钻井液用植物油润滑剂的制备及摩擦学性能研究

为了使钻井液用植物油润滑剂在高压和高温氧化后仍具有良好的抗磨减摩性能,将层状固体润滑剂石墨、蛇纹石加入植物油中,合成了几种含固体润滑剂的钻井液用植物油润滑剂;利用UMT-2球盘式摩擦试验机考察了各润滑剂的摩擦性能;在摇臂钻床上模拟钻探的摩擦工况,考察了合成的润滑剂的抗磨性能,利用扫描电子显微镜观察了钻头的磨损形貌。结果表明,在植物油中添加石墨、蛇纹石可以降低植物油的摩擦因数和摩擦副的磨损,同时可使植物油在高温氧化后仍能保持良好的减摩抗磨性能。     

干滑动条件下45CrNi材料摩擦磨损规律研究

以某自行火炮底座传动箱摩擦副所用材料45CrNi为研究对象,考察了该材料在不同热处理状态下（530℃回火、380℃回火、830℃淬火及原始状态）组成摩擦副时的干滑动摩擦磨损特性。试验结果表明：530℃回火盘和摩始销组成摩擦配副时结合最好,具有较好的摩擦磨损性能,销试样磨损率最小;在较低速度下载荷是影响材料摩擦因数的主要因素,而速度对摩擦因数的影响较小;粘着磨损是材料配副磨损的主要形式。     

润滑剂对轮轨摩擦与磨损的影响

利用MMS-2A磨损试验机模拟轮轨系统在润滑油、二硫化钼锂基脂、植物油和石墨钙基脂4种润滑剂润滑下的摩擦与磨损行为,研究润滑剂对轮轨副摩擦、磨损特性的影响.结果表明:与干态相比,4种润滑剂均使摩擦副的摩擦因数减小,表面磨痕深度减小,磨损量降低,其中石墨钙基脂的减摩和抗磨效果最好;试验结束后,轮轨试样接触表面的硬度均有不同程度的增加,其中涂有石墨钙基脂的轮轨试样的表面硬度增加最小.     

有机钼复合润滑剂在高温微动和滑动条件下的摩擦磨损行为

以矿物基650SN油作为基础油,采用复配技术制备了有机钼复合润滑剂。利用SRV微动磨损试验机和T-11滑动磨损试验机考察了该复合剂的高温摩擦学行为,采用扫描电子显微镜和X射线光电子能谱仪对其润滑下的磨痕表面形貌和表面膜的元素组成进行了分析,探讨了复合剂的减摩润滑机制。结果表明:有机钼复合剂具有良好的高温微动和滑动摩擦学行为,与基础油相比,复合剂能够使钢-钢摩擦副在高温微动和滑动过程中的摩擦因数降低28%和43%,抵抗微动和滑动磨损的能力分别提高53%和54%。这是由于有机钼复合剂通过分解、吸附和摩擦化学反应,在摩擦副金属表面形成了含磷酸盐的沉积膜和含FeS、MoS2的化学反应膜共同组成的复合边界润滑膜,从而表现出优良的减摩润滑效果。     

材料干滑动摩擦磨损性能的研究进展

介绍高温、高速、载流、气氛、磁场等苛刻条件下材料的干滑动摩擦磨损特性的研究方法和研究结果。得到以下几点结论:材料的干摩擦磨损特性与速度、载荷之间存在着对应关系,当pv值超过临界值后,材料的摩擦因数和磨损率发生突变;摩擦面温度的升高会降低材料的干摩擦磨损性能;环境气氛的改变不影响金属摩擦副pv特性的基本规律,但显著影响其摩擦因数和磨损率数值的大小;电流的存在恶化材料的干摩擦性能;施加磁场可显著改善材料的摩擦磨损性能,并且磁场强度是影响材料干摩擦特性的主要因素。     

润滑油对蜗杆传动效率影响的研究

合理的选用润滑剂以提高蜗杆传动的效率，减少磨损发热已成为研究蜗杆传动热点的问题之一。本文主要介绍了在标准试验机和蜗杆试验台上所进行的一系列筛选试验研究及其主要成果，从而为合理地选用润滑剂（油）提供了科学的依据。     

蒙脱石和坡缕石纳米润滑油添加剂的摩擦学性能

将KH550偶联剂修饰的纳米蒙脱石和纳米坡缕石,分别按质量比3%添加到150N基础油中制备2种纳米润滑油分散体系,用激光粒度分析仪、TEM、IR表征纳米添加剂的分散稳定性,在MMU-10G摩擦磨损试验机上测试2种纳米润滑油对45#钢的减摩抗磨性能,用SEM和EDX等分析摩擦试样表面成分与形貌的变化及影响摩擦学性能的机制。结果表明:纳米蒙脱石平均粒径较小,在150N基础油中分散更稳定;2种纳米润滑油相比纯基础油润滑时的平均摩擦因数和磨损量均明显下降,其中纳米蒙脱石润滑油的抗磨减摩性能最好;2种纳米润滑油润滑时摩擦试样表面分别生成了含蒙脱石和坡缕石特征元素的自修复膜层,其中蒙脱石特征元素含量相对较高,说明纳米蒙脱石摩擦学性能更好。     

纳米铜润滑添加剂在四球机上的摩擦学性能研究及机理探讨

用MRS-10J四球摩擦磨损试验机考察了N68基础油和添加了自修复纳米铜润滑添加剂NT1的N68NT1的摩擦学性能,用扫描电子显微镜（SEM）、x射线能量色谱仪（EDS）分析了钢球表面的磨斑形貌和组成,同时初步分析了纳米铜润滑添加剂的润滑机理.结果表明：自修复纳米铜润滑油添加剂NT1能显著改善N68基础油的摩擦学性能;在载荷为296 N、392 N、490 N,试验时间为30 min的试验条件下,摩擦副的摩擦因数同基础油的相比分别下降了33.8%、39.4%和55.5%;钢球的磨斑直径分别下降了46.5%、45.6%和32.5%;同N68相比,N68NT1的pB值提高了33.3%;这可能同摩擦过程中钢球表面上沉积膜的协同作用有关.     

不同环境气氛对高速干滑动钢/铜摩擦副磨损机制的影响

利用MMS-1G型高温高速销-盘摩擦磨损试验机,以钢/铜摩擦副为研究对象,研究了不同环境气氛对高速干滑动钢/铜摩擦副磨损机制的影响,应用扫描电子显微镜(SEM)、能谱分析仪(EDS)对销试样磨损表面进行分析。结果表明:随着pv值的增加,氧气条件下的磨损机制由粘着磨损转变为氧化磨损;氮气条件下的磨损机制由粘着磨损转变为金属流变和磨粒磨损。氮气气氛条件下的摩擦因数和磨损率均高于氧气气氛条件下的摩擦因数和磨损率。     

磷化-皂化处理27SiMn钢的摩擦磨损性能研究

冷拔法生产液压缸筒前,需对毛坯管进行磷化、皂化等预处理,以在冷拔表面形成一层塑性良好且具有极压性能的磷酸盐膜和皂化膜。对冷拔法生产液压缸筒常用的材料27SiMn钢进行磷化、皂化处理,在CETR UMT-2型试验机上考察了27SiMn钢磷化-皂化处理表面的摩擦学性能,采用扫描电镜观察分析了磨损表面形貌,探讨了磨损机制。结果表明:27SiMn钢经磷化-皂化处理后,与YT5硬质合金对摩时摩擦因数明显降低,此时摩擦因数受润滑介质的影响不明显;干摩擦状态下磷化-皂化处理前、后27SiMn钢的摩擦因数均随滑动速度的增加而增加,油润滑状态下则相反。     

Effects of Loadings on Friction and Wear Behaviors of Cathodic Arc Ion Plating AlTiN Coating at High Temperature

A layer of AlTiN coating was deposited on YT14 cutting tool by cathodic arc ion plating (CAIP) and the coefficients of friction (COFs) of the AlTiN coating under different loads at a temperature of 800°C were investigated with a high-temperature wear tester. The wear morphologies, chemical elements, and phases of the coating after wear were analyzed with scanning electron microscopy (SEM), energy-dispersive spectrometry (EDS), and X-ray diffraction (XRD), respectively, and the contours of wear tracks were investigated with a comprehensive measurement tester for material surface performance. The effects of loads on COFs and wear resistance of the AlTiN coating were analyzed, and the wear mechanism of the AlTiN coating at high temperature is discussed. The results show that the mixed oxides of Al₂O₃ and TiO₂ are produced under high temperature to improve the lubrication performance and wear resistance of the AlTiN coating. The average COFs of the coating under loads of 5, 7, and 9 N are 0.6495, 0.5897, and 0.3898, respectively. The COFs of the coating decrease with increasing load; as a result, the AlTiN coating is suitable for heavy loads at high temperature. The friction and wear mechanisms of the AlTiN coating are primarily composed of oxidation wear and abrasive wear, accompanied by fatigue wear and adhesive wear.     

磁性液体摩擦学性能研究

在溶液中原位合成了含磁性纳米微粒的磁性液体,利用MRH-3高速环块摩擦试验机考察了液体石蜡基磁性液体的摩擦学性能.结果表明:制备的磁性液体颗粒大小均匀, 粒径分布窄,在液体石蜡中具有良好的分散稳定性;磁性液体的减摩和抗磨能力随着其密度的增加而增加;在相同试验条件下,磁性液体比液体石蜡具有更好的减摩和抗磨性能,并具有更高的承载能力.     

Tribological Performance and Wear Mechanism of Compound Containing S,P, and B as EP/AW Additives in Copper Foil Oil

Research and development on the high biodegradability of additives is indispensable for environmentally friendly lubricants, which is one of the key factors to advance lubricant technology toward “greener” chemistry. The tribological performance of fatty alcohol polyoxyethylene phosphate acid ester (EK), boron-containing amide (BT), dialkyl dithiophosphate ester (DDE), and a mixture of these (compound) as extreme pressure (EP)/antiwear (AW) additives in hydrogenated base oil (GH) were investigated using a four-ball testing machine. The elemental composition and chemical characteristics of the AW films generated on the surfaces of the steel balls were studied using X-ray photoelectron spectroscopy (XPS), and their AW mechanisms are hereby proposed. Thermal degradation tests were conducted to identify their thermal stabilities using thermogravimetry and differential scanning calorimetry. The results show that these additives can greatly improve the EP/AW properties of GH. XPS analyses of the worn surfaces indicate that decomposed borate esters and organic sulfide or nitrides were adsorbed on the worn surface, and the P and S elements of the compound reacted with the metal and existed in the form of phosphates and sulfates, both of which contributed to the formation of a boundary lubricating film. Moreover, these additives provide the lubricants with excellent oxidation resistance and thermal stability.     

Tribological Features of Refined,Deodorized, and Bleached Palm Olein with Mineral Oil Blend

Vegetable oils have been investigated to replace petroleum-based lubricants due to their environmentally friendly characteristics, and these oils have become an important source of biolubricants. For the purpose of ensuring the ability of vegetable oils as a neat or partial biolubricants, image processing techniques were employed to explore the tribological characteristics of vegetable oil with a mineral oil blend. Refined, bleached, and deodorized palm olein blended with mineral oils was investigated using a four-ball tribotester and design of experiments with volumetric blend ratios of 20 to 80%. An optimized value E53.11/RB46.89 was obtained from the investigation, in compliance with ASTM D4172 standard. From the results, the E53.11/RB46.89 blend reduces the friction coefficient and wear scar diameter as well as the material lost in comparison with neat mineral oil. It is concluded that the E53.11/RB46.89 blend could be a potential partial biolubricant due to its negligible negative impact on wear and it provides satisfactory performance as a lubricant.     

Tribological properties of carbon-nanotube-reinforced copper composites

Tribological properties of carbon-nanotube-reinforced copper composites were investigated using a pin-on-disk test rig under dry conditions. The composites containing 4–16 vol% carbon nanotubes (CNTs) were fabricated by a powder-metallurgy technique. The tests were carried out at normal loads between 10 and 50 N, and the effect of volume fraction of CNTs on tribological behavior of the composites was examined. The composites revealed a low coefficient of friction compared with the copper matrix alloy. Due to the effects of the reinforcement and reduced friction, the wear rate of the composites decreased with increasing volume fraction of CNTs at low and intermediate loads. The composites with a high volume fraction of CNTs exhibited high porosity and their wear resistance decreased under high-load conditions.     

双层滑片压缩机滑片摩擦及磨损分析

介绍了作者研制的双层滑片压缩机，这种压缩机的每个滑片槽内都安放两块重叠而又可以相对自由滑动的滑片。利用建立的动力学模型时双层滑片压缩机的运动，受力，摩擦，磨损及强度等进行了全面分析，结果表明双层滑片结构能够减少正约束力的幅值，降低摩擦损和磨损量，在改善端部密封的同时又减轻了滑片摩擦和磨损，使机器的工作寿命及机械效率得到提高。     

滚动与滑动耦合作用下GCr15钢的磨损行为研究

选用GCr15钢在M2000磨损试验机上进行了干摩擦和油润滑的摩擦磨损试验，用表面粗糙度仪测量试件在不同磨损阶段的表面形貌，用称重法测量其磨损量，分析了滚动与滑动耦合作用下GCr15钢的磨损机理。研究表明，在滚动与滑动耦合作用下GCr15钢的磨损以滑动摩擦磨损为主，温度和润滑条件直接决定着GCr15钢的磨损情况。     

TiAlN涂层往复滑动的摩擦学性能研究

为研究硬质合金表面沉积的TiA lN涂层的摩擦学行为,在不同介质(干态、乳化液、冷却油)条件和试验参数(法向载荷和位移幅值)下,进行了往复滑动摩擦磨损试验。在动力学分析基础上,结合光学显微镜(OM)、激光共焦扫描显微镜(LCSM)、扫描电子显微镜(SEM)和电子能谱(EDS)等微观分析手段对摩擦学性能进行了研究。结果显示:在同样条件下,涂层在试验初期的摩擦因数较小;法向载荷增大,涂层的摩擦因数降低,而位移幅值对涂层摩擦因数的影响不明显;基体的磨损机制主要为磨粒磨损,而涂层剥落是剥层和氧化磨损共同作用的结果;在润滑条件下,涂层的摩擦学性能得到了很大的改善,使涂层寿命得到显著延长,其中冷却油的效果最明显。     

润滑油粘度对缸套/活塞环摩擦学性能的影响

在内燃机实际运行中,润滑油的粘度直接影响到润滑油膜的状态,因而活塞环在缸套中不同位置时的摩擦、润滑状态各不相同。文中以缸套活塞环为研究对象,建立了润滑计算模型,并运用该模型对缸内压力、温度、油膜厚度和摩擦系数进行了分析。结果表明,润滑油膜厚度和摩擦系数随转速改变而发生变化,而剪切稀化导致润滑油粘度减小是引起该变化的主要原因。最后,通过对计算结果的分析,提出了适用于缸套活塞环的润滑油粘度指标。     

PCrMo钢的摩擦磨损特性实验研究

采用自制的销盘式摩擦磨损试验机、光学及扫描电子显微镜，研究了PCrMo钢配副的干滑动摩擦磨损特性。结果表明：摩擦因数随着载荷的增加而增加，随着滑动速度的增加而减小；磨损率随着载荷的增加而增加，随着滑动速度的增加先增加而后降低。PCrMo磨损失效机理主要表现为疲劳剥落和粘着磨损。