL is implemented in 0.18 $muhbox{m}$ CMOS. Experimental results show that the proposed semidigital method effectively suppresses the out-of-band quantization noise, resulting in nearly 30% reduction in short-term jitter.      

Zn$_{1 - x}$Mg$_{x}$ O Homojunction-Based Ultraviolet Photodetector

Zn$_{1 - {x}}$ Mg$_{x}$ O p-n photodiodes were fabricated on (0001) sapphire substrates using a pulsed laser deposition technique with different Mg contents. Ti–Au and Ni–Au metals deposited using vacuum evaporation were used as n-type and p-type contacts, respectively. The X-ray diffraction analysis showed the Zn$_{1 - {x}}$Mg$_{x}$O double layers have a single phase hexagonal wurtzite structure. The optical bandgap of Zn$_{1 - {x}}$Mg$_{x}$O films has been tuned from 3.27 to 4.26 eV by increasing the Mg content ${x} =0.0$ to ${x}=0.34$. Correspondingly, the cutoff wavelength of the resultant detectors varies from 380 to 284 nm. Zn$_{1 - {x}}$Mg$_{x}$O p-n photodiodes with different Mg contents exhibit very good performance, with a very low dark current (${≪}$ 20 pA) at the bias voltage of 10 V. The ultraviolet to visible rejection ratio is more than three orders of magnitude.      

Pentacene-Based Low-Voltage Strain Sensors With PVP/$ hbox{Ta}_{2}hbox{O}_{5}$ Hybrid Gate Dielectrics

Field-controllable pentacene-semiconductor-based strain sensors were fabricated with hybrid gate dielectrics using polyvinyl phenol (PVP) and high-$k$ inorganic tantalum pentoxide $(hbox{Ta}_{2}hbox{O}_{5})$ onto polyethylene naphthalate films. The $hbox{Ta}_{2}hbox{O}_{5}$ gate-dielectric layer combined with a thin PVP layer to form very smooth and hydrophobic surfaces turns out to improve the molecular structures of pentacene films significantly. The PVP– $hbox{Ta}_{2}hbox{O}_{5}$ hybrid-gate-dielectric films exhibit a high dielectric constant of 19.27 and a leakage-current density of as low as 100 $hbox{nA/cm}^{2}$ . The sensors employing a thin-film-transistor-like Wheatstone bridge configuration able to operate at reduced voltage ($sim$4 V) show good device characteristics with a field-effect mobility of 1.89 $hbox{cm}^{2}/hbox{V} cdot hbox{s}$ and a threshold voltage of $-$0.5 V. The strain sensor characterized with bending at 45$^{circ}$ with respect to the bridge bias direction with different bending radii of 50-, 40-, 30-, 20-, and 8-mm displays output signals improved in linearity in a low range of operating voltages.      

$hbox{TiN/ZrO}_{2}$/Ti/Al Metal–Insulator–Metal Capacitors With Subnanometer CET Using ALD-Deposited $hbox{ZrO}_{2}$ for DRAM Applications

We provide the first report of the structural and electrical properties of $hbox{TiN/ZrO}_{2}$/Ti/Al metal–insulator–metal capacitor structures, where the $hbox{ZrO}_{2}$ thin film (7–8 nm) is deposited by ALD using the new zirconium precursor ZrD-04, also known as Bis(methylcyclopentadienyl) methoxymethyl. Measured capacitance–voltage ($C$– $V$) and current–voltage ( $I$–$V$) characteristics are reported for premetallization rapid thermal annealing (RTP) in $hbox{N}_{2}$ for 60 s at 400 $^{circ}hbox{C}$, 500 $^{circ}hbox{C}$, or 600 $^{ circ}hbox{C}$. For the RTP at 400 $^{circ}hbox{C}$ , we find very low leakage current densities on the order of nanoamperes per square centimeter at a gate voltage of 1 V and low capacitance equivalent thickness values of $sim$ 0.9 nm at a gate voltage of 0 V. The dielectric constant of $ hbox{ZrO}_{2}$ is 31 $pm$ 2 after RTP treatment at 400 $^{circ}hbox{C}$.      

A 0.13 $mu$ m CMOS Quad-Band GSM/GPRS/EDGE RF Transceiver Using a Low-Noise Fractional-N Frequency Synthesizer and Direct-Conversion Architecture

This paper presents a single-chip CMOS quad-band (850/900/1800/1900 MHz) RF transceiver for GSM/GPRS/EDGE applications which adopts a direct-conversion receiver, a direct-conversion transmitter and a fractional-N frequency synthesizer with a built-in DCXO. In the GSM mode, the transmitter delivers 4 dBm of output power with 1$^{circ}$ RMS phase error and the measured phase noise is ${-}$164.5 dBc/Hz at 20 MHz offset from a 914.8$~$MHz carrier. In the EDGE mode, the TX RMS EVM is 2.4% with a 0.5 $~$dB gain step for the overall 36 dB dynamic range. The RX NF and IIP3 are 2.7 dB/ ${-}$12 dBm for the low bands (850/900 MHz) and 3 dB/${-}$ 11 dBm for the high bands (1800/1900 MHz). This transceiver is implemented in 0.13 $mu$m CMOS technology and occupies 10.5 mm$^{2}$ . The device consumes 118 mA and 84 mA in TX and RX modes from 2.8 V, respectively and is housed in a 5$,times,$ 5 mm$^{2}$ 40-pin QFN package.      

Impacts of $hbox{N}_{2}$ and $hbox{NH}_{3}$ Plasma Surface Treatments on High-Performance LTPS-TFT With High-$kappa$ Gate Dielectric

Low-temperature polycrystalline-silicon thin-film transistors (LTPS-TFTs) with high- $kappa$ gate dielectrics and plasma surface treatments are demonstrated for the first time. Significant field-effect mobility $mu_{rm FE}$ improvements of $sim$86.0% and 112.5% are observed for LTPS-TFTs with $hbox{HfO}_{2}$ gate dielectric after $hbox{N}_{2}$ and $ hbox{NH}_{3}$ plasma surface treatments, respectively. In addition, the $hbox{N}_{2}$ and $ hbox{NH}_{3}$ plasma surface treatments can also reduce surface roughness scattering to enhance the field-effect mobility $mu_{rm FE}$ at high gate bias voltage $V_{G}$, resulting in 217.0% and 219.6% improvements in driving current, respectively. As a result, high-performance LTPS-TFT with low threshold voltage $V_{rm TH} sim hbox{0.33} hbox{V}$, excellent subthreshold swing S.S. $sim$0.156 V/decade, and high field-effect mobility $mu_{rm FE} sim hbox{62.02} hbox{cm}^{2}/hbox{V} cdot hbox{s}$ would be suitable for the application of system-on-panel.      

First Insight Into the Lifetime Acceleration Model of High-$k$ $hbox{ZrO}_{2}/hbox{SiO}_{2}/hbox{ZrO}_{2}$ Stacks for Advanced DRAM Technology Nodes

Long-term reliability results over six orders of magnitude in time are presented showing that the voltage acceleration model for $hbox{ZrO}_{2}/hbox{SiO}_{2}/hbox{ZrO}_{2}$ exhibits an exponential dependence with voltage, down to 2 V. The voltage acceleration parameter $gamma$ is between 10 and 15 $hbox{V}^{-1}$, depending on the biasing polarity. Soft-breakdown behavior (SILC) is evident prior to the onset of hard breakdown as a result of barrier lowering or charge accumulation in the high- $k$ film. Under ac stress conditions, this SILC branch is lowered in magnitude, translating to a gain in lifetime to breakdown.      

Fabrication of a Blue $Mtimes N$ Pixel Organic Light-Emitting Diode Video Display Incorporating a Thermally Stable Emitter

A 7$times$ 11 pixel blue OLED display was fabricated using a patterned indium–tin–oxide (ITO) substrate. The fabrication process for an $M times N$ pixel organic light-emitting diode (OLED) video display including an electrical insulating layer and a physical pixel separator layer is presented. An efficient and thermally stable blue fluorescent organic material, ${hbox{6}},{hbox{6}}^{prime}$ -bis((2-$p$ -biphenyl)-4-phenylquinoline) (B2PPQ), was used in combination with an evaporated hole-transport small molecule with a high ionization potential.      

Low-Voltage Organic Field-Effect Transistor With PMMA/$ hbox{ZrO}_{2}$ Bilayer Dielectric

This paper reports on the application of a bilayer polymethylmethacrylate (PMMA)/ $hbox{ZrO}_{2}$ dielectric in copper phthalocyanine (CuPc) organic field-effect transistors (OFETs). By depositing a PMMA layer on $hbox{ZrO}_{2}$, the leakage of the dielectric is reduced by one order of magnitude compared to single-layer $hbox{ZrO}_{2}$. A high-quality interface is obtained between the organic semiconductor and the combined insulators. By integrating the advantages of polymer and high- $k$ dielectrics, the device achieves both high mobility and low threshold voltage. The typical field-effect mobility, threshold voltage, on/off current ratio, and subthreshold slope of OFETs with bilayer dielectric are $hbox{5.6}timeshbox{10}^{-2} hbox{cm}^{2}/hbox{V} cdot hbox{s}$, 0.8 V, $hbox{1.2} times hbox{10}^{3}$, and 2.1 V/dec, respectively. By using the bilayer dielectrics, the hysteresis observed in the devices with single-layer $hbox{ZrO}_{2}$ is no longer present.      

A Programmable 25-MHz to 6-GHz $K/L$ Frequency Multiplier With Digital $K_{rm vco}$ Compensation

A programmable rational-$K/L$ frequency multiplier that can synthesize any frequency between 25 MHz and 6 GHz from an input clock ranging from 1 to 5.5 GHz is presented. The architecture employs a fractional-$N$ input clock divider followed by a fractional- $N$ PLL. In contrast to conventional architectures, this allows large $K$ and $L$ , whose maximum values are limited only by the word-length of digital $SigmaDelta$ modulators. Additionally, to alleviate large $K_{rm vco}$ variation and fractional spurs, which are inevitable in wide tuning range VCOs and fractional-$N$ synthesizers, new compensation techniques are implemented without involving additional circuitry. This is an ideal solution to support a programmable serializer/deserializer on a field-programmable gate array.      

A Dual-Band Self-Oscillating Mixer for -Band and -Band Applications

A self-oscillating mixer that employs both the fundamental and harmonic signals generated by the oscillator subcircuit in the mixing process is experimentally demonstrated. The resulting circuit is a dual-band down-converting mixer that can operate in $C$ -band from 5.0 to 6.0 GHz, or in $X$-band from 9.8 to 11.8 GHz. The oscillator uses active superharmonic coupling to enforce the quadrature relationship of the fundamental outputs. Either the fundamental outputs of the oscillator or the second harmonic oscillator output signals that exists at the common-mode nodes are connected to the mixer via a set of complementary switches. The mixer achieves a conversion gain between 5–12 dB in both frequency bands. The output 1-dB compression points for both modes of the mixer are approximately $-{hbox{5 dBm}}$ and the output third-order intercept point for $C$ -band and $X$ -band operation are 12 and 13 dBm, respectively. The integrated circuit was fabricated in 0.13-$mu {hbox{m}}$ CMOS technology and measures ${hbox{0.525 mm}}^{2}$ including bonding pads.