油润滑下MoSi2材料的摩擦磨损性能

运用M-200型摩擦磨损试验机测定了油润滑条件下MoSi2与45调质钢、45淬火钢和CrWMn钢配对时的摩擦磨损性能，采用扫描电镜和微探针分析了摩擦副表面的形貌，探讨了磨损机理：结果表明：采用20号机械油润滑可有效地降低MoSi2材料的磨损率及摩擦因数；与低硬度的45调质钢和45淬火钢对摩时，MoSi2材料的主要磨损机制为晶间断裂、疲劳断裂、轻微粘着磨损和磨粒磨损；MoSi2材料与高硬度的CrWMn钢对摩时，主要磨损机制表现为粘着磨损、微犁削式磨粒磨损，并在偶件表面材料凸点的前端形成楔块。     

Effect of Graphite on Friction and Wear Characteristics of Molybdenum Dithiocarbamate

The effects of graphite powder on the friction and wear characteristics of molybdenum dithiocarbamate MoDTC were studied in reciprocated sliding contact using a ball-on-plate type tester. The oil used was squalane, a pure hydrocarbon. The addition of MoDTC alone to the oil showed a high coefficient of friction at an early stage of a rubbing test, since the extent of the formation of a surface film containing MoS₂ was insufficient to decrease the coefficient of friction. The high friction at the early stage brought about noticeable wear. On the other hand, the addition of graphite powder together with succinimide-type dispersant to the oil containing MoDTC considerably improved the friction and wear performance not only at the early stage but also at the steady stage. The added graphite powder seems to cover the part of rubbing surfaces without a film containing MoS₂ to reduce the friction and wear, not only at the steady stage after the running-in process, but also in the running-in process or at the early stage.     

A Study of Wear Chemistry and Contact Temperature Using a Microsample Four-Ball Wear Test

This study demonstrates that insight into the tribological reactions taking place in mixed and boundary lubrication can be provided by combining microsample four-ball wear tests with chemical analysis using gel permeation chromatography (GPC) as the principal analytical tool. At the end of the microsample four-ball wear test the lubricant turns into a grease-like mixture preventing the liquid lubricant from recirculating into the wear track and thus causing failure. Analyses of the various lubricant samples after their failure in the microsample test all show a relatively small amount of insoluble deposits and a large quantity of unreacted fresh lubricant. Virtually no intermediate reaction products were found. Combining this information with lubricant stability and the fact that a large quantity of lubricant flowed through the sliding junction while only a small portion was oxidized suggests that two very different thermal environments exist in the concentrated contact. The insoluble deposits are typical of thermal oxidative reactions that require temperatures of400°C or above. The unreacted lubricant found at failure indicates that this portion of the lubricant sample was maintained at temperatures of 150°C or below. The formation of grease-like mixture with as little as four percent reacted material indicates the remaining liquid lubricant and its insoluble reaction deposits were well mixed throughout the test. These findings suggest that the hot zones causing severe lubricant degradation are in the immediate vicinity of the asperity-asperity contacts while the low temperature zone - the valleys between asperities which are in the majority - are much cooler.     

硅油润滑对莫来石基陶瓷摩擦磨损性能的影响研究

莫来石基陶瓷具有一系列优异的性能,其在摩擦学领域中的应用越来越广泛。本文研究了硅油润滑对该类陶瓷摩擦磨损性能的影响规律。研究结果表明,硅油可明显地降低莫来石基陶瓷的摩擦系数和磨损率,但却使摩擦系数在稳定阶段的波动幅度增加。硅油润滑条件下,莫来石基陶瓷的磨损机理主要是微观断裂和磨料磨损。     

固体润滑剂对碳纤维增强尼龙复合材料摩擦学性能的影响

分别制备了PTFE／碳纤维、MoS2／碳纤维混杂增强的尼龙66复合材料,用MM-2000型摩擦磨损试验机评价其摩擦磨损性能,用SEM和XPS分析了磨损表面。结果表明：PTFE／碳纤维混杂增强可以明显改善尼龙复合材料摩擦学性能;MoS2／碳纤维混杂增强没有改善复合材料的摩擦学性能;MoS2在摩擦过程中氧化生成的MoO3充当了摩擦副之间的磨粒,其磨损机理推测为粘着和磨粒磨损的综合作用。     

磨屑对润滑油摩擦性能的影响

通过实验和模拟研究磨粒对润滑油摩擦性能的影响。首先通过微纳米压/划痕试验测量含磨屑润滑油的摩擦因数。同时,建立边界润滑体系模型,采用分子动力学方法模拟含磨屑润滑油膜在不同载荷下沿膜厚方向的压缩率和密度分布;对体系的上下固体壁面施加方向相反的剪切速度,计算出壁面原子的应力、摩擦力、正压力和摩擦因数;分析不同粒径磨屑的动态行为特征;通过减少润滑油分子数量,探究乏油工况下含磨屑润滑体系的摩擦性能。结果表明,润滑体系摩擦因数的模拟值与试验值一致;磨屑的存在会降低油膜的压缩率,同时在高载下磨屑的存在会对油膜的分层产生破坏,影响磨屑附近的密度分布;含小粒径磨屑的润滑体系的摩擦因数比含大粒径磨屑的润滑体系的小,表明磨粒聚集长大现象会恶化润滑油的润滑性能;磨屑在剪切过程中同时存在滚动和滑动,含小粒径磨屑的润滑体系剪切过程中表现出波动幅度更大的角速度;随着载荷的增大,磨屑角速度减小,波动幅度降低;在乏油工况下,磨屑会在剪切过程中出现变形破碎现象。     

润滑剂对轮轨摩擦与磨损的影响

利用MMS-2A磨损试验机模拟轮轨系统在润滑油、二硫化钼锂基脂、植物油和石墨钙基脂4种润滑剂润滑下的摩擦与磨损行为,研究润滑剂对轮轨副摩擦、磨损特性的影响.结果表明:与干态相比,4种润滑剂均使摩擦副的摩擦因数减小,表面磨痕深度减小,磨损量降低,其中石墨钙基脂的减摩和抗磨效果最好;试验结束后,轮轨试样接触表面的硬度均有不同程度的增加,其中涂有石墨钙基脂的轮轨试样的表面硬度增加最小.     

用SRV试验机评价柴油机油摩擦磨损性能

采用SRV^?4型摩擦磨损试验机为试验平台,以某商用车公司提供的发动机缸套-活塞环截取件作为摩擦副试验件,以15W-40 CF-4和15W-40 CI-4发动机油为润滑介质,建立评价柴油机油摩擦磨损性能的模拟试验方法,并使用该方法对油品配方中减摩剂的区分性及不同材质活塞环与润滑油的适配性等进行考察。试验结果表明:建立的模拟试验方法能较好地区分出具有优异抗磨性能的柴油机油,同样对油品配方中减摩剂和不同材质活塞环与润滑油适配性等有着较好的区分性,可以作为润滑油品开发者和OEM汽车厂家对油品配方开发和摩擦副材质筛选的模拟评价手段。     

The Effect of Different Temperatures on Friction and Wear Properties of CFRPEEK against AISI 431 Steel under Water Lubrication

The tribological behavior of 30 vol% carbon fiber–reinforced polyetheretherketone (CFRPEEK) against AISI 431 steel under different temperatures of water lubrication was investigated. Friction and wear tests were carried out on a disc-on-disc contact test apparatus under different operating conditions. The results reveal that the lubricant temperature has a significant effect on the friction and wear properties of CFRPEEK sliding against AISI 431 steel. The average friction coefficient and wear rate of CFRPEEK increase with increasing lubricant temperature. However, the wear rate of AISI 431 steel did not have a positive correlation with the wear rate of CFRPEEK under different temperatures of water lubrication. Moreover, the original and worn surfaces of CFRPEEK and AISI 431 steel were imaged by environmental scanning electron microscopy and optical microscopy, respectively. The main tribological mechanisms of CFRPEEK sliding against AISI 431 steel were adhesive wear, and increasing the temperature of the lubricant could accelerate wear.     

基体材料对铜合金镶嵌轴承摩擦磨损性能的影响

在端面摩擦磨损试验机上对锡青铜、铝青铜、铝黄铜镶嵌轴承试样进行了常温下干摩擦对比实验,探讨了不同铜合金基体对镶嵌轴承摩擦磨损性能的影响。结果表明,锡青铜镶嵌轴承在各种实验条件下均表现出了优良的摩擦磨损性能,适合于用作轴承材料。铝黄铜和铝青铜镶嵌轴承的摩擦磨损性能较差,尤其是在载荷较大时性能更差。     

载流下MoS2/Ag纳米复合薄膜摩擦学性能

MoS₂基纳米复合薄膜具有良好的摩擦学性能,但较差的导电性能限制了其在载流条件下作为润滑材料的应用。为提高MoS₂基纳米复合薄膜的导电性能,采用非平衡磁控溅射系统沉积2种不同Ag含量的MoS₂/Ag纳米复合薄膜,并在不同的电流条件下研究MoS₂/Ag纳米复合薄膜与GCr15钢球对摩时的摩擦学性能。结果表明：在载流下2种MoS₂/Ag纳米复合薄膜表现出相似的摩擦性能,而低掺杂MoS₂/Ag薄膜具有更佳的耐磨性能,这归因于低掺杂MoS₂/Ag薄膜具有较好的力学性能;无载流时,MoS₂/Ag纳米复合薄膜在摩擦过程中生成的氧化物颗粒增加了磨损、降低了润滑性,磨损机制主要为磨粒磨损;电流小于0.5 A时,电流促进了转移膜形成,使得摩擦因数降低,但磨损率增加,磨损机制主要为黏着磨损;当电流大于0.5 A时,由于电弧烧蚀加速了薄膜的磨损,磨损机制主要为磨粒磨损、黏着磨损和电弧腐蚀磨损。     

机油添加剂对在用车辆发动机减磨效果的研究

本文根据市场上对机油添加剂的使用介绍，有目的地筛选几种添加剂对在用车辆发动机进行减磨效果试验，通过试验，所选润滑油添加剂能起到减磨作用，延长发动机使用寿命。在此基础上，提出了进一步研究的方向。     

Friction and Wear Properties of IF–MoS2 as Additive in Paraffin Oil

Inorganic fullerene-like (IF) MoS₂ nanoparticles with diameters ranging from 70 to 120 nm were synthesized by desulphurizing the MoS₃ precursor and characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Tribological properties of the IF–MoS₂, as lubricating oil additive, were evaluated using a MMW-1 four-ball tribotester. The wear scar was examined with an optical microscope and scanning electron microscopy (SEM). The wear resistance of the paraffin oil was improved and the friction coefficient of the oil was decreased by addition of the IF–MoS₂ nanoparticles. The mechanism of friction and wear of the IF–MoS₂ nanoparticles was discussed.     

碳黑对MoS2纳米润滑油的摩擦磨损性能影响

以PAO6润滑油为基础油,MoS2为纳米添加剂,制备质量分数为0.02％的纳米润滑油.通过自主研制的缸套-活塞环摩擦实验台,对添加不同浓度碳黑颗粒的MoS2纳米添纳米润滑油的摩擦学性能进行研究;通过电子扫描显微镜(SEM)对缸套表面磨痕进行观察.结果表明,低浓度的碳黑(0.01wt％和0.1wt％)可以进一步改善纳米润...     

半金属基粉末摩擦片摩擦磨损性能研究

在不同工况下研究半金属基粉末摩擦片与淬火45#钢配副时,载荷和转速对其摩擦磨损性能的影响,并分析其磨损机制。结果表明,在油润滑和水润滑下,半金属基摩擦片高速下的磨损量要明显低于低速下的磨损量,而干摩擦下其高载高速下的磨损要高于高载低速时的磨损量。油润滑下随载荷的增大,半金属基摩擦片的摩擦因数逐渐升高;水润滑下随载荷的增大,高速时摩擦因数先增大后减小,低速时则逐渐降低;干摩擦下随载荷的增大,高速时摩擦因数呈现出先升高后降低再升高的趋势,低速时则先升高后降低。干摩擦时摩擦面十分粗糙,有比较明显的沟状磨痕和硬质颗粒脱落后残留的凹坑;而水润滑和油润滑时摩擦面较为光滑。     

基础油的性能检测及其在工业润滑油液中的应用技术

介绍浓硫酸显色法、加热法、烘干法、放置法、理化测试法、仪器分析法等6种基础油不同性能的常规测试法,并对基础油的应用技术进行讨论;指出在润滑油调配时尽量选用黏度中心值或范围接近的基础油,优先选用性能贡献率较大的基础油,新基础油和新型添加剂的合理配伍将是今后润滑油液调配的关键技术。     

全陶瓷球轴承油润滑特性及其对服役性能影响规律

相比于金属球轴承,全陶瓷球轴承在极端工况下的服役性能更加突出。为了揭示全陶瓷球轴承油润滑特性,提高全陶瓷球轴承的运转性能与使用寿命,以6208CE氮化硅全陶瓷深沟球轴承为例,对其在油润滑工况下所表现出的摩擦、振动、温升等特性进行试验研究,探讨供油量对全陶瓷球轴承润滑状态的影响,并对试验后的全陶瓷球轴承接触微区表层进行解析。研究发现：全陶瓷球轴承油润滑服役过程中,在某个特定工况下存在一个最佳供油量,使得轴承可实现全膜润滑,从而表现出最好的摩擦、振动、温升等特性;小于最佳供油量时,为乏油状态,轴承接触微区存在油-固混合润滑状态;大于最佳供油量时,过多润滑油液会产生的黏滞阻力;相比于载荷,轴承的转速对最佳供油量的取值具有决定性影响。研究成果对于揭示全陶瓷球轴承油润滑特性,丰富其润滑理论与方法具有一定指导意义。     

利用PDSC考察环境友好润滑油基础油氧化安定性的研究

结合环境友好润滑油产品的开发工作,用加压差热扫描示量法(PDSC)研究了菜籽油、双酯、多元醇酯等几种基础油的氧化稳定性,并与旋转氧弹的结果进行了比较;对菜籽油在不同温度下的氧化反应特性进行了考察,并采用阿仑尼乌斯公式计算了菜籽油氧化反应的活化能,初步研究了其氧化反应机制。试验结果表明,PDSC可用于评价基础油的氧化安定性,合成酯的氧化安定性明显优于菜籽油,且多元醇酯的氧化安定性最好。     

润滑油中磨粒的X-荧光能谱测试方法研究与应用

采用7种不同磨粒含量标准油样,通过选择合理的特征元素、测试参数和元素测试组合方案,按照0~1×10-4、1×10-4~5×10-4两种磨粒质量分数范围,分段建立包含标准曲线、分析流程的润滑油中磨粒的EDXRF光谱测试方法。应用建立的测试方法,对某柴油机润滑油进行跟踪监测,验证该方法的跟踪监测能力;以26个同型设备油样为对象,对该方法与原子发射光谱、PQ铁磁性颗粒分析仪分析结果进行比较。结果表明,建立的润滑油EDXRF光谱测试方法能够有效地监测润滑油中的磨损颗粒,特别是针对大的磨损颗粒有着特殊的优势。     

硫磷化改性菜子油润滑剂的制备及其摩擦学性能

以菜子油为原料，甲醇为酯交换剂，并以S粉和P2O5作为改性剂，合成了一种带有极压元素硫和磷的多羟基脂肪酸(酯)极压润滑剂，在制备成2%(质量分数)左右的乳化液后，经摩擦学性能考察，结果表明：该润滑液的最大无咬卡载荷(PB)为1260N，表面磨斑直径(WSD)和摩擦因数(μ)的最佳值分别为0．33mm和0.039，达到并超过了资料报导的目前以油为润滑介质的国内同类产品的性能指标。