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L. C. Brown 《Metallurgical and Materials Transactions A》1984,15(3):449-458
A theoretical study has been made of the shape change of precipitates dissolving under volume diffusion control. It is shown
that square and similarly shaped precipitates become circular during dissolution at a rate controlled by the saturation conditions.
Shape change is little affected by diffusion fields from adjacent precipitates. Experimental measurements were made of dissolution
of the θ phase in aluminum-copper alloys. These had shapes that could be approximated to distorted spheres. It was found that
the precipitates dissolved at a rate controlled by volume diffusion and that the precipitates became spherical by the time
their radius had decreased 50 pct as indicated by the theory. Both surface and bulk precipitates were studied. There was a
much higher density of surface precipitates due to preferential nucleation. However, their dissolution characteristics were
the same as bulk precipitates. 相似文献
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The requirement for light in the anti-HIV-1 activity of hypericin was investigated. The hypericin concentration-dependence and light dosage-dependence of the reaction were measured. Under conditions in which hypericin caused substantial inactivation of HIV-1, there was a strict requirement for visible light. Only when the concentration of hypericin approached the cytotoxic level was there an apparent light-independent antiviral effect. This strict light-requirement for the antiviral effect could explain some of the apparently discrepant results reported by other workers. Furthermore if hypericin is contemplated for use in humans, the importance of light must be considered. 相似文献
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